CN105601939A - 纳米SiO2杂化梳状有机氟硅共聚物的制备方法及其制品与应用 - Google Patents
纳米SiO2杂化梳状有机氟硅共聚物的制备方法及其制品与应用 Download PDFInfo
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- CN105601939A CN105601939A CN201511020090.1A CN201511020090A CN105601939A CN 105601939 A CN105601939 A CN 105601939A CN 201511020090 A CN201511020090 A CN 201511020090A CN 105601939 A CN105601939 A CN 105601939A
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- sio
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- hydridization
- fluorinated silicone
- organic fluorinated
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910052681 coesite Inorganic materials 0.000 title claims abstract description 51
- 229910052906 cristobalite Inorganic materials 0.000 title claims abstract description 51
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 51
- 229910052682 stishovite Inorganic materials 0.000 title claims abstract description 51
- 229910052905 tridymite Inorganic materials 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 235000012239 silicon dioxide Nutrition 0.000 title abstract description 6
- 229920001577 copolymer Polymers 0.000 title abstract 6
- 239000004744 fabric Substances 0.000 claims abstract description 31
- 239000004593 Epoxy Substances 0.000 claims abstract description 27
- 238000010992 reflux Methods 0.000 claims abstract description 13
- 230000003075 superhydrophobic effect Effects 0.000 claims abstract description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000000706 filtrate Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000004821 distillation Methods 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 33
- 238000012986 modification Methods 0.000 claims description 24
- 230000004048 modification Effects 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 12
- -1 amido silicon Chemical compound 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 230000006837 decompression Effects 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000006068 polycondensation reaction Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- HRWYHCYGVIJOEC-UHFFFAOYSA-N 2-(octoxymethyl)oxirane Chemical compound CCCCCCCCOCC1CO1 HRWYHCYGVIJOEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 238000003906 pulsed field gel electrophoresis Methods 0.000 claims 2
- 238000000034 method Methods 0.000 abstract description 15
- 230000002209 hydrophobic effect Effects 0.000 abstract description 10
- 239000004753 textile Substances 0.000 abstract description 3
- 229920001600 hydrophobic polymer Polymers 0.000 abstract description 2
- MQQVPMQKCUZOOY-UHFFFAOYSA-N C(C1CO1)OC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(F)(F)F)(F)F)F Chemical compound C(C1CO1)OC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(F)(F)F)(F)F)F MQQVPMQKCUZOOY-UHFFFAOYSA-N 0.000 abstract 1
- 229920013822 aminosilicone Polymers 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000012237 artificial material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002977 biomimetic material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
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CN201511020090.1A CN105601939B (zh) | 2015-12-28 | 2015-12-28 | 纳米SiO2杂化梳状有机氟硅共聚物的制备方法及其制品与应用 |
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CN201511020090.1A CN105601939B (zh) | 2015-12-28 | 2015-12-28 | 纳米SiO2杂化梳状有机氟硅共聚物的制备方法及其制品与应用 |
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CN105601939A true CN105601939A (zh) | 2016-05-25 |
CN105601939B CN105601939B (zh) | 2018-06-15 |
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CN201511020090.1A Active CN105601939B (zh) | 2015-12-28 | 2015-12-28 | 纳米SiO2杂化梳状有机氟硅共聚物的制备方法及其制品与应用 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107254054A (zh) * | 2017-07-03 | 2017-10-17 | 陕西科技大学 | 一种溶剂型疏水疏油性纳米杂化氟硅树脂的制备方法及其应用 |
CN108252082A (zh) * | 2016-12-28 | 2018-07-06 | 日华化学株式会社 | 防水剂组合物、防水性纤维制品和防水性纤维制品的制造方法 |
CN108456307A (zh) * | 2017-02-20 | 2018-08-28 | 广州希森美克新材料科技有限公司 | 一种SiO2杂化梳状有机氟硅共聚物的合成方法 |
CN111910439A (zh) * | 2020-07-02 | 2020-11-10 | 科凯精细化工(上海)有限公司 | 一种无机纳米SiO2杂化有机硅无氟防水剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101805434A (zh) * | 2010-02-23 | 2010-08-18 | 厦门大学 | 超疏水的氟硅聚合物/纳米二氧化硅杂化纳米材料及其制备方法 |
CN102634987A (zh) * | 2012-04-27 | 2012-08-15 | 陕西科技大学 | 一种氟烷基羧烃基聚硅氧烷/纳米粒子超疏水性复合膜及其制备方法 |
CN104262639A (zh) * | 2014-09-05 | 2015-01-07 | 陕西科技大学 | 超疏水型交联聚硅氧烷-聚倍半硅氧烷纳米球杂化材料的制备方法 |
-
2015
- 2015-12-28 CN CN201511020090.1A patent/CN105601939B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805434A (zh) * | 2010-02-23 | 2010-08-18 | 厦门大学 | 超疏水的氟硅聚合物/纳米二氧化硅杂化纳米材料及其制备方法 |
CN102634987A (zh) * | 2012-04-27 | 2012-08-15 | 陕西科技大学 | 一种氟烷基羧烃基聚硅氧烷/纳米粒子超疏水性复合膜及其制备方法 |
CN104262639A (zh) * | 2014-09-05 | 2015-01-07 | 陕西科技大学 | 超疏水型交联聚硅氧烷-聚倍半硅氧烷纳米球杂化材料的制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108252082A (zh) * | 2016-12-28 | 2018-07-06 | 日华化学株式会社 | 防水剂组合物、防水性纤维制品和防水性纤维制品的制造方法 |
CN108252082B (zh) * | 2016-12-28 | 2021-04-27 | 日华化学株式会社 | 防水剂组合物、防水性纤维制品和防水性纤维制品的制造方法 |
CN108456307A (zh) * | 2017-02-20 | 2018-08-28 | 广州希森美克新材料科技有限公司 | 一种SiO2杂化梳状有机氟硅共聚物的合成方法 |
CN108456307B (zh) * | 2017-02-20 | 2020-12-01 | 广州希森美克新材料科技股份有限公司 | 一种SiO2杂化梳状有机氟硅共聚物的合成方法 |
CN107254054A (zh) * | 2017-07-03 | 2017-10-17 | 陕西科技大学 | 一种溶剂型疏水疏油性纳米杂化氟硅树脂的制备方法及其应用 |
CN107254054B (zh) * | 2017-07-03 | 2020-10-13 | 陕西科技大学 | 一种溶剂型疏水疏油性纳米杂化氟硅树脂的制备方法及其应用 |
CN111910439A (zh) * | 2020-07-02 | 2020-11-10 | 科凯精细化工(上海)有限公司 | 一种无机纳米SiO2杂化有机硅无氟防水剂及其制备方法 |
CN111910439B (zh) * | 2020-07-02 | 2022-10-18 | 科凯精细化工(上海)有限公司 | 一种无机纳米SiO2杂化有机硅无氟防水剂及其制备方法 |
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Denomination of invention: Preparation and application of nano-SiO2 hybrid comb-like organofluorosilicone copolymer Effective date of registration: 20190701 Granted publication date: 20180615 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: 2019440000247 |
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Denomination of invention: Preparation and application of nano-SiO2hybrid comb-like organofluorosilicone copolymer Effective date of registration: 20200826 Granted publication date: 20180615 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2020980005427 |
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