CN105576325B - 用于金属-空气蓄电池的两相电解质 - Google Patents
用于金属-空气蓄电池的两相电解质 Download PDFInfo
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- CN105576325B CN105576325B CN201510744573.XA CN201510744573A CN105576325B CN 105576325 B CN105576325 B CN 105576325B CN 201510744573 A CN201510744573 A CN 201510744573A CN 105576325 B CN105576325 B CN 105576325B
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- 229910052751 metal Inorganic materials 0.000 title claims description 34
- 239000002184 metal Substances 0.000 title claims description 34
- 238000005868 electrolysis reaction Methods 0.000 title claims description 6
- 239000002608 ionic liquid Substances 0.000 claims abstract description 69
- 239000003792 electrolyte Substances 0.000 claims abstract description 61
- 239000012071 phase Substances 0.000 claims abstract description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000008346 aqueous phase Substances 0.000 claims abstract description 13
- -1 pyridine Cation Chemical class 0.000 claims description 35
- 229910052744 lithium Inorganic materials 0.000 claims description 15
- 150000001768 cations Chemical class 0.000 claims description 11
- 239000011244 liquid electrolyte Substances 0.000 claims description 11
- 229910001416 lithium ion Inorganic materials 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical class C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000011148 porous material Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 150000003624 transition metals Chemical group 0.000 claims description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 6
- IEFUHGXOQSVRDQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-methyl-1-propylpiperidin-1-ium Chemical compound CCC[N+]1(C)CCCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F IEFUHGXOQSVRDQ-UHFFFAOYSA-N 0.000 claims description 6
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical class C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000011149 active material Substances 0.000 claims description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 5
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- 229910000733 Li alloy Inorganic materials 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
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- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003115 supporting electrolyte Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 4
- 150000001412 amines Chemical class 0.000 claims 3
- HYGWNUKOUCZBND-UHFFFAOYSA-N azanide Chemical compound [NH2-] HYGWNUKOUCZBND-UHFFFAOYSA-N 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- 229910007035 Li(CF3SO3) Inorganic materials 0.000 claims 1
- 229910013454 LiC4 Inorganic materials 0.000 claims 1
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- 239000011630 iodine Substances 0.000 claims 1
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 claims 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims 1
- KTQDYGVEEFGIIL-UHFFFAOYSA-N n-fluorosulfonylsulfamoyl fluoride Chemical compound FS(=O)(=O)NS(F)(=O)=O KTQDYGVEEFGIIL-UHFFFAOYSA-N 0.000 claims 1
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- 239000001301 oxygen Substances 0.000 description 16
- 229910052760 oxygen Inorganic materials 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
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- 230000008020 evaporation Effects 0.000 description 3
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- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
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- 229910015015 LiAsF 6 Inorganic materials 0.000 description 2
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- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 2
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 2
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- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0045—Room temperature molten salts comprising at least one organic ion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0094—Composites in the form of layered products, e.g. coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/533,286 US9666916B2 (en) | 2014-11-05 | 2014-11-05 | Biphase electrolyte for a metal-air battery |
| US14/533,286 | 2014-11-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105576325A CN105576325A (zh) | 2016-05-11 |
| CN105576325B true CN105576325B (zh) | 2018-10-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510744573.XA Active CN105576325B (zh) | 2014-11-05 | 2015-11-05 | 用于金属-空气蓄电池的两相电解质 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US9666916B2 (enExample) |
| JP (1) | JP6461766B2 (enExample) |
| CN (1) | CN105576325B (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10868332B2 (en) | 2016-04-01 | 2020-12-15 | NOHMs Technologies, Inc. | Modified ionic liquids containing phosphorus |
| US10177427B2 (en) * | 2017-02-10 | 2019-01-08 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| US10826145B2 (en) | 2017-02-10 | 2020-11-03 | General Electric Company | Electrochemical cell for use in high temperature metal-air battery |
| EP4087005A1 (en) | 2017-07-17 | 2022-11-09 | Nohms Technologies, Inc. | Phosphorus-containing electrolytes |
| JP7125023B2 (ja) * | 2017-10-26 | 2022-08-24 | 国立大学法人東京農工大学 | 混合エントロピー電池及び発電方法 |
| CN108808175A (zh) * | 2018-07-11 | 2018-11-13 | 上海钧旺汽车技术有限公司 | 一种用于铝空电池智能自动补充水装置 |
| US11267707B2 (en) | 2019-04-16 | 2022-03-08 | Honeywell International Inc | Purification of bis(fluorosulfonyl) imide |
| CN114735648B (zh) * | 2021-01-07 | 2023-07-28 | 中国石油化工股份有限公司 | 一种化学环制氢的载氧体及其制备方法和应用 |
| CN114914541B (zh) * | 2021-07-08 | 2025-05-16 | 郑州大学 | 一种锂金属电池电解液及其应用和锂金属电池 |
| CN118782985B (zh) * | 2024-08-22 | 2025-11-11 | 嘉庚创新实验室 | 电解液及其制备方法和金属空气电池 |
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| CN1680482A (zh) * | 2005-02-04 | 2005-10-12 | 武汉大学 | 一种非水/水两相凝胶电解质及其制备方法和电池 |
| CN101550086A (zh) * | 2008-04-02 | 2009-10-07 | 三星工程株式会社 | 与各种极性/非极性溶剂可混溶的离子液体及其制备方法 |
| CN101752628A (zh) * | 2010-01-21 | 2010-06-23 | 浙江大学 | 可再充电金属氢化物空气电池 |
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| CN103069626A (zh) * | 2010-08-17 | 2013-04-24 | 丰田自动车株式会社 | 用于金属-空气电池的液体空气电极和具有所述液体空气电极的金属-空气电池 |
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| JP2010103059A (ja) * | 2008-10-27 | 2010-05-06 | Toyota Motor Corp | 空気電池 |
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| CN102971904B (zh) * | 2010-05-12 | 2016-06-08 | 亚利桑那董事会代表亚利桑那大学 | 具有性能增强添加剂的金属-空气电池 |
| WO2011159391A1 (en) | 2010-06-15 | 2011-12-22 | Fluidic, Inc. | Metal-air cell with tuned hydrophobicity |
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-
2014
- 2014-11-05 US US14/533,286 patent/US9666916B2/en active Active
-
2015
- 2015-11-04 JP JP2015216247A patent/JP6461766B2/ja active Active
- 2015-11-05 CN CN201510744573.XA patent/CN105576325B/zh active Active
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| CN103547584A (zh) * | 2011-06-17 | 2014-01-29 | 流体公司 | 利用碳酸二烷基酯季铵化来合成杂离子化合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20160126605A1 (en) | 2016-05-05 |
| CN105576325A (zh) | 2016-05-11 |
| JP6461766B2 (ja) | 2019-01-30 |
| JP2016092010A (ja) | 2016-05-23 |
| US9666916B2 (en) | 2017-05-30 |
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