CN105648646A - Anti-mite antibacterial healthy knitting fabric and preparation method thereof - Google Patents

Anti-mite antibacterial healthy knitting fabric and preparation method thereof Download PDF

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Publication number
CN105648646A
CN105648646A CN201610181949.5A CN201610181949A CN105648646A CN 105648646 A CN105648646 A CN 105648646A CN 201610181949 A CN201610181949 A CN 201610181949A CN 105648646 A CN105648646 A CN 105648646A
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Prior art keywords
antibacterial
demodicid mite
mite
preparation
fiber
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CN105648646B (en
Inventor
董勤霞
沈碧如
林世芬
马仁和
徐相琴
胡永海
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Ningbo Daqian Textile Co Ltd
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Ningbo Daqian Textile Co Ltd
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/004Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8228Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
    • D06P3/8233Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye using dispersed dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
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    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses an anti-mite antibacterial healthy knitting fabric and a preparation method thereof. Anti-bacterium and bacterium-resistant silver fibers, anti-bacterium and bacterium-resistant polyester fibers, jute fibers and/or cotton fibers and/or regenerated cellulose fibers are adopted as raw materials to be woven into a gray fabric, then preprocessing, dyeing, softening finishing, anti-mite antibacterial finishing and drying shaping are conducted, and the anti-mite antibacterial healthy knitting fabric is obtained. According to the anti-mite antibacterial healthy knitting fabric and the preparation method thereof, independently designed separant and an anti-mite finishing agent are adopted, biological activity of the anti-mite finishing agent and binding firmness of textiles are guaranteed, the relatively durable anti-mite effect is achieved, direct contact between the human body and mites on the fabric can be reduced, sensibility of the skin is protected, and safety of contact with the human body is guaranteed.

Description

A kind of antibacterial healthy knitted fabric of anti-demodicid mite and preparation method thereof
Technical field
The invention belongs to textile technology field, be specifically related to a kind of antibacterial healthy knitted fabric of anti-demodicid mite and preparation method thereof.
Background technology
People are when contacting bookcase or suitcase room dirt a long time ago, and the situation such as sneeze, rhinorrhea will occur, and once suspect the anaphylaxis being probably caused by room dirt. But do not know what main allergen is, until just know that the main allergen in room dirt is dust mite in 1969 always.
Dust mite is a kind of biology that health is extremely harmful, is the spontaneous demodicid mite of a kind of gnawing property, is with powder-type material for food, such as animal scurf, flour, cotton young cake and fungus etc. Its energy transmitted virus, antibacterial, can cause the multiple diseases such as bronchial asthma, rhinitis, dermatitis, folliculitis, scabies. According to data introduction, having the asthma patient of 60% that dust mite can be produced anaphylaxis, the childhood asthma of about 80% is due to dust mite allergy. The asthma prevalence of China is significantly high, is the second largest respiratory tract disease of China. Dust mite is widely distributed, is mostly derived from living environment. Household's demodicid mite class in room dirt is distributed widely in the place having crowd to live, and is strong allergen, causes the general allergic effect of human body. Including allergic asthma, allergia nose bulbar conjunctiva inflammation, atopic eczema, dermatitis, allergic urticaria etc., demodicid mite property allergic effect accounts for about 80% that this disease is planted. The asthma of 50%-80% is all caused by dust mite according to estimates, and it can also cause many kinds of eczemas, Radix Glycyrrhizae heat, Hay Fever and other anaphylactic disease. Causing and breathe heavily the Digestive system that albumen is dust mite enteroendocrine, its effect is very strong. The Therapeutic Method that the disease caused currently for dust mite allergy is not good, can only carry out the quantity that prevention is exactly necessary controlling dust mite. Therefore, it is very urgent for developing a kind of knitwear with the antibacterial healthy functions of anti-demodicid mite.
Along with the raising that pathogenic bacterium biohazard is recognized by people, to the prescription of textile also by traditional practicality and attractive in appearance, more they tend to pay attention to the polyfunctional demand side of safety and health. For the demand in market, the present invention is from antibacterial, the selection of antiseptic raw material, the fabric texture of fabric, the formulation of weaving process, dyeing and Final finishing multilayer technology, and research and development have the healthy knitted fabric that anti-demodicid mite is antibacterial.
Summary of the invention
The present invention solves the problems referred to above of the prior art, it is proposed to a kind of antibacterial healthy knitted fabric of anti-demodicid mite and preparation method thereof.
Present invention employing has the silver-colored fiber of antibacterial bacteriostatic of bacteria resistance function, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and cotton fiber and regenerated celulose fibre is raw material, research and development knitting and weaving technique and applicable fabric structure, after pre-treatment, dyeing, carry out the functional treatment of anti-mite finishing agent, binding agent and surfactant again, the antibacterial healthy knitted fabric of anti-demodicid mite prepared, it is possible to reach to keep persistently, anti-demodicid mite fungistatic effect fast and efficiently.
For achieving the above object, the present invention is by the following technical solutions:
The preparation method that the first aspect of the invention is to provide a kind of antibacterial healthy knitted fabric of anti-demodicid mite, comprises the following steps:
(1) weaving: adopting the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and/or cotton fiber and/or regenerated celulose fibre yarn or its long filament is raw material, by intertexture or scribbled braiding, is woven into 150g/m2-250g/m2Grey cloth;
(2) pre-treatment: grey cloth is placed in bath raio 1:5-10, temperature is process 30-60 minute in the solution of 50 DEG C-105 DEG C, and hot water wash, cold water are washed; Described solution composition is: interleaving agent M5-10g/L, penetrating agent 0.5-3g/L, and deoil yarn agent 0.5-3g/L, tea saponin 2-8g/L, silicone based defoamer 0.5-2g/L;
(3) dyeing: after being placed in the dye liquor of bath raio 1:5-10,100-135 DEG C by the grey cloth after pre-treatment to carry out dyeing 30-60 minute, be placed in 80 DEG C of reduction cleaning liquid 15-30 minute, washing; Described dye liquor measures as 1-10% with (o.w.f) containing disperse dyes X, dispersant NNO0.5-2g/L, glacial acetic acid HAC0.5-1g/L, regulate PH5-6; Described reduction cleaning liquid contains caustic lye of soda 0.5-6.0g/L, sodium hydrosulfite 0.5-2g/L;
(4) soft finish: by dyeing the grey cloth after washing with the speed of 20m/min, soft finish is carried out by soft groove, containing interior amido silicon oil 10-42g/L in softening agent in described soft groove, temperature 25-35 DEG C, and the fabric after soft finish is carried out dehydration, drying;
(5) anti-demodicid mite antibacterial finish: the grey cloth after soft finish is put into bath raio 1:4-10, PH6 (0.5g/LHAC acetic acid), temperature is run 15-30 minute in the anti-demodicid mite bacteriostatic solution of 40-50 DEG C, dehydration (or with the speed of 20m/min by groove two soak two roll carry out anti-demodicid mite antibacterial finish); Wherein, described anti-demodicid mite bacteriostatic solution consists of: anti-mite finishing agent 20-140g/L, binding agent 10-30g/L and surfactant 1-4g/L; Liquid carrying rate is 55-75%;
(6) setting is dried: dehydration or the grey cloth after padding are dried, dry temperature 95 DEG C, time 20-30s; Grey cloth tentering on forming machine after drying is shaped, temperature 115-195 DEG C, speed 4-25m/min.
Further, in described step (1), grey cloth is formed by the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and regenerated celulose fibre 10-40%:10-40%:20-50%:20-50% by mass percentage weaving.
Further, described step (1) adopt two-sided many needle tracks knitting machine be woven into 150g/m2-250g/m2Two-sided tissue grey cloth, its two sides all shows front coil, the mixed yarn that a veil electric is silver fiber and flaxen fiber is constituted, the mixed yarn that another side yarn is the polyester fiber of antibacterial bacteriostatic and regenerated celulose fibre is constituted.
Further, described in described step (1), knitting fabric is with the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and regenerated celulose fibre for raw material, wherein, the mass percent of described silver fiber, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and regenerated celulose fibre is 15%:20%:30%:35%.
Further, one or more in flax fiber, oil flax fibre, china-hemp fibers, ramee, apocynum fibre of flaxen fiber in described step (1).
Further, in described step (1), regenerated celulose fibre is selected from More for one or more in fiber, tencel fiber, regenerated bamboo fiber, viscose rayon.
Further, in described step (2), interleaving agent M is formulated by 5-10 part trishydroxymethylaminomethane, 15-25 part acrylic acid and styrene copolymer, 5-10 part ethanol, 3-5 part nanometer silicon carbide, 3-5 part tributyl, 5-10 part water by weight.
Further, described step (2) interleaving agent M is formulated by 8 parts of trishydroxymethylaminomethane, 20 parts of acrylic acid and styrene copolymer, 7 parts of ethanol, 4 parts of nanometer silicon carbides, 4 parts of tributyls, 8 parts of water by weight.
Further, described nanometer silicon carbide particle diameter is 30-70nm.
Further, measuring as 3% with (o.w.f) containing disperse dyes X in the dye liquor of described step (3), dispersant NNO1g/L, glacial acetic acid HAC0.5g/L regulate PH5-6 (or ammonium dihydrogen phosphate 2g/L); Described reduction cleaning liquid contains caustic lye of soda 1.2g/L, sodium hydrosulfite 0.8g/L.
Further, menthyl-3 that in described step (5), anti-mite finishing agent is foretold amide Econazole chrysanthemum ester by 20-30 part polyoxyethylene polyamines, 20-30 part alkoxyl pyrrole by weight, 10-20 part Eucalyptus is extracted, 8-alcohol and different Mentha arvensis L. syn.M.haplocalyxBrig alcohol and citronellol mixture (comprise the vegetable matter that Cypress ethereal oil, Fructus Kaki be puckery, Pyrethrum is extracted), 10-15 part polyacrylic resin, 5-10 part EDTA and 2-5 part diethanolamine composition.
Further, menthyl-3 that in described step (5), anti-mite finishing agent mark by weight is foretold amide Econazole chrysanthemum esters by 25 parts of polyoxyethylene polyamines, 25 parts of alkoxyl pyrroles, 15 portions of Eucalyptuss extract, 8-alcohol and different Mentha arvensis L. syn.M.haplocalyxBrig alcohol and citronellol mixture (comprise the vegetable matter that Cypress ethereal oil, Fructus Kaki be puckery, Pyrethrum is extracted), 13 parts of polyacrylic resins, 7 parts of EDTA and 3 parts of diethanolamine compositions.
Wherein, the menthyl-3 that described Eucalyptus is extracted, 8-alcohol and different Mentha arvensis L. syn.M.haplocalyxBrig alcohol and citronellol mixture, for taking the supernatant that eucalyptus leaves extracts after high temperature decocting in water in distilled water, concrete preparation method is: by 15g eucalyptus leaves raw material high temperature decocting in water 10-20 minute in 1000ml, the distilled water of 100 DEG C, extract the supernatant after decocting in water, obtain menthyl-3 that Eucalyptus is extracted, 8-alcohol and different Mentha arvensis L. syn.M.haplocalyxBrig alcohol and citronellol mixture.
Further, described step (5) binding agent is super soft environment-protective binding agent TEP, and addition is 15-25g/L.
Further, described step (5) surfactant is alkyl glucoside surfactant, and addition is 2.5-3g/L.
Further, in described step (5), solution composition is anti-mite finishing agent 120g/L, binding agent 20g/L and surfactant 3g/L.
The second aspect of the invention is to provide a kind of antibacterial healthy knitted fabric of anti-demodicid mite prepared such as said method.
The third aspect of the invention is to provide the application on clothing, home textile articles for use, sports goods, health care, demodicid mite antibacterial, anti-of a kind of described antibacterial healthy knitted fabric of anti-demodicid mite.
The present invention adopts technique scheme, compared with prior art, has the following technical effect that
The antibacterial healthy knitted fabric of the anti-demodicid mite of the present invention adopts the fiber with bacteria resistance function to be that raw material is woven into suitable fabric structure, and adopt special anti-demodicid mite antibacterial finish and dyeing to process, and dust mite is had high activity by the anti-mite finishing agent adopted, anti-demodicid mite is effective, and production and processing condition acidproof, alkaline-resisting, resistant to elevated temperatures can be born, good with other additive compatibility, there is good safety and persistency;The binding agent of the present invention and surfactant optimal proportion, it is ensured that the fastness that the biological activity of anti-mite finishing agent is combined with textile, reached relatively durable anti-demodicid mite effect; The knitting fabric of the present invention has the multiple pathogenic bacteria of suppression, effect of anti-demodicid mite simultaneously; Can walk quickly and keep away, reduce human body and directly contact with the acarid on fabric, the sensitivity of protection skin, it is ensured that the safety of human contact.
Detailed description of the invention
Below by specific embodiment, the present invention being carried out detailed and concrete introduction, so that being better understood from the present invention, but following embodiment is not limiting as the scope of the invention.
The preparation of the antibacterial healthy knitted fabric of the anti-demodicid mite of embodiment 1, comprises the following steps:
(1) weaving: with the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flax fiber and regenerated celulose fibre for raw material, be 15%:20%:30%:35% by mass percentage, adopt two-sided many needle tracks knitting machine to be woven into 200g/m2Two-sided tissue grey cloth, its two sides all shows front coil, the mixed yarn that a veil electric is silver fiber and flax fiber is constituted, the mixed yarn that another side yarn is polyester fiber and More is constituted for fiber;
(2) pre-treatment: grey cloth is placed in bath raio 1:6, temperature is process 40 minutes in the solution of 100 �� 3 DEG C, and hot water wash 15 minutes, cold water wash 15 minutes; Wherein solution composition is: interleaving agent M6g/L, penetrating agent 1g/L, and deoil yarn agent 1.2g/L, tea saponin 4g/L (or hydrogen peroxide 5%, with fabric weight o.w.f, stabilizer 1.5g/L, sodium hydroxide 1g/L, soda 2g/L), silicone based defoamer 0.5g/L.
(3) dyeing: the grey cloth after pre-treatment is placed in bath raio 1:6, after the dye liquor of 130 DEG C carrying out dyeing 50 minutes, reduction cleaning 80 DEG C, 15 minutes, it is washed to neutrality; Measuring as 5% with (o.w.f) containing disperse dyes X in described dye liquor, dispersant NNO0.5g/L, glacial acetic acid HAC0.8g/L regulate PH5-6 (or ammonium dihydrogen phosphate 2g/L); Described reduction cleaning liquid contains caustic lye of soda 1.5g/L, sodium hydrosulfite 0.8g/L;
(4) soft finish: by dyeing the grey cloth after washing with the speed of 20m/min, soft finish is carried out by soft groove, containing interior amido silicon oil 25g/L, temperature 25 DEG C in softening agent in described soft groove, and the fabric after soft finish is carried out dewatered drying;
(5) anti-demodicid mite antibacterial finish: above-mentioned grey cloth is put into bath raio 1:5, PH6 (0.5g/LHAC glacial acetic acid), temperature is run 30 minutes in the solution of 40-50 DEG C, dehydration (or with the speed of 20m/min by groove two soak two roll carry out anti-demodicid mite antibacterial finish); Wherein anti-demodicid mite bacteriostatic solution consists of: anti-mite finishing agent 50g/L, binding agent 20g/L and surfactant 1.5g/L; Liquid carrying rate is 60-65%.
(6) dry setting: dried by the grey cloth after dehydration, dry temperature 95 DEG C, time 20-30s; Grey cloth tentering on forming machine after drying is shaped, temperature 115-160 DEG C, speed 15m/min, prepare the antibacterial healthy knitted fabric 1 of anti-demodicid mite.
The preparation of the antibacterial healthy knitted fabric of the anti-demodicid mite of embodiment 2, comprises the following steps:
(1) weaving: with the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, china-hemp fibers and regenerated celulose fibre for raw material, adopts two-sided many needle tracks knitting machine to be woven into 200g/m for 15%:15%:35%:35% by mass percentage2Two-sided tissue grey cloth, its two sides all shows front coil, the mixed yarn that a veil electric is silver fiber and china-hemp fibers is constituted, the mixed yarn that another side yarn is polyester fiber and More is constituted for fiber;
(2) pre-treatment: grey cloth is placed in bath raio 1:9, temperature is process 50 minutes in the solution of 85 DEG C, and hot water wash 15 minutes, cold water wash 15 minutes; Described solution composition is: interleaving agent M6g/L, penetrating agent 2g/L, and deoil yarn agent 2g/L, tea saponin 5g/L, silicone based defoamer 1.5g/L;
(3) dyeing: the grey cloth after pre-treatment is placed in bath raio 1:6, after carrying out dyeing 40 minutes, is placed in 80 DEG C of reduction cleaning liquid 20 minutes, is washed to neutrality in the dye liquor of 120 DEG C; Described dye liquor measures as 1% with (o.w.f) containing disperse dyes X, dispersant NNO1g/L, glacial acetic acid HAC0.8g/L, regulate PH5-6; Described reduction cleaning liquid contains caustic lye of soda 4g/L, sodium hydrosulfite 1g/L;
(4) soft finish: by dyeing the grey cloth after washing with the speed of 20m/min, soft finish is carried out by soft groove, containing interior amido silicon oil 25g/L in softening agent in described soft groove, temperature 25-35 DEG C, and the fabric after soft finish is carried out dehydration, drying;
(5) anti-demodicid mite antibacterial finish: the grey cloth after soft finish is put into bath raio 1:5, PH6 (0.5g/LHAC glacial acetic acid), temperature is run 25 minutes in the anti-demodicid mite bacteriostatic solution of 45 DEG C, dehydration (or with the speed of 20m/min by groove two soak two roll carry out anti-demodicid mite antibacterial finish); Wherein, described anti-demodicid mite bacteriostatic solution consists of: anti-mite finishing agent 110g/L, binding agent 20g/L and surfactant 3g/L; Liquid carrying rate is 55-75%;
(6) setting is dried: dehydration or the grey cloth after padding are dried, dry temperature 95 DEG C, time 20-30s; Grey cloth tentering on forming machine after drying is shaped, temperature 115-180 DEG C, speed 4-25m/min, prepare the antibacterial healthy knitted fabric 2 of anti-demodicid mite.
The preparation of the antibacterial healthy knitted fabric of the anti-demodicid mite of embodiment 3, comprises the following steps:
(1) weaving: with the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, ramee and regenerated celulose fibre for raw material, adopts two-sided many needle tracks knitting machine to be woven into 200g/m for 20%:20%:30%:30% by mass percentage2Two-sided tissue grey cloth, its two sides all shows front coil, the mixed yarn that a veil electric is silver fiber and ramee is constituted, and another side yarn is the mixed yarn that polyester fiber and regenerated bamboo fiber are constituted;
(2) pre-treatment: grey cloth is placed in bath raio 1:6, temperature is process 40 minutes in the solution of 80 DEG C, and hot water wash 15 minutes, cold water wash 15 minutes; Described solution composition is: interleaving agent M8g/L, penetrating agent 2g/L, and deoil yarn agent 1g/L, tea saponin 4g/L, silicone based defoamer 1g/L;
(3) dyeing: the grey cloth after pre-treatment is placed in bath raio 1:8, after carrying out dyeing 50 minutes, is placed in 80 DEG C of reduction cleaning liquid 20 minutes, is washed to neutrality in the dye liquor of 120 DEG C; Described dye liquor measures as 4% with (o.w.f) containing disperse dyes X, dispersant NNO1.5g/L, glacial acetic acid HAC1g/L, regulate PH5-6; Described reduction cleaning liquid contains caustic lye of soda 5g/L, sodium hydrosulfite 1g/L;
(4) soft finish: by dyeing the grey cloth after washing with the speed of 20m/min, soft finish is carried out by soft groove, containing interior amido silicon oil 20g/L, temperature 30 DEG C in softening agent in described soft groove, and the fabric after soft finish is carried out dehydration, drying;
(5) anti-demodicid mite antibacterial finish: the grey cloth after soft finish is put into bath raio 1:5, PH6 (0.5g/LHAC glacial acetic acid), temperature is run 15 minutes in the anti-demodicid mite bacteriostatic solution of 50 DEG C, dehydration (or with the speed of 20m/min by groove two soak two roll carry out anti-demodicid mite antibacterial finish);Wherein, described anti-demodicid mite bacteriostatic solution consists of: anti-mite finishing agent 120g/L, binding agent 15g/L and surfactant 3g/L; Liquid carrying rate is 55-75%;
(6) setting is dried: dehydration or the grey cloth after padding are dried, dry temperature 95 DEG C, time 20-30s; Grey cloth tentering on forming machine after drying is shaped, setting temperature 150-185 DEG C, speed 4-25m/min, prepare the antibacterial healthy knitted fabric 3 of anti-demodicid mite.
The indices of the antibacterial healthy knitted fabric of anti-demodicid mite that above-described embodiment 1, embodiment 2 and embodiment 3 prepare is tested, concrete each embodiment test result such as table 1 below:
The antibacterial healthy knitted fabric test result of the anti-demodicid mite of table 1
The indices of the antibacterial healthy knitted fabric of anti-demodicid mite that above-described embodiment 1, embodiment 2 and embodiment 3 prepare is carried out anti-demodicid mite test, test index according to GB GBT24253-2009, concrete each embodiment test result such as table 2 below:
The anti-demodicid mite test result of the antibacterial healthy knitted fabric of the anti-demodicid mite of table 2
Detection Embodiment 1 Embodiment 2 Embodiment 3
Scattering ratio before washing 95% 98% 92%
Suppression ratio before washing 95% 95% 96%
Wash 20 scattering ratios 60% 63% 59%
Wash 20 suppression ratio 65% 66% 60%
By above-mentioned table 1 fabric each index test result and table 2 anti-demodicid mite test result it can be seen that adopt special anti-demodicid mite to press down and process with interleaving agent, it is ensured that the fastness that the biological activity of anti-mite finishing agent is combined with textile, reach relatively durable anti-demodicid mite effect; Simultaneously the knitting fabric of the present invention before washing mosquito-proof scattering ratio and anophelifuge suppression ratio up to 95%; through washing scattering ratio and the anophelifuge suppression ratio that can keep more than 60% after 20 times; there is the multiple pathogenic bacteria of suppression; effect of anti-demodicid mite; can walk quickly and keep away, reduce human body and directly contact with the acarid on fabric; the sensitivity of protection skin, it is ensured that the safety of human contact.
Above specific embodiments of the invention being described in detail, but it is intended only as example, the present invention is not restricted to particular embodiments described above. To those skilled in the art, any equivalent modifications that the present invention is carried out and replacement are also all among scope of the invention. Therefore, the equalization made without departing from the spirit and scope of the invention converts and amendment, all should contain within the scope of the invention.

Claims (10)

1. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite, it is characterised in that comprise the following steps:
(1) weaving: adopting the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and/or cotton fiber and/or regenerated celulose fibre is raw material, by being woven into 150g/m2-250g/m2Grey cloth;
(2) pre-treatment: grey cloth is placed in bath raio 1:5-10, temperature is process 30-60 minute in the solution of 50 DEG C-105 DEG C, and hot water wash, cold water are washed; Described solution composition is: interleaving agent M5-10g/L, penetrating agent 0.5-3g/L, and deoil yarn agent 0.5-3g/L, tea saponin 2-8g/L, silicone based defoamer 0.5-2g/L;
(3) dyeing: after being placed in the dye liquor of bath raio 1:5-10,100-135 DEG C by the grey cloth after pre-treatment to carry out dyeing 30-60 minute, be placed in 80 DEG C of reduction cleaning liquid 15-30 minute, washing; Described dye liquor measures as 1-10% with (o.w.f) containing disperse dyes X, dispersant NNO0.5-2g/L, glacial acetic acid HAC0.5-1g/L, regulate PH5-6; Described reduction cleaning liquid contains caustic lye of soda 0.5-6.0g/L, sodium hydrosulfite 0.5-2g/L;
(4) soft finish: by dyeing the grey cloth after washing with the speed of 20m/min, soft finish is carried out by soft groove, containing interior amido silicon oil 10-42g/L in softening agent in described soft groove, temperature 25-35 DEG C, and the fabric after soft finish is carried out dehydration, drying;
(5) anti-demodicid mite antibacterial finish: the grey cloth after soft finish is put into bath raio 1:4-10, PH6 (0.5g/LHAC acetic acid), temperature is run 15-30 minute in the anti-demodicid mite bacteriostatic solution of 40-50 DEG C, dehydration (or with the speed of 20m/min by groove two soak two roll carry out anti-demodicid mite antibacterial finish); Wherein, described anti-demodicid mite bacteriostatic solution consists of: anti-mite finishing agent 20-140g/L, binding agent 10-30g/L and surfactant 1-4g/L; Liquid carrying rate is 55-75%;
(6) setting is dried: dehydration or the grey cloth after padding are dried, dry temperature 95 DEG C, time 20-30s; Grey cloth tentering on forming machine after drying is shaped, setting temperature 115-195 DEG C, speed 4-25m/min.
2. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterized in that, in described step (1), grey cloth is formed by the silver-colored fiber of antibacterial bacteriostatic, the polyester fiber of antibacterial bacteriostatic, flaxen fiber and regenerated celulose fibre 10-40%:10-40%:20-50%:20-50% by mass percentage weaving.
3. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterized in that, in described step (1), regenerated celulose fibre is selected from More for one or more in fiber, tencel fiber, regenerated bamboo fiber, viscose rayon.
4. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterized in that, in described step (2), interleaving agent M is formulated by 5-10 part trishydroxymethylaminomethane, 15-25 part acrylic acid and styrene copolymer, 5-10 part ethanol, 3-5 part nanometer silicon carbide, 3-5 part tributyl, 5-10 part water by weight.
5. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 4, it is characterised in that described nanometer silicon carbide particle diameter is 30-70nm.
6. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterized in that, measuring as 3% with (o.w.f) containing disperse dyes X in the dye liquor of described step (3), dispersant NNO1g/L, glacial acetic acid HAC0.5g/L regulate PH5-6 (or ammonium dihydrogen phosphate 2g/L); Described reduction cleaning liquid contains caustic lye of soda 1.2g/L, sodium hydrosulfite 0.8g/L.
7. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterized in that, menthyl-3 that in described step (5), anti-mite finishing agent is foretold amide Econazole chrysanthemum ester by 20-30 part polyoxyethylene polyamines, 20-30 part alkoxyl pyrrole by weight, 10-20 part Eucalyptus is extracted, 8-alcohol and different Mentha arvensis L. syn.M.haplocalyxBrig alcohol and citronellol mixture, 10-15 part polyacrylic resin, 5-10 part EDTA and 2-5 part diethanolamine composition.
8. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterised in that described step (5) binding agent is super soft environment-protective binding agent TEP.
9. the preparation method of the antibacterial healthy knitted fabric of anti-demodicid mite according to claim 1, it is characterised in that described step (5) surfactant is alkyl glucoside surfactant.
10. the antibacterial healthy knitted fabric of anti-demodicid mite that prepared by a method as described in any one of claim 1-9.
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CN107338650A (en) * 2016-11-28 2017-11-10 江西服装学院 A kind of New Regenerated Cellulosic Fibers and preparation method thereof
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CN107326505A (en) * 2017-09-06 2017-11-07 南通冠洲国际贸易有限公司 A kind of moisture absorption Mould-proof shell fabric
CN108950803A (en) * 2018-08-02 2018-12-07 南通罗都服饰有限公司 A kind of anti-radiation health care composite material
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