CN103911860B - A kind of artificial fibre fire-proof flame-retarded agent - Google Patents
A kind of artificial fibre fire-proof flame-retarded agent Download PDFInfo
- Publication number
- CN103911860B CN103911860B CN201310737588.4A CN201310737588A CN103911860B CN 103911860 B CN103911860 B CN 103911860B CN 201310737588 A CN201310737588 A CN 201310737588A CN 103911860 B CN103911860 B CN 103911860B
- Authority
- CN
- China
- Prior art keywords
- fire
- artificial fibre
- proof flame
- retarded agent
- polyvinyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002994 synthetic fiber Polymers 0.000 title claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 24
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003063 flame retardant Substances 0.000 claims abstract description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 12
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000013256 coordination polymer Substances 0.000 claims abstract description 12
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004753 textile Substances 0.000 abstract description 4
- 230000000979 retarding effect Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Abstract
The invention discloses a kind of artificial fibre fire-proof flame-retarded agent.With parts by weight, the present invention is composed of the following components: fire retardant CP:10 ~ 20, methyl acrylate: 6 ~ 10, ethyl acetate: 3 ~ 5, trimethylol melamine: 3 ~ 8, glycidyl methacrylate: 4 ~ 8, acrylic acid-2-ethyl propyl ester: 3 ~ 8, methacrylic acid: 4 ~ 8, diethyl phthalate: 1 ~ 3, polyvinyl alcohol: 10 ~ 20, water: 200 ~ 400.Compared with prior art, the present invention has good fire protection flame retarding effect to the textiles that artificial fibre is made, and in addition, the present invention also has good mildew-resistant, anti-corrosion function.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, more specifically relate to a kind of artificial fibre fire-proof flame-retarded agent.
Background technology
Artificial fibre belongs to combustible material, and slightly not careful just easy initiation fire, therefore, carries out fire protection flame retarding process to artificial fibre, is prevent fire from occurring or reduce the important measures of fire damage.China also expressly provides at present, must use fire-proof flame-retardant fibre textiles in seagoing vessel, aircraft and luxurious hotel etc.
Summary of the invention
The object of the invention is to the deficiency overcoming prior art existence, a kind of artificial fibre fire-proof flame-retarded agent is provided.
For achieving the above object, this invention takes following technical scheme:
A kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:10 ~ 20, methyl acrylate: 6 ~ 10, ethyl acetate: 3 ~ 5,
Trimethylol melamine: 3 ~ 8, glycidyl methacrylate: 4 ~ 8,
Acrylic acid-2-ethyl propyl ester: 3 ~ 8, methacrylic acid: 4 ~ 8,
Diethyl phthalate: 1 ~ 3, polyvinyl alcohol: 10 ~ 20, water: 200 ~ 400.
As preferably, described a kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:10, methyl acrylate: 6, ethyl acetate: 3,
Trimethylol melamine: 3, glycidyl methacrylate: 4,
Acrylic acid-2-ethyl propyl ester: 3, methacrylic acid: 4,
Diethyl phthalate: 1, polyvinyl alcohol: 10, water: 200.
As preferably, described a kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:20, methyl acrylate: 10, ethyl acetate: 5,
Trimethylol melamine: 8, glycidyl methacrylate: 8,
Acrylic acid-2-ethyl propyl ester: 8, methacrylic acid: 8,
Diethyl phthalate: 3, polyvinyl alcohol: 20, water: 400.
As preferably, described a kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:16, methyl acrylate: 8, ethyl acetate: 4,
Trimethylol melamine: 6, glycidyl methacrylate: 6,
Acrylic acid-2-ethyl propyl ester: 5, methacrylic acid: 6,
Diethyl phthalate: 2, polyvinyl alcohol: 15, water: 300.
The preparation method of described a kind of artificial fibre fire-proof flame-retarded agent is: by proportioning, each component mixed, dispersed with stirring evenly after finished product.
Compared with prior art, the present invention has good fire protection flame retarding effect to the textiles that artificial fibre is made, and in addition, the present invention also has good mildew-resistant, anti-corrosion function.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:10, methyl acrylate: 6, ethyl acetate: 3,
Trimethylol melamine: 3, glycidyl methacrylate: 4,
Acrylic acid-2-ethyl propyl ester: 3, methacrylic acid: 4,
Diethyl phthalate: 1, polyvinyl alcohol: 10, water: 200.
Embodiment 2
A kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:20, methyl acrylate: 10, ethyl acetate: 5,
Trimethylol melamine: 8, glycidyl methacrylate: 8,
Acrylic acid-2-ethyl propyl ester: 8, methacrylic acid: 8,
Diethyl phthalate: 3, polyvinyl alcohol: 20, water: 400.
Embodiment 3
A kind of artificial fibre fire-proof flame-retarded agent, with parts by weight, composed of the following components:
Fire retardant CP:16, methyl acrylate: 8, ethyl acetate: 4,
Trimethylol melamine: 6, glycidyl methacrylate: 6,
Acrylic acid-2-ethyl propyl ester: 5, methacrylic acid: 6,
Diethyl phthalate: 2, polyvinyl alcohol: 15, water: 300.
The preparation method of described a kind of artificial fibre fire-proof flame-retarded agent is: by proportioning, each component mixed, dispersed with stirring evenly after finished product.
Claims (4)
1. an artificial fibre fire-proof flame-retarded agent, is characterized in that, with parts by weight, composed of the following components:
Fire retardant CP:10 ~ 20, methyl acrylate: 6 ~ 10, ethyl acetate: 3 ~ 5,
Trimethylol melamine: 3 ~ 8, glycidyl methacrylate: 4 ~ 8,
Acrylic acid-2-ethyl propyl ester: 3 ~ 8, methacrylic acid: 4 ~ 8,
Diethyl phthalate: 1 ~ 3, polyvinyl alcohol: 10 ~ 20, water: 200 ~ 400.
2. a kind of artificial fibre fire-proof flame-retarded agent according to claim 1, is characterized in that, with parts by weight, composed of the following components:
Fire retardant CP:10, methyl acrylate: 6, ethyl acetate: 3,
Trimethylol melamine: 3, glycidyl methacrylate: 4,
Acrylic acid-2-ethyl propyl ester: 3, methacrylic acid: 4,
Diethyl phthalate: 1, polyvinyl alcohol: 10, water: 200.
3. a kind of artificial fibre fire-proof flame-retarded agent according to claim 1, is characterized in that, with parts by weight, composed of the following components:
Fire retardant CP:20, methyl acrylate: 10, ethyl acetate: 5,
Trimethylol melamine: 8, glycidyl methacrylate: 8,
Acrylic acid-2-ethyl propyl ester: 8, methacrylic acid: 8,
Diethyl phthalate: 3, polyvinyl alcohol: 20, water: 400.
4. a kind of artificial fibre fire-proof flame-retarded agent according to claim 1, is characterized in that, with parts by weight, composed of the following components:
Fire retardant CP:16, methyl acrylate: 8, ethyl acetate: 4,
Trimethylol melamine: 6, glycidyl methacrylate: 6,
Acrylic acid-2-ethyl propyl ester: 5, methacrylic acid: 6,
Diethyl phthalate: 2, polyvinyl alcohol: 15, water: 300.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310737588.4A CN103911860B (en) | 2013-12-27 | 2013-12-27 | A kind of artificial fibre fire-proof flame-retarded agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310737588.4A CN103911860B (en) | 2013-12-27 | 2013-12-27 | A kind of artificial fibre fire-proof flame-retarded agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103911860A CN103911860A (en) | 2014-07-09 |
| CN103911860B true CN103911860B (en) | 2016-03-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310737588.4A Expired - Fee Related CN103911860B (en) | 2013-12-27 | 2013-12-27 | A kind of artificial fibre fire-proof flame-retarded agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN103911860B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017183535A1 (en) * | 2016-04-18 | 2017-10-26 | 昭和電工株式会社 | Fiber treatment agent, method for producing processed fiber article, and processed fiber article |
| CN106521669A (en) * | 2016-08-31 | 2017-03-22 | 浙江益南纤维科技有限公司 | Novel composite viscose fiber special for fireproof flame-retardant fabric |
| CN111395000A (en) * | 2019-05-16 | 2020-07-10 | 佛山市三水中信达地毯制品有限公司 | Special fireproof flame retardant for carpet and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102330329A (en) * | 2011-07-29 | 2012-01-25 | 苏州卡奇特纺织有限公司 | Fire retardant for viscose fabric |
| CN102965939A (en) * | 2012-11-22 | 2013-03-13 | 吴江福茂纺织有限公司 | Fire-proof flame retardant specially used for curtain and preparation method thereof |
| CN103103772A (en) * | 2012-11-08 | 2013-05-15 | 吴江市钱氏纺织有限公司 | Antistatic finishing agent and preparation method thereof |
| CN103243549A (en) * | 2013-05-09 | 2013-08-14 | 湖州吉昌丝绸有限公司 | Fabric fire retardant |
| CN103290676A (en) * | 2013-05-16 | 2013-09-11 | 陈林美 | Oiling agent for fiber |
| CN103437182A (en) * | 2013-09-02 | 2013-12-11 | 徐文 | Improved fireproof flame retardant for textiles |
-
2013
- 2013-12-27 CN CN201310737588.4A patent/CN103911860B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102330329A (en) * | 2011-07-29 | 2012-01-25 | 苏州卡奇特纺织有限公司 | Fire retardant for viscose fabric |
| CN103103772A (en) * | 2012-11-08 | 2013-05-15 | 吴江市钱氏纺织有限公司 | Antistatic finishing agent and preparation method thereof |
| CN102965939A (en) * | 2012-11-22 | 2013-03-13 | 吴江福茂纺织有限公司 | Fire-proof flame retardant specially used for curtain and preparation method thereof |
| CN103243549A (en) * | 2013-05-09 | 2013-08-14 | 湖州吉昌丝绸有限公司 | Fabric fire retardant |
| CN103290676A (en) * | 2013-05-16 | 2013-09-11 | 陈林美 | Oiling agent for fiber |
| CN103437182A (en) * | 2013-09-02 | 2013-12-11 | 徐文 | Improved fireproof flame retardant for textiles |
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| CN103911860A (en) | 2014-07-09 |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lin Qianqian Inventor before: Chen Yonglin |
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| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160215 Address after: Jiangdong District 315000 Zhejiang city of Ningbo Province Yue Sheng Road No. 311 building 003 (14-5) (central office) Applicant after: NINGBO JIANGDONG LINQING ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD. Address before: 215228 Jiangsu City, Wujiang Province, Shengze Town, silk Center Plaza, room 3, apartment, Room 405, No. Applicant before: Suzhou Huace Textile Technology Co., Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161207 Address after: 224500 Yancheng City Binhai Modern Agriculture Park Road, No. 88, Jiangsu Patentee after: Jiangsu Huifeng Textile Co., Ltd. Address before: Jiangdong District 315000 Zhejiang city of Ningbo Province Yue Sheng Road No. 311 building 003 (14-5) (central office) Patentee before: NINGBO JIANGDONG LINQING ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160330 Termination date: 20191227 |