CN105637045B - 制备乳液聚合产物的方法 - Google Patents

制备乳液聚合产物的方法 Download PDF

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CN105637045B
CN105637045B CN201480057202.8A CN201480057202A CN105637045B CN 105637045 B CN105637045 B CN 105637045B CN 201480057202 A CN201480057202 A CN 201480057202A CN 105637045 B CN105637045 B CN 105637045B
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weight
water
acid
polymer
shell
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CN105637045A (zh
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D·克洛斯
J·莱斯温
D·施佩克尔
K·罗施曼
M·杰斯特
H·威斯
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BASF SE
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/06Making microcapsules or microballoons by phase separation
    • B01J13/14Polymerisation; cross-linking
    • B01J13/16Interfacial polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/126Polymer particles coated by polymer, e.g. core shell structures
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/41Organic pigments; Organic dyes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/42Gloss-reducing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Cosmetics (AREA)
  • Paper (AREA)
CN201480057202.8A 2013-08-22 2014-08-18 制备乳液聚合产物的方法 Active CN105637045B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13181399.0 2013-08-22
EP13181399 2013-08-22
PCT/EP2014/067522 WO2015024882A1 (de) 2013-08-22 2014-08-18 Verfahren zur herstellung von emulsionspolymerisaten

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CN105637045A CN105637045A (zh) 2016-06-01
CN105637045B true CN105637045B (zh) 2020-03-24

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US (1) US10000600B2 (fi)
EP (1) EP3036293B1 (fi)
JP (1) JP6856377B2 (fi)
KR (1) KR102270311B1 (fi)
CN (1) CN105637045B (fi)
AU (1) AU2014310714B2 (fi)
CA (1) CA2921876C (fi)
ES (1) ES2974272T3 (fi)
FI (1) FI3036293T3 (fi)
MX (1) MX2016002324A (fi)
PH (1) PH12016500317A1 (fi)
PL (1) PL3036293T3 (fi)
PT (1) PT3036293T (fi)
RU (1) RU2690457C2 (fi)
SA (1) SA516370587B1 (fi)
WO (1) WO2015024882A1 (fi)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
WO2017073443A1 (ja) * 2015-10-29 2017-05-04 日本ゼオン株式会社 中空重合体粒子の水性分散液の製造方法、紙塗工用組成物および塗工紙
CN109312033A (zh) * 2016-06-20 2019-02-05 阿科玛股份有限公司 含乙烯基酯的抗水解胶乳
MY192619A (en) * 2016-10-07 2022-08-29 Basf Se Method for producing aqueous dispersions
WO2018172476A1 (de) * 2017-03-23 2018-09-27 Basf Coatings Gmbh Wässrige farbpigmentpasten enthaltend ein polymerisat und daraus hergestellte basislacke
EP3707255A1 (en) 2017-11-09 2020-09-16 Basf Se Coatings of enzyme particles comprising organic white pigments
WO2020244485A1 (en) * 2019-06-03 2020-12-10 Shenzhen Aimsea Industrial Co., Ltd Low temperature impact modifiers with good transparency and weatherability

Citations (4)

* Cited by examiner, † Cited by third party
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CN101223202A (zh) * 2005-07-14 2008-07-16 巴斯福股份公司 生产乳液聚合物的方法
CN101624429A (zh) * 2008-07-08 2010-01-13 罗门哈斯公司 芯-壳聚合物颗粒
CN102510886A (zh) * 2009-07-22 2012-06-20 巴斯夫欧洲公司 成膜聚合物和有机中空粒子用于涂层剂的用途
WO2012130712A1 (de) * 2011-03-30 2012-10-04 Basf Se Wässrige mehrstufige polymerisatdispersion, verfahren zu deren herstellung und deren verwendung als bindemittel für die beschichtung von untergründen

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DE2501123C2 (de) 1975-01-14 1984-02-09 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Suspensions-Copolymerisaten
FI103894B (fi) 1997-03-05 1999-10-15 Neste Oy Menetelmä onttopolymeeripartikkelilateksin valmistamiseksi
US6020435A (en) 1997-11-05 2000-02-01 Rohm And Haas Company Process for preparing polymer core shell type emulsions and polymers formed therefrom
RU2128670C1 (ru) * 1998-03-03 1999-04-10 Акционерное общество открытого типа "Пластполимер" Способ получения латекса с полыми полимерными частицами
AU782902B2 (en) * 2000-09-29 2005-09-08 Rohm And Haas Company Processes for chemically-modifying the surface of emulsion polymer particles
EP2272923A1 (en) * 2004-09-02 2011-01-12 Rohm and Haas Company Method of using hollow sphere polymers
EP1940885A4 (en) 2005-10-27 2010-04-07 Valspar Sourcing Inc PROCESS FOR PREPARING POLYMER PARTICLES
EP2511312B1 (en) 2011-03-21 2013-06-05 Organik Kimya Sanayi Ve Tic. A.S. Process of preparing an emulsion containing core-sheath-shell polymer particles
CN102746601B (zh) * 2011-04-18 2014-11-26 罗门哈斯公司 耐水白涂料用共聚物分散体

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101223202A (zh) * 2005-07-14 2008-07-16 巴斯福股份公司 生产乳液聚合物的方法
CN101624429A (zh) * 2008-07-08 2010-01-13 罗门哈斯公司 芯-壳聚合物颗粒
CN102510886A (zh) * 2009-07-22 2012-06-20 巴斯夫欧洲公司 成膜聚合物和有机中空粒子用于涂层剂的用途
WO2012130712A1 (de) * 2011-03-30 2012-10-04 Basf Se Wässrige mehrstufige polymerisatdispersion, verfahren zu deren herstellung und deren verwendung als bindemittel für die beschichtung von untergründen

Also Published As

Publication number Publication date
US20160208038A1 (en) 2016-07-21
RU2690457C2 (ru) 2019-06-03
CA2921876A1 (en) 2015-02-26
EP3036293B1 (de) 2024-01-17
NZ716868A (en) 2021-09-24
WO2015024882A1 (de) 2015-02-26
CN105637045A (zh) 2016-06-01
US10000600B2 (en) 2018-06-19
CA2921876C (en) 2022-12-13
JP6856377B2 (ja) 2021-04-07
JP2016534194A (ja) 2016-11-04
KR102270311B1 (ko) 2021-06-30
EP3036293A1 (de) 2016-06-29
PH12016500317B1 (en) 2016-05-16
RU2016110137A (ru) 2017-09-27
PL3036293T3 (pl) 2024-06-17
SA516370587B1 (ar) 2018-07-23
KR20160046849A (ko) 2016-04-29
FI3036293T3 (fi) 2024-03-27
MX2016002324A (es) 2016-11-30
PT3036293T (pt) 2024-02-28
RU2016110137A3 (fi) 2018-05-21
PH12016500317A1 (en) 2016-05-16
AU2014310714B2 (en) 2018-03-08
ES2974272T3 (es) 2024-06-26
AU2014310714A1 (en) 2016-03-17

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