CN1026078C - Method for making coloured glass wall tile (floor brick) - Google Patents
Method for making coloured glass wall tile (floor brick) Download PDFInfo
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- CN1026078C CN1026078C CN 93110410 CN93110410A CN1026078C CN 1026078 C CN1026078 C CN 1026078C CN 93110410 CN93110410 CN 93110410 CN 93110410 A CN93110410 A CN 93110410A CN 1026078 C CN1026078 C CN 1026078C
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Abstract
The present invention relates to a method for manufacturing colored glass wall tiles, which comprises the five working procedures of glass treatment, color pattern printing, light magnesium oxide foaming molding brick manufacture, binding and edge grinding. A manufactured product is formed by a glass layer, a color pattern layer, an adhesive layer and a light magnesium oxide foaming molding brick layer. The method can use the offset printing technique so as to print photographic images having 95% of high precision on glass to recreate the sight of the nature. The method does not use high temperature sintering, the product has no natural crack performance, the performance of product manufactured by the method is better than that of ceramic wall floor bricks, and the product is a new product for developing high-grade new products from buildings. The method can not destroy land sources and ecological balance, and the present invention can be widely popularized and utilized.
Description
The present invention relates to a kind of manufacture method of coloured glass wall tile (floor brick), its product belongs to the surface decoration material on wall in the building fitting-out work or ground.
At present, widely used ceramic wall and floor bricks in the fitting-out work of building, its method for making is with selected earth, stone and other auxiliary material, stir fine and smooth mud uniformly through a few hours mills, adobe is made in oven dry then, glazing, screen printing pattern again, after the kiln high temperature sintering form.This method is because of a large amount of earth of need, occupies existing farmland and destroys land resource so can cause.In addition, raw-material mixer mill stirs, and the high temperature sintering of adobe all needs to consume a large amount of energy behind oven dry and the silk-screen.The adobe surface of ceramic wall and floor bricks is smooth inadequately again, the regularity error is big, thickness is nonstandard, so can only adopt method printing color dullness, the coarse product of pattern of serigraphy, and glaze can produce shortcomings such as exposure cracking, glaze be easy to wear again when sintering, has influenced the decorate properties and the physical life of ceramic wall and floor bricks greatly.From the viewpoint of development, it can not satisfy the demand of building industry to high gear time finishing development.
Learn that by literature search application number is 89105834.6 and is called in the patent application of " preparation method of ceramic-glass paintings ", has introduced the picture of being made up of pottery, glass and pattern.Preparation method is one or more layers glass of bonding on pottery, glass top or below pattern is arranged, through 760～850 ℃ firing temperature, the contact-making surface of pottery and glass, glass and glass sticked to one and make ceramic-glass paintings.More particularly, be that glass is attached in the pattern contour on the pottery, and fix, paint ceramic glazing dyestuff on glass being coated with again, fire by decorating firing kiln and form with glue.Also can be attached to glass on the ceramic wafer of painting good pattern, fire by decorating firing kiln and form.Also can on biscuit of ceramics, paint picture, after Dayao burns till, be stained with glass again and fire through decorating firing kiln and form with under-glaze pigment.There are two shortcomings in this method, and the first needs decorating firing kiln to fire, thereby consumes a large amount of energy, its two, this picture is the pattern with the hand drawn picture, pattern can not reappear the view that photographic effects is arranged of nature.
The objective of the invention is to overcome above-mentioned shortcoming and provide a kind of, do not take the method for the manufacturing coloured glass wall tile (floor brick) in farmland without high temperature sintering.The present invention also aims to adopt offset printing technology to print out the photography pattern, replace the method for existing screen printing pattern with 95% high-precision printing net-point.The present invention also aims to provide have no exposure cracking phenomenon, pattern can reflect landscape of nature with being really true to life and not easy to wear, surfacing is smooth, regularity good, the coloured glass wall tile (floor brick) that is easy to fit up use again of consistency of thickness.
The objective of the invention is to realize by following measure:
The product of manufacturing of the present invention is made up of for four layers glassy layer, multicolour pattern layer, adhesive phase and magnesia light-weight foam mold pressing brick.Glassy layer is water white plate glass or the safety glass that common float glass process is made, and it is positioned at superficial layer.The multicolour pattern layer is to be imprinted on multicolour pattern above the glass with offset printing technology.Adhesive phase is that the silicone rubber kinds adhesive of cold curing is formed, and it is coated on the multicolour pattern layer.Magnesia light-weight foam mold pressing brick stirs after adding water by magnesia, magnesium chloride, fine sand, cement, expanded perlite, blowing agent, the accelerator of technical grade again, makes through the room temperature mold pressing.This layer is positioned at the bottom of wall floor tile, and it is the carrier of glassy layer, multicolour pattern layer and adhesive phase.Its direct and wall or ground stickup.
Manufacture method of the present invention several steps in the following order carries out:
1. the selection of glass and processing.
Water white plate glass or the safety glass of selecting for use the thick common float glass process of 3-5mm to make, by the specification requirement that product is different glass aniseed is cut, handle with glass cleaner then, so that offset ink is firmly on the printing surface attached to glass.
Glass cleaner mainly is made up of hydrofluoric acid and water, adds scale remover, surfactant, solvent and forms.Wherein, hydrofluoric acid is except that playing degreasing scale removal effect, and also corrodible glass makes its surface slightly coarse.Scale remover can be selected ammonium acid fluoride, acetate, orthophosphoric acid for use, and surfactant can be selected dodecyl sodium sulfate for use, neopelex, and ethylene glycol n-butyl ether, solvent are isopropyl alcohol.Above-mentioned material all adopts chemical reagent, chemical pure grade.
The prescription of glass cleaner is as follows: umber by weight calculates:
(40%) 0.5～10 part in hydrofluoric acid
0.05～0.07 part of dodecyl sodium sulfate
4.0～8.0 parts of ethylene glycol n-butyl ethers
0.5～10 part of acetate (20% the aqueous solution)
0～8 part of isopropyl alcohol
Water to 100 part
Compound method: above-mentioned each material umber is by weight poured in the water successively, added water to capacity at last, stir evenly.
Glass being placed in the cleaning agent, at room temperature flooding 30 minutes, is that method washes then routinely, oven dry or airing.
Glass is selected the thickness optimum of 3-5mm for use, if thickness greater than 5mm, has then increased the weight of wall floor tile, causes decorated thing load overweight; If less than 3mm, Glass breadks easily then, impact resistance is not enough, can not tempering.
2. hectographic printing multicolour pattern layer:
On the glass surface of handling well, with existing offset printing technology printing color patterned layer.
Adopt existing offset printing technology, comprising the positive photography, electronic scanning, plate-making, the process of solarization PS version, with the printing process that circle flattens, the glass face for the treatment of seal carries out direct chromaticity printing.Use UV curable ink; Technological parameter is by the requirement of printing ink specification.The detailed method 88108317.8 hectographic printing methods of can consulting produce the plate glass picture and wooden splint is drawn.The multicolour pattern layer has the thickness of 2～3 μ m.
Automatically detect printing quality with electronic computer, comprise promptly whether red, yellow, blue, black four kinds of colors meet the original text standard of drawing a design, and whether the cross hairs chromatography is accurate.It is stand-by to cut apart the glass that has qualified multicolour pattern layer with cutting machine again.
3. make magnesia light-weight foam mold pressing brick:
Umber by weight calculates:
With 20 parts in the magnesia of technical grade, 10 parts in magnesium chloride, 20 parts of 450# cement, particle diameter is 25 parts of the fine sands of 1.6～2.2mm, unit weight is 150～250 kilograms/cubic metre 20 parts of expanded perlites, a little blowing agent such as aluminium powder, the accelerator mixture that it is made up of alum mud, aluminum oxide clinker and quick lime as (Shanghai Silicate Prods. Works's production) of 771 models, its chemical composition mainly is aluminium oxide, calcium oxide, iron oxide, silica, potassium oxide, sodium oxide molybdena.Above-mentioned substance is mixed successively, is 100 parts with above-mentioned compounding substances, adds water again and stirs for 50 parts, pours in the mould that coats releasing agent, and 0.5 kg/cm of pressurizeing got final product the demoulding after 30 minutes.Normal temperature solidified 24 hours down.Can be made into length and width, thick be 15.2 * 15.2 * 5(mm); 15.2 * 20 * 5(mm), 30.5 * 30.5 * 8(mm), 30.5 * 61 * 8(mm) all sizes.
Above-mentioned releasing agent is: with the Chinese wax of 150～200 grams, heat to 90 ℃ of fusings, pour in the machine oil of 100 grams, stir evenly and get final product.
4. bonding:
With the one side that has been printed on multicolour pattern on glass, evenly coat silicone rubber kinds adhesive such as GPS-4 silicone adhesive (Shanghai Rubber Products Insitute's production), KH-80 silicone rubber adhesive (chemical plant, Gai County, Liaoning Province), one branch of GN-521(morning twilight chemical research institute), it is thick to be coated with about 1mm, after magnesia light-weight foam mold pressing brick aligns mutually, is pressurised into 0.05～0.30 kg/cm, the blank of a coloured glass wall tile (floor brick) is promptly made in cold curing 24 hours.Silicone rubber kinds adhesive ambient temperature curable, easy to use, also have the advantage that elasticity, heat endurance and resistance to weathering can be good.
5. edging:
With the blank of bonding good coloured glass wall tile (floor brick), wear into the inclined-plane of 3mm or 5mm with glass edge-grinding machine, so just made coloured glass wall tile (floor brick).
The present invention compared with prior art has following advantage:
1. manufacturing process of the present invention does not need high temperature sintering, but energy savings.Do not have waste gas again and discharge, pollution-free to atmosphere.
2. the present invention is a primary raw material with glass, without raw materials such as potter's clay, china clay, thereby needn't take the farmland, can not destroy the land resource and the ecological balance.
3. glass can adopt offset printing technology after specially treated, prints off the site of 95% highly dense, reproduce the view of the Nature, have the strong third dimension and the sense of reality, improved the decorative effect of wall floor tile greatly, this be ceramic wall and floor bricks with the way of serigraphy can not compare.
4. the present invention does not adopt high temperature sintering and uses the bonding method of room temperature, thereby the watch crystal layer can not produce plane deformation and exposure cracking phenomenon, thereby has solved the technical barrier of the insurmountable exposure cracking of ceramic wall and floor bricks.
5. multicolour pattern layer of the present invention is positioned at the back of glass, is clipped between glass, adhesive and the foamed moulded brick of magnesia inorganic light weight, so multicolour pattern can directly not worn and not torn.
6. the bottom of coloured glass wall tile (floor brick) is the foamed moulded brick layer of magnesia inorganic light weight, water absorption rate reaches 10～15%, can directly paste securely on the wall with common 450# cement, can't be directly be attached to technical problem on the wall thereby solved glass, greatly reduce the decoration cost of wall on glass with cement.
Product of the present invention is measured light transmittance by the standard GB2680-81 of the countries concerned, press GB8917-lateral bending Qu Qiangdu, survey anti-rapid heat cycle by GB2581-, carry out the anti-freezing property test by GB6955-, " carry out by the method for testing of practical bonding handbook (compile in plum east) with reference to Science and Technology of Shanghai document publishing house for shear strength.
It is as follows that product of the present invention is tested its result through enterprise product quality inspection center, Guangdong Province:
(table is seen the literary composition back)
Accompanying drawing 1 is the structural representation of glass tile for wall and floor.
Accompanying drawing 2 is the process chart of the preparation method of coloured glass wall tile (floor brick).
Now the invention will be further described by reference to the accompanying drawings:
The present invention is made up of the foamed moulded brick layer 4 of glassy layer 1, multicolour pattern layer 2, adhesive phase 3 and magnesia lightweight. Glassy layer 1 is the water white plate glass that common float glass process is made, and it is positioned at superficial layer. Multicolour pattern layer 2 is to be imprinted on multicolour pattern above the glass with offset printing technology. Adhesive phase 3 is silicone rubber kinds adhesives of cold curing, and it is coated on the multicolour pattern layer 2. The foamed moulded brick layer 4 of magnesia lightweight is the fine sand of 1.6～2.2mm, expanded perlite, blowing agent, accelerator, the water that unit weight is 150～250 kilograms/cubic metre by magnesia, magnesium chloride, the particle diameter of technical grade, after the mixing, makes through the room temperature mold pressing. This layer is positioned at the bottom of wall floor tile, and it is carrying originally of glassy layer 1, multicolour pattern layer 2 and adhesive phase 3. Its direct and wall or ground stickup.
The cutting of 2 glass aniseed and glass pre-treatment, drying process are included in 1 operation with reference to the accompanying drawings. Be designed into the art designing from product pattern and draw draft, photography the Nature subject matter, carry out electronic scanning, plate-making, shine the PS version, the technology that glass offset printing four-colour chromatography, photocuring are processed and electronic computer automatically detects printing quality and cuts apart the qualified glass that prints all is included in the hectographic printing multicolour pattern layer operation 2. The making of lightweight mold pressing brick belongs to operation 3. The bonding operation 4 that belongs to of glass and mold pressing brick. The bonding edging that carries out well belongs to operation 5. Make at last finished product.
Further set forth the preparation method of coloured glass wall tile (floor brick) more in conjunction with the embodiments.
1. the selection of glass and processing:
Water white plate glass or the safety glass of selecting for use the thick common float glass process of 5mm to make.Size by six patterns is cut glass aniseed, carries out cleaning treatment with glass cleaner then.Cleaning agent formula is as follows: (can select one of following three prescriptions for use) calculates by weight:
Material name 123
Hydrofluoric acid 0.5 5 10
Dodecyl sodium sulfate 0.07 0.07 0.5
Ethylene glycol n-butyl ether 8.0/8.0
Acetate (20%) 5.0 5.0/
Isopropyl alcohol/8.0 8.0
Water 86.43 81.93 73.5
Compound method is that above-mentioned each material umber is by weight poured in the water successively, adds water to capacity at last, stirs evenly.
Glass is placed in the above-mentioned cleaning agent, and dipping is 30 minutes under the room temperature, and water cleans back oven dry or airing then.
2. hectographic printing multicolour pattern layer:
Adopt existing offset printing technology, comprising the positive photography, electronic scanning, plate-making, the process of solarization PS version with the printing process that circle flattens, can be used JB600 type offset press, and the glass face for the treatment of seal carries out direct chromaticity printing.Use goddess's board offset printing light-curable ink of Tianjin printing ink factory, use high-pressure sodium lamp, lamp solidified 0.1～0.3 second apart from 20～40 centimetres.The multicolour pattern layer has the thickness of 2～3 μ m.
Machine detects printing quality automatically as calculated, and qualified products are stand-by with cutting machine cutting back again.
3. make magnesia light-weight foam mold pressing brick:
Umber by weight calculates:
20 parts of technical grades of magnesia
10 parts of technical grades of magnesium chloride
20 parts of 450# of cement
25 parts of particle diameters of fine sand are 1.6～2.2mm
20 parts of unit weights of expanded perlite are 150～250
Kilogram/cubic meter
2.5 parts of aluminium powders
No. 771 2.5 parts of accelerators (Shanghai Silicate Prods. Works)
Behind the above-mentioned material mixing, the water that adds 50 parts again stirs evenly.Pour in the mould that coats releasing agent 0.5 kg/cm of pressurizeing, the demoulding after 30 minutes into.Normal temperature solidified 24 hours down.Can be made into 15.2 * 15.2 * 5(mm) or 30.5 * 30.5 * 8(mm) mold pressing brick.
4. bonding:
With the one side that has been printed on multicolour pattern on glass, it is thick evenly to coat the about 1mm of GPS-4 silicone adhesive (Shanghai Rubber Products Insitute's production), after magnesia light-weight foam mold pressing brick aligns mutually, 0.20 kg/cm of pressurizeing, the blank of a coloured glass wall tile (floor brick) is promptly made in cold curing 24 hours.
5. edging:
With above-mentioned blank, wear into the inclined-plane of 3mm with glass edge-grinding machine, so just made coloured glass wall tile (floor brick).
Measured result
Sequence number Interventions Requested standard-required
1 2 3
1 light transmittance 〉=70(%) 84.6 84.9 85.7
2 flexural strengths 〉=30(MPa) 42.30 39.26 46.29
3 shear strengths 〉=2.5(N/mm
2)＞4.38＞4.49＞4.38
43 hours was one to meet with-20～25 ℃ 3 hours, 10 ± 2 ℃
The freezing-thawing test circulation, the no breach in 30 circulation backs, variable color, distortion, bubble require requirement
5 5% hydrochloric acid solutions soaked 336 hours, no breach, met
Acid resisting test distortion, bubble and obvious variable color requirement requirement
6 5% sodium hydroxide solutions soaked 336 hours, did not have to split to meet to meet
Alkaline resistance test mouth, variable color, distortion, bubble and obvious variable color requirement requirement
7 50 ± 2 ℃, relative temperature 90～99%, 288 meet for a short time
There are not breach, variable color, distortion, bubble requirement requirement requirement during Water Resistance Test
8 100 ± 2 ℃ 100 hours, no breach, distortion meet
Heat-resistance test bubble and obvious variable color requirement requirement
Claims (1)
- A kind of manufacture method of coloured glass wall tile (floor brick) is characterized in that it being that in the following order several steps carries out:A: glass is selected and handled: select the water white plate glass or the safety glass of the thick common float glass process manufacturing of 3-5mm for use, after aniseed is cut on request, carry out cleaning treatment with glass cleaner, cleaning agent formula is: in the umber of weight(40%) 0.5～10 part of chemical pure of hydrofluoric acid0.05～0.07 part of chemical pure of dodecyl sodium sulfate4.0～8.0 parts of chemical pures of ethylene glycol n-butyl ether0.5～10 part of chemical pure of acetate (20% the aqueous solution)0～8.0 part of chemical pure of isopropyl alcoholWater to 100 partGlass is placed in the cleaning agent, and dipping is 30 minutes under the room temperature, and method water routinely cleans only then, oven dry or airing;B. hectographic printing multicolour pattern layer:Adopt existing offset printing technology, with the printing process that circle flattens, the glass for the treatment of seal carries out the glass chromaticity printing, uses ultraviolet photo-curing printing ink, and the multicolour pattern layer has the thickness of 2～3 μ m;C. make magnesia light-weight foam mold pressing brick:Umber by weight calculates:20 parts of technical grades of magnesia10 parts of technical grades of magnesium chloride20 parts of 450# of cement25 parts of particle diameters of fine sand are 1.6～2.2mm20 parts of unit weights of expanded perlite are 150～250 kilograms/cubic metreBlowing agent is an amount ofAccelerator is an amount ofWith said mixture matter is 100 parts, add to pour in the mould after 50 parts water stirs evenly, and 0.5 kg/cm of pressurizeing, the demoulding after 30 minutes, normal temperature solidified 24 hours down;D. bonding:With the one side that has been printed on multicolour pattern on glass, it is thick evenly to coat the about 1mm of silicone rubber kinds adhesive, with magnesia light-weight foam mold pressing brick mutually to after the agent, the pressurization 0.05～0.30 kg/cm, cold curing 24 hours;E. edging:With the blank of bonding good coloured glass wall tile (floor brick), wear into the inclined-plane of 3mm or 5mm, so just made coloured glass wall tile (floor brick).
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93110410 CN1026078C (en) | 1993-01-03 | 1993-01-03 | Method for making coloured glass wall tile (floor brick) |
| MYPI93002089A MY110828A (en) | 1992-10-14 | 1993-10-12 | A process for making color printed glass slabs for wall and floor and the resulting product |
| GB9321175A GB2271529B (en) | 1992-10-14 | 1993-10-14 | A process for making colour printed glass slabs for wall and floor and the resulting product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93110410 CN1026078C (en) | 1993-01-03 | 1993-01-03 | Method for making coloured glass wall tile (floor brick) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1082989A CN1082989A (en) | 1994-03-02 |
| CN1026078C true CN1026078C (en) | 1994-10-05 |
Family
ID=4988282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93110410 Expired - Fee Related CN1026078C (en) | 1992-10-14 | 1993-01-03 | Method for making coloured glass wall tile (floor brick) |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1026078C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101852006A (en) * | 2010-04-30 | 2010-10-06 | 朱开刚 | Method for producing ceramic ground line brick |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4153360B2 (en) * | 2003-05-15 | 2008-09-24 | ナノックス株式会社 | Reflective liquid crystal display |
| JP4100626B2 (en) * | 2004-01-30 | 2008-06-11 | Ｈｏｙａ株式会社 | Manufacturing method of glass material for press molding and manufacturing method of optical component |
| CN110922163A (en) * | 2019-11-27 | 2020-03-27 | 广西净雨环保科技有限公司 | Process formula of environment-friendly ceramic product |
-
1993
- 1993-01-03 CN CN 93110410 patent/CN1026078C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101852006A (en) * | 2010-04-30 | 2010-10-06 | 朱开刚 | Method for producing ceramic ground line brick |
| CN101852006B (en) * | 2010-04-30 | 2012-05-23 | 朱开刚 | Method for producing ceramic ground line brick |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1082989A (en) | 1994-03-02 |
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