CN105542529A - Anti-oxidative, flame-retardant and anti-rust metal sheet coating - Google Patents
Anti-oxidative, flame-retardant and anti-rust metal sheet coating Download PDFInfo
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- CN105542529A CN105542529A CN201610036752.2A CN201610036752A CN105542529A CN 105542529 A CN105542529 A CN 105542529A CN 201610036752 A CN201610036752 A CN 201610036752A CN 105542529 A CN105542529 A CN 105542529A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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Abstract
The invention relates to an anti-oxidative, flame-retardant and anti-rust metal sheet coating which consists of the following components in parts by mass: 26 to 30 parts of hydroxyethyl cellulose, 28 to 32 parts of stannous octoate, 24 to 28 parts of methylsilane, 28 to 32 parts of acetofenate, 24 to 28 parts of diester fumarate, 28 to 32 parts of cerium oxide, 24 to 28 parts of dimethylaminopropylamine, 30 to 34 parts of sodium oleate, 24 to 28 parts of trimethylol propane trimethacrylate, 28 to 32 parts of cellulose acetate butyrate, 24 to 28 parts of vinyl acetate, 28 to 32 parts of smectite powder, 24 to 28 parts of sea-foam stone powder, 28 to 32 parts of titanium dioxide, 24 to 28 parts of zinc phosphate, 28 to 32 parts of phthalocyanine blue, 24 to 28 parts of tributyl citrate, 28 to 32 parts of benzotriazole, 24 to 28 parts of methyl sulfonate, 28 to 32 parts of ethyl borate and 24 to 28 parts of silicon metal powder. A preparation method for the coating is simple, and the prepared product has higher flame retardancy, acid and alkali resistance and anti-rust and antibacterial performance, and is suitable for use in various fields.
Description
Technical field
The present invention relates to a kind of anti-oxidant fire-retardant anti-rust metal sheet material coating, belong to formulation for coating material technical field.
Background technology
Metal finishing is that one can change surface characteristics of metal, reaches the technology of the objects such as pre-preventing metal corrosion, the fatigue strength improving metal and anti-stress corrosion performance.Apply coating equably in metallic surface, the coating of formation can make metallic surface and surrounding medium keep apart, thus protection matrix.Utilize coating anticorrosion, anti-oxidant, antirust, there is more advantages, as lower in easy construction, strong adaptability, cost, therefore can widespread use in various industrial system.
Summary of the invention
The object of the present invention is to provide a kind of anti-oxidant fire-retardant anti-rust metal sheet material coating, to realize the anti-oxidant fire-retardant antirust function of sheet metal coating better.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of anti-oxidant fire-retardant anti-rust metal sheet material coating, be made up of the component of following mass fraction: Natvosol 26 ~ 30 parts, stannous octoate 28 ~ 32 parts, methyl-monosilane 24 ~ 28 parts, acetofenate 28 ~ 32 parts, dimethyl ester 24 ~ 28 parts, cerium oxide 28 ~ 32 parts, dimethylaminopropylamine 24 ~ 28 parts, sodium oleate 30 ~ 34 parts, trimethylolpropane trimethacrylate 24 ~ 28 parts, cellulose acetate butyrate 28 ~ 32 parts, vinyl-acetic ester 24 ~ 28 parts, montmorillonite powder 28 ~ 32 parts, sepiolite powder 24 ~ 28 parts, titanium dioxide 28 ~ 32 parts, zinc phosphate 24 ~ 28 parts, phthalocyanine blue 28 ~ 32 parts, tributyl citrate 24 ~ 28 parts, benzotriazole 28 ~ 32 parts, methanesulfonate ester 24 ~ 28 parts, ethyl-borate 28 ~ 32 parts, metallic silicon power 24 ~ 28 parts.
Further, above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating, be made up of the component of following mass fraction: Natvosol 26 parts, stannous octoate 28 parts, methyl-monosilane 24 parts, acetofenate 28 parts, dimethyl ester 24 parts, cerium oxide 28 parts, dimethylaminopropylamine 24 parts, sodium oleate 30 parts, trimethylolpropane trimethacrylate 24 parts, cellulose acetate butyrate 28 parts, vinyl-acetic ester 24 parts, montmorillonite powder 28 parts, sepiolite powder 24 parts, titanium dioxide 28 parts, zinc phosphate 24 parts, phthalocyanine blue 28 parts, tributyl citrate 24 parts, benzotriazole 28 parts, methanesulfonate ester 24 parts, ethyl-borate 28 parts, metallic silicon power 24 parts.
Further, above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating, be made up of the component of following mass fraction: Natvosol 28 parts, stannous octoate 30 parts, methyl-monosilane 26 parts, acetofenate 30 parts, dimethyl ester 26 parts, cerium oxide 30 parts, dimethylaminopropylamine 26 parts, sodium oleate 32 parts, trimethylolpropane trimethacrylate 26 parts, cellulose acetate butyrate 30 parts, vinyl-acetic ester 26 parts, montmorillonite powder 30 parts, sepiolite powder 26 parts, titanium dioxide 30 parts, zinc phosphate 26 parts, phthalocyanine blue 30 parts, tributyl citrate 26 parts, benzotriazole 30 parts, methanesulfonate ester 26 parts, ethyl-borate 30 parts, metallic silicon power 26 parts.
Further, above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating, be made up of the component of following mass fraction: Natvosol 30 parts, stannous octoate 32 parts, methyl-monosilane 28 parts, acetofenate 32 parts, dimethyl ester 28 parts, cerium oxide 32 parts, dimethylaminopropylamine 28 parts, sodium oleate 34 parts, trimethylolpropane trimethacrylate 28 parts, cellulose acetate butyrate 32 parts, vinyl-acetic ester 28 parts, montmorillonite powder 32 parts, sepiolite powder 28 parts, titanium dioxide 32 parts, zinc phosphate 28 parts, phthalocyanine blue 32 parts, tributyl citrate 28 parts, benzotriazole 32 parts, methanesulfonate ester 28 parts, ethyl-borate 32 parts, metallic silicon power 28 parts.
Further, above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating production step is as follows:
(1) Natvosol of described mass fraction, stannous octoate, methyl-monosilane, acetofenate, dimethyl ester, cerium oxide, dimethylaminopropylamine, sodium oleate, trimethylolpropane trimethacrylate, cellulose acetate butyrate, vinyl-acetic ester, sepiolite powder, zinc phosphate, phthalocyanine blue, tributyl citrate, benzotriazole, methanesulfonate ester, ethyl-borate, metallic silicon power are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the montmorillonite powder of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the titanium dioxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
This beneficial effect of the invention is: this anti-oxidant fire-retardant anti-rust metal sheet material preparation technology of coating method is simple, and prepared product has comparatively superior fire-retardant, acid and alkali-resistance, anti-rusting antibiotic performance, is adapted at multiple fields and uses, improve product performance.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
Embodiment 1
Anti-oxidant fire-retardant anti-rust metal sheet material coating in the present embodiment, be made up of the component of following mass fraction: Natvosol 26 parts, stannous octoate 28 parts, methyl-monosilane 24 parts, acetofenate 28 parts, dimethyl ester 24 parts, cerium oxide 28 parts, dimethylaminopropylamine 24 parts, sodium oleate 30 parts, trimethylolpropane trimethacrylate 24 parts, cellulose acetate butyrate 28 parts, vinyl-acetic ester 24 parts, montmorillonite powder 28 parts, sepiolite powder 24 parts, titanium dioxide 28 parts, zinc phosphate 24 parts, phthalocyanine blue 28 parts, tributyl citrate 24 parts, benzotriazole 28 parts, methanesulfonate ester 24 parts, ethyl-borate 28 parts, metallic silicon power 24 parts.
Above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating production step is as follows:
(1) Natvosol of described mass fraction, stannous octoate, methyl-monosilane, acetofenate, dimethyl ester, cerium oxide, dimethylaminopropylamine, sodium oleate, trimethylolpropane trimethacrylate, cellulose acetate butyrate, vinyl-acetic ester, sepiolite powder, zinc phosphate, phthalocyanine blue, tributyl citrate, benzotriazole, methanesulfonate ester, ethyl-borate, metallic silicon power are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 5400r/min, jitter time is 60min;
(2) add the montmorillonite powder of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 5200r/min, and jitter time is 50min;
(3) add the titanium dioxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 4800r/min, and jitter time is 40min; Mix rear obtained this product.
Embodiment 2
Anti-oxidant fire-retardant anti-rust metal sheet material coating in the present embodiment, be made up of the component of following mass fraction: Natvosol 28 parts, stannous octoate 30 parts, methyl-monosilane 26 parts, acetofenate 30 parts, dimethyl ester 26 parts, cerium oxide 30 parts, dimethylaminopropylamine 26 parts, sodium oleate 32 parts, trimethylolpropane trimethacrylate 26 parts, cellulose acetate butyrate 30 parts, vinyl-acetic ester 26 parts, montmorillonite powder 30 parts, sepiolite powder 26 parts, titanium dioxide 30 parts, zinc phosphate 26 parts, phthalocyanine blue 30 parts, tributyl citrate 26 parts, benzotriazole 30 parts, methanesulfonate ester 26 parts, ethyl-borate 30 parts, metallic silicon power 26 parts.
Above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating production step is as follows:
(1) Natvosol of described mass fraction, stannous octoate, methyl-monosilane, acetofenate, dimethyl ester, cerium oxide, dimethylaminopropylamine, sodium oleate, trimethylolpropane trimethacrylate, cellulose acetate butyrate, vinyl-acetic ester, sepiolite powder, zinc phosphate, phthalocyanine blue, tributyl citrate, benzotriazole, methanesulfonate ester, ethyl-borate, metallic silicon power are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion 5200r/min, jitter time is 45min;
(2) add the montmorillonite powder of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion 5000r/min, and jitter time is 40min;
(3) add the titanium dioxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion 4700r/min, and jitter time is 30min; Mix rear obtained this product.
Embodiment 3
Anti-oxidant fire-retardant anti-rust metal sheet material coating in the present embodiment, be made up of the component of following mass fraction: Natvosol 30 parts, stannous octoate 32 parts, methyl-monosilane 28 parts, acetofenate 32 parts, dimethyl ester 28 parts, cerium oxide 32 parts, dimethylaminopropylamine 28 parts, sodium oleate 34 parts, trimethylolpropane trimethacrylate 28 parts, cellulose acetate butyrate 32 parts, vinyl-acetic ester 28 parts, montmorillonite powder 32 parts, sepiolite powder 28 parts, titanium dioxide 32 parts, zinc phosphate 28 parts, phthalocyanine blue 32 parts, tributyl citrate 28 parts, benzotriazole 32 parts, methanesulfonate ester 28 parts, ethyl-borate 32 parts, metallic silicon power 28 parts.
Above-mentioned anti-oxidant fire-retardant anti-rust metal sheet material coating production step is as follows:
(1) Natvosol of described mass fraction, stannous octoate, methyl-monosilane, acetofenate, dimethyl ester, cerium oxide, dimethylaminopropylamine, sodium oleate, trimethylolpropane trimethacrylate, cellulose acetate butyrate, vinyl-acetic ester, sepiolite powder, zinc phosphate, phthalocyanine blue, tributyl citrate, benzotriazole, methanesulfonate ester, ethyl-borate, metallic silicon power are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, jitter time is 30min;
(2) add the montmorillonite powder of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) add the titanium dioxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion 4600r/min, and jitter time is 20min; Mix rear obtained this product.
Carry out performance measurement for the product in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available prod, measured data are as shown in table 1.Fire protection flame retarding level estimate adopts UL94 standard.
Table 1 the performance test results
Visible, product of the present invention has corrosion-resistant, fire protection flame retarding, antirust, anti-microbial property preferably.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. an anti-oxidant fire-retardant anti-rust metal sheet material coating, it is characterized in that: be made up of the component of following mass fraction: Natvosol 26 ~ 30 parts, stannous octoate 28 ~ 32 parts, methyl-monosilane 24 ~ 28 parts, acetofenate 28 ~ 32 parts, dimethyl ester 24 ~ 28 parts, cerium oxide 28 ~ 32 parts, dimethylaminopropylamine 24 ~ 28 parts, sodium oleate 30 ~ 34 parts, trimethylolpropane trimethacrylate 24 ~ 28 parts, cellulose acetate butyrate 28 ~ 32 parts, vinyl-acetic ester 24 ~ 28 parts, montmorillonite powder 28 ~ 32 parts, sepiolite powder 24 ~ 28 parts, titanium dioxide 28 ~ 32 parts, zinc phosphate 24 ~ 28 parts, phthalocyanine blue 28 ~ 32 parts, tributyl citrate 24 ~ 28 parts, benzotriazole 28 ~ 32 parts, methanesulfonate ester 24 ~ 28 parts, ethyl-borate 28 ~ 32 parts, metallic silicon power 24 ~ 28 parts.
2. anti-oxidant fire-retardant anti-rust metal sheet material coating according to claim 1, it is characterized in that: described anti-oxidant fire-retardant anti-rust metal sheet material coating is made up of the component of following mass fraction: Natvosol 26 parts, stannous octoate 28 parts, methyl-monosilane 24 parts, acetofenate 28 parts, dimethyl ester 24 parts, cerium oxide 28 parts, dimethylaminopropylamine 24 parts, sodium oleate 30 parts, trimethylolpropane trimethacrylate 24 parts, cellulose acetate butyrate 28 parts, vinyl-acetic ester 24 parts, montmorillonite powder 28 parts, sepiolite powder 24 parts, titanium dioxide 28 parts, zinc phosphate 24 parts, phthalocyanine blue 28 parts, tributyl citrate 24 parts, benzotriazole 28 parts, methanesulfonate ester 24 parts, ethyl-borate 28 parts, metallic silicon power 24 parts.
3. anti-oxidant fire-retardant anti-rust metal sheet material coating according to claim 1, it is characterized in that: described anti-oxidant fire-retardant anti-rust metal sheet material coating is made up of the component of following mass fraction: Natvosol 28 parts, stannous octoate 30 parts, methyl-monosilane 26 parts, acetofenate 30 parts, dimethyl ester 26 parts, cerium oxide 30 parts, dimethylaminopropylamine 26 parts, sodium oleate 32 parts, trimethylolpropane trimethacrylate 26 parts, cellulose acetate butyrate 30 parts, vinyl-acetic ester 26 parts, montmorillonite powder 30 parts, sepiolite powder 26 parts, titanium dioxide 30 parts, zinc phosphate 26 parts, phthalocyanine blue 30 parts, tributyl citrate 26 parts, benzotriazole 30 parts, methanesulfonate ester 26 parts, ethyl-borate 30 parts, metallic silicon power 26 parts.
4. anti-oxidant fire-retardant anti-rust metal sheet material coating according to claim 1, it is characterized in that: described anti-oxidant fire-retardant anti-rust metal sheet material coating is made up of the component of following mass fraction: Natvosol 30 parts, stannous octoate 32 parts, methyl-monosilane 28 parts, acetofenate 32 parts, dimethyl ester 28 parts, cerium oxide 32 parts, dimethylaminopropylamine 28 parts, sodium oleate 34 parts, trimethylolpropane trimethacrylate 28 parts, cellulose acetate butyrate 32 parts, vinyl-acetic ester 28 parts, montmorillonite powder 32 parts, sepiolite powder 28 parts, titanium dioxide 32 parts, zinc phosphate 28 parts, phthalocyanine blue 32 parts, tributyl citrate 28 parts, benzotriazole 32 parts, methanesulfonate ester 28 parts, ethyl-borate 32 parts, metallic silicon power 28 parts.
5. the anti-oxidant fire-retardant anti-rust metal sheet material coating according to claim 1 or 4, is characterized in that: described anti-oxidant fire-retardant anti-rust metal sheet material coating production step is as follows:
(1) Natvosol of described mass fraction, stannous octoate, methyl-monosilane, acetofenate, dimethyl ester, cerium oxide, dimethylaminopropylamine, sodium oleate, trimethylolpropane trimethacrylate, cellulose acetate butyrate, vinyl-acetic ester, sepiolite powder, zinc phosphate, phthalocyanine blue, tributyl citrate, benzotriazole, methanesulfonate ester, ethyl-borate, metallic silicon power are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the montmorillonite powder of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the titanium dioxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109054608A (en) * | 2018-06-15 | 2018-12-21 | 苏州益可泰电子材料有限公司 | metal material and preparation method thereof |
| CN109054635A (en) * | 2018-06-15 | 2018-12-21 | 苏州益可泰电子材料有限公司 | High molecular material and preparation method thereof |
| CN113045920A (en) * | 2021-05-13 | 2021-06-29 | 深圳中宝新材科技有限公司 | Anti-oxidation bonding copper wire and preparation method thereof |
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| CN109054608A (en) * | 2018-06-15 | 2018-12-21 | 苏州益可泰电子材料有限公司 | metal material and preparation method thereof |
| CN109054635A (en) * | 2018-06-15 | 2018-12-21 | 苏州益可泰电子材料有限公司 | High molecular material and preparation method thereof |
| CN109054608B (en) * | 2018-06-15 | 2021-03-19 | 苏州益可泰电子材料有限公司 | Metal material and preparation method thereof |
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Application publication date: 20160504 |