CN105707118A - Pesticide composition containing phosmet and bifenazate - Google Patents
Pesticide composition containing phosmet and bifenazate Download PDFInfo
- Publication number
- CN105707118A CN105707118A CN201610177852.7A CN201610177852A CN105707118A CN 105707118 A CN105707118 A CN 105707118A CN 201610177852 A CN201610177852 A CN 201610177852A CN 105707118 A CN105707118 A CN 105707118A
- Authority
- CN
- China
- Prior art keywords
- bifenazate
- phosmet
- composition pesticide
- pesticide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000005653 Bifenazate Substances 0.000 title claims abstract description 62
- 239000005921 Phosmet Substances 0.000 title claims abstract description 62
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000000575 pesticide Substances 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 13
- 241001454293 Tetranychus urticae Species 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 239000004563 wettable powder Substances 0.000 claims description 5
- 239000002552 dosage form Substances 0.000 claims description 4
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 13
- 241000238631 Hexapoda Species 0.000 abstract description 9
- 241000607479 Yersinia pestis Species 0.000 abstract description 8
- 230000002195 synergetic effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 241000258937 Hemiptera Species 0.000 abstract description 5
- 241000255777 Lepidoptera Species 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 5
- 241001414989 Thysanoptera Species 0.000 abstract description 4
- 239000002917 insecticide Substances 0.000 abstract description 3
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 230000000266 injurious effect Effects 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 230000000856 effect on pests Effects 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 31
- 230000001988 toxicity Effects 0.000 description 11
- 231100000419 toxicity Toxicity 0.000 description 11
- -1 carbazic acid isopropyl ester Chemical class 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 241000238876 Acari Species 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KQEODPNNXMKKIR-UHFFFAOYSA-N sulfonylcalcium Chemical compound [Ca].S(=O)=O KQEODPNNXMKKIR-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000005557 antagonist Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000003129 miticidal effect Effects 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000005080 plant death Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition and application thereof. Effective components are bifenazate and phosmet. The ratio of parts by weight of the phosmet to the bifenazate is 25:1-1:25, the compound synergistic effect of the two effective components is remarkable, and the excellent prevention and treatment effect on various mite injurious insects on flowers and crops such as fruit trees and vegetables is achieved. According to the composition, the prevention and treatment effect on mite injurious insects is improved, the good treatment effect on pests such as Lepidoptera, thysanoptera and homoptera is achieved, an insecticidal spectrum is expanded, the pesticide consumption amount is further lowered, the residual quantity of pesticide on crops is decreased, environmental pollution is relieved, and production of pest resistance to insecticide is lowered.
Description
Technical field
The present invention relates to composition pesticide and application thereof, the composition pesticide being specifically effective ingredient with phosmet and Bifenazate, it is primarily adapted for use in the various mite pests on the crops such as fruit tree, vegetable and flowers, the harmful organisms such as Lepidoptera, Thysanoptera, Homoptera is had simultaneously and double preferably control effect.
Background technology
Phosmet (phosemet) chemical name: O, O-dimethyl-S-(phthalimide methyl) phosphorodithioate, molecular formula: C11H12NO4PS2, phosmet is a kind of broad-spectrum organophosphorous pesticide, has stomach toxicity and action of contace poison, plant tissue has certain permeability.Can effectively preventing Lepidoptera, Homoptera, mite pest.
Bifenazate (bifenazate) chemical name: 3-(4-methoxyl biphenyl base-3-base) carbazic acid isopropyl ester, molecular formula: C17H20N2O3, Bifenazate is a kind of novel selectivity foliar spray acaricide, and the mechanism of action is the antagonist of the γ-aminobutyric acid (GABA) of the nervus centralis conducting system to demodicid mite class.It is effective to each life stage of demodicid mite class, has ovicidal activity with to the activity of knocking down becoming demodicid mite, and the lasting period is long, and Predatory Mites is not had toxicity, it is recommended to use dosage is interior to crop safety.
Evil demodicid mite is Arachnoidea acarina pest, is one of important pests endangering multiple kinds of crops, all has distribution in China's most area.Evil demodicid mite be gathered in vacuum side of blade more, adult, nymph are thrust with mouthpart and suck juice in leaf, often result in plant leaf blade chlorophyll impaired, affects photosynthesis, cause leaf malformation, and time serious, blade is withered comes off, even because of blade fall light cause plant death；It addition, many harmful demodicid mites also propagate viral diseases of plants and fungal disease.Evil demodicid mite fertility extremely strong, 1 year up to more than 10 generations, 20～30 generation at most.Irrational dispenser makes ecological deterioration, and natural enemy quantity reduces.
In agricultural production, due to long-term continuous administration single variety acaricide and not scientifical use pesticide, cause that the Drug resistance of evil demodicid mite is day by day serious；Simultaneously as problems such as the excessive increases using pesticide to result in environmental pollution and peasant's drug cost, it is unfavorable for the sustainable development of agricultural.Therefore, develop compound drug efficient, low toxicity, low-residual, not only facilitate the Drug resistance delaying evil demodicid mite, but also using dosage can be reduced, save cost, reduce the pollution to environment.
The compounded formula of phosmet and Bifenazate is screened and conducts in-depth research by the present inventor, on the basis of substantial amounts of formula indoor screening test and field medicine effect test, find that phosmet and Bifenazate carry out composite, within the scope of certain compound proportion, mite pest is shown synergistic function, after further study, the present invention is completed.
Summary of the invention
It is an object of the invention to provide a kind of composition pesticide containing phosmet and Bifenazate, said composition has obvious synergistic function, consumption can be reduced, reduce pesticide residual on crops, alleviate the pesticide pollution to environment, delay the various drug-fast generation of harmful demodicid mite, can be used for preventing and treating agriculturally multiple mites insect.
The technical scheme is that a kind of composition pesticide containing phosmet and Bifenazate, active component is made up of phosmet and Bifenazate, and the ratio of weight and number of phosmet and Bifenazate is 25: 1～1: 25；Further, described phosmet and the ratio of weight and number of Bifenazate are 7: 1～1: 7.It is furthermore preferred that the ratio of weight and number of described phosmet and Bifenazate is 1: 1.
In composition pesticide, the weight percentage of active component phosmet and Bifenazate is the 0.5%～90% of gross weight, and all the other are allow in pesticide to use and acceptable auxiliary element；Further, described phosmet and the weight percentage of Bifenazate are the 25%～40% of gross weight.
Described composition pesticide is configured to any one dosage form with phosmet and Bifenazate for the auxiliary agent of permission on active component and pesticide；Further, described dosage form is aqueous emulsion, suspending agent, water dispersible granules, wettable powder, suspension emulsion or granule.
Described composition pesticide is for agriculturally preventing and treating the application of various harmful demodicid mite；Further, described harmful demodicid mite is Tetranychus cinnabarinus or Tetranychus urticae.
Present invention also offers a kind of method preventing and treating harmful demodicid mite, use the composition pesticide containing phosmet and Bifenazate.
The auxiliary agent that the present invention adopts includes each analog assistants such as wetting agent, dispersant, thickening agent, defoamer, antifreezing agent, filler.
The wetting agent that adopted, dispersant are one or more in dispersing agent MF, sodium lignin sulfonate, calcium lignosulfonate, dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate, sodium butylnaphthalenesulfonate, naphthalene sulfonic acid condensate sodium salt, alkylphenol polyoxyethylene, castor oil polyoxyethylene ether etc.；
The thickening agent adopted is one or both in xanthan gum, sodium alginate；
The defoamer adopted be in tributyl phosphate and organic silicon defoamer one or both；
The antifreezing agent adopted is one or more in ethylene glycol, propylene glycol and carbamide；
The filler adopted is one or more in white carbon, Kaolin, attapulgite, ammonium sulfate, glucose, white carbon, water-washed kaoline etc.；
The soluble additive adopted is dimethylbenzene, toluene, methanol, butanone, isopropanol, n-butyl alcohol, n-amyl alcohol, ethylene glycol, solvent naphtha S200#；
The emulsifying agent adopted is one or more in Sodium Trideceth phosphate ester, Oleum Ricini resin polyoxyethylene ether, polyoxyethylene sulfonyl Oleum Ricini nonionic, sulfonyl calcium succinate anion, polycarboxylic acid salt, calcium dodecyl benzene sulfonate etc..
The processing technique of the various preparation of composition pesticide of the present invention is all prior art, can be varied from according to different situations.
Composition pesticide provided by the invention, is mainly used in the various demodicid mite classes on preventing and treating crops, such as Tetranychus cinnabarinus, Tetranychus urticae etc.；The harmful organisms such as Lepidoptera, Thysanoptera, Homoptera are had simultaneously and double preferably control effect.
Composition pesticide provided by the invention has following beneficial effect:
1. composition pesticide provided by the invention, the medicament different by two kinds of mechanisms of action of phosmet and Bifenazate forms, expand the use scope of phosmet and Bifenazate single dose, and in ratio of weight and number 25: 1～1: 25 scope, mite pest is shown obvious synergistic function, solve the defect to some mite pest weak effect when single dose is used alone.
2. pesticide combination provided by the invention, decreases the using dosage of pesticide, reduces pesticide residual on crops, reduces drug cost and the pesticide adverse effect to ecological environment.
3. pesticide combination provided by the invention, it is possible to reduce long-term single use phosmet or the resistance risk of Bifenazate generation, extend the service life of medicament, the comprehensive control important in inhibiting to insect.
4. pesticide combination provided by the invention, has harmful organisms such as Lepidoptera, Thysanoptera, Homopteras and double preferably controls effect.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage more short and sweet, below in conjunction with embodiment, present disclosure is described further, but the present invention is only limitted to absolutely not these examples.Presented below is only the reasonable case study on implementation of the present invention, is used only for describing the present invention, unintelligible for limitation of the scope of the invention.
1. formula and formulation examples
Embodiment one
For 30% Bifenazate phosmet aqueous emulsion (EW), but it is not limited only to 30% in actual application, it is possible to according to preferred proportion reasonably optimizing in claims, particular instantiation:
Bifenazate 12%, phosmet 18%, dimethylbenzene 12%, isopropanol 1%, Sodium Trideceth phosphate ester 1.5%, Oleum Ricini resin polyoxyethylene ether 2%, xanthan gum 0.10%, carbamide 1.5%, sodium benzoate 0.20%, triethanolamine 0.8%, water is supplied, after first Bifenazate fully being dissolved, add all the other auxiliary agents such as surfactant, stabilizer, water, through high speed shear to particle diameter D after stirring90=5 μm, the uniform water-soluble emulsion of the micro-strip that is creamy white blue-fluorescence.
Embodiment two
Compositions comprises following constituent content when making suspending agent:
For 25% Bifenazate phosmet suspending agent (SC), but it is not limited only to 30% in actual application, it is possible to according to preferred proportion reasonably optimizing in claims, particular instantiation:
Bifenazate 8%, phosmet 17%, polyoxyethylene sulfonyl Oleum Ricini nonionic 2%, sulfonyl calcium succinate anion 1%, polycarboxylate 1%, xanthan gum 0.15%, carbamide 2.5%, sodium benzoate 0.30%, triethanolamine 0.8%; water is supplied; above-mentioned material put into successively after hybrid reactor stirs by formula proportion and requirement, through sand mill speed lapping to particle diameter D90=5 μm, then through homogenizing, allotment in uniform canescence suspension.
Embodiment three
Compositions comprises following constituent content when making water dispersible granules:
For 30% Bifenazate phosmet water dispersible granules (WG), the former medicine 20% of the former medicine of Bifenazate 10%, phosmet, naphthalene sulfonic acid condensate sodium salt 8%, sodium lauryl sulphate 5%, ammonium sulfate 15%, glucose 10%, white carbon 2%, water-washed kaoline are supplied.First by former medicine and other auxiliary agent mix homogeneously, gas powder, adding water kneading, last pelletize also dries.
Embodiment four
Compositions comprises following constituent content when making wettable powder:
For 40% Bifenazate Phosmet wettable powder (WP), the former medicine 28% of the former medicine of Bifenazate 12%, phosmet, organosilicon 8%, di-2-ethylhexylphosphine oxide LOMAR PWA EINECS 246-676-2 naphthalene 5%, sodium lauryl sulphate 3%, white carbon 2%, precipitated calcium carbonate 15%, water-washed kaoline are supplied.First former medicine and other auxiliary agent mix homogeneously are crushed to particle diameter D then through high velocity air90=27 μm, in the powdery solid of canescence good fluidity.
Above formula example and used soluble additive are only limitted to this test, but the Agrotechnical formulation product prepared according to the group required in this patent is not limited only to these soluble additives, it is also possible to variant, all in the extent of competence of this patent.
2. the indoor biological determination of activity of the present composition and field efficacy checking
Embodiment five: the indoor joint toxicity measuring of Tetranychus cinnabarinus is tested by phosmet and Bifenazate
For examination insecticide: the Tetranychus cinnabarinus of breeding is raised in indoor
Test medicine: the 98% former medicine of phosmet and the former medicine of 97% Bifenazate
Test method adopts leaf disc spray, and concrete operation method is as follows:
First the Broad Bean Leaves card punch of indoor plantation is made leaf butterfly of the same size, in culture dish, place one piece of sponge, it puts filter paper, then the leaf dish back side is placed on filter paper upward, every ware puts 4 leaf dish, and every leaf dish accesses 30 health, age consistent Tetranychus cinnabarinus and becomes demodicid mite.Often processing and arrange 4 repetitions, a piece of leaf dish is for once to repeat, and arranges blank.
Being placed under potter spray tower by the culture dish being placed with leaf dish, spray under 50PSI pressure, spray amount is 2ml, take out culture dish after sedimentation 30s, then the culture dish processed is put into 25 DEG C, cultivate in 12h/12h illumination box, check dead borer population after 72h, calculate mortality rate.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and the co-toxicity coefficient (CTC) of compound drug mixture is calculated according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (with phosmet for standard agent, its toxicity index is 100)
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
The percentage composition of B in the percentage composition+B medicament toxicity index × mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to the criteria for classifying of co-toxicity coefficient (CTC), CTC < 80 is antagonism, and 80 < CTC < 120 are summation action, and CTC > 120 is potentiation.
Table 1 phosmet and the Bifenazate indoor joint toxicity measuring result to Tetranychus cinnabarinus
As can be seen from Table 1, when phosmet and Bifenazate are composite in the scope of 25: 1～1: 25 (by weight), co-toxicity coefficient (CTC) is all higher than 120, Tetranychus cinnabarinus is shown synergistic function, it is seen that phosmet and Bifenazate is composite has reasonability and feasibility.Wherein, when the proportioning of phosmet and Bifenazate is 1: 1, both composite best results.
Embodiment six: the indoor joint toxicity measuring of Tetranychus urticae is tested by phosmet and Bifenazate
For examination insecticide: the Tetranychus urticae of breeding is raised in indoor
Test medicine: the 98% former medicine of phosmet and the former medicine of 97% Bifenazate
Test method adopts leaf disc spray, and concrete operation method is identical with embodiment five, becomes demodicid mite to replace with Tetranychus urticae Tetranychus cinnabarinus.
Table 2 phosmet and the Bifenazate indoor joint toxicity measuring result to Tetranychus urticae
As can be seen from Table 2, when phosmet and Bifenazate are composite in the scope of 15: 1～1: 20 (by weight), co-toxicity coefficient (CTC) is all higher than 120, Tetranychus urticae is shown synergistic function, it is seen that phosmet and Bifenazate is composite has reasonability and feasibility.Wherein, when the proportioning of phosmet and Bifenazate is 1: 1, both composite best results.
Embodiment seven: phosmet and the composite field control effectiveness test to Tetranychus cinnabarinus of Bifenazate
Adopt 25% phosmet Bifenazate aqueous emulsion for preventing and treating Tetranychus cinnabarinus, insect population radix is investigated before dispenser, after medicine, 7d, 14d, 30d investigate residual demodicid mite number alive respectively, 2 strains are investigated in investigation Shi Mei community, every strain looks into 5 blades respectively by orientation, 4, the four corners of the world, every community looks into 40 blades altogether, records demodicid mite number of living, and calculates prevention effect.Prevention effect computational methods are as follows:
Prevention effect (%)=(1-CK1×Pt1/CK2×Pt2)×100。
Wherein: CK1 represents insect population number before the medicine of check plot；Pt1 represents insect population number after treatment region medicine；
CK2 represents insect population number after the medicine of check plot；Pt2 represents insect population number before treatment region medicine.
Table 3 respectively processes the result of the test of chemical control Tetranychus cinnabarinus
As can be seen from Table 3, when 30% phosmet Bifenazate aqueous emulsion uses 2000-2500 times, after medicine, the preventive effect of Tetranychus cinnabarinus is superior to preventive effect when each single dose is used alone by 7d, 14d, 30d, after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.Test survey process not finding, mandarin tree is produced poisoning by this compound drug.
In sum, the composition pesticide that the present invention adopts two kinds of active component to be phosmet and Bifenazate, there is synergistic function, compared with existing unitary agent, miticidal effect significantly improves, and the lasting period is long, to crop safety, it is worth promoting the use of in agricultural production.
Claims (10)
1. the composition pesticide containing phosmet and Bifenazate, it is characterised in that active component is made up of phosmet and Bifenazate, and the ratio of weight and number of phosmet and Bifenazate is 25: 1～1: 25.
2. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that described phosmet and the ratio of weight and number of Bifenazate are 7: 1～1: 7.
3. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1 and 2, it is characterised in that described phosmet and the ratio of weight and number of Bifenazate are 1: 1.
4. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that weight summation is composition pesticide the 0.5%～90% of described phosmet and Bifenazate.
5. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that weight summation is composition pesticide the 25%～40% of described phosmet and Bifenazate.
6. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1, it is characterised in that described composition pesticide is configured to any one dosage form with phosmet and Bifenazate for the auxiliary agent of permission on active component and pesticide.
7. a kind of composition pesticide containing phosmet and Bifenazate according to claim 6, it is characterised in that described dosage form is aqueous emulsion, suspending agent, water dispersible granules, wettable powder, suspension emulsion or granule.
8. a kind of composition pesticide containing phosmet and Bifenazate according to claim 1 is for the application of agriculturally preventing and treating evil demodicid mite.
9. application according to claim 8, it is characterised in that described harmful demodicid mite is Tetranychus cinnabarinus or Tetranychus urticae.
10. the method preventing and treating harmful demodicid mite, it is characterised in that use containing the composition pesticide described in claim 1.
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| CN109221211A (en) * | 2018-09-30 | 2019-01-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing lufenuron and cycolxylidin |
| CN110367269A (en) * | 2019-08-07 | 2019-10-25 | 江西正邦作物保护有限公司 | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin |
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Denomination of invention: A pesticide combination containing imidacloprid and biphenylhydrazine ester Granted publication date: 20180206 Pledgee: Nanchang County Branch of Jiujiang Bank Co.,Ltd. Pledgor: Jiangxi Zhengbang crop protection Co.,Ltd. Registration number: Y2024980033325 |