CN106521669A - Novel composite viscose fiber special for fireproof flame-retardant fabric - Google Patents
Novel composite viscose fiber special for fireproof flame-retardant fabric Download PDFInfo
- Publication number
- CN106521669A CN106521669A CN201610779139.XA CN201610779139A CN106521669A CN 106521669 A CN106521669 A CN 106521669A CN 201610779139 A CN201610779139 A CN 201610779139A CN 106521669 A CN106521669 A CN 106521669A
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- China
- Prior art keywords
- parts
- acid
- methacrylic acid
- cotton fiber
- bisphenol
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses novel composite viscose fiber special for fireproof flame-retardant fabric; the novel composite viscose fiber is prepared from, by weight, 80-88 parts of soluble cellulose xanthate, 10-15 parts of ammonium phosphate, 3-6 parts of styrene polymer, 4-5 parts of bisphenol A, 1.5-2 parts of ammonium molybdate, 2.5-4 parts of styrene-acrylonitrile copolymer, 3-5 parts of methyl acrylate, 6-8 parts of ethyl acetate, 7-10 parts of glycidyl methacrylate, 4-8 parts of 2-ethylpropyl acrylate, 2-3 parts of methacrylic acid, 4-5 parts of diethyl phthalate, and 15-30 parts of polyvinyl alcohol. By adding the various components to the soluble cellulose xanthate, the produced fiber has good flame retardancy and fireproof property; chances for a fire can be effectively slimmed, the spreading speed of a fire can be decreased, and mass toxic harmful gases are rarely produced after burning.
Description
【Technical field】
The present invention relates to the technical field of chemical industry, the particularly technical field of people's cotton fiber.
【Background technology】
Common people's cotton fiber belongs to combustible material, is not slightly easy for initiation fire with caution, therefore, people's cotton fiber is produced
During carry out the improvement of fire protection flame retarding, be to prevent fire from occurring or reducing the important measures of fire damage.China is also bright at present
Text regulation, must use fire-proof flame-retardant fibre textile in seagoing vessel, aircraft and luxurious hotel etc..
【The content of the invention】
The purpose of the present invention is exactly to solve the problems of the prior art, proposes that a kind of fire protection flame retarding fabric special utility is combined
People's cotton fiber, can make fiber have good fire retardant performance.
For achieving the above object, the present invention proposes a kind of compound people's cotton fiber of fire protection flame retarding fabric special utility, including
Following components and each component mass fraction is：Soluble cellulose xanthate acid 80-88 parts, ammonium phosphate salt 10-15 parts, styrene gather
Compound 3-6 parts, the double 4-5 parts of bisphenol-A, ammonium molybdate 1.5-2 parts, SAN 2.5-4 parts, methyl acrylate 3-5
Part, ethyl acetate 6-8 parts, GMA 7-10 parts, acrylic acid-2-ethyl propyl ester 4-8 parts, methacrylic acid
2-3 parts, diethyl phthalate 4-5 parts, polyvinyl alcohol 15-30 parts.
Preferably, the soluble cellulose xanthate acid be by native cellulose be raw material, Jing alkalization, aging and yellow
Make etc. operation.
Preferably, each component mass fraction is：80 parts of soluble cellulose xanthate acid, 10 parts of ammonium phosphate salt, benzene
5 parts of ethene polymers, bisphenol-A are double 4 parts, 1.5 parts of ammonium molybdate, 4 parts of SAN, 5 parts of methyl acrylate, vinegar
7 parts of acetoacetic ester, 10 parts of GMA, 5 parts of acrylic acid-2-ethyl propyl ester, 2 parts of methacrylic acid, adjacent benzene two
4 parts of formic acid diethylester, 30 parts of polyvinyl alcohol.
Preferably, each component mass fraction is：85 parts of soluble cellulose xanthate acid, 13 parts of ammonium phosphate salt, benzene
5 parts of ethene polymers, bisphenol-A are double 4.5 parts, 1.8 parts of ammonium molybdate, 3 parts of SAN, 3 parts of methyl acrylate,
6 parts of ethyl acetate, 8 parts of GMA, 7 parts of acrylic acid-2-ethyl propyl ester, 2.5 parts of methacrylic acid, adjacent benzene
4.5 parts of dicarboxylate, 16 parts of polyvinyl alcohol.
Preferably, each component mass fraction is：88 parts of soluble cellulose xanthate acid, 15 parts of ammonium phosphate salt, benzene
6 parts of ethene polymers, bisphenol-A are double 5 parts, 2 parts of ammonium molybdate, 4 parts of SAN, 4 parts of methyl acrylate, acetic acid
6 parts of ethyl ester, 7 parts of GMA, 8 parts of acrylic acid-2-ethyl propyl ester, 3 parts of methacrylic acid, phthalic acid
5 parts of diethylester, 20 parts of polyvinyl alcohol.
Beneficial effects of the present invention：The present invention is by various components are added in soluble cellulose xanthate acid so that
Obtained fiber has good flame-retardant performance, can effectively reduce the probability of happening of fire, slows down spreading for the intensity of a fire
Speed, while be not likely to produce substantial amounts of toxic and harmful after it there is burning.
The feature and advantage of the present invention will be described in detail by embodiment.
【Specific embodiment】
Specific embodiment one：
A kind of fire protection flame retarding fabric special utility of the present invention is combined people's cotton fiber, and each component mass fraction is：It is soluble fine
Plain 80 parts of the xanthate acid of dimension, 10 parts of ammonium phosphate salt, 5 parts of styrene polymer, double 4 parts bisphenol-A, 1.5 parts of ammonium molybdate, styrene-the third
4 parts of alkene lonitrile copolymer, 5 parts of methyl acrylate, 7 parts of ethyl acetate, 10 parts of GMA, acrylic acid -2- second
5 parts of base propyl ester, 2 parts of methacrylic acid, 4 parts of diethyl phthalate, 30 parts of polyvinyl alcohol.
Specific embodiment two：
A kind of fire protection flame retarding fabric special utility of the present invention is combined people's cotton fiber, and each component mass fraction is：It is soluble fine
Plain 85 parts of the xanthate acid of dimension, 13 parts of ammonium phosphate salt, 5 parts of styrene polymer, double 4.5 parts bisphenol-A, 1.8 parts of ammonium molybdate, styrene-
3 parts of acrylonitrile copolymer, 3 parts of methyl acrylate, 6 parts of ethyl acetate, 8 parts of GMA, acrylic acid -2- second
7 parts of base propyl ester, 2.5 parts of methacrylic acid, 4.5 parts of diethyl phthalate, 16 parts of polyvinyl alcohol.
Specific embodiment three：
A kind of fire protection flame retarding fabric special utility of the present invention is combined people's cotton fiber, and each component mass fraction is：It is soluble fine
Plain 88 parts of the xanthate acid of dimension, 15 parts of ammonium phosphate salt, 6 parts of styrene polymer, double 5 parts bisphenol-A, 2 parts of ammonium molybdate, styrene-propene
4 parts of lonitrile copolymer, 4 parts of methyl acrylate, 6 parts of ethyl acetate, 7 parts of GMA, acrylic acid-2-ethyl third
8 parts of ester, 3 parts of methacrylic acid, 5 parts of diethyl phthalate, 20 parts of polyvinyl alcohol.
The course of work of the present invention：
In the course of the work, various components are added to a kind of compound people's cotton fiber of fire protection flame retarding fabric special utility of the present invention
In soluble cellulose xanthate acid so that obtained fiber has good flame-retardant performance, can effectively reduce fire
Probability of happening, slow down the rate of propagation of the intensity of a fire, at the same occur burning after be not likely to produce substantial amounts of toxic and harmful.
Above-described embodiment is the description of the invention, is not limitation of the invention, it is any to simple transformation of the present invention after
Scheme belong to protection scope of the present invention.
Claims (5)
1. a kind of fire protection flame retarding fabric special utility is combined people's cotton fiber, it is characterised in that：Including following components and each group sub-prime
Measuring number is：Soluble cellulose xanthate acid 80-88 parts, ammonium phosphate salt 10-15 parts, styrene polymer 3-6 parts, bisphenol-A are double
4-5 parts, ammonium molybdate 1.5-2 parts, SAN 2.5-4 parts, methyl acrylate 3-5 parts, ethyl acetate 6-8 parts,
GMA 7-10 parts, acrylic acid-2-ethyl propyl ester 4-8 parts, methacrylic acid 2-3 parts, phthalic acid
Diethylester 4-5 parts, polyvinyl alcohol 15-30 parts.
2. a kind of fire protection flame retarding fabric special utility as claimed in claim 1 is combined people's cotton fiber, it is characterised in that：It is described can
It is raw material by native cellulose that cellulose of solubleness xanthate acid is, the operation such as Jing alkalization, aging and yellow is made.
3. a kind of fire protection flame retarding fabric special utility as claimed in claim 1 is combined people's cotton fiber, it is characterised in that：It is described each
Constituent mass number is：80 parts of soluble cellulose xanthate acid, 10 parts of ammonium phosphate salt, 5 parts of styrene polymer, bisphenol-A double 4
Part, the contracting of 1.5 parts of ammonium molybdate, 4 parts of SAN, 5 parts of methyl acrylate, 7 parts of ethyl acetate, methacrylic acid
10 parts of water glyceride, 5 parts of acrylic acid-2-ethyl propyl ester, 2 parts of methacrylic acid, 4 parts of diethyl phthalate, polyvinyl alcohol
30 parts.
4. a kind of fire protection flame retarding fabric special utility as claimed in claim 1 is combined people's cotton fiber, it is characterised in that：It is described each
Constituent mass number is：85 parts of soluble cellulose xanthate acid, 13 parts of ammonium phosphate salt, 5 parts of styrene polymer, bisphenol-A double 4.5
Part, the contracting of 1.8 parts of ammonium molybdate, 3 parts of SAN, 3 parts of methyl acrylate, 6 parts of ethyl acetate, methacrylic acid
8 parts of water glyceride, 7 parts of acrylic acid-2-ethyl propyl ester, 2.5 parts of methacrylic acid, 4.5 parts of diethyl phthalate, polyethylene
16 parts of alcohol.
5. a kind of fire protection flame retarding fabric special utility as claimed in claim 1 is combined people's cotton fiber, it is characterised in that：It is described each
Constituent mass number is：88 parts of soluble cellulose xanthate acid, 15 parts of ammonium phosphate salt, 6 parts of styrene polymer, bisphenol-A double 5
Part, 2 parts of ammonium molybdate, 4 parts of SAN, 4 parts of methyl acrylate, 6 parts of ethyl acetate, Glycidyl methacrylate
7 parts of glyceride, 8 parts of acrylic acid-2-ethyl propyl ester, 3 parts of methacrylic acid, 5 parts of diethyl phthalate, polyvinyl alcohol 20
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610779139.XA CN106521669A (en) | 2016-08-31 | 2016-08-31 | Novel composite viscose fiber special for fireproof flame-retardant fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610779139.XA CN106521669A (en) | 2016-08-31 | 2016-08-31 | Novel composite viscose fiber special for fireproof flame-retardant fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106521669A true CN106521669A (en) | 2017-03-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610779139.XA Pending CN106521669A (en) | 2016-08-31 | 2016-08-31 | Novel composite viscose fiber special for fireproof flame-retardant fabric |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597806A (en) * | 2008-06-06 | 2009-12-09 | 北京化工大学 | A kind of fire resistant viscose acetal fibre spinning solution and preparation method thereof |
| CN103710033A (en) * | 2013-12-10 | 2014-04-09 | 龙迪 | Environment-friendly and fireproof flame retardant |
| CN103911860A (en) * | 2013-12-27 | 2014-07-09 | 苏州华策纺织科技有限公司 | Artificial fiber fireproof fire retardant |
| CN104178836A (en) * | 2014-08-19 | 2014-12-03 | 吉林化纤股份有限公司 | Flame-retardant viscose staple fiber and preparation method thereof |
| CN105218863A (en) * | 2015-10-21 | 2016-01-06 | 昌邑市龙港无机硅有限公司 | A kind of silica-based fire retardant |
-
2016
- 2016-08-31 CN CN201610779139.XA patent/CN106521669A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597806A (en) * | 2008-06-06 | 2009-12-09 | 北京化工大学 | A kind of fire resistant viscose acetal fibre spinning solution and preparation method thereof |
| CN103710033A (en) * | 2013-12-10 | 2014-04-09 | 龙迪 | Environment-friendly and fireproof flame retardant |
| CN103911860A (en) * | 2013-12-27 | 2014-07-09 | 苏州华策纺织科技有限公司 | Artificial fiber fireproof fire retardant |
| CN104178836A (en) * | 2014-08-19 | 2014-12-03 | 吉林化纤股份有限公司 | Flame-retardant viscose staple fiber and preparation method thereof |
| CN105218863A (en) * | 2015-10-21 | 2016-01-06 | 昌邑市龙港无机硅有限公司 | A kind of silica-based fire retardant |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20170322 |