CN110367269A - A kind of Pesticidal combination containing fluorine oxazole amide and avermectin - Google Patents
A kind of Pesticidal combination containing fluorine oxazole amide and avermectin Download PDFInfo
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- CN110367269A CN110367269A CN201910727987.XA CN201910727987A CN110367269A CN 110367269 A CN110367269 A CN 110367269A CN 201910727987 A CN201910727987 A CN 201910727987A CN 110367269 A CN110367269 A CN 110367269A
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- Prior art keywords
- pesticidal combination
- avermectin
- fluorine
- oxazole amide
- amide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention discloses a kind of Pesticidal combination containing fluorine oxazole amide and avermectin, belongs to technical field of pesticide.A kind of Pesticidal combination containing fluorine oxazole amide and avermectin, the composition includes a effective amount of active components A and active constituent B, wherein, active components A is fluorine oxazole amide, active constituent B is avermectin, and active components A and the weight ratio of active constituent B 1: 20~20: 1, the mass percent that the sum of the active components A and the weight of active constituent B account for Pesticidal combination total weight is 0.5%~80%, and surplus is agriculturally acceptable surfactant or liquid diluent.The present composition can prevent and treat various pests agriculturally, especially to diamondback moth and beet armyworm and have many advantages, such as apparent synergistic effect, holding effect are long, dosage is few, it is at low cost, delay pest resistance to insecticide.
Description
Technical field
The invention belongs to technical field of pesticide, are related to a kind of Pesticidal combination containing fluorine oxazole amide and avermectin.
Background technique
Fluorine oxazole amide, English common name: Fluxametamide, CAS 928783-29-3, molecular formula
C20H16C12F3N3O3.Fluorine oxazole amide is the isoxazole class insecticide of Japanese Nissan chemical company exploitation, is had to many insect pests
Broad ranges of efficacy is mainly used for the crops such as vegetables, fruit tree, cotton, soybean, tea tree prevention and treatment lepidoptera pest, aleyrodid, Liriomyza, first
The pests such as worm and mite class.
Avermectin is new bio source insecticides, english common name: Abamectin, molecular formula: C48H72O14
(Bla)·C47H70O14(B1b).Avermectin is the natural products separated from edaphon, is had to insect and mite class
Tag and stomach poison function and has faint fumigation action, no systemic action, but it has very strong osmosis to blade, can kill
Subepidermal pest has good preventive effect to various pests such as Lepidoptera, coleoptera, Diptera, Homopteras.But avermectin
There is also some disadvantages such as easily to decompose in the environment for single dose, the lasting period is short.Due to avermectin broad spectrum activity (report at present Ah
Dimension rhzomorph insecticidal spectrum have 84 kinds), high efficiency cause peasant household to its excessively rely on, when carrying out field control without reasonably taking turns
Use is changed, pest is caused to increase its resistance, drug cost increases.
The increase of pest resistance to insecticide is the major issue that chemical prevention faces, and the unreasonable use of pesticide causes at present
Severe pests such as lepidoptera pest such as diamondback moth, mite pest resistance level on crops is continuously increased, to promote field
Dosage is continuously increased into vicious circle, is caused a series of problems, such as pesticide residue increases, environmental pollution is serious, is unfavorable for agriculture
The sustainable development of industry.Meanwhile the use of pesticide single dose more easily leads to pest resistance to insecticide generation, by utilizing different types of agriculture
Medicine is compounded, and screening is reasonably excellent to match composition, improves field control effect, and reducing dosage reduces cost, reduces anti-medicine
Property increase speed and extend the service life of medicament, to the sustainable development of pesticide using being of great significance.
The present inventor has made intensive studies the compounding of fluorine oxazole amide and avermectin, sieves in a large amount of formula indoor
On the basis of choosing test and field control effectiveness test, it is found that fluorine oxazole amide and avermectin are compounded, in certain compounding ratio
Apparent synergistic effect is showed to diamondback moth and beet armyworm in example range.
Summary of the invention
In order to solve the above problem, the invention discloses a kind of Pesticidal combination containing fluorine oxazole amide and avermectin,
The Pesticidal combination has apparent synergistic effect to diamondback moth and beet armyworm within the scope of certain compound proportion, quick-acting
Property, lasting effect are excellent, and dosage is low and environmental pollution is small.
Technical scheme is as follows:
A kind of Pesticidal combination containing fluorine oxazole amide and avermectin includes a effective amount of active components A and activity
Ingredient B, active components A are fluorine oxazole amide, and active constituent B is avermectin.
In above-mentioned Pesticidal combination, the weight ratio of the active components A and active constituent B are 1: 20~20: 1；Preferably 1
: 10~10: 1；Preferred proportion is 4: 1.
In above-mentioned Pesticidal combination, the sum of the active components A and the weight of active constituent B account for the gross weight of Pesticidal combination
The mass percent of amount is 0.5%~80%, remaining is agriculturally acceptable carrier and auxiliary agent.
In above-mentioned Pesticidal combination, the Pesticidal combination can be prepared as appointing according to methods well known to those skilled in the art
A kind of dosage form for suitable agriculture production application of anticipating；Preferably wettable powder, water dispersible granules, aqueous emulsion, microemulsion, outstanding
Floating agent, suspension emulsion formulation.
Above-mentioned Pesticidal combination is applied to squama by the application of a kind of fluorine-containing oxazole amide and the Pesticidal combination of avermectin
The prevention and treatment of wing mesh pest and/or mite pest.
In the application of above-mentioned Pesticidal combination, the lepidoptera pest includes beet armyworm, diamondback moth, bollworm, two changes
Snout moth's larva and rice leaf roller, the mite pest include red spider；Preferably beet armyworm, diamondback moth.
Composition pesticide provided by the invention has the advantage that
1, fluorine oxazole amide provided by the invention and avermectin belong to the pesticide compositional of different Action mechanisms, right
Pest action site is more, expands the insecticidal spectrum of fluorine oxazole amide and avermectin.
2, the present invention provides a effective amount of fluorine oxazole amides and avermectin mixture increases with synergistic function
Effect is obvious, and control efficiency is excellent, can reduce the administration dosage of each bioactive substance, reduce use cost, delays pest anti-
Property the effect that generates, reduce harm to environment.
It should be understood that
The carrier and auxiliary agent includes emulsifier, solvent, wetting agent, dispersing agent, thickener, stabilizer, antifreezing agent, disappears
One of infusion is several, can also include the other types auxiliary agent of the industry.
The emulsifier is calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkyl phenol polyoxyethylene ether sulfo group
Succinate, styrylphenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, fatty acid polyoxy
Any one of vinyl esters, polyoxyethylene aliphatic alcohol ether or more than one mixtures formed with arbitrary proportion.
The solvent is dimethylbenzene, toluene, chlorobenzene, dichlorotoleune, paraffin, hexamethylene, mineral oil, vegetable oil, alcohols, third
The mixing of one or more of ketone, cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylformamide, dimethyl sulfoxide, water etc.
Object.
The wetting agent be lauryl sodium sulfate, dodecyl benzene sulfonic acid, pull open powder, wetting and penetrating agent, spaonin powder,
One of silkworm excrement, spaonin powder are a variety of.
The dispersing agent be polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulfat,
Alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkyl phenol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, fatty acid
One of polyoxyethylene ester, glycerol fatty acid ester polyoxyethylene ethe are a variety of.
The thickener is xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, aluminum magnesium silicate, gathers
One of vinyl alcohol is a variety of.
The stabilizer is one of sodium citrate, resorcinol.
The antifreezing agent is one of ethylene glycol, propylene glycol, glycerine, urea or a variety of.
The defoaming agent is silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fatty alcohol
One of class compound is a variety of.
Used filler is white carbon black, kaolin, attapulgite, ammonium sulfate, glucose, white carbon black, water-washed kaoline
Deng one of or it is a variety of.
Specific embodiment
In order to keep the objectives, technical solutions, and advantages of the present invention more concise, below with reference to embodiment to the present invention
Content be described further, but the present invention is by no means limited to these examples.Presented below is only that the present invention is relatively good
Case study on implementation is used only to describe the present invention, and is not to be construed as limitation of the scope of the invention.
1. formula and preparation processing craft embodiment
One: 40% fluorine oxazole amide avermectin wettable powder (WP) of embodiment
Fluorine oxazole amide raw medicine 28%, the former medicine of AVM 12%, organosilicon 8%, di-2-ethylhexylphosphine oxide naphthalene sulfonic acids naphthalene 5%, ten
Sodium dialkyl sulfate 3%, white carbon black 2%, precipitated calcium carbonate 15%, water-washed kaoline are supplied.
First raw medicine and other auxiliary agents are uniformly mixed and are crushed to 5 μm of partial size D90 < through high-speed flow again, is flowed in canescence
The good powdery solid of property.
Two: 16% fluorine oxazole amide avermectin wettable powder (WP) of embodiment
Fluorine oxazole amide raw medicine 10%, the former medicine of AVM 6%, lauryl sodium sulfate 4%, polyacrylate copolymerization
1%, sulfonate 2%, white carbon black 5%, anhydrous sodium sulphate 20% add kaolin to complement to 100%.
Each component is weighed in proportion, to get to 16% fluorine oxazole amide avermectin wettable powder after co-grinding.
Three: 30% fluorine oxazole amide avermectin suspending agent (SC) of embodiment
Fluorine oxazole amide 20%, avermectin 10%, polyoxyethylene sulfonyl castor oil nonionic 2%, sulfonyl amber
Sour calcium anion 1%, polycarboxylate 1%, xanthan gum 0.15%, urea 2.5%, sodium benzoate 0.30%, triethanolamine
0.8%, water complements to 100%.
Above-mentioned material is successively put into hybrid reactor after mixing evenly by formula rate, through sand mill high speed grinding to grain
D90=5 μm of diameter, then through homogeneous, allotment in uniform canescence suspension.
Example IV: 30% fluorine oxazole amide abamectin aqueous emulsion (EW)
Fluorine oxazole amide 18%, avermectin 12%, dimethylbenzene 12%, isopropanol 1%, Sodium Trideceth phosphorus
Acid esters 1.5%, castor-oil plant oleoresin polyoxyethylene ether 2%, xanthan gum 0.10%, urea 1.5%, sodium benzoate 0.2%, three ethyl alcohol
Amine 0.8%, water complements to 100%.First active constituent is added after completely dissolution remaining auxiliary agent such as surfactant, stabilizer,
Water, through high speed shear to D90=5 μm of partial size after stirring evenly, the uniform water-soluble emulsion of the micro-strip that is creamy white blue-fluorescence.
Five: 30% fluorine oxazole amide avermectin water dispersible granules (WG) of embodiment
Fluorine oxazole amide 20%, avermectin 10%, naphthalene sulfonic acid condensate sodium salt 8%, lauryl sodium sulfate 5%, sulphur
Sour ammonium 15%, glucose 10%, white carbon black 2%, water-washed kaoline complement to 100%.
First raw medicine and other auxiliary agents are uniformly mixed, gas powder, add water kneading, is finally granulated and dry.
It is formulated example and institute above and is only limitted to this test using soluble additive, but is matched according to assembling for being required in this patent
The Agrotechnical formulation product of system is not limited only to these soluble additives, can also be variant, all in the extent of competence of this patent.
2. the indoor biological activity assay and field efficacy of the present composition are verified
Embodiment six: the indoor toxicity determination test of fluorine oxazole amide and Abamectin on Plutella
For trying insect: the close diamondback moth larvae of or so 3 ages of indoor raising Individual Size
Test medicine: 98% fluorine oxazole amide raw medicine and 97% the former medicine of AVM
Test method uses leaf dipping method, and the specific operation method is as follows:
It is 1: 1,4: 1,8 that fluorine oxazole amide, VM single dose and fluorine oxazole amide and avermectin weight ratio, which is arranged:
1, totally 11 chemicals treatments such as 15: 1,20: 1, such as acetone dilution of each chemicals treatment solvent are dissolved into mother liquor, and according to equal ratios
Method is provided with 7 concentration gradients.The cabbage leaves of no pesticide are fabricated to leaf butterfly of the same size with punch, will be handled well
Leaf dish be dipped in liquid medicine to be measured, taken out after 10s and dry and is placed in the culture dish containing moisturizing filter paper, then access pickles
Moth larvae, each to repeat access 30, each processing is repeated 4 times, using solvent as blank control.The diamondback moth handled well is placed in
Temperature is 25 ± 1 DEG C, humidity 80%, checked after breeding observing 72h in the growth cabinet of photoperiod L: D=16: 8h it is small
Diamond-back moth dead larvae quantity.
Using the logarithm of drug concentration (mg/L) as independent variable x, the probit value with corrected mortality is y, establishes poison respectively
Power regression equation is for statistical analysis with DPS statistical analysis software, calculates the LC of each medicament50, and calculated according to Sun Yunpei's Method
The co-toxicity coefficient (CTC) of compound drug mixture.Co-toxicity coefficient CTC, calculation formula are as follows: (using fluorine oxazole amide as standard agent,
100) its toxicity index is
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to the criteria for classifying of co-toxicity coefficient (CTC), CTC < 80 is antagonism, and 80 < CTC < 120 are summation action,
CTC > 120 is synergistic effect.
Table 1: the The Toxicity Determination result of fluorine oxazole amide and Abamectin on Plutella
As it can be seen from table 1 fluorine oxazole amide and avermectin are in 20:1~1: when being compounded in the range of 20 (by weight),
Co-toxicity coefficient (CTC) is all larger than 120, shows synergistic function to diamondback moth, it is seen that fluorine oxazole amide and avermectin are multiple
With with reasonability and feasibility.Wherein, when the proportion of fluorine oxazole amide and avermectin is 4: 1, the two compounding effect is best.
Embodiment seven: the indoor toxicity determination test of fluorine oxazole amide and avermectin to beet armyworm
For trying insect: the close beet exigua larvae of Individual Size of or so indoor 3 age of raising
Test medicine: 98% fluorine oxazole amide raw medicine and 97% the former medicine of AVM
Test method uses leaf dipping method, and concrete operation method changes diamondback moth into beet armyworm and try with embodiment six
It tests.
The The Toxicity Determination result of 2 fluorine oxazole amide of table and avermectin to beet armyworm
From table 2 it can be seen that when fluorine oxazole amide and avermectin compound in the range of 20: 1~1: 20 (by weight),
Co-toxicity coefficient (CTC) is all larger than 120, shows synergistic function to beet armyworm, it is seen that fluorine oxazole amide and avermectin
Compounding has reasonability and feasibility.Wherein, when the proportion of fluorine oxazole amide and avermectin is 4: 1, the two compounding effect is most
It is good.
Embodiment eight: fluorine oxazole amide and the abamectin compounded field control effectiveness test to diamondback moth
Test is carried out in Nanchang City, Jiangxi Province suburb herbary wild cabbage planting site, and diamondback moth occurs serious.Day during test
Gas is based on fine or cloudy, no Precipitation Process.
Every processing is repeated 4 times, every cell 20m2For 1 repetition, each cell random alignment is uniformly sprayed with conventional nebulizers
Mist.
Investigation method is to sample before application at 5 points of every cell diagonal line, and every selection calibration has Eggs of Diamondback Moth and larva
2 plants of wild cabbage, then every repetition amount to 10 plants of probability demarcation strains on diamondback moth larvae head number in this, as be administered before insect population.In
The 1st, 3,7 and 14d investigate the diamondback moth larvae number survived in fixed point singling respectively and calculate each treated control efficiency after application,
Control efficiency calculation method is as follows:
Control efficiency (%)={ 1-CK0×PT1/(CK1×PT0)}×100
Wherein: CK0Represent insect population number before the medicine of check plot, CK1Represent insect population number after the medicine of check plot；PT0Before representing treatment region medicine
Insect population number, PT1Represent insect population number after treatment region medicine.
Treatment agent needed for this test is provided by positive nation's Biochemical Research.
Table 3: the test result of each processing chemical control diamondback moth
From table 3 it can be seen that embodiment one, two, three, four and five, 1d, 3d, 7d, 14d are equal to the preventive effect of diamondback moth after medicine
Better than each single dose be used alone preventive effect, while after medicine 14d preventive effect still up to 80% or more.It does not find in the process of experimental investigation
The compound drug generates phytotoxicity phenomenon to Target crops.
Therefore, fluorine oxazole amide and avermectin pesticides composition disclosed by the invention to lepidoptera pest diamondback moth and
Beet armyworm all has synergistic function, and effect significantly improves compared with single formulation, and the lasting period is long, to crop safety,
It is worth promoting the use of in agricultural production.
Claims (9)
1. a kind of Pesticidal combination containing fluorine oxazole amide and avermectin, it is characterised in that: the Pesticidal combination includes
A effective amount of active components A and active constituent B, active components A are fluorine oxazole amide, and active constituent B is avermectin.
2. the Pesticidal combination of a kind of fluorine-containing oxazole amide and avermectin according to claim 1, it is characterised in that: institute
State active components A and active constituent B weight ratio in Pesticidal combination are as follows: 1: 20~20: 1.
3. the Pesticidal combination of a kind of fluorine-containing oxazole amide and avermectin according to claim 1, it is characterised in that: institute
State active components A and active constituent B weight ratio in Pesticidal combination are as follows: 1: 10~10: 1.
4. the Pesticidal combination of fluorine-containing oxazole amide and avermectin according to claim 1, it is characterised in that: described to kill
Active components A and active constituent B weight ratio in worm composition are as follows: 4: 1.
5. the Pesticidal combination of a kind of fluorine-containing oxazole amide and avermectin according to claim 1, it is characterised in that: institute
It states the sum of active components A and active constituent B weight in Pesticidal combination and accounts for the mass percent of Pesticidal combination total weight and be
0.5%~80%, surplus is agriculturally acceptable carrier and auxiliary agent.
6. the Pesticidal combination of a kind of fluorine-containing oxazole amide and avermectin according to claim 1, it is characterised in that: institute
Any one suitable agriculture production application can be prepared as according to methods well known to those skilled in the art by stating Pesticidal combination
Dosage form.
7. the Pesticidal combination of a kind of fluorine-containing oxazole amide and avermectin according to claim 6, it is characterised in that: institute
The dosage form for stating Pesticidal combination preparation is wettable powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, suspoemulsion.
8. the application of a kind of fluorine-containing oxazole amide and the Pesticidal combination of avermectin, it is characterised in that: appoint claim 1-7
A kind of Pesticidal combination of anticipating is applied to the prevention and treatment of lepidoptera pest and/or mite pest.
9. the application of a kind of fluorine-containing oxazole amide according to claim 8 and the Pesticidal combination of avermectin, feature
Be: the lepidoptera pest includes beet armyworm, diamondback moth, bollworm, striped rice borer and rice leaf roller, the mite pest
Including red spider.
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| CN201910727987.XA CN110367269A (en) | 2019-08-07 | 2019-08-07 | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin |
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| CN201910727987.XA CN110367269A (en) | 2019-08-07 | 2019-08-07 | A kind of Pesticidal combination containing fluorine oxazole amide and avermectin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111328813A (en) * | 2020-04-18 | 2020-06-26 | 江西正邦作物保护有限公司 | Acaricidal synergist containing plant source |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105707118A (en) * | 2016-03-25 | 2016-06-29 | 江西正邦生物化工有限责任公司 | Pesticide composition containing phosmet and bifenazate |
| CN106659160A (en) * | 2014-06-30 | 2017-05-10 | 日产化学工业株式会社 | Insecticide, miticide, nematicide, molluscicide, disinfectant, or bactericide composition, and pest control method |
| JP2018108989A (en) * | 2017-01-05 | 2018-07-12 | 日産化学工業株式会社 | Unpleasant pest control agent and unpleasant pest control method |
| JP2019048883A (en) * | 2018-11-30 | 2019-03-28 | 日産化学株式会社 | Isoxazoline-substituted benzamide compound and pest control agent |
-
2019
- 2019-08-07 CN CN201910727987.XA patent/CN110367269A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106659160A (en) * | 2014-06-30 | 2017-05-10 | 日产化学工业株式会社 | Insecticide, miticide, nematicide, molluscicide, disinfectant, or bactericide composition, and pest control method |
| CN105707118A (en) * | 2016-03-25 | 2016-06-29 | 江西正邦生物化工有限责任公司 | Pesticide composition containing phosmet and bifenazate |
| JP2018108989A (en) * | 2017-01-05 | 2018-07-12 | 日産化学工業株式会社 | Unpleasant pest control agent and unpleasant pest control method |
| JP2019048883A (en) * | 2018-11-30 | 2019-03-28 | 日産化学株式会社 | Isoxazoline-substituted benzamide compound and pest control agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111328813A (en) * | 2020-04-18 | 2020-06-26 | 江西正邦作物保护有限公司 | Acaricidal synergist containing plant source |
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Application publication date: 20191025 |