CN105555855B - 包含三硫代碳酸酯的加成-断裂剂 - Google Patents

包含三硫代碳酸酯的加成-断裂剂 Download PDF

Info

Publication number
CN105555855B
CN105555855B CN201480051409.4A CN201480051409A CN105555855B CN 105555855 B CN105555855 B CN 105555855B CN 201480051409 A CN201480051409 A CN 201480051409A CN 105555855 B CN105555855 B CN 105555855B
Authority
CN
China
Prior art keywords
meth
weight
acrylate
composition
dental
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480051409.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN105555855A (zh
Inventor
A·R·弗诺夫
W·H·莫泽
A·S·阿比尔雅曼
G·D·乔利
L·R·克雷普斯基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN105555855A publication Critical patent/CN105555855A/zh
Application granted granted Critical
Publication of CN105555855B publication Critical patent/CN105555855B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/61—Cationic, anionic or redox initiators
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/62—Photochemical radical initiators
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/70—Preparations for dentistry comprising inorganic additives
    • A61K6/71—Fillers
    • A61K6/76—Fillers comprising silicon-containing compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Inorganic Chemistry (AREA)
  • Biophysics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Dental Preparations (AREA)
  • Polymerisation Methods In General (AREA)
CN201480051409.4A 2013-09-20 2014-09-05 包含三硫代碳酸酯的加成-断裂剂 Active CN105555855B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361880348P 2013-09-20 2013-09-20
US61/880,348 2013-09-20
PCT/US2014/054190 WO2015041863A1 (en) 2013-09-20 2014-09-05 Trithiocarbonate-containing addition-fragmentation agents

Publications (2)

Publication Number Publication Date
CN105555855A CN105555855A (zh) 2016-05-04
CN105555855B true CN105555855B (zh) 2018-08-14

Family

ID=51570899

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480051409.4A Active CN105555855B (zh) 2013-09-20 2014-09-05 包含三硫代碳酸酯的加成-断裂剂

Country Status (6)

Country Link
US (1) US9532929B2 (https=)
EP (1) EP3046962B1 (https=)
JP (1) JP6410803B2 (https=)
KR (1) KR102226633B1 (https=)
CN (1) CN105555855B (https=)
WO (1) WO2015041863A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105683257B (zh) 2013-10-16 2018-02-13 3M创新有限公司 包含烯丙基二硫化物的加成‑断裂低聚物
US11952447B2 (en) * 2018-03-30 2024-04-09 Mitsui Chemicals, Inc. Polymerizable composition for dental material, and dental material obtained from said composition
CN112352008B (zh) * 2018-07-04 2023-01-31 巴斯夫欧洲公司 使用基于具有环状硫代碳酸酯单元的化合物的双组分粘合剂的粘合方法
US20230265220A1 (en) * 2018-11-28 2023-08-24 Ivoclar Vivadent Ag Photopolymerizable Dental Composites With Rapid Curing And Low Shrinkage Stress
EP3659575A1 (de) 2018-11-28 2020-06-03 Ivoclar Vivadent AG Photopolymerisierbare dentale komposite mit schneller aushärtung und geringer schrumpfspannung
DE102019122174A1 (de) 2019-08-19 2021-02-25 Voco Gmbh Dentale polymerisierbare Zusammensetzung auf der Basis kondensierter Silane
CN112138603A (zh) * 2020-09-11 2020-12-29 塔里木大学 双头单尾表面活性剂的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010202572A (ja) * 2009-03-03 2010-09-16 Ube Ind Ltd トリチオカーボネート化合物及びその製法
CN102083863A (zh) * 2008-03-07 2011-06-01 卡内基梅隆大学 改进的受控自由基聚合方法
CN102321198A (zh) * 2011-06-28 2012-01-18 苏州大学 一种制备双峰分布聚合物的方法
WO2013028397A2 (en) * 2011-08-23 2013-02-28 3M Innovative Properties Company Dental compositions comprising addition-fragmentation agents

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2801185A (en) 1952-05-16 1957-07-30 Du Pont Silica hydrosol powder
US3496250A (en) 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
US4522958A (en) 1983-09-06 1985-06-11 Ppg Industries, Inc. High-solids coating composition for improved rheology control containing chemically modified inorganic microparticles
US4547323A (en) 1984-03-21 1985-10-15 Scm Corporation Synthesis of 2,2-dimethyl-4-methyleneglutaric acid and derivatives
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
US4886861A (en) 1985-04-23 1989-12-12 E. I. Dupont De Nemours And Company Molecular weight control in free radical polymerizations
US5324879A (en) 1985-12-03 1994-06-28 Commonwealth Scientific And Industrial Research Organisation Oligomerization process
CA1323949C (en) 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
AU618772B2 (en) 1987-12-30 1992-01-09 Minnesota Mining And Manufacturing Company Photocurable ionomer cement systems
US5154762A (en) 1991-05-31 1992-10-13 Minnesota Mining And Manufacturing Company Universal water-based medical and dental cement
US5506279A (en) 1993-10-13 1996-04-09 Minnesota Mining And Manufacturing Company Acrylamido functional disubstituted acetyl aryl ketone photoinitiators
US5501727A (en) 1994-02-28 1996-03-26 Minnesota Mining And Manufacturing Company Color stability of dental compositions containing metal complexed ascorbic acid
US6126922A (en) 1995-11-17 2000-10-03 3M Innovative Properties Company Fluorid-releasing compositions and compositions with improved rheology
JP4083257B2 (ja) 1997-03-19 2008-04-30 株式会社ジーシー 歯科充填用レジン組成物
DE19943712C1 (de) 1999-09-08 2001-05-17 Ivoclar Ag Schaan Hydrolysierbare und polymerisierbare Silane auf der Basis von Methylendithiepan
AU3505400A (en) 1999-10-28 2001-05-08 3M Innovative Properties Company Dental materials with nano-sized silica particles
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6572693B1 (en) 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
EP1244754A1 (en) 1999-11-22 2002-10-02 3M Innovative Properties Company Water-based coating composition
US6586483B2 (en) 2001-01-08 2003-07-01 3M Innovative Properties Company Foam including surface-modified nanoparticles
DE10106372A1 (de) 2001-02-12 2002-08-29 Ivoclar Vivadent Ag Thermochromer Dentalwerkstoff
JP5329734B2 (ja) 2001-08-15 2013-10-30 スリーエム イノベイティブ プロパティズ カンパニー 硬化性自己支持形構造および方法
US7393882B2 (en) 2002-01-31 2008-07-01 3M Innovative Properties Company Dental pastes, dental articles, and methods
US7632098B2 (en) 2003-08-12 2009-12-15 3M Innovative Properties Company Self-adhesive dental compositions and methods
US7090721B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7090722B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Acid-reactive dental fillers, compositions, and methods
US7649029B2 (en) 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
US7156911B2 (en) 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
US20060278241A1 (en) 2004-12-14 2006-12-14 Gualberto Ruano Physiogenomic method for predicting clinical outcomes of treatments in patients
US7241437B2 (en) 2004-12-30 2007-07-10 3M Innovative Properties Company Zirconia particles
JP2008535936A (ja) * 2005-02-10 2008-09-04 ザ リージェンツ オブ ザ ユニバーシティ オブ コロラド， ア ボディー コーポレイト 架橋ポリマーにおける応力緩和
CN102512329A (zh) 2005-05-09 2012-06-27 3M创新有限公司 含有杂化单体的牙科组合物
JP5260505B2 (ja) 2006-06-09 2013-08-14 デンツプライ インターナショナル インコーポレーテッド 低応力流動性歯科用組成物
US20100021869A1 (en) 2006-12-28 2010-01-28 Abuelyaman Ahmed S (meth)acryloyl-containing materials, compositions, and methods
JP2011510002A (ja) 2008-01-15 2011-03-31 デンツプライ インターナショナル インコーポレーテッド 調節された重合応力のための機能性樹脂組成物
CN101735184A (zh) 2008-11-11 2010-06-16 深圳市海川实业股份有限公司 一种三硫代碳酸酯链转移剂及其制备方法
US7838110B2 (en) 2008-12-02 2010-11-23 3M Innovative Properties Company Aziridine-functional photoactive crosslinking compounds
EP2552380B1 (en) 2010-03-31 2019-04-24 3M Innovative Properties Company Polymerizable isocyanurate monomers and dental compositions
EP2401998A1 (en) 2010-07-02 2012-01-04 3M Innovative Properties Company Dental composition, kit of parts and use thereof
EP2675422B1 (en) * 2011-02-15 2020-09-30 3M Innovative Properties Company Dental compositions comprising ethylenically unsaturated addition-fragmentation agent
US20120208965A1 (en) * 2011-02-15 2012-08-16 3M Innovative Properties Company Addition-fragmentation agents
WO2012112321A2 (en) 2011-02-15 2012-08-23 3M Innovative Properties Company Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer
US8455565B2 (en) 2011-05-18 2013-06-04 3M Innovative Properties Company Disulfide monomers comprising ethylenically unsaturated groups suitable for dental compositions
US9758597B2 (en) * 2011-08-05 2017-09-12 The Regents Of The University Of Colorado, A Body Corporate Reducing polymerization-induced shrinkage stress by reversible addition-fragmentation chain transfer
US8980969B2 (en) 2011-08-23 2015-03-17 3M Innovative Properties Company Addition-fragmentation agents
WO2014051228A1 (ko) * 2012-09-26 2014-04-03 제일모직 주식회사 편광판용 점착제 조성물, 이로부터 형성된 점착층을 포함하는 편광판 및 이를 포함하는 광학 디스플레이 부재
JP6351608B2 (ja) 2012-11-12 2018-07-04 スリーエム イノベイティブ プロパティズ カンパニー 付加開裂剤を含む歯科用組成物
US9410030B2 (en) 2012-11-12 2016-08-09 3M Innovative Properties Company Addition-fragmentation agents
WO2014099317A1 (en) 2012-12-17 2014-06-26 3M Innovative Properties Company Addition-fragmentation oligomers
CN105051007B (zh) 2013-03-20 2020-03-13 3M创新有限公司 高折射率加成-断裂剂

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102083863A (zh) * 2008-03-07 2011-06-01 卡内基梅隆大学 改进的受控自由基聚合方法
JP2010202572A (ja) * 2009-03-03 2010-09-16 Ube Ind Ltd トリチオカーボネート化合物及びその製法
CN102321198A (zh) * 2011-06-28 2012-01-18 苏州大学 一种制备双峰分布聚合物的方法
WO2013028397A2 (en) * 2011-08-23 2013-02-28 3M Innovative Properties Company Dental compositions comprising addition-fragmentation agents

Also Published As

Publication number Publication date
EP3046962B1 (en) 2018-05-23
CN105555855A (zh) 2016-05-04
WO2015041863A1 (en) 2015-03-26
US20160206520A1 (en) 2016-07-21
EP3046962A1 (en) 2016-07-27
US9532929B2 (en) 2017-01-03
JP6410803B2 (ja) 2018-10-24
JP2016531956A (ja) 2016-10-13
KR102226633B1 (ko) 2021-03-10
KR20160058159A (ko) 2016-05-24

Similar Documents

Publication Publication Date Title
CN104870484B (zh) 加成-断裂低聚物
CN107406723B (zh) 加成-断裂低聚物
CN105683257B (zh) 包含烯丙基二硫化物的加成‑断裂低聚物
CN105555855B (zh) 包含三硫代碳酸酯的加成-断裂剂
CN105051007B (zh) 高折射率加成-断裂剂
CN106029802B (zh) 具有高折射率基团的加成-断裂低聚物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant