CN105638693A - Insecticidal combination containing chlorofluoro cyantraniliprole and fipronil - Google Patents
Insecticidal combination containing chlorofluoro cyantraniliprole and fipronil Download PDFInfo
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- CN105638693A CN105638693A CN201610187065.0A CN201610187065A CN105638693A CN 105638693 A CN105638693 A CN 105638693A CN 201610187065 A CN201610187065 A CN 201610187065A CN 105638693 A CN105638693 A CN 105638693A
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- ethiprole
- insect amide
- chlorine fluorine
- cyanogen insect
- fluorine cyanogen
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of insecticide application, and particularly relates to an insecticidal combination containing chlorofluoro cyantraniliprole and fipronil. The insecticidal combination is formed by using chlorofluoro cyantraniliprole and fipronil as active ingredients for bi-element compounding, and a mass ratio of chlorofluoro cyantraniliprol to fipronil is 1:50-50:1. The insecticidal combination has obvious synergistic effect, and prevention and control effect of the insecticidal combination is obviously better than that when a single preparation is used solely, so that insecticide consumption is lowered, prevention and control cost is lowered, insecticide resistance of pests is delayed, and environment pollution is reduced.
Description
Technical field
The invention belongs to pesticides application technical field, relate to a kind of composition pesticide, the Pesticidal combination of a kind of containing chlorine fluorine cyanogen insect amide and ethiprole specifically.
Background technology
Chlorine fluorine cyanogen insect amide (ZJ4042) { the chloro-N1-of 3-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide } is that its insecticidal spectrum is mainly lepidoptera pest (especially the snout moth's larva of rice) by a kind of phthalic diamides insecticide of Zhejiang Research Institute of Chemical Industry, Ltd.'s independent development.
Ethiprole is that a kind of Phenylpyrazole insecticides, insecticidal spectrum are wide, to insect based on stomach poison function, have concurrently and tag and certain systemic action, its mechanism of action is in that the chloride metabolism hindering insecticide ��-aminobutyric acid to control, therefore the important pests such as aphid, leafhopper, plant hopper, lepidopterous larvae, flies and coleoptera there is significantly high insecticidal activity, to crop without poisoning. This medicament can impose on soil, it is possible to foliar spray. Impose on soil and can effectively prevent and treat corn root leaf A, wireworm and cutworm. During foliage spray, diamondback moth, cabbage butterfly, rice thrips etc. all there are is high-level preventive effect, and the lasting period is long.
Being carried out by the pesticide active ingredient of the different mechanisms of action composite is develop pesticide new product at present and prevent and treat a kind of effectively quick way of resistance pest and disease damage. Different pesticide active ingredients carry out composite after, three kinds of type of action can be shown: summation action, potentiation and antagonism. Generally, only by substantial amounts of test just can learn different pesticide active ingredient composite after type of action. The Recompounded pesticide of screening tool potentiation, it is possible to significantly improve prevention effect, reduce Pesticide use amount, reduce cost accounting, it is also possible to expanding prevention is composed, and delays the generation of pest and disease damage resistance, is one of the important means of current integrated pest prevention and control.
Inventor is tested and field control effectiveness test by a large amount of indoor biometricses, filter out the Pesticidal combination of chlorine fluorine cyanogen insect amide and ethiprole, said composition has potentiation within the specific limits, and the Lepidoptera on crops, Semiptera, homoptera pest are respectively provided with good preventive effect by the compositions of the present invention. Up to now, the Pesticidal combination being effective ingredient with chlorine fluorine cyanogen insect amide and ethiprole, at home and abroad there is not yet relevant report.
Summary of the invention
It is an object of the invention to outstanding problem big for common insecticides dosage, that cost accounting is high, insecticidal spectrum is narrow, resistance generation is fast, providing the Pesticidal combination of a kind of containing chlorine fluorine cyanogen insect amide and ethiprole, said composition tool improves prevention effect, expansion insecticidal spectrum, delaying drug resistance generation, reduces pesticide dosage and the advantage reducing cost.
The technical scheme is that
The Pesticidal combination of a kind of containing chlorine fluorine cyanogen insect amide and ethiprole, this Pesticidal combination is that described chlorine fluorine cyanogen insect amide and ethiprole mass ratio are 1:50-50:1 with chlorine fluorine cyanogen insect amide and ethiprole for effective ingredient.
As preferably, in described Pesticidal combination, the mass ratio of chlorine fluorine cyanogen insect amide and ethiprole is 1:30-50:1.
Preferred as the best, in described Pesticidal combination, the mass ratio of chlorine fluorine cyanogen insect amide and ethiprole is 1:10.
The invention also discloses a kind of pesticidal preparations comprising described Pesticidal combination, wherein the quality of chlorine fluorine cyanogen insect amide and ethiprole accounts for the 1-80% of pesticidal preparations gross mass, and all the other are the auxiliary element allowing in pesticide to use.
As preferably, described auxiliary element is made up of one or more in solvent, cosolvent, emulsifying agent, wetting agent, dispersant, thickening agent, antifreezing agent, carrier and disintegrating agent.
As preferably, described solvent is esters or sulfone class, and described esters is sec-butyl acetate and ethyl acetate; Sulfone class is dimethyl sulfoxide.
As preferably, described cosolvent is ketone or higher alcohol, and described ketone is Ketohexamethylene and N-ketopyrrolidine; Higher alcohol is n-butyl alcohol.
As preferably, described emulsifying agent, wetting agent, dispersant are nonionic surfactant or anion surfactant, and described nonionic surfactant is castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxyethylene poly-oxygen propylene aether, aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer, tristyrylphenyl polyoxyethylene ether and calcium dodecyl benzene sulfonate castor oil polyoxyethylene ether; Anion surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate sodium lauryl sulphate, thermally coupled distillation columns and aliphatic alcohol polyoxyvinethene phosphate ammonium salt.
As preferably, described thickening agent is xanthan gum, arabic gum, Magnesiumaluminumsilicate and polyvinyl alcohol.
As preferably, described antifreezing agent is polyhydric alcohol, and described polyhydric alcohol is ethylene glycol, glycerol and propylene glycol.
As preferably, described carrier is white carbon, Kaolin or kieselguhr.
As preferably, described disintegrating agent is ammonium sulfate, sodium chloride or ammonium sulfate.
Described insecticides can adopt method well known in the art to prepare into the formulations of pesticide of applicable agricultural use. As preferably, the formulations of pesticide that can prepare are aqueous emulsion, microemulsion, suspending agent, wettable powder or water dispersible granules.
Lepidoptera on crops, Semiptera, homoptera pest are respectively provided with good preventive effect by described Pesticidal combination.
Compared with prior art, the invention has the beneficial effects as follows:
1. the Pesticidal combination of the present invention is after two kinds of effective ingredient are composite, has obvious potentiation, improves prevention effect.
2. no interactions resistance between two kinds of effective ingredient of the Pesticidal combination of the present invention, thus composite after use can the generation of delaying drug resistance and development.
3. the Pesticidal combination of the present invention can reduce the consumption that makes of pesticide, reduces cost accounting, reduces environmental pollution, thus alleviating the pressure to environment.
Detailed description of the invention
Present invention specific examples below is described in detail its beneficial effect.
One, indoor virulence test measures
1. experiment material: test medicine adopts 95% chlorine fluorine cyanogen insect amide and the former medicine of 95% ethiprole; Examination worm beet armyworm is the population adopting man-made feeds to raise continuously in laboratory, and examination worm is 4-5 instar larvae;Prodenia litura is the population adopting man-made feeds to raise continuously in laboratory, and examination worm is 3 instar larvaes; Striped rice borer is to adopt rice seedling to raise continuously in laboratory, and examination worm is 3 instar larvaes.
2. test method: adopted leaf butterfly nebulization, each single dose arranges 5 different concentration with Mixed Pharmacy, often processes and sets 3 repetitions, makes blank with clear water.
3. operating procedure: beet armyworm adopts drop method, and the pronotary at 5 instar larvaes drips 1 �� L medicinal liquid, feeds the man-made feeds of cleaning, 48h investigation examination worm mortality rate after process.
Prodenia litura, striped rice borer adopt leaching leaf butterfly feeding method, take cleaning cabbage and break into leaf butterfly, dry after medicine soaks 10s, put in plate, access Prodenia litura or striped rice borer 3 instar larvae, every ware puts 3 pieces of leaf butterflies, Prodenia litura that select indoor feeding, that healthy, age is consistent or striped rice borer 3 instar larvae are inoculated on leaf butterfly, and every leaf butterfly inoculates 20, then the culture dish processed is put into 12h/12h lighting box and cultivates, 48h checks dead borer population, calculates mortality rate. Often process and set 3 repetitions, make blank with clear water.
4. computational methods: test data has been analyzed with DPS statistical analysis software, calculate the LC50 of each medicament, evaluate the insecticidal activity of each medicament. And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) �� 100.
The percentage composition of B in the percentage composition+B medicament toxicity index �� mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index �� mixture.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] �� 100.
According to the NY/T1154.13-2008 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC)>=120 shows as potentiation; Co-toxicity coefficient (CTC)��80 shows as antagonism;<120 show as summation action to 80<co-toxicity coefficient (CTC).
5. result of the test (referring to table 1-3)
Table 1 chlorine fluorine cyanogen insect amide and the ethiprole indoor joint toxicity measuring to beet armyworm
Table 2 chlorine fluorine cyanogen insect amide and the ethiprole indoor joint toxicity measuring to Prodenia litura
Table 3 chlorine fluorine cyanogen insect amide and the ethiprole indoor joint toxicity measuring to striped rice borer
Toxicity Determination result shows: in said composition, the mass ratio of chlorine fluorine cyanogen insect amide and ethiprole is within the scope of 1:50-50:1, co-toxicity coefficient is all higher than 120, and namely the biological activity of beet armyworm, Prodenia litura and striped rice borer is all shown as potentiation by said composition; Especially the mass ratio of chlorine fluorine cyanogen insect amide and ethiprole is within the scope of 1:30-50:1, and co-toxicity coefficient is all more than 130, and potentiation becomes apparent from; Particularly when the mass ratio of chlorine fluorine cyanogen insect amide and ethiprole is 1:10, potentiation is the most obvious.
Two, embodiment prepared by pesticide
Embodiment 1: 1% chlorine fluorine cyanogen insect amide ethiprole aqueous emulsion
Embodiment 2: 10% chlorine fluorine cyanogen insect amide ethiprole aqueous emulsion
Embodiment 3: 15% chlorine fluorine cyanogen insect amide ethiprole aqueous emulsion
Described in above-described embodiment 1-3, the preparation method of aqueous emulsion is: after effective ingredient chlorine fluorine cyanogen insect amide and ethiprole solvent, cosolvent fully being dissolved, and input emulsifying agent, dispersant, wetting agent form oil phase after being sufficiently stirred for; Antifreezing agent is added to the water dissolving, forms aqueous phase; Aqueous phase is slowly added in oil phase, use high-speed shearing machine shear, aqueous emulsion.
Embodiment 4: 5% chlorine fluorine cyanogen insect amide ethiprole microemulsion
Embodiment 5: 8% chlorine fluorine cyanogen insect amide ethiprole microemulsion
Embodiment 6: 15% chlorine fluorine cyanogen insect amide ethiprole microemulsion
Described in above-described embodiment 4-6, the preparation method of microemulsion is: after active component chlorine fluorine cyanogen insect amide and ethiprole solvent, cosolvent fully being dissolved, and puts into emulsifying agent, forms oil phase after being sufficiently stirred for;Antifreezing agent is added to the water and obtains aqueous phase; Aqueous phase is slowly added in oil phase, use high-speed shearing machine shear, transparent microemulsion.
Embodiment 7: 20% chlorine fluorine cyanogen insect amide ethiprole suspending agent
Embodiment 8: 30% chlorine fluorine cyanogen insect amide ethiprole suspending agent
Embodiment 9: 50% chlorine fluorine cyanogen insect amide ethiprole suspending agent
Described in above-described embodiment 7-9, the preparation method of suspending agent is: after using jet mill to pulverize active component chlorine fluorine cyanogen insect amide and ethiprole, put in stirred tank, put into dispersant, wetting agent, antifreezing agent and water simultaneously, after being sufficiently stirred for, will material suction sand mill be fully ground, after having ground, in suction high-speed shearing machine, after adding thickening agent, carry out high speed shear, after having sheared, namely prepare suspending agent.
Embodiment 10: 50% chlorine fluorine cyanogen insect amide ethiprole wettable powder
Embodiment 11: 60% chlorine fluorine cyanogen insect amide ethiprole wettable powder
Embodiment 12: 80% chlorine fluorine cyanogen insect amide ethiprole wettable powder
Described in above-described embodiment 10-12, the preparation method of wettable powder is: by formula proportion, by effective ingredient and preparation auxiliary element mix homogeneously, pulverizes through jet mill, remixes uniformly, namely prepares wettable powder.
Embodiment 13: 25% chlorine fluorine cyanogen insect amide ethiprole water dispersible granules
Embodiment 14: 50% chlorine fluorine cyanogen insect amide ethiprole water dispersible granules
Embodiment 15: 70% chlorine fluorine cyanogen insect amide ethiprole water dispersible granules
Described in above-described embodiment 13-15, the preparation method of water dispersible granules is: by formula proportion, after effective ingredient and preparation auxiliary element mix homogeneously, pulverize through jet mill, mix homogeneously again, then, add a certain amount of water and this mixture is mediated, extruder grain, drying is sieved, and namely obtains water dispersible granules.
Three, field control effectiveness test
Embodiment 16: the complex preparation of chlorine fluorine cyanogen insect amide and the ethiprole prevention effect to beet armyworm
As can be seen from the above table, 50% chlorine fluorine cyanogen insect amide MTI-446 wettable powder uses 25ga.i./ha, 50% chlorine fluorine cyanogen insect amide MTI-446 water dispersible granules to use 30d after 25ga.i./ha medicine that the preventive effect of beet armyworm is superior to each single dose (comparison) and is used alone, while in test survey process, do not find that Oryza sativa L. is produced poisoning by this compound drug.
Embodiment 17: the complex preparation of chlorine fluorine cyanogen insect amide and the ethiprole prevention effect to rice-stem borer
As can be seen from the above table, 10% chlorine fluorine cyanogen insect amide ethiprole aqueous emulsion uses 25ga.i./ha, 25% chlorine fluorine cyanogen insect amide ethiprole water dispersible granules to use 30d after 25ga.i./ha medicine that the preventive effect of rice-stem borer is superior to each single dose (comparison) and is used alone, while in test survey process, do not find that Oryza sativa L. is produced poisoning by this compound drug.
In sum, the containing chlorine fluorine cyanogen insect amide of the present invention and the Pesticidal combination of ethiprole have synergistic function, and compared with existing unitary agent, pest control effect significantly improves, and to crop safety, highly popularization and application in agricultural production.
The foregoing is only presently preferred embodiments of the present invention, it is not limited to the scope of the substantial technological content of the present invention, the substantial technological content of the present invention is broadly to be defined in the right of application, any technology that other people complete or method, if defined with claims hereof scope is identical, or simply the replacement of a kind of equivalence, is regarded as being covered by among this right.
Claims (8)
1. the Pesticidal combination of a containing chlorine fluorine cyanogen insect amide and ethiprole, it is characterised in that: described Pesticidal combination is that the mass ratio of described chlorine fluorine cyanogen insect amide and ethiprole is 1:50-50:1 with chlorine fluorine cyanogen insect amide and ethiprole for effective ingredient.
2. Pesticidal combination according to claim 1, it is characterised in that: described effective ingredient chlorine fluorine cyanogen insect amide and ethiprole mass ratio be 1:30-50:1.
3. Pesticidal combination according to claim 1, it is characterised in that: described effective ingredient chlorine fluorine cyanogen insect amide and ethiprole mass ratio be 1:10.
4. the pesticidal preparations comprising the arbitrary described Pesticidal combination of claims 1 to 3, it is characterized in that: in described pesticidal preparations, the quality of effective ingredient chlorine fluorine cyanogen insect amide and ethiprole accounts for the 1-80% of pesticidal preparations gross mass, all the other are the auxiliary element allowing in pesticide to use.
5. pesticidal preparations according to claim 4, it is characterised in that: described pesticide allow the auxiliary element used be made up of one or more in solvent, cosolvent, emulsifying agent, wetting agent, dispersant, thickening agent, antifreezing agent, carrier and disintegrating agent; Described solvent is esters or sulfone class, described cosolvent is ketone or higher alcohol, described emulsifying agent, wetting agent, dispersant are nonionic surfactant or anion surfactant, described thickening agent is xanthan gum, arabic gum, Magnesiumaluminumsilicate and polyvinyl alcohol, described antifreezing agent is polyhydric alcohol, described carrier is white carbon, Kaolin or kieselguhr, and described disintegrating agent is ammonium sulfate, sodium chloride or ammonium sulfate.
6. pesticidal preparations according to claim 4, it is characterised in that: described esters is sec-butyl acetate and ethyl acetate; Sulfone class is dimethyl sulfoxide; Described ketone is Ketohexamethylene and N-ketopyrrolidine; Higher alcohol is n-butyl alcohol; Described nonionic surfactant is castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxyethylene poly-oxygen propylene aether, aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer, tristyrylphenyl polyoxyethylene ether and calcium dodecyl benzene sulfonate castor oil polyoxyethylene ether; Anion surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate sodium lauryl sulphate, thermally coupled distillation columns and aliphatic alcohol polyoxyvinethene phosphate ammonium salt; Described polyhydric alcohol is ethylene glycol, glycerol and propylene glycol.
7. pesticidal preparations according to claim 4, it is characterised in that: the dosage form of described pesticidal preparations is aqueous emulsion, microemulsion, suspending agent, wettable powder or water dispersible granules.
8. according to claim 4 pesticidal preparations in the application preventing and treating agriculturally insect.
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| CN201610187065.0A CN105638693A (en) | 2016-03-29 | 2016-03-29 | Insecticidal combination containing chlorofluoro cyantraniliprole and fipronil |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
| CN106538554A (en) * | 2016-09-29 | 2017-03-29 | 天峨县全盛蜂业科技有限公司 | A kind of miticide composition containing paichongding and chlorine fluorine cyanogen insect amide |
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| CN105152998A (en) * | 2015-08-25 | 2015-12-16 | 海利尔药业集团股份有限公司 | Methylthio-diafenthiuron pesticide and application thereof |
| CN105163582A (en) * | 2013-04-19 | 2015-12-16 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and fipronil or ethiprole |
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2016
- 2016-03-29 CN CN201610187065.0A patent/CN105638693A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105163582A (en) * | 2013-04-19 | 2015-12-16 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and fipronil or ethiprole |
| CN105152998A (en) * | 2015-08-25 | 2015-12-16 | 海利尔药业集团股份有限公司 | Methylthio-diafenthiuron pesticide and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
| CN106538554A (en) * | 2016-09-29 | 2017-03-29 | 天峨县全盛蜂业科技有限公司 | A kind of miticide composition containing paichongding and chlorine fluorine cyanogen insect amide |
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