CN105622007B - A kind of environment friendly flame-retardant polymer cement waterproof paint and its production technology - Google Patents

A kind of environment friendly flame-retardant polymer cement waterproof paint and its production technology Download PDF

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Publication number
CN105622007B
CN105622007B CN201510959492.1A CN201510959492A CN105622007B CN 105622007 B CN105622007 B CN 105622007B CN 201510959492 A CN201510959492 A CN 201510959492A CN 105622007 B CN105622007 B CN 105622007B
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Prior art keywords
parts
powder
production technology
liquid material
water
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CN201510959492.1A
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CN105622007A (en
Inventor
刘晓东
胡希宝
李超
张冬冬
李国森
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Hongyuan Waterproof Technology Group Co ltd
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WEIFANG HONGYUAN WATERPROOF MATERIAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/10Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of environment friendly flame-retardant polymer cement waterproof paint, including liquid material and powder.The liquid material and the weight of powder ratio are liquid material:Powder=1:0.8~1:1.5.The liquid material, in parts by weight, including following raw material components:0.1 ~ 0.4 part of 65 ~ 85 parts of ethene-vinyl acetate emulsion, 0.1 ~ 0.7 part of emulsifying agent, 1 ~ 17 part of plasticizer, 0.3 ~ 0.7 part of defoamer, 0.4 ~ 0.6 part of dispersant, 10 ~ 15 parts of water, preservative powder, in parts by weight, including following raw material components:25 ~ 35 parts of cement, 20 ~ 30 parts of coarse whiting, 20 ~ 30 parts of silica flour, 5 ~ 10 parts of ptfe micropowder, 5 ~ 10 parts of microencapsulated powder oil, 0.1 ~ 0.5 part of water reducer.Water-repellent paint of the present invention, environmental protection, no organic matter evaporate;For nonflammable material.

Description

A kind of environment friendly flame-retardant polymer cement waterproof paint and its production technology
Technical field
The present invention relates to a kind of water-repellent paint, and in particular to a kind of environment friendly flame-retardant polymer cement waterproof paint, belongs to Building water-proof paint field.
Background technology
With the development of society, the quality of the life of people gradually steps up, requirement of the people to architecture quality also more and more higher. We were the development of extensive style in the past, and interests are first, manufacture in a rough and slipshod way, very big influence is caused to environment, meanwhile, in the product of building No small potential safety hazard has also been buried in terms of matter.
Waterproof is indispensable for architectural engineering, but in the industry starting stage, because industry integral level is low, Various low side waterproof materials are widely used, and while building safety is protected, but generate great shadow to our body Ring.Such as the various organic solvents used in bitumen flue gas caused by asphalt felt hot melt application and oil paint, none The health of constructor and user are not being wrecked.
Polymer cement waterproof paint is a kind of new two-component mixed by the powder such as polymer emulsion and cement Aqueous waterproofing paint.It is characterized in using water as decentralized medium, harm will not be produced to human body, wherein and not bituminous, it will not produce Raw bitumen flue gas, it is one of building water-proof paint that state key is promoted.
Although the product relative solvent type coating, asphalt felt have very big environment-friendly advantage, in most cases, its VOC content is that comparison is high, and the general benzene class plasticizer that faces is easy to migrate, poisonous, therefore develops a kind of painting of low VOC content It is imperative to expect.In addition, after the product film forming, polymer substance is still fallen within, is flammable, this security of the lives and property to the mankind Bring great potential safety hazard.So developing a kind of environment friendly flame-retardant polymer cement waterproof paint has important meaning.
Prior art has following defect:(1)Fire resistance is poor, severe compromise be present;(2)It is volatile go out it is harmful Organic compound;(3)Tensile strength is not high, and low temperature flexibility is poor, and adhesive strength is low.
The content of the invention
For above-mentioned technical problem, the present invention provides a kind of environment friendly flame-retardant polymer cement waterproof paint, with realize with Lower goal of the invention:
1st, the fire resistance of water-repellent paint is improved, reduces potential safety hazard;
2nd, water-repellent paint reactive organometal compound of the present invention is made to volatilize;
3rd, it is high to improve water-repellent paint tensile strength;
4th, water-repellent paint low temperature flexibility is improved;
5th, water-repellent paint adhesive strength is improved.
For achieving the above object, the present invention provides following technical scheme:
A kind of environment friendly flame-retardant polymer cement waterproof paint, including liquid material and powder.
It is the further improvement to above-mentioned technical proposal below:
The liquid material and the weight of powder ratio are liquid material:Powder=1:0.8~1:1.5.
The liquid material, in parts by weight, including following raw material components:
Raw material components parts by weight
65 ~ 85 parts of ethene-vinyl acetate emulsion
0.1 ~ 0.7 part of emulsifying agent
1 ~ 17 part of plasticizer
0.3 ~ 0.7 part of defoamer
0.4 ~ 0.6 part of dispersant
10 ~ 15 parts of water
0.1 ~ 0.4 part of preservative.
The powder, in parts by weight, including following raw material components:
Raw material components parts by weight
25 ~ 35 parts of cement
20 ~ 30 parts of coarse whiting
20 ~ 30 parts of silica flour
5 ~ 10 parts of ptfe micropowder
5 ~ 10 parts of microencapsulated powder oil
0.1 ~ 0.5 part of water reducer.
The ethylene-vinyl acetate emulsion:Glass temperature range is -15 DEG C ~ 10 DEG C;
The defoamer is the combination of one or both of organic silicon defoamer, mineral oil defoaming agent.
The plasticizer is chlorinated paraffin -52;The dispersant is sodium polyacrylate;Preservative used is isothiazoline Ketone.
The ptfe micropowder mesh number is 1250 mesh;
The microencapsulated powder oil mesh number is the mesh of 200 mesh ~ 325;
The cement is No. 32.5 white portland cements;
The coarse whiting is 200 ~ 400 mesh powdered whitings;
The silica flour mesh number is 200 ~ 400 mesh.
The water reducer is melamine polycarboxylate based water reducer or melamine superplasticizer.
A kind of production technology of environment friendly flame-retardant polymer cement waterproof paint, described production technology produce including liquid material Technique and powder production technology.
Described liquid material production technology includes:
Ethene-vinyl acetate emulsion is added in reactor, then respectively by the 50% of the total dosage of defoamer, emulsification Agent, dispersant add reactor, open stirring, and rotating speed is 1000 r/min, stir 5 ~ 10 min;Rotating speed is reduced to 800 ~ 900 R/min, plasticizer is added, stir 30 ~ 40 min;
Rotating speed is reduced to 500 ~ 600r/min, water is added, stirs 10min, stand 5 min;
Preservative and remaining defoamer are eventually adding, 10 min, blowing are stirred with 400r/min.
Described powder production technology includes:
Ptfe micropowder, microencapsulated powder oil, water reducer are mixed, add the 25% of the total dosage of silica flour, mixing is equal It is even, premix is obtained, it is standby;
The 50% of the total dosage of 50% and coarse whiting of the total dosage of cement is added into agravic agitator tank, mixes 5 ~ 10 min;
The premix prepared is added, mixes 5 ~ 10 min;
Remaining cement, coarse whiting and silica flour are added into agitator tank, mixes 20 ~ 30 min;Blowing.
Compared with prior art, the invention has the advantages that:
1st, the combustibility of water-repellent paint of the present invention can reach B1Level, is nonflammable material;
2nd, water-repellent paint of the present invention will not volatilize organic compound, environment friendly and pollution-free;
3rd, water-repellent paint tensile strength of the present invention is high, and tensile strength is 1.6~2.6MPa;
4th, water-repellent paint low temperature flexibility of the present invention is good, -10~-20 DEG C of flawlesses;
5th, water-repellent paint adhesive strength of the present invention is high, and adhesive strength is up to 0.7~1.1MPa.
Product film has good elasticity and pliability, is adapted to base course crack, can be constructed in moisture substrate, bonding Firmly.In addition, the polymer emulsion and fire proofing selected, safety and environmental protection is nontoxic, free from environmental pollution.
Embodiment
For the present invention is expanded on further, embodiment is given below to illustrate.
A kind of environment friendly flame-retardant polymer cement waterproof paint of embodiment 1
The weight ratio of the water-repellent paint, including liquid material and powder bi-component, liquid material and powder is liquid material:Powder=1:1.
The formula of the water-repellent paint is
The glass transition temperature of the ethene-vinyl acetate emulsion is -12 DEG C;
The defoamer is organic silicon defoamer;
Preservative used is isothiazolinone;
The ptfe micropowder mesh number is 1250 mesh;
The dispersant is sodium polyacrylate.
A kind of environment friendly flame-retardant polymer cement waterproof paint of embodiment 2
The weight ratio of the water-repellent paint, including liquid material and powder bi-component, liquid material and powder is liquid material:Powder=1: 1.2。
The formula of the water-repellent paint is
The ethene-vinyl acetate emulsion glass transition temperature is 9 DEG C;
The defoamer is organic silicon defoamer;
Preservative used is isothiazolinone;
The ptfe micropowder mesh number is 1250 mesh;
The water reducer is melamine superplasticizer;
The emulsifying agent model AS-801;
The plasticizer is chlorinated paraffin -52;
The dispersant is sodium polyacrylate.
A kind of environment friendly flame-retardant polymer cement waterproof paint of embodiment 3
The weight ratio of the water-repellent paint, including liquid material and powder bi-component, liquid material and powder is liquid material:Powder=1: 1.5。
The formula of the water-repellent paint is:
The ethene-vinyl acetate emulsion glass transition temperature is 0.8 DEG C;
The defoamer is mineral oil defoaming agent;
Preservative used is isothiazolinone;
The ptfe micropowder mesh number is 1250 mesh;
The water reducer is melamine polycarboxylate based water reducer;
The emulsifying agent model AS-801;
The plasticizer is chlorinated paraffin -52;
The dispersant is sodium polyacrylate.
In embodiment 1-3:
Ethene-the vinylacetate:It is limited purchased from Celanese (China) Investment Co., Ltd or wacker chemicals share Company;
The emulsifying agent is purchased from DOW Chemical(China)Investment Co., Ltd.
A kind of production technology of environment friendly flame-retardant polymer cement waterproof paint of embodiment 4
Step 1, liquid material production technology
Each component is weighed by formula;
Ethene-vinyl acetate emulsion is added in reactor, then respectively by the 50% of the total dosage of defoamer, emulsification Agent, dispersant add reactor, and rotating speed is 1000 r/min, stir 5 ~ 10 min;
Rotating speed is reduced to 800 ~ 900 r/min, plasticizer is added, stirs 30 ~ 40 min;
Rotating speed is reduced to 500 ~ 600 r/min, water is added, stirs 10 min, stand 5 min;
Preservative and remaining defoamer are added, 10 min are stirred with 400 r/min;Blowing.
Step 2, powder production technology
Each component is weighed by formula;
Ptfe micropowder, microencapsulated powder oil, water reducer are mixed, add the 25% of the total dosage of silica flour, mixing is equal It is even, premix is obtained, it is standby;
The 50% of the total dosage of 50% and coarse whiting of the total dosage of cement is added into agravic agitator tank, mixes 5 ~ 10 min;To Premix is added in agitator tank, mixes 5 ~ 10 min;
Remaining cement, coarse whiting and silica flour are eventually adding, mixes 20 ~ 30 min, blowing.
Step 3, liquid material and powder mixing
Liquid material is well mixed by weight with powder;Finished product.
As a result detect:
Performance Indexs measure is carried out to embodiment 1-3 water-repellent paint;Detection method is with reference to GB/T 23445-2009《It is poly- Compound cement waterproof paint》、GB 8624-1997《Classification on burning behaviour for building materials》With JC 1066-2008《Building is anti- Limits of harmful substances in water paint》;
Testing result is shown in Table 1;
The performance indications testing result of the embodiment 1-3 of table 1 water-repellent paint
Through experiment:
The fire resistance rating of water-repellent paint of the present invention is up to the B of GB 86241Level, is nonflammable material;
Water-repellent paint of the present invention will not volatilize VOC, environment friendly and pollution-free;
Water-repellent paint solid content of the present invention is 73.3~81.3%;
Water-repellent paint tensile strength of the present invention is 1.6~2.6MPa;
Water-repellent paint low temperature flexibility of the present invention is good, -10~-20 DEG C of flawlesses;
Water-repellent paint adhesive strength of the present invention is high, and adhesive strength is up to 0.7~1.1MPa.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still can be with Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic.It is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., it should be included in the guarantor of the present invention Within the scope of shield.Citing described above for best mode for carrying out the invention, wherein the part do not addressed in detail is this area The common knowledge of those of ordinary skill;Protection scope of the present invention is defined by the content of claim, any based on the present invention's Technical inspiration and the equivalent transformation carried out, also within protection scope of the present invention.

Claims (5)

  1. A kind of 1. environment friendly flame-retardant polymer cement waterproof paint, it is characterised in that:Including liquid material and powder;
    The liquid material, in parts by weight, including following raw material components:
    Raw material components parts by weight
    65 ~ 85 parts of ethene-vinyl acetate emulsion
    0.1 ~ 0.7 part of emulsifying agent
    1 ~ 17 part of plasticizer
    0.3 ~ 0.7 part of defoamer
    0.4 ~ 0.6 part of dispersant
    10 ~ 15 parts of water
    0.1 ~ 0.4 part of preservative;
    The powder, in parts by weight, including following raw material components:
    Raw material components parts by weight
    25 ~ 35 parts of cement
    20 ~ 30 parts of coarse whiting
    20 ~ 30 parts of silica flour
    5 ~ 10 parts of ptfe micropowder
    5 ~ 10 parts of microencapsulated powder oil
    0.1 ~ 0.5 part of water reducer;
    The ethylene-vinyl acetate emulsion:Glass temperature range is -15 DEG C ~ 10 DEG C;
    The defoamer is the combination of one or both of organic silicon defoamer, mineral oil defoaming agent;
    The plasticizer is chlorinated paraffin -52;The dispersant is sodium polyacrylate;Preservative used is OIT Class;
    The ptfe micropowder mesh number is 1250 mesh;
    The microencapsulated powder oil mesh number is the mesh of 200 mesh ~ 325;
    The cement is No. 32.5 white portland cements;
    The coarse whiting is 200 ~ 400 mesh powdered whitings;
    The silica flour mesh number is 200 ~ 400 mesh;
    The water reducer is melamine polycarboxylate based water reducer or melamine superplasticizer.
  2. A kind of 2. environment friendly flame-retardant polymer cement waterproof paint according to claim 1, it is characterised in that:The liquid material Weight ratio with powder is liquid material:Powder=1:0.8~1:1.5.
  3. 3. a kind of production technology of environment friendly flame-retardant polymer cement waterproof paint according to claim 1, its feature exist In:Described production technology includes liquid material production technology and powder production technology.
  4. 4. a kind of production technology of environment friendly flame-retardant polymer cement waterproof paint according to claim 3, its feature exist In:Described liquid material production technology includes:
    Ethene-vinyl acetate emulsion is added in reactor, then respectively by the 50% of the total dosage of defoamer, emulsifying agent, Dispersant adds reactor, opens stirring, and rotating speed is 800 ~ 1200 r/min, stirs 5 ~ 10 min;Rotating speed is reduced to 800 ~ 900 R/min, plasticizer is added, stir 30 ~ 40 min;
    Rotating speed is reduced to 500 ~ 600r/min, water is added, stirs 10 ± 1min, stand 5 ± 1min;
    Preservative and remaining defoamer are eventually adding, 10 ± 1min, blowing are stirred with 400 ± 50r/min.
  5. 5. a kind of production technology of environment friendly flame-retardant polymer cement waterproof paint according to claim 3, its feature exist In:Described powder production technology includes:
    Ptfe micropowder, microencapsulated powder oil, water reducer are mixed, add the 25% of the total dosage of silica flour, is well mixed, Premix is obtained, it is standby;
    The 50% of the total dosage of 50% and coarse whiting of the total dosage of cement is added into agravic agitator tank, mixes 5 ~ 10 min;
    The premix prepared is added, mixes 5 ~ 10 min;
    Remaining cement, coarse whiting and silica flour are added into agitator tank, mixes 20 ~ 30 min;Blowing.
CN201510959492.1A 2015-12-21 2015-12-21 A kind of environment friendly flame-retardant polymer cement waterproof paint and its production technology Active CN105622007B (en)

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CN107140911B (en) * 2017-06-14 2019-10-01 惠州东方雨虹建筑材料有限责任公司 The polymer cement waterproof paint and its preparation method and application that can be scratched
CN107311568B (en) * 2017-07-14 2019-09-17 苏州市建筑科学研究院集团股份有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107555855B (en) * 2017-08-01 2020-06-02 岳阳东方雨虹防水技术有限责任公司 Bi-component water-based waterproof coating and preparation method thereof
CN109370275A (en) * 2018-10-30 2019-02-22 宿松汉邦新型建材有限公司 A kind of cement waterproof paint adding white marble sand
CN109437735A (en) * 2018-11-22 2019-03-08 福建工程学院 A kind of super-hydrophobic cement and its application method
CN110627454A (en) * 2019-11-05 2019-12-31 厦门高辰新材料有限公司 Polymer cement waterproof mortar and preparation method thereof
CN113024051A (en) * 2019-12-24 2021-06-25 湖南军信环保股份有限公司 Targeting chelating agent and method for treating refuse leachate membrane filtration concentrated solution salt slurry
CN116179009A (en) * 2022-12-28 2023-05-30 北京东方雨虹防水技术股份有限公司 Paraffin oil modifier and preparation method thereof, waterproof coating containing paraffin oil modifier and preparation method of waterproof coating

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US6291556B1 (en) * 1999-03-26 2001-09-18 Shin-Etsu Chemical Co., Ltd. Semiconductor encapsulating epoxy resin composition and semiconductor device
CN101108945B (en) * 2007-07-19 2010-06-09 北京东方雨虹防水技术股份有限公司 Flame-proof type polyalcohol cement basis composite water-proof paint
CN104559528A (en) * 2015-01-27 2015-04-29 苏州奥莱鑫建材有限公司 Anticorrosive fireproof paint
CN105062281A (en) * 2015-08-17 2015-11-18 惠州东方雨虹建筑材料有限责任公司 I-type environment-friendly two-component polymer cement waterproof paint and preparation method

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Address after: 262735 Taitou Town, Shouguang City, Weifang City, Shandong Province, 2000 meters west of the government

Patentee after: HONGYUAN WATERPROOF TECHNOLOGY GROUP Co.,Ltd.

Address before: 262735 Taitou Town, Shouguang City, Weifang City, Shandong Province, 2000 meters west of the government

Patentee before: WEIFANG HONGYUAN WATERPROOF MATERIAL Co.,Ltd.

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Denomination of invention: An environmentally friendly flame-retardant polymer cement waterproof coating and its production process

Effective date of registration: 20230829

Granted publication date: 20171121

Pledgee: Shandong Shouguang Rural Commercial Bank Co.,Ltd.

Pledgor: HONGYUAN WATERPROOF TECHNOLOGY GROUP Co.,Ltd.

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