CN1724271A - Polished ceramic tile with colour decorating glaze and its preparation method and equipment - Google Patents
Polished ceramic tile with colour decorating glaze and its preparation method and equipment Download PDFInfo
- Publication number
- CN1724271A CN1724271A CN 200410058947 CN200410058947A CN1724271A CN 1724271 A CN1724271 A CN 1724271A CN 200410058947 CN200410058947 CN 200410058947 CN 200410058947 A CN200410058947 A CN 200410058947A CN 1724271 A CN1724271 A CN 1724271A
- Authority
- CN
- China
- Prior art keywords
- coat enamel
- cover
- illuminated
- glaze
- ceramic tile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
A polished and enameled color ceramic tile is composed of substrate, priming enamel layer, printed color pattern layer and polished surface enamel layer. Its preparing process includes such steps as forming substrate, applying priming enamel, printing color pattern, applying surficial enamel, baking, calcination and polishing. Its apparatus is composed of several units associated with said preparing steps.
Description
Technical field
The present invention relates to the preparation method and the equipment thereof of a kind of illuminated glaze polished glazed tile, this ceramic tile.
Background technology
Ceramic tile in the market can be divided into two classes: a class is a glazed tile, and another kind of is polished bricks.
Glazed tile comprises end base, is positioned at one deck ground-coat enamel on the end base and is positioned at ground glaze layer last layer cover-coat enamel.The true qualities glazed tile is just formed by these three layers usually.If the illuminated glazed tile also has the illuminated pattern on cover-coat enamel, its preparation technology forms end base and dry, applies one deck ground-coat enamel on end base, applies one deck glazing siccative amount and be generally 400-700g/m on ground-coat enamel
2The cover-coat enamel of (thickness is generally the 0.3-0.5 millimeter), printing illuminated pattern is fired glazed body on cover coat.Its shortcoming is the surface of pattern at glaze, easily be worn, and the glossiness on surface is lower.No matter be true qualities glazed tile or illuminated glazed tile, after burning till, all do not polish, also can't polish that reason is the not enough and picture on surface easy to wear of cover-coat enamel thickness.Flatness of glazed tile (levy with the center curvature kilsyth basalt, national standard is ± 0.4%) and surface gloss (being generally the 70-85 degree) are not very high, can't satisfy the more and more stricter requirement of building decorating industry.
Polished bricks is the ceramic tile of a class based on the porcelain base substrate.Because base substrate is that homogeneity porcelain and hardness are higher, therefore can after firing, directly polish.The flatness of polished bricks improves to some extent (center curvature degree national standard is ± 0.3%) than above-mentioned glazed tile, but surface gloss is then not as glazed tile (the glossiness national standard is＞55 degree, the actual 60-75 degree that mostly is).Simultaneously, what polished bricks presented is the stone material true qualities, can not satisfy the special illuminated or the demand of pattern.Moreover the anti-pollution characteristic of polished bricks is relatively poor.Therefore it uses quite limitation.Developed the technology that adds illuminated to polished bricks in recent years, promptly made required printing glaze penetrate into the following certain depth in polished bricks surface, made through keeping these printing glazes after the polishing by infiltration technology.Yet the repetition stability of this infiltration technology is relatively poor, and the lines of illuminated are undistinct, and it is serious that phenomenon is oozed on the limit, makes that the illuminated color between the different batches product exists than big-difference.In addition, the infiltration technology limitation is bigger, can't obtain the variation of complicated color pattern, dull coloring, with low uncertainty, the level that is beyond expression.This class illuminated polished bricks also can not satisfy far away ceramic tile in the requirement aspect pattern fineness and the illuminated solid colour.
Also having a kind of technology is when end blank molding, relies on computer cloth technology that the toner material of different colours is placed according to required pattern, finally obtains the illuminated brick.This process using be the dry method cloth, resulting illuminated is more mechanical single.By comparison, can control the gray scale of pattern, shade etc. by regulating concentration during the wet method printing, to express strong third dimension and color.
Summary of the invention
An object of the present invention is to provide a kind of illuminated glaze polished glazed tile, it can satisfy the requirement to ceramic tile illuminated pattern and color well, and has high-flatness and high surface gloss.
Another object of the present invention provides a kind of method of production illuminated glaze polished glazed tile.
A further object of the invention provides a kind of equipment of production illuminated glaze polished glazed tile.
The invention provides a kind of illuminated glaze polished glazed tile, it comprises end base, be positioned at one deck ground-coat enamel on the end base, be positioned at the illuminated stamp on the ground glaze layer and be positioned at one deck cover-coat enamel on the illuminated stamp, and described cover-coat enamel is through polishing.
In a preferred embodiment of the invention, described cover-coat enamel is transparent.Ceramic tile of the present invention preferably center curvature degree is ± 0.2%, and glossiness is the 90-100 degree.
The present invention also provides a kind of method for preparing illuminated glaze polished glazed tile, and this method may further comprise the steps: (1) end blank molding; (2) on end base, apply one deck ground-coat enamel; (3) printing illuminated pattern on ground-coat enamel; (4) on the illuminated pattern, apply one deck cover-coat enamel again; (5) glazed body that has applied cover-coat enamel is dried; (6) glazed body of drying is fired; (7) after firing, the glaze of ceramic tile is polished.
In a preferred embodiment of the invention, added CMS in the described cover-coat enamel.The consumption of CMS preferably accounts for the 0.1-0.4 weight % of cover-coat enamel gross weight.The glazing siccative amount of cover-coat enamel is preferably 800-1200g/m in the step (4)
2The thickness of cover-coat enamel is preferably the 0.6-1.2 millimeter before the polishing after firing.In the sintering procedure of step (6), maximum sintering temperature preferably is controlled at 1050-1250 ℃.In addition, preferably polish, also ceramic tile is carried out edging except glaze to ceramic tile.Adopt the continous way polishing machine to polish and edging.
The present invention also provides a kind of equipment for preparing illuminated glaze polished glazed tile, and this equipment comprises successively as lower device: end blank molding device, at the device that applies ground glaze layer on the end base, at device, the device that applies cover coat on the illuminated pattern, glazed body drying unit, the glazed body baking apparatus of printing illuminated pattern and the device that cover-coat enamel is polished on the ground-coat enamel.
Illuminated glaze polished glazed tile of the present invention combines the advantage of muffle painting technology and glossing, can not only satisfy the requirement of various decorative patterns, and its surface smoothness and glossiness are all very high.Production method of the present invention adjusts and improves by the ceramic tile production method to prior art, thereby can produce the illuminated glaze polished glazed tile of the present invention of various sizes simply efficiently.The device just of production illuminated glaze polished glazed tile of the present invention is done some changes to existing equipment and is got final product, and need not to invest again the brand-new production equipment of purchasing.
Description of drawings
Fig. 1 is the generalized section of an embodiment of illuminated glaze polished glazed tile of the present invention.
Fig. 2 is the schematic diagram that the present invention prepares the equipment of illuminated glaze polished glazed tile.
The specific embodiment
Illuminated glaze polished glazed tile of the present invention comprises end base 11 as shown in Figure 1, is positioned at one deck ground-coat enamel 12 on the end base 11, is positioned at illuminated stamp 13 on 12 layers of the ground-coat enamels, is positioned at one deck cover-coat enamel 14 on the illuminated stamp 13, and this aspect glaze is through polishing.Cover coat is preferably transparent.
In the illuminated glaze polished glazed tile of the present invention, the raw material of end base, ground-coat enamel and illuminated stamp and composition all are similar to end base, ground-coat enamel and the illuminated stamp of the illuminated glazed tile described in the background technology.In order to be illustrated in more detail, below to the raw material of end base, ground-coat enamel and illuminated stamp with form and make a brief description.Should be appreciated that end base, ground-coat enamel and the illuminated stamp in the illuminated glaze polished glazed tile of the present invention is not limited to these explanations, base of any end, ground-coat enamel and illuminated stamp that those of ordinary skills know all can be used for the present invention.
End base can be ceramic base, Shi matter base or the porcelain base of using always, and its material is formed and represented to be generally (with molar part) in Sai Geshi: 0.05-0.30 KNaO; 0.05-0.50 CaO; 1.0 Al
2O
36-12 SiO
20.02-0.40 MgO.
One deck ground-coat enamel is arranged on end base, and ground-coat enamel is known as cosmetic soil again, and its effect is the adhesion that improves between end base and the cover-coat enamel, covers the bad painted of end base, and a desired background of decorative effect is provided.The composition of cosmetic soil is generally: 0-40 weight portion flux, 10-40 weight portion feldspar, 0-30 weight portion quartz, 5-30 weight portion kaolin, ball clay and/or clay, 0-25 weight portion opacifiers, and optional colorant, its consumption is decided on requirement.
Be positioned at the illuminated stamp on the ground glaze layer, claim printing glaze again.Printing glaze is made up of ceramic printing colorant, printing powdered frit (flux) and stamp-pad ink three parts.Colorant is the source of pattern color, and the printing powdered frit is the medium of colorant and cover-coat enamel fusion, and stamp-pad ink is to finish the necessary carrier of printing, and it will decompose when firing fully.Printing glaze generally includes 0.1-50 weight portion colorant, 10-100 weight portion printing powdered frit and 40-200 weight portion stamp-pad ink.Various printing glazes can show different colors based on different chemical compositions.Those of ordinary skills can select suitable printing glaze according to required color pattern.
One deck cover-coat enamel is arranged on the illuminated stamp, and it is to be positioned at the uppermost one deck vitreous material of ceramic tile, and required decorative effect and antifouling waterproof and durability is provided.The cover-coat enamel material of ceramic tile of the present invention and conventional cover-coat enamel of the prior art are roughly the same, and the composition of representing in Sai Geshi is generally (with molar part): 0.05-0.20 KNaO; 0.05-0.40 CaO; 0.10-0.60 Al
2O
32.00-6.00 SiO
20.02-0.20 MgO; 0.02-0.30 B
2O
30.01-0.20 ZnO.In a preferred embodiment of the present invention, the difference of conventional cover-coat enamel is in cover-coat enamel of the present invention and the prior art: add CMS in the cover-coat enamel raw material, be used for significantly shortening cover coat and apply the exsiccation time afterwards.The consumption of CMS can be selected according to the required exsiccation time, only otherwise the present invention is had a negative impact, preferably accounted for the 0.1-0.4 weight % of cover-coat enamel gross weight, was more preferably 0.15-0.3 weight %.The CMS that is added is removed in sintering procedure.This aspect glaze is through polishing, and the glossiness of cover-coat enamel is measured with vancometer according to the GB/T13891 standard, is generally the 90-100 degree, preferably the 93-100 degree.
The flatness of illuminated glaze polished glazed tile of the present invention is levied with the center curvature kilsyth basalt, adopts ISO/DIS13006-1994 Ceramic Tiles standard to record, and is ± 0.3%, preferably ± 0.2%.
The method that the present invention prepares illuminated glaze polished glazed tile mainly may further comprise the steps successively: end blank molding, apply ground-coat enamel, printing illuminated pattern, apply cover-coat enamel, dry, fire, polish.
End blank molding can adopt the formation method of base at the bottom of the existing glazed tile, and its technology for example comprises extrusion moulding, powder compacting method etc.
Apply the ground-coat enamel method that applies that ground-coat enamel can adopt existing glazed tile, for example can use the glaze machine that gets rid of, waterfall type slip shower, waterfall type slip shower clock.
The printing of illuminated pattern can be adopted the illuminated printing technology of existing glazed tile, and printing equipment commonly used is such as but not limited to screen process press, cylinder press or aerograph machine.
On the illuminated pattern, apply in the technology of cover-coat enamel,, therefore should apply the cover-coat enamel of adequate thickness because this aspect glaze also will experience polishing after burning till.Cover-coat enamel applies thickness and is generally the 0.8-1.5 millimeter, preferably the 1.0-1.5 millimeter.Glazing siccative amount is 800-1200g/m
2Thicker cover coat at wet method glazing gained preferably adds CMS in cover-coat enamel coating, this can significantly shorten the exsiccation time of cover coat.The consumption of CMS can be selected according to the required exsiccation time, only otherwise the present invention is had a negative impact, preferably accounted for the 0.1-0.4 weight % of cover-coat enamel gross weight, was more preferably 0.15-0.3 weight %.
The purpose of oven dry is the moisture that reduces in the glazed body, preferably moisture content is controlled to be to be less than or equal to 0.5 weight %.Those skilled in the art can easily determine the temperature and time of oven dry according to necessary requirement.The temperature of oven dry is such as but not limited to 70-240 ℃, and drying time was such as but not limited to 20 minutes to 4 hours.
In the sintering procedure, maximum sintering temperature is controlled in 1050-1250 ℃ the scope usually, preferably 1100-1200 ℃.Those skilled in the art can and look concrete condition and select appropriate firing temperature curve under the requirement of satisfying this maximum sintering temperature according to concrete equipment.Firing time is generally 30-120 minute, preferably 45-60 minute.The thickness of firing the back cover-coat enamel is generally the 0.6-1.2 millimeter, preferably the 0.8-1.0 millimeter.
Adopt polishing machine to carry out to the polishing of cover-coat enamel, conventional polishing machine can for example be the M656 type of MBKD300/600-16, the REORINT of Kodak, the DELTA type of FLAM.These polishing machines possess all that corase grind allocates, fine-grinding and polishing, buffing polishing, edging chamfering four major parts, and every group of bistrique is adjustable in pressure.
Fig. 2 is the schematic diagram of an embodiment of the production equipment of illuminated glaze polished glazed tile of the present invention.The production equipment of illuminated glaze polished glazed tile comprises end blank molding machine 21, ground-coat enamel slip shower 22, illuminated pattern printing machine 23, cover-coat enamel slip shower 24, glazed body drying plant 25, glazed body baking apparatus 26, sorting unit 27 (can choose wantonly), cover-coat enamel burnishing device 28 successively.Wherein cover-coat enamel burnishing device 28 comprises kibbling mill 30, atomizer mill 31, finishing polish 32, one edging 33 and two road edgings 34.
The above-mentioned machine of in the production equipment of the present invention all can be in the prior art with the corresponding machine in normal service of each road technology, different is, various machines in the production equipment of the present invention have special and the corresponding position arrangement of ceramic tile structure of the present invention, be cover-coat enamel slip shower 24 between illuminated pattern printing machine 23 and glazed body baking apparatus 26, and before glazed body baking apparatus 26, increase glazed body drying plant 25.Thus, production equipment of the present invention only needs existing equipment is done some little changes, just can prepare novel illuminated glaze polished glazed tile of the present invention.
The invention will be further described below in conjunction with embodiment, and these embodiment only play illustration, never limit the scope of the invention.
Embodiment 1
Mix mountain mud in 24 weight portion illites, 13 weight portions, 14 weight portion carclazytes, 19 weight portion porcelain stones, 21 weight portion hypothermia graits and 9 weight portion wollastonites, grind, homogenizing, efflorescence in spray tower, ageing is 24 hours then, at 280kgf/cm
2Pressure be 300 * 300mm down with press-molding
2Blank, with this blank in 1080 ± 10 ℃ of biscuitings 45 minutes, base on earth.
Apply ground-coat enamel with the ground-coat enamel slip shower on end base, the prescription of ground-coat enamel is 12 weight portion kaolin, 8 weight portion ball clays, 12 weight portion quartz, 54 weight portion feldspars, 14 weight portion frit KR-64 (Shanghai moisten bold and unconstrained Tao Ye Co., Ltd), 0.2 weight portion CMS and 0.2 weight portion sodium phosphate trimer (STPP).The glaze volume of ground-coat enamel is 360 ± 20g/m
2
On ground-coat enamel, print illuminated pattern (printing glaze) with screen process press.The prescription of this printing glaze is 100 weight portion stamp powdered frits, 152 weight portion stamp-pad ink R-300 (Shanghai moisten bold and unconstrained Tao Ye Co., Ltd), 2.7 weight portion zirconium iron pinks, 8.6 weight portion praseodymium zirconium Huangs, 1.7 weight portion cobalt blacks.
Then, apply cover-coat enamel with the cover-coat enamel slip shower, the prescription of cover-coat enamel is 27 weight portion frit KR-33 (Shanghai moisten bold and unconstrained Tao Ye Co., Ltd), 65 weight portion frits 1610 (Da Hong enamel frit makeing Co., Ltd), 8 weight portion kaolin, 0.25 weight portion CMS and 0.1 weight portion sodium phosphate trimer (STPP).The glaze volume of cover-coat enamel is 900g/m
2, cover-coat enamel thickness is 1.0 millimeters.
In 120 ℃ drying oven, glazed body was dried 40 minutes.The moisture content of the glazed body of drying is less than or equal to 0.4 weight %, it is sent into kiln fire, and the firing time is 60 minutes, and maximum sintering temperature is controlled in 1160 ℃.Fire finish after, the thickness of cover-coat enamel is 0.8 millimeter.Carry out sorting then, the ceramic tile cover-coat enamel is polished with REORINT M656 type polishing machine.
Gained illuminated glaze polished glazed tile is ± 0.15% according to ISO/DIS13006-1994 Ceramic Tiles canonical measure center curvature degree.Measuring its glossiness according to the GB/T13891 standard with vancometer, is 99 °.
Embodiment 2
Prepare end base and apply ground-coat enamel by embodiment 1 identical mode.
On ground-coat enamel, print illuminated pattern (printing glaze) with cylinder press.The prescription of this printing glaze is 100 weight portion stamp powdered frits, 197 weight portion stamp-pad ink R-300,14.0 weight portion praseodymium zirconium Huangs, 33.6 weight portions gold palm fibre.
Then, apply cover-coat enamel with the cover-coat enamel slip shower, identical among the prescription of cover-coat enamel and the embodiment 1, only the consumption with CMS changes 0.1 weight portion into.The glaze volume of cover-coat enamel is 800g/m
2, cover-coat enamel thickness is 0.8 millimeter.
In 240 ℃ drying oven, glazed body was dried 20 minutes.The moisture content of the glazed body of drying is less than or equal to 0.5 weight %, it is sent into kiln fire, and the firing time is 120 minutes, and maximum sintering temperature is controlled in 1050 ℃.Fire finish after, the thickness of cover-coat enamel is 0.6 millimeter.Carry out sorting then, the ceramic tile cover-coat enamel is polished with FLAM DELTA type polishing machine.
Gained illuminated glaze polished glazed tile is ± 0.18% according to ISO/DIS13006-1994 Ceramic Tiles canonical measure center curvature degree.Measuring its glossiness according to the GB/T13891 standard with vancometer, is 97 °.
Embodiment 3
Prepare end base and apply ground-coat enamel by embodiment 1 identical mode.
On ground-coat enamel, print illuminated pattern (printing glaze) with the aerograph machine.The prescription of this printing glaze is 100 weight portion stamp powdered frits, 154 weight portion stamp-pad ink R-300,7.2 weight portion praseodymium zirconium Huangs, 4.3 weight portions gold palm fibre and 3.2 weight portion cobalt blacks.
Then, apply cover-coat enamel with the cover-coat enamel slip shower, identical among the prescription of cover-coat enamel and the embodiment 1, only the consumption with CMS changes 0.4 weight portion into.The glaze volume of cover-coat enamel is 1200g/m
2, cover-coat enamel thickness is 1.5 millimeters.
In 70 ℃ drying oven, glazed body was dried 4 hours.The moisture content of the glazed body of drying is less than or equal to 0.2 weight %, it is sent into kiln fire, and the firing time is 30 minutes, and maximum sintering temperature is controlled in 1250 ℃.Fire finish after, the thickness of cover-coat enamel is 1.2 millimeters.Carry out sorting then, the ceramic tile cover-coat enamel is polished with the MBKD300/600-16 type polishing machine of Kodak.
Gained illuminated glaze polished glazed tile is ± 0.20% according to ISO/DIS13006-1994 Ceramic Tiles canonical measure center curvature degree.Measuring its glossiness according to the GB/T13891 standard with vancometer, is 95 °.
Claims (13)
1. illuminated glaze polished glazed tile, it comprises end base, be positioned at one deck ground-coat enamel on the end base, be positioned at the illuminated stamp on the ground glaze layer and be positioned at one deck cover-coat enamel on the illuminated stamp, described cover-coat enamel is through polishing.
2. ceramic tile as claimed in claim 1 is characterized in that described cover-coat enamel is transparent.
3. ceramic tile as claimed in claim 1 is characterized in that the center curvature degree of ceramic tile is ± 0.2%.
4. ceramic tile as claimed in claim 1, the glossiness that it is characterized in that the ceramic tile cover-coat enamel is the 90-100 degree.
5. method for preparing illuminated glaze polished glazed tile, this method may further comprise the steps:
(1) end blank molding;
(2) on end base, apply one deck ground-coat enamel;
(3) printing illuminated pattern on ground-coat enamel;
(4) on the illuminated pattern, apply one deck cover-coat enamel again;
(5) glazed body that has applied cover-coat enamel is dried;
(6) glazed body of drying is fired;
(7) after firing, the glaze of ceramic tile is polished.
6. method as claimed in claim 5 is characterized in that having added CMS in described cover-coat enamel.
7. method as claimed in claim 6 is characterized in that CMS accounts for the 0.1-0.4 weight % of cover-coat enamel gross weight.
8. method as claimed in claim 5 is characterized in that the glazing siccative amount of cover-coat enamel in the step (4) is 800-1200g/m
2
9. method as claimed in claim 5, the thickness of cover-coat enamel is the 0.6-1.2 millimeter before it is characterized in that polishing after firing.
10. method as claimed in claim 5 is characterized in that in the sintering procedure of step (6), and maximum sintering temperature is controlled at 1050-1250 ℃.
11. method as claimed in claim 5 is characterized in that also ceramic tile being carried out edging except the glaze to ceramic tile polishes.
12., it is characterized in that adopting the continous way polishing machine to polish and edging as claim 5 or 11 described methods.
13. an equipment for preparing illuminated glaze polished glazed tile, this equipment comprise successively as lower device: end blank molding device, at the device that applies ground glaze layer on the end base, at device, the device that on the illuminated pattern, applies cover coat, glazed body drying unit, the glazed body baking apparatus of printing illuminated pattern and the device that cover-coat enamel is polished on the ground-coat enamel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410058947 CN1724271A (en) | 2004-07-23 | 2004-07-23 | Polished ceramic tile with colour decorating glaze and its preparation method and equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410058947 CN1724271A (en) | 2004-07-23 | 2004-07-23 | Polished ceramic tile with colour decorating glaze and its preparation method and equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1724271A true CN1724271A (en) | 2006-01-25 |
Family
ID=35923951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410058947 Pending CN1724271A (en) | 2004-07-23 | 2004-07-23 | Polished ceramic tile with colour decorating glaze and its preparation method and equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1724271A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102001855A (en) * | 2010-09-17 | 2011-04-06 | 霍镰泉 | Carpet simulated ceramic tile |
| CN101157543B (en) * | 2007-09-27 | 2011-09-21 | 广东金意陶陶瓷有限公司 | Method for making ceramic tile with metallic luster local interspersing surface |
| CN102351572A (en) * | 2011-06-20 | 2012-02-15 | 徐超 | Equipment and preparation method for ceramic brick with male and female surfaces and continuous texture |
| CN101586387B (en) * | 2009-06-16 | 2012-05-16 | 霍镰泉 | Method for producing inner wall ceramic chip |
| CN102635214A (en) * | 2012-05-10 | 2012-08-15 | 信益陶瓷(中国)有限公司 | Universal ceramic tile used for wall surface and ground |
| CN102635215A (en) * | 2012-05-10 | 2012-08-15 | 信益陶瓷(中国)有限公司 | Interior wall tile |
| CN101571000B (en) * | 2008-04-28 | 2013-02-06 | 章云树 | Foaming mosaic and manufacturing method thereof |
| CN101619614B (en) * | 2009-07-21 | 2013-04-24 | 霍镰泉 | Method for producing polished porcelain tile |
| CN103274767A (en) * | 2013-05-06 | 2013-09-04 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile with purely flat glaze and manufacturing method for ceramic tile |
| CN104446344A (en) * | 2014-11-01 | 2015-03-25 | 景德镇景浮宫陶瓷文化有限公司 | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method |
| CN105622173A (en) * | 2015-12-23 | 2016-06-01 | 蒙娜丽莎集团股份有限公司 | Ink-jetted penetrating archaized brick capable of being repolished after being paved and production method of ink-jetted penetrating archaized brick |
| CN110256113A (en) * | 2019-07-01 | 2019-09-20 | 广东易成陶瓷实业有限公司 | A kind of ceramic large area overglaze color anticracking color technique of white clouds soil |
| CN114103503A (en) * | 2021-11-19 | 2022-03-01 | 福建省德化县邦威陶瓷有限公司 | Firing process of marble fancy glaze |
-
2004
- 2004-07-23 CN CN 200410058947 patent/CN1724271A/en active Pending
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157543B (en) * | 2007-09-27 | 2011-09-21 | 广东金意陶陶瓷有限公司 | Method for making ceramic tile with metallic luster local interspersing surface |
| CN101571000B (en) * | 2008-04-28 | 2013-02-06 | 章云树 | Foaming mosaic and manufacturing method thereof |
| CN101586387B (en) * | 2009-06-16 | 2012-05-16 | 霍镰泉 | Method for producing inner wall ceramic chip |
| CN101619614B (en) * | 2009-07-21 | 2013-04-24 | 霍镰泉 | Method for producing polished porcelain tile |
| CN102001855B (en) * | 2010-09-17 | 2013-04-24 | 霍镰泉 | Carpet simulated ceramic tile |
| CN102001855A (en) * | 2010-09-17 | 2011-04-06 | 霍镰泉 | Carpet simulated ceramic tile |
| CN102351572A (en) * | 2011-06-20 | 2012-02-15 | 徐超 | Equipment and preparation method for ceramic brick with male and female surfaces and continuous texture |
| CN102635214A (en) * | 2012-05-10 | 2012-08-15 | 信益陶瓷(中国)有限公司 | Universal ceramic tile used for wall surface and ground |
| CN102635215A (en) * | 2012-05-10 | 2012-08-15 | 信益陶瓷(中国)有限公司 | Interior wall tile |
| CN103274767A (en) * | 2013-05-06 | 2013-09-04 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile with purely flat glaze and manufacturing method for ceramic tile |
| CN103274767B (en) * | 2013-05-06 | 2015-01-07 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile with purely flat glaze and manufacturing method for ceramic tile |
| CN104446344A (en) * | 2014-11-01 | 2015-03-25 | 景德镇景浮宫陶瓷文化有限公司 | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method |
| CN105622173A (en) * | 2015-12-23 | 2016-06-01 | 蒙娜丽莎集团股份有限公司 | Ink-jetted penetrating archaized brick capable of being repolished after being paved and production method of ink-jetted penetrating archaized brick |
| CN105622173B (en) * | 2015-12-23 | 2018-07-31 | 蒙娜丽莎集团股份有限公司 | After a kind of paving can the ink-jet of re-polishing ooze colored Antique Imitation Tiles and its manufacturing method |
| CN110256113A (en) * | 2019-07-01 | 2019-09-20 | 广东易成陶瓷实业有限公司 | A kind of ceramic large area overglaze color anticracking color technique of white clouds soil |
| CN114103503A (en) * | 2021-11-19 | 2022-03-01 | 福建省德化县邦威陶瓷有限公司 | Firing process of marble fancy glaze |
| CN114103503B (en) * | 2021-11-19 | 2023-08-04 | 福建省德化县邦威陶瓷有限公司 | Firing process of marble fancy glaze |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110054510B (en) | A kind of anti-skidding ink-jet Ceramic Tiles of wet water height and preparation method thereof with sagging glaze effect | |
| CN107915479B (en) | Porcelain whole-body archaized brick and preparation method thereof | |
| CN105948503B (en) | A kind of abrasion-resistant clear glaze and the method using its preparation glazed tile | |
| CN105948820B (en) | A kind of Wear-resistant glaze material and the method using its preparation glazed tile | |
| CN109279918A (en) | A kind of sheen brick and preparation method thereof | |
| CN107963814A (en) | Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree | |
| CN110482859B (en) | Starlight glaze ceramic tile and preparation method thereof | |
| CN111548014A (en) | Microcrystal glaze, wear-resistant glaze, transparent microcrystal wear-resistant fully-polished glaze tile and preparation method | |
| CN1724271A (en) | Polished ceramic tile with colour decorating glaze and its preparation method and equipment | |
| CN109279919A (en) | A kind of water mill essence stone brick and preparation method thereof | |
| CN111116235B (en) | Fine dry particle ceramic tile, preparation method thereof and fine dry particle glaze | |
| CN108752057B (en) | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees | |
| CN113461443B (en) | Ceramic plate with matte dry particle texture and preparation method thereof | |
| CN107915480B (en) | Ink-jet permeable light-transmitting brick and preparation method thereof | |
| CN112723870B (en) | Ceramic rock plate with color jade effect and preparation method thereof | |
| CN114773093B (en) | Dry grain glaze, ceramic tile with time stamp effect and preparation method thereof | |
| CN110436963A (en) | Dry granular glaze and there is white suspension floccule dry-particle ceramic tile and preparation method thereof | |
| CN113716967A (en) | Ceramic tile with flashing effect and preparation method thereof | |
| CN103664236B (en) | Metal fancy glaze and there is full throwing glaze ceramic tile and the production technique thereof of metal effect | |
| CN106810297B (en) | Production process of ceramic tile with high-brightness matte surface and precious metal luster | |
| CN115043589B (en) | Colorful flash dry particle and positioning diamond colorful effect marble-imitated ceramic tile | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| CN109400217A (en) | A kind of finishing impression vitreous brick and preparation method thereof | |
| CN109516691A (en) | A kind of full burnishing surface ceramic of dark images and preparation method thereof | |
| CN113968728B (en) | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |