CN105707118A - Pesticide composition containing phosmet and bifenazate - Google Patents
Pesticide composition containing phosmet and bifenazate Download PDFInfo
- Publication number
- CN105707118A CN105707118A CN201610177852.7A CN201610177852A CN105707118A CN 105707118 A CN105707118 A CN 105707118A CN 201610177852 A CN201610177852 A CN 201610177852A CN 105707118 A CN105707118 A CN 105707118A
- Authority
- CN
- China
- Prior art keywords
- bifenazate
- phosmet
- composition pesticide
- pesticide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Abstract
The invention relates to a pesticide composition and application thereof. Effective components are bifenazate and phosmet. The ratio of parts by weight of the phosmet to the bifenazate is 25:1-1:25, the compound synergistic effect of the two effective components is remarkable, and the excellent prevention and treatment effect on various mite injurious insects on flowers and crops such as fruit trees and vegetables is achieved. According to the composition, the prevention and treatment effect on mite injurious insects is improved, the good treatment effect on pests such as Lepidoptera, thysanoptera and homoptera is achieved, an insecticidal spectrum is expanded, the pesticide consumption amount is further lowered, the residual quantity of pesticide on crops is decreased, environmental pollution is relieved, and production of pest resistance to insecticide is lowered.
Description
Technical field
The present invention relates to composition pesticide and application thereof, the composition pesticide being specifically effective ingredient with phosmet and Bifenazate, it is primarily adapted for use in the various mite pests on the crops such as fruit tree, vegetable and flowers, the harmful organisms such as Lepidoptera, Thysanoptera, Homoptera is had simultaneously and double preferably control effect.
Background technology
Phosmet (phosemet) chemical name: O, O-dimethyl-S-(phthalimide methyl) phosphorodithioate, molecular formula: C11H12NO4PS2, phosmet is a kind of broad-spectrum organophosphorous pesticide, has stomach toxicity and action of contace poison, plant tissue has certain permeability.Can effectively preventing Lepidoptera, Homoptera, mite pest.
Bifenazate (bifenazate) chemical name: 3-(4-methoxyl biphenyl base-3-base) carbazic acid isopropyl ester, molecular formula: C17H20N2O3, Bifenazate is a kind of novel selectivity foliar spray acaricide, and the mechanism of action is the antagonist of the γ-aminobutyric acid (GABA) of the nervus centralis conducting system to demodicid mite class.It is effective to each life stage of demodicid mite class, has ovicidal activity with to the activity of knocking down becoming demodicid mite, and the lasting period is long, and Predatory Mites is not had toxicity, it is recommended to use dosage is interior to crop safety.
Evil demodicid mite is Arachnoidea acarina pest, is one of important pests endangering multiple kinds of crops, all has distribution in China's most area.Evil demodicid mite be gathered in vacuum side of blade more, adult, nymph are thrust with mouthpart and suck juice in leaf, often result in plant leaf blade chlorophyll impaired, affects photosynthesis, cause leaf malformation, and time serious, blade is withered comes off, even because of blade fall light cause plant death；It addition, many harmful demodicid mites also propagate viral diseases of plants and fungal disease.Evil demodicid mite fertility extremely strong, 1 year up to more than 10 generations, 20～30 generation at most.Irrational dispenser makes ecological deterioration, and natural enemy quantity reduces.
In agricultural production, due to long-term continuous administration single variety acaricide and not scientifical use pesticide, cause that the Drug resistance of evil demodicid mite is day by day serious；Simultaneously as problems such as the excessive increases using pesticide to result in environmental pollution and peasant's drug cost, it is unfavorable for the sustainable development of agricultural.Therefore, develop compound drug efficient, low toxicity, low-residual, not only facilitate the Drug resistance delaying evil demodicid mite, but also using dosage can be reduced, save cost, reduce the pollution to environment.
The compounded formula of phosmet and Bifenazate is screened and conducts in-depth research by the present inventor, on the basis of substantial amounts of formula indoor screening test and field medicine effect test, find that phosmet and Bifenazate carry out composite, within the scope of certain compound proportion, mite pest is shown synergistic function, after further study, the present invention is completed.
Summary of the invention
It is an object of the invention to provide a kind of composition pesticide containing phosmet and Bifenazate, said composition has obvious synergistic function, consumption can be reduced, reduce pesticide residual on crops, alleviate the pesticide pollution to environment, delay the various drug-fast generation of harmful demodicid mite, can be used for preventing and treating agriculturally multiple mites insect.
The technical scheme is that a kind of composition pesticide containing phosmet and Bifenazate, active component is made up of phosmet and Bifenazate, and the ratio of weight and number of phosmet and Bifenazate is 25: 1～1: 25；Further, described phosmet and the ratio of weight and number of Bifenazate are 7: 1～1: 7.It is furthermore preferred that the ratio of weight and number of described phosmet and Bifenazate is 1: 1.
In composition pesticide, the weight percentage of active component phosmet and Bifenazate is the 0.5%～90% of gross weight, and all the other are allow in pesticide to use and acceptable auxiliary element；Further, described phosmet and the weight percentage of Bifenazate are the 25%～40% of gross weight.
Described composition pesticide is configured to any one dosage form with phosmet and Bifenazate for the auxiliary agent of permission on active component and pesticide；Further, described dosage form is aqueous emulsion, suspending agent, water dispersible granules, wettable powder, suspension emulsion or granule.
Described composition pesticide is for agriculturally preventing and treating the application of various harmful demodicid mite；Further, described harmful demodicid mite is Tetranychus cinnabarinus or Tetranychus urticae.
Present invention also offers a kind of method preventing and treating harmful demodicid mite, use the composition pesticide containing phosmet and Bifenazate.
The auxiliary agent that the present invention adopts includes each analog assistants such as wetting agent, dispersant, thickening agent, defoamer, antifreezing agent, filler.
The wetting agent that adopted, dispersant are one or more in dispersing agent MF, sodium lignin sulfonate, calcium lignosulfonate, dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate, sodium butylnaphthalenesulfonate, naphthalene sulfonic acid condensate sodium salt, alkylphenol polyoxyethylene, castor oil polyoxyethylene ether etc.；
The thickening agent adopted is one or both in xanthan gum, sodium alginate；
The defoamer adopted be in tributyl phosphate and organic silicon defoamer one or both；
The antifreezing agent adopted is one or more in ethylene glycol, propylene glycol and carbamide；
The filler adopted is one or more in white carbon, Kaolin, attapulgite, ammonium sulfate, glucose, white carbon, water-washed kaoline etc.；
The soluble additive adopted is dimethylbenzene, toluene, methanol, butanone, isopropanol, n-butyl alcohol, n-amyl alcohol, ethylene glycol, solvent naphtha S200#；
The emulsifying agent adopted is one or more in Sodium Trideceth phosphate ester, Oleum Ricini resin polyoxyethylene ether, polyoxyethylene sulfonyl Oleum Ricini nonionic, sulfonyl calcium succinate anion, polycarboxylic acid salt, calcium dodecyl benzene sulfonate etc..
The processing technique of the various preparation of composition pesticide of the present invention is all prior art, can be varied from according to different situations.
Composition pesticide provided by the invention, is mainly used in the various demodicid mite classes on preventing and treating crops, such as Tetranychus cinnabarinus, Tetranychus urticae etc.；The harmful organisms such as Lepidoptera, Thysanoptera, Homoptera are had simultaneously and double preferably control effect.
Composition pesticide provided by the invention has following beneficial effect:
1. composition pesticide provided by the invention, the medicament different by two kinds of mechanisms of action of phosmet and Bifenazate forms, expand the use scope of phosmet and Bifenazate single dose, and in ratio of weight and number 25: 1～1: 25 scope, mite pest is shown obvious synergistic function, solve the defect to some mite pest weak effect when single dose is used alone.
2. pesticide combination provided by the invention, decreases the using dosage of pesticide, reduces pesticide residual on crops, reduces drug cost and the pesticide adverse effect to ecological environment.
3. pesticide combination provided by the invention, it is possible to reduce long-term single use phosmet or the resistance risk of Bifenazate generation, extend the service life of medicament, the comprehensive control important in inhibiting to insect.
4. pesticide combination provided by the invention, has harmful organisms such as Lepidoptera, Thysanoptera, Homopteras and double preferably controls effect.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage more short and sweet, below in conjunction with embodiment, present disclosure is described further, but the present invention is only limitted to absolutely not these examples.Presented below is only the reasonable case study on implementation of the present invention, is used only for describing the present invention, unintelligible for limitation of the scope of the invention.
1. formula and formulation examples
Embodiment one
For 30% Bifenazate phosmet aqueous emulsion (EW), but it is not limited only to 30% in actual application, it is possible to according to preferred proportion reasonably optimizing in claims, particular instantiation:
Bifenazate 12%, phosmet 18%, dimethylbenzene 12%, isopropanol 1%, Sodium Trideceth phosphate ester 1.5%, Oleum Ricini resin polyoxyethylene ether 2%, xanthan gum 0.10%, carbamide 1.5%, sodium benzoate 0.20%, triethanolamine 0.8%, water is supplied, after first Bifenazate fully being dissolved, add all the other auxiliary agents such as surfactant, stabilizer, water, through high speed shear to particle diameter D after stirring90=5 μm, the uniform water-soluble emulsion of the micro-strip that is creamy white blue-fluorescence.
Embodiment two
Compositions comprises following constituent content when making suspending agent:
For 25% Bifenazate phosmet suspending agent (SC), but it is not limited only to 30% in actual application, it is possible to according to preferred proportion reasonably optimizing in claims, particular instantiation:
Bifenazate 8%, phosmet 17%, polyoxyethylene sulfonyl Oleum Ricini nonionic 2%, sulfonyl calcium succinate anion 1%, polycarboxylate 1%, xanthan gum 0.15%, carbamide 2.5%, sodium benzoate 0.30%, triethanolamine 0.8%; water is supplied; above-mentioned material put into successively after hybrid reactor stirs by formula proportion and requirement, through sand mill speed lapping to particle diameter D90=5 μm, then through homogenizing, allotment in uniform canescence suspension.
Embodiment three
Compositions comprises following constituent content when making water dispersible granules:
For 30% Bifenazate phosmet water dispersible granules (WG), the former medicine 20% of the former medicine of Bifenazate 10%, phosmet, naphthalene sulfonic acid condensate sodium salt 8%, sodium lauryl sulphate 5%, ammonium sulfate 15%, glucose 10%, white carbon 2%, water-washed kaoline are supplied.First by former medicine and other auxiliary agent mix homogeneously, gas powder, adding water kneading, last pelletize also dries.
Embodiment four
Compositions comprises following constituent content when making wettable powder:
For 40% Bifenazate Phosmet wettable powder (WP), the former medicine 28% of the former medicine of Bifenazate 12%, phosmet, organosilicon 8%, di-2-ethylhexylphosphine oxide LOMAR PWA EINECS 246-676-2 naphthalene 5%, sodium lauryl sulphate 3%, white carbon 2%, precipitated calcium carbonate 15%, water-washed kaoline are supplied.First former medicine and other auxiliary agent mix homogeneously are crushed to particle diameter D then through high velocity air90=27 μm, in the powdery solid of canescence good fluidity.
Above formula example and used soluble additive are only limitted to this test, but the Agrotechnical formulation product prepared according to the group required in this patent is not limited only to these soluble additives, it is also possible to variant, all in the extent of competence of this patent.
2. the indoor biological determination of activity of the present composition and field efficacy checking
Embodiment five: the indoor joint toxicity measuring of Tetranychus cinnabarinus is tested by phosmet and Bifenazate
For examination insecticide: the Tetranychus cinnabarinus of breeding is raised in indoor
Test medicine: the 98% former medicine of phosmet and the former medicine of 97% Bifenazate
Test method adopts leaf disc spray, and concrete operation method is as follows:
First the Broad Bean Leaves card punch of indoor plantation is made leaf butterfly of the same size, in culture dish, place one piece of sponge, it puts filter paper, then the leaf dish back side is placed on filter paper upward, every ware puts 4 leaf dish, and every leaf dish accesses 30 health, age consistent Tetranychus cinnabarinus and becomes demodicid mite.Often processing and arrange 4 repetitions, a piece of leaf dish is for once to repeat, and arranges blank.
Being placed under potter spray tower by the culture dish being placed with leaf dish, spray under 50PSI pressure, spray amount is 2ml, take out culture dish after sedimentation 30s, then the culture dish processed is put into 25 DEG C, cultivate in 12h/12h illumination box, check dead borer population after 72h, calculate mortality rate.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and the co-toxicity coefficient (CTC) of compound drug mixture is calculated according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (with phosmet for standard agent, its toxicity index is 100)
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
The percentage composition of B in the percentage composition+B medicament toxicity index × mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to the criteria for classifying of co-toxicity coefficient (CTC), CTC < 80 is antagonism, and 80 < CTC < 120 are summation action, and CTC > 120 is potentiation.
Table 1 phosmet and the Bifenazate indoor joint toxicity measuring result to Tetranychus cinnabarinus
As can be seen from Table 1, when phosmet and Bifenazate are composite in the scope of 25: 1～1: 25 (by weight), co-toxicity coefficient (CTC) is all higher than 120, Tetranychus cinnabarinus is shown synergistic function, it is seen that phosmet and Bifenazate is composite has reasonability and feasibility.Wherein, when the proportioning of phosmet and Bifenazate is 1: 1, both composite best results.
Embodiment six: the indoor joint toxicity measuring of Tetranychus urticae is tested by phosmet and Bifenazate
For examination insecticide: the Tetranychus urticae of breeding is raised in indoor
Test medicine: the 98% former medicine of phosmet and the former medicine of 97% Bifenazate
Test method adopts leaf disc spray, and concrete operation method is identical with embodiment five, becomes demodicid mite to replace with Tetranychus urticae Tetranychus cinnabarinus.
Table 2 phosmet and the Bifenazate indoor joint toxicity measuring result to Tetranychus urticae
As can be seen from Table 2, when phosmet and Bifenazate are composite in the scope of 15: 1～1: 20 (by weight), co-toxicity coefficient (CTC) is all higher than 120, Tetranychus urticae is shown synergistic function, it is seen that phosmet and Bifenazate is composite has reasonability and feasibility.Wherein, when the proportioning of phosmet and Bifenazate is 1: 1, both composite best results.
Embodiment seven: phosmet and the composite field control effectiveness test to Tetranychus cinnabarinus of Bifenazate
Adopt 25% phosmet Bifenazate aqueous emulsion for preventing and treating Tetranychus cinnabarinus, insect population radix is investigated before dispenser, after medicine, 7d, 14d, 30d investigate residual demodicid mite number alive respectively, 2 strains are investigated in investigation Shi Mei community, every strain looks into 5 blades respectively by orientation, 4, the four corners of the world, every community looks into 40 blades altogether, records demodicid mite number of living, and calculates prevention effect.Prevention effect computational methods are as follows:
Prevention effect (%)=(1-CK1×Pt1/CK2×Pt2)×100。
Wherein: CK1 represents insect population number before the medicine of check plot；Pt1 represents insect population number after treatment region medicine；
CK2 represents insect population number after the medicine of check plot；Pt2 represents insect population number before treatment region medicine.
Table 3 respectively processes the result of the test of chemical control Tetranychus cinnabarinus
As can be seen from Table 3, when 30% phosmet Bifenazate aqueous emulsion uses 2000-2500 times, after medicine, the preventive effect of Tetranychus cinnabarinus is superior to preventive effect when each single dose is used alone by 7d, 14d, 30d, after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.Test survey process not finding, mandarin tree is produced poisoning by this compound drug.
In sum, the composition pesticide that the present invention adopts two kinds of active component to be phosmet and Bifenazate, there is synergistic function, compared with existing unitary agent, miticidal effect significantly improves, and the lasting period is long, to crop safety, it is worth promoting the use of in agricultural production.
Claims (10)
1. the composition pesticide containing phosmet and Bifenazate, it is characterised in that active component is made up of phosmet and Bifenazate, and the ratio of weight and number of phosmet and Bifenazate is 25: 1～1: 25.
2. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that described phosmet and the ratio of weight and number of Bifenazate are 7: 1～1: 7.
3. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1 and 2, it is characterised in that described phosmet and the ratio of weight and number of Bifenazate are 1: 1.
4. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that weight summation is composition pesticide the 0.5%～90% of described phosmet and Bifenazate.
5. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that weight summation is composition pesticide the 25%～40% of described phosmet and Bifenazate.
6. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that described composition pesticide is configured to any one dosage form with phosmet and Bifenazate for the auxiliary agent of permission on active component and pesticide.
7. a kind of composition pesticide containing phosmet and Bifenazate according to claim 6, it is characterised in that described dosage form is aqueous emulsion, suspending agent, water dispersible granules, wettable powder, suspension emulsion or granule.
8. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1 is for the application of agriculturally preventing and treating evil demodicid mite.
9. application according to claim 8, it is characterised in that described harmful demodicid mite is Tetranychus cinnabarinus or Tetranychus urticae.
10. the method preventing and treating harmful demodicid mite, it is characterised in that use containing the composition pesticide described in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610177852.7A CN105707118B (en) | 2016-03-25 | 2016-03-25 | A kind of composition pesticide containing phosmet and Bifenazate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610177852.7A CN105707118B (en) | 2016-03-25 | 2016-03-25 | A kind of composition pesticide containing phosmet and Bifenazate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105707118A true CN105707118A (en) | 2016-06-29 |
| CN105707118B CN105707118B (en) | 2018-02-06 |
Family
ID=56158213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610177852.7A Active CN105707118B (en) | 2016-03-25 | 2016-03-25 | A kind of composition pesticide containing phosmet and Bifenazate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105707118B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109122713A (en) * | 2018-09-30 | 2019-01-04 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing phosmet and guadipyr |
| CN109221211A (en) * | 2018-09-30 | 2019-01-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing lufenuron and cycolxylidin |
| CN110367269A (en) * | 2019-08-07 | 2019-10-25 | 江西正邦作物保护有限公司 | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6093843A (en) * | 1999-10-06 | 2000-07-25 | Uniroyal Chemical Company, Inc. | 4-hydroxybiphenyl hydrazide derivatives |
| DE102004010716A1 (en) * | 2003-03-18 | 2004-08-12 | Syngenta Participations Ag | New synergistic herbicidal composition, useful for total or selective weed control, contains 5-hydroxypyrazole derivative and, as synergist, an insecticidal or acaricidal agent |
| CN103004864A (en) * | 2013-01-10 | 2013-04-03 | 北京市农林科学院 | Pesticide composition containing bifenazate and phoxim |
| CN103039511A (en) * | 2012-12-25 | 2013-04-17 | 北京市农林科学院 | Bifenazate and chlorpyrifos contained synergistic acaricidal combination |
| CN103918692A (en) * | 2014-03-27 | 2014-07-16 | 广东中迅农科股份有限公司 | Pesticide composition containing indoxacarb and bifenazate |
| CN105211084A (en) * | 2014-12-23 | 2016-01-06 | 京博农化科技股份有限公司 | A kind of suspending agent containing pymetrozine and Bifenazate |
-
2016
- 2016-03-25 CN CN201610177852.7A patent/CN105707118B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6093843A (en) * | 1999-10-06 | 2000-07-25 | Uniroyal Chemical Company, Inc. | 4-hydroxybiphenyl hydrazide derivatives |
| DE102004010716A1 (en) * | 2003-03-18 | 2004-08-12 | Syngenta Participations Ag | New synergistic herbicidal composition, useful for total or selective weed control, contains 5-hydroxypyrazole derivative and, as synergist, an insecticidal or acaricidal agent |
| CN103039511A (en) * | 2012-12-25 | 2013-04-17 | 北京市农林科学院 | Bifenazate and chlorpyrifos contained synergistic acaricidal combination |
| CN103004864A (en) * | 2013-01-10 | 2013-04-03 | 北京市农林科学院 | Pesticide composition containing bifenazate and phoxim |
| CN103918692A (en) * | 2014-03-27 | 2014-07-16 | 广东中迅农科股份有限公司 | Pesticide composition containing indoxacarb and bifenazate |
| CN105211084A (en) * | 2014-12-23 | 2016-01-06 | 京博农化科技股份有限公司 | A kind of suspending agent containing pymetrozine and Bifenazate |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109122713A (en) * | 2018-09-30 | 2019-01-04 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing phosmet and guadipyr |
| CN109221211A (en) * | 2018-09-30 | 2019-01-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing lufenuron and cycolxylidin |
| CN110367269A (en) * | 2019-08-07 | 2019-10-25 | 江西正邦作物保护有限公司 | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105707118B (en) | 2018-02-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101999382B (en) | Mite-killing composition containing etoxazole and bifenazate | |
| CN105707118A (en) | Pesticide composition containing phosmet and bifenazate | |
| CN102405914B (en) | Synergistic mite killing composition containing cyflumetofen and clofentezine | |
| CN104542618A (en) | Synergetic acaricidal composition containing cyenopyrafen and etoxazole | |
| CN104082300B (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN104115861B (en) | A kind of insecticide acaricide composition containing sulfur-phosphor and cyflumetofen | |
| CN102017960B (en) | Acaricidal composition containing etoxazole and pyridaben | |
| CN104106593B (en) | A kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles | |
| CN104522010A (en) | Synergistic acaricidal composition containing cyenopyrafen and bifenazate | |
| CN111328813A (en) | Acaricidal synergist containing plant source | |
| CN105685068A (en) | Acaricidal composition containing cyenopyrafen and spirotetramat | |
| CN104381294A (en) | Insect and mite killing composition containing xiaochongliulin and spirodiclofen | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN104585179B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and spirodiclofen | |
| CN102696631B (en) | Synergistic acaricidal composition containing etoxazole and chlorfenapyr | |
| CN104255751A (en) | Mite-killing composition containing etoxazole and vermectin | |
| CN102823606B (en) | Acaricidal composition containing bifenazate | |
| CN110367269A (en) | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN104082322B (en) | A kind of containing Nylar with the insecticide acaricide composition of Bifenazate | |
| CN103098820B (en) | The Synergistic mite killing composition of Bifenazate and gamma cyhalothrin | |
| CN104521999B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and Ivermectin HCL | |
| CN109122713A (en) | A kind of composition pesticide containing phosmet and guadipyr |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Gongli Inventor after: Di Wenbo Inventor after: Huang Jiacheng Inventor after: Zhu Zhiyin Inventor after: Wei Fanglin Inventor before: Chen Gongli Inventor before: Di Wenbo Inventor before: Huang Jiacheng Inventor before: Zhu Zhiyin Inventor before: Wei Fanglin |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 330800 new century industrial city, Gao An, Yichun, Jiangxi Patentee after: Jiangxi Zheng Bang crop protection Co., Ltd. Address before: 330800 new century Industrial Park, Gao An, Yichun, Jiangxi Patentee before: JIANGXI ZHENGBANG BIO-CHEMICAL CO., LTD. |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 330300 west side of Xinghuo Industrial Park Xinghuo Industrial Park, Yongxiu County, Jiujiang City, Jiangxi Province Patentee after: Jiangxi Zhengbang crop protection Co.,Ltd. Address before: 330800 new century industrial city, Gao An, Yichun, Jiangxi Patentee before: JIANGXI ZHENGBANG CROP PROTECTION Co.,Ltd. |
|
| CP03 | Change of name, title or address |