CN106589753A - Anti-flaming organic glass and preparation method thereof - Google Patents
Anti-flaming organic glass and preparation method thereof Download PDFInfo
- Publication number
- CN106589753A CN106589753A CN201611183477.3A CN201611183477A CN106589753A CN 106589753 A CN106589753 A CN 106589753A CN 201611183477 A CN201611183477 A CN 201611183477A CN 106589753 A CN106589753 A CN 106589753A
- Authority
- CN
- China
- Prior art keywords
- retardant
- parts
- composite flame
- fire
- lucite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/10—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/12—Esters of phenols or saturated alcohols
- C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses anti-flaming organic glass which comprises the following raw materials in parts by weight: 100-120 parts of methyl methacrylate, 5-10 parts of composite flame retardant, 10-12 parts of oxalic acid acrylate, 1-3 parts of trioctyl acetylcitrate, 13-17 parts of rubber particles, 2-4 parts of carboxymethylcellulose, 2-4 parts of modified carbon fibers and 0.5-1 part of lauroyl peroxide. The preparation process of the composite flame retardant comprises the following steps: uniformly mixing diethyl chlorophosphate with tetrahydrofuran; regulating the temperature; adding triethylamine and uniformly mixing; dropwise adding hydroxyethyl acrylate into the tetrahydrofuran solution and stirring under the heat preservation mode; increasing the temperature to the room temperature; stirring under the heat preservation mode and then purifying, thereby acquiring a material A; mixing the material A with expansible graphite and ammonium polyphosphate, thereby acquiring the composite flame retardant. The invention also discloses a preparation method for the anti-flaming organic glass. The anti-flaming organic glass is high in fire resistance and toughness.
Description
Technical field
The present invention relates to lucite technical field, more particularly to a kind of fire-retardant lucite and preparation method thereof.
Background technology
Lucite is to be by the macromolecular compound of methyl methacrylate polymerization, referred to as polymethylacrylic acid
Methyl ester, is abbreviated as PMMA.Lucite is widely used in the aspects such as daily life, industry, building, space flight.Lucite is divided into
Water white transparency, colored transparent, pearly-lustre, four kinds of lucite of embossing.Lucite is commonly called as acrylic, middle a surname's acryl, sub- Gree,
Lucite surface is smooth, beautiful in colour, and proportion is little, and intensity is larger, corrosion-resistant, moisture-proof, sun-proof, good insulation preformance, sound insulation property
It is good；But lucite easily burns, anti-flammability is low, toughness is low, easy to crack.It is usually added into fire retardant to improve lucite
Anti-flammability, but fire retardant can affect the toughness of lucite so that and the anti-flammability and toughness of lucite can not be balanced.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of fire-retardant lucite and preparation method thereof,
Good flame resistance of the present invention, toughness are high.
A kind of fire-retardant lucite proposed by the present invention, its raw material include by weight：Methyl methacrylate 100-120
Part, composite flame-retardant agent 5-10 parts, ethanedioic acid diacrylate 10-12 parts, ATOC 1-3 parts, rubber particles 13-
17 parts, carboxymethyl cellulose 2-4 parts, modified carbon fiber 2-4 parts, lauroyl peroxide 0.5-1 parts；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran is mixed, temperature is adjusted,
Triethylamine mixing is subsequently adding, then the tetrahydrofuran solution of Deca 2-(Acryloyloxy)ethanol, insulated and stirred, are warming up to room temperature, is protected
Temperature stirring, purification obtain material A；Material A is mixed to get into composite flame-retardant agent with modified expansible graphite, APP.
Preferably, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran is mixed, temperature is adjusted
For 0-4 DEG C, triethylamine mixing is subsequently adding, it is then molten with the tetrahydrofuran of the speed Deca 2-(Acryloyloxy)ethanol of 4-6 drops/min
Liquid, insulated and stirred 5-6h are warming up to room temperature, and insulated and stirred 8-10h filters to take filtrate, and rotary evaporation obtains material A；By material A
Composite flame-retardant agent is mixed to get with modified expansible graphite, APP.
Preferably, in the preparation process of composite flame-retardant agent, modified expansible graphite changes for vinyltrimethoxy silane
Property expansible graphite.
Preferably, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate, triethylamine, the weight of 2-(Acryloyloxy)ethanol
Amount is than being 1.7-3：1-1.8：1.2-2.
Preferably, in the preparation process of composite flame-retardant agent, material A, modified expansible graphite, the weight ratio of APP
For 2-3：1-2：3-4.
Preferably, modified carbon fiber is vinyltrimethoxy silane modified carbon fiber.
The invention allows for the preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-proof
Agent, ethanedioic acid diacrylate, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, peroxidating
During lauroyl adds methyl methacrylate, stirring and evenly mixing is warming up to 55-65 DEG C, insulated and stirred 40-50min, ice-water bath cooling
To 5-10 DEG C, 60-80min is stood, 45-55 DEG C is warming up to, be incubated 22-26h, then heat to 65-70 DEG C, be incubated 22-26h,
75-80 DEG C is warming up to again, 2-4h is incubated, is finally warming up to 95-100 DEG C, be incubated 2-3h, be cooled to room temperature and obtain fire-retardant organic glass
Glass.
Preferably, with the speed stirring and evenly mixing of 200-300r/min.
Preferably, room temperature is cooled to the speed of 0.5-1.5 DEG C/min.
In the preparation process of above-mentioned composite flame-retardant agent, tetrahydrofuran is solvent, does not specify its consumption, true according to concrete operations
Fixed its consumption.
The present invention obtains material A with 2-(Acryloyloxy)ethanol reaction from diethyl chloro-phosphate, removes chlorine element, increases this
Bright flame-proof environmental protection, and introduce carbon-carbon double bond, the material A containing carbon-carbon double bond and vinyltrimethoxy silane are modified can
Expanded graphite cooperates, and may be homogenously dispersed in methyl methacrylate, and methyl methacrylate can intercalation enter can be swollen
The interlayer of swollen graphite, increases the toughness and impact resistance of the present invention, under the effect of initiator lauroyl peroxide, ethanedioic acid dipropyl
Olefin(e) acid ester, methyl methacrylate and material A, modified expansible graphite crosslinking copolymerization, form complex network, so as in poly- methyl
Introduce the P elements and expansible graphite of good flame resistance in methyl acrylate copoly chain, and with dispersed phosphorus poly- in a network
Sour ammonium cooperates, so as to greatly increase the anti-flammability and toughness of the present invention；Vinyltrimethoxy silane modified carbon fiber can
In being dispersed in methacrylic acid and with its copolymerization, so as to further increase the present invention toughness and heat-resisting quantity, carbon modified
Fiber is cooperated with rubber particles, can increase the toughness and impact resistance of the present invention；Carboxymethyl cellulose can promote each thing
Matter is dispersed；Each material cooperates so that the present invention has good anti-flammability and toughness.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of fire-retardant lucite, its raw material include by weight：110 parts of methyl methacrylate, composite flame-retardant agent 7
Part, 11 parts of ethanedioic acid diacrylate, 2 parts of ATOC, 15 parts of rubber particles, 3 parts of carboxymethyl cellulose are modified
3 parts of carbon fiber, 0.8 part of lauroyl peroxide；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran is mixed, temperature is adjusted,
Triethylamine mixing is subsequently adding, then the tetrahydrofuran solution of Deca 2-(Acryloyloxy)ethanol, insulated and stirred, are warming up to room temperature, is protected
Temperature stirring, purification obtain material A；Material A is mixed to get into composite flame-retardant agent with modified expansible graphite, APP.
The preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-retardant agent, two propylene of ethanedioic acid
Acid esters, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, lauroyl peroxide add methyl-prop
In e pioic acid methyl ester, stirring and evenly mixing is warming up to 60 DEG C, and insulated and stirred 45min, ice-water bath are cooled to 7 DEG C, stands 70min, is warming up to
50 DEG C, 24h is incubated, 67 DEG C are then heated to, be incubated 24h, then be warming up to 78 DEG C, be incubated 3h, be finally warming up to 97 DEG C, be incubated
2.5h, is cooled to room temperature and obtains fire-retardant lucite.
Embodiment 2
A kind of fire-retardant lucite, its raw material include by weight：100 parts of methyl methacrylate, composite flame-retardant agent 10
Part, 10 parts of ethanedioic acid diacrylate, 3 parts of ATOC, 13 parts of rubber particles, 4 parts of carboxymethyl cellulose, ethylene
2 parts of base trimethoxy silane modified carbon fiber, 1 part of lauroyl peroxide；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran are mixed, adjusting temperature is
0 DEG C, it is subsequently adding triethylamine mixing, then with the tetrahydrofuran solution of the speed Deca 2-(Acryloyloxy)ethanol of 6 drop/min, insulation
Stirring 5h, is warming up to room temperature, and insulated and stirred 10h filters to take filtrate, and rotary evaporation obtains material A；By material A and vinyl three
Be modified expansible graphite, APP of methoxy silane is mixed to get composite flame-retardant agent, wherein, diethyl chloro-phosphate, triethylamine,
The weight ratio of 2-(Acryloyloxy)ethanol is 1.7：1.8：1.2, material A, vinyltrimethoxy silane are modified expansible graphite, poly- phosphorus
The weight ratio of sour ammonium is 3：1：4.
The preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-retardant agent, two propylene of ethanedioic acid
Acid esters, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, lauroyl peroxide add methyl-prop
In e pioic acid methyl ester, with the speed stirring and evenly mixing of 200r/min, 65 DEG C are warming up to, insulated and stirred 40min, ice-water bath are cooled to 10
DEG C, 60min is stood, 55 DEG C are warming up to, 22h is incubated, is then heated to 70 DEG C, be incubated 22h, then be warming up to 80 DEG C, be incubated 2h, most
After be warming up to 100 DEG C, be incubated 2h, room temperature is cooled to the speed of 1.5 DEG C/min and obtains fire-retardant lucite.
Embodiment 3
A kind of fire-retardant lucite, its raw material include by weight：120 parts of methyl methacrylate, composite flame-retardant agent 5
Part, 12 parts of ethanedioic acid diacrylate, 1 part of ATOC, 17 parts of rubber particles, 2 parts of carboxymethyl cellulose, ethylene
4 parts of base trimethoxy silane modified carbon fiber, 0.5 part of lauroyl peroxide；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran are mixed, adjusting temperature is
4 DEG C, it is subsequently adding triethylamine mixing, then with the tetrahydrofuran solution of the speed Deca 2-(Acryloyloxy)ethanol of 4 drop/min, insulation
Stirring 6h, is warming up to room temperature, and insulated and stirred 8h filters to take filtrate, and rotary evaporation obtains material A；By material A and vinyl front three
Be modified expansible graphite, APP of TMOS is mixed to get composite flame-retardant agent, wherein, diethyl chloro-phosphate, triethylamine, third
The weight ratio of olefin(e) acid hydroxyl ethyl ester is 3：1：2, material A, vinyltrimethoxy silane are modified expansible graphite, the weight of APP
Amount is than being 2：2：3.
The preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-retardant agent, two propylene of ethanedioic acid
Acid esters, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, lauroyl peroxide add methyl-prop
In e pioic acid methyl ester, with the speed stirring and evenly mixing of 300r/min, 55 DEG C are warming up to, insulated and stirred 50min, ice-water bath are cooled to 5 DEG C,
80min is stood, 45 DEG C are warming up to, 26h is incubated, is then heated to 65 DEG C, be incubated 26h, then be warming up to 75 DEG C, be incubated 4h, finally
95 DEG C are warming up to, 3h are incubated, room temperature are cooled to the speed of 0.5 DEG C/min and obtain fire-retardant lucite.
Embodiment 4
A kind of fire-retardant lucite, its raw material include by weight：105 parts of methyl methacrylate, composite flame-retardant agent 8
Part, 10.5 parts of ethanedioic acid diacrylate, 2.5 parts of ATOC, 14 parts of rubber particles, carboxymethyl cellulose 3.5
Part, 2.5 parts of vinyltrimethoxy silane modified carbon fiber, 0.9 part of lauroyl peroxide；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran are mixed, adjusting temperature is
1 DEG C, it is subsequently adding triethylamine mixing, then with the tetrahydrofuran solution of the speed Deca 2-(Acryloyloxy)ethanol of 6 drop/min, insulation
Stirring 5.2h, is warming up to room temperature, and insulated and stirred 9.5h filters to take filtrate, and rotary evaporation obtains material A；By material A and vinyl
Be modified expansible graphite, APP of trimethoxy silane is mixed to get composite flame-retardant agent, wherein, diethyl chloro-phosphate, three second
Amine, the weight ratio of 2-(Acryloyloxy)ethanol are 2.2：1.6：1.4, material A, vinyltrimethoxy silane be modified expansible graphite,
The weight ratio of APP is 2.7：1.2：3.8.
The preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-retardant agent, two propylene of ethanedioic acid
Acid esters, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, lauroyl peroxide add methyl-prop
In e pioic acid methyl ester, with the speed stirring and evenly mixing of 230r/min, 63 DEG C are warming up to, insulated and stirred 42min, ice-water bath are cooled to 8 DEG C,
65min is stood, 53 DEG C are warming up to, 23h is incubated, is then heated to 68 DEG C, be incubated 23h, then be warming up to 79 DEG C, be incubated 2.5h, most
After be warming up to 98 DEG C, be incubated 2.3h, room temperature is cooled to the speed of 1.2 DEG C/min and obtains fire-retardant lucite.
Embodiment 5
A kind of fire-retardant lucite, its raw material include by weight：115 parts of methyl methacrylate, composite flame-retardant agent 6
Part, 11.5 parts of ethanedioic acid diacrylate, 1.5 parts of ATOC, 16 parts of rubber particles, carboxymethyl cellulose 2.5
Part, 3.5 parts of vinyltrimethoxy silane modified carbon fiber, 0.7 part of lauroyl peroxide；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran are mixed, adjusting temperature is
3 DEG C, it is subsequently adding triethylamine mixing, then with the tetrahydrofuran solution of the speed Deca 2-(Acryloyloxy)ethanol of 4 drop/min, insulation
Stirring 5.8h, is warming up to room temperature, and insulated and stirred 8.5h filters to take filtrate, and rotary evaporation obtains material A；By material A and vinyl
Be modified expansible graphite, APP of trimethoxy silane is mixed to get composite flame-retardant agent, wherein, diethyl chloro-phosphate, three second
Amine, the weight ratio of 2-(Acryloyloxy)ethanol are 2.5：1.2：1.8, material A, vinyltrimethoxy silane be modified expansible graphite,
The weight ratio of APP is 2.3：1.8：3.2.
The preparation method of fire-retardant lucite described above, comprises the steps：By composite flame-retardant agent, two propylene of ethanedioic acid
Acid esters, ATOC, rubber particles, carboxymethyl cellulose, modified carbon fiber, lauroyl peroxide add methyl-prop
In e pioic acid methyl ester, with the speed stirring and evenly mixing of 270r/min, 57 DEG C are warming up to, insulated and stirred 48min, ice-water bath are cooled to 6 DEG C,
75min is stood, 47 DEG C are warming up to, 25h is incubated, is then heated to 67 DEG C, be incubated 25h, then be warming up to 77 DEG C, be incubated 3.5h, most
After be warming up to 96 DEG C, be incubated 2.7h, room temperature is cooled to the speed of 0.8 DEG C/min and obtains fire-retardant lucite.
Performance detection is carried out to embodiment 1-5, it is as a result as follows：
| Project | Limited oxygen index % | Bending strength MPa |
| Embodiment 1 | 47 | 171 |
| Embodiment 2 | 48 | 170 |
| Embodiment 3 | 49 | 172 |
| Embodiment 4 | 48 | 171 |
| Embodiment 5 | 50 | 173 |
The present invention can be seen that by upper table result there is good anti-flammability and toughness.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, should all be included within the scope of the present invention.
Claims (9)
1. a kind of fire-retardant lucite, it is characterised in that its raw material includes by weight：Methyl methacrylate 100-120 parts,
Composite flame-retardant agent 5-10 parts, ethanedioic acid diacrylate 10-12 parts, ATOC 1-3 parts, rubber particles 13-17
Part, carboxymethyl cellulose 2-4 parts, modified carbon fiber 2-4 parts, lauroyl peroxide 0.5-1 parts；
Wherein, in the preparation process of composite flame-retardant agent, diethyl chloro-phosphate and tetrahydrofuran is mixed, temperature is adjusted, then
Triethylamine is added to mix, then the tetrahydrofuran solution of Deca 2-(Acryloyloxy)ethanol, insulated and stirred, are warming up to room temperature, and insulation is stirred
Mix, purification obtains material A；Material A is mixed to get into composite flame-retardant agent with modified expansible graphite, APP.
2. fire-retardant lucite according to claim 1, it is characterised in that in the preparation process of composite flame-retardant agent, by chlorine
Diethyl phosphate and tetrahydrofuran are mixed, and it is 0-4 DEG C to adjust temperature, are subsequently adding triethylamine mixing, then with 4-6 drops/min's
The tetrahydrofuran solution of speed Deca 2-(Acryloyloxy)ethanol, insulated and stirred 5-6h are warming up to room temperature, and insulated and stirred 8-10h is filtered
Filtrate is taken, rotary evaporation obtains material A；Material A is mixed to get into composite flame-retardant agent with modified expansible graphite, APP.
3. fire-retardant lucite according to claim 1 or claim 2, it is characterised in that in the preparation process of composite flame-retardant agent, change
Property expansible graphite be the modified expansible graphite of vinyltrimethoxy silane.
4. the fire-retardant lucite according to any one of claim 1-3, it is characterised in that in the preparation process of composite flame-retardant agent
In, diethyl chloro-phosphate, triethylamine, the weight ratio of 2-(Acryloyloxy)ethanol are 1.7-3：1-1.8：1.2-2.
5. the fire-retardant lucite according to any one of claim 1-4, it is characterised in that in the preparation process of composite flame-retardant agent
In, material A, modified expansible graphite, the weight ratio of APP are 2-3：1-2：3-4.
6. the fire-retardant lucite according to any one of claim 1-5, it is characterised in that modified carbon fiber is vinyl front three
TMOS modified carbon fiber.
7. a kind of preparation method of lucite fire-retardant as described in any one of claim 1-6, it is characterised in that including following step
Suddenly：By composite flame-retardant agent, ethanedioic acid diacrylate, ATOC, rubber particles, carboxymethyl cellulose, modified
During carbon fiber, lauroyl peroxide add methyl methacrylate, stirring and evenly mixing is warming up to 55-65 DEG C, insulated and stirred 40-
50min, ice-water bath are cooled to 5-10 DEG C, stand 60-80min, are warming up to 45-55 DEG C, are incubated 22-26h, then heat to 65-
70 DEG C, 22-26h is incubated, then is warming up to 75-80 DEG C, be incubated 2-4h, be finally warming up to 95-100 DEG C, be incubated 2-3h, be cooled to room
Temperature obtains fire-retardant lucite.
8. the preparation method of fire-retardant lucite according to claim 7, it is characterised in that with the speed of 200-300r/min
Stirring and evenly mixing.
9. according to claim 7 or 8 fire-retardant lucite preparation method, it is characterised in that with 0.5-1.5 DEG C/min's
Speed is cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611183477.3A CN106589753A (en) | 2016-12-20 | 2016-12-20 | Anti-flaming organic glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611183477.3A CN106589753A (en) | 2016-12-20 | 2016-12-20 | Anti-flaming organic glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589753A true CN106589753A (en) | 2017-04-26 |
Family
ID=58600241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611183477.3A Pending CN106589753A (en) | 2016-12-20 | 2016-12-20 | Anti-flaming organic glass and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106589753A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236233A (en) * | 2017-07-25 | 2017-10-10 | 佛山市正略信息科技有限公司 | A kind of high-temperature-resistant antistatic lucite and preparation method thereof |
| CN109265598A (en) * | 2017-07-19 | 2019-01-25 | 上海广大有机玻璃有限公司 | A kind of fire-retardant organic glass and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724122A (en) * | 2009-10-30 | 2010-06-09 | 锦西化工研究院 | Method for preparing copolymerized modified organic glass |
| CN102190847A (en) * | 2011-05-18 | 2011-09-21 | 陕西理工学院 | Manufacture method for flame-retardant heat-insulation acrylic sheet |
| CN102295813A (en) * | 2011-05-18 | 2011-12-28 | 陕西理工学院 | Preparation method of antiflaming heat insulation acrylic plate |
| CN103232664A (en) * | 2013-04-17 | 2013-08-07 | 陕西理工学院 | Acrylic solid plate with characteristics of fire retardation, high strength and high toughness, and preparation method thereof |
| CN103333448A (en) * | 2013-07-11 | 2013-10-02 | 常熟市慧丰塑料制品有限公司 | Formula of multifunctional polymethylmethacrylate |
-
2016
- 2016-12-20 CN CN201611183477.3A patent/CN106589753A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724122A (en) * | 2009-10-30 | 2010-06-09 | 锦西化工研究院 | Method for preparing copolymerized modified organic glass |
| CN102190847A (en) * | 2011-05-18 | 2011-09-21 | 陕西理工学院 | Manufacture method for flame-retardant heat-insulation acrylic sheet |
| CN102295813A (en) * | 2011-05-18 | 2011-12-28 | 陕西理工学院 | Preparation method of antiflaming heat insulation acrylic plate |
| CN103232664A (en) * | 2013-04-17 | 2013-08-07 | 陕西理工学院 | Acrylic solid plate with characteristics of fire retardation, high strength and high toughness, and preparation method thereof |
| CN103333448A (en) * | 2013-07-11 | 2013-10-02 | 常熟市慧丰塑料制品有限公司 | Formula of multifunctional polymethylmethacrylate |
Non-Patent Citations (6)
| Title |
|---|
| DENNIS PRICE，等: "Flame retarding poly(methyl methacrylate) modified with phosphorus-containing compounds", 《POLYMER DEGRADATON AND STABILITY》 * |
| DENNIS PRICE，等: "Flame retarding poly(methyl methacrylate) with phosphorus-containing compounds：comparison of an additive with a reactive approach", 《POLYMER DEGRADATION AND STABILITY》 * |
| 国家防火建筑材料质量监督检验中心: "《中国防火建材产品技术手册》", 31 July 2006, 四川科学科技出版社 * |
| 林雪梅，等: "可膨胀石墨的应用研究进展", 《江苏化工》 * |
| 王晓丽，等: "丙烯酸乙基磷酸二乙酯的合成及其阻燃性能的研究", 《化学与生物工程》 * |
| 闫利，等: "有机玻璃增韧改性的研究进展", 《中国塑料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109265598A (en) * | 2017-07-19 | 2019-01-25 | 上海广大有机玻璃有限公司 | A kind of fire-retardant organic glass and preparation method thereof |
| CN107236233A (en) * | 2017-07-25 | 2017-10-10 | 佛山市正略信息科技有限公司 | A kind of high-temperature-resistant antistatic lucite and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104449419B (en) | A kind of ultraviolet-heat dual cure optical adhesive containing POLYBUTADIENE EPOXY RESIN | |
| CN105017703B (en) | A kind of preparation method of fire-retardant acryl plates | |
| CN106751309B (en) | A kind of fire-retardant toughened organic glass | |
| CN102731872A (en) | Sizing material for high-temperature-resisting rubber sole and preparation process thereof | |
| CN105315399A (en) | Highly-transparent flame-retardant modified organic glass and preparation method thereof | |
| CN106589753A (en) | Anti-flaming organic glass and preparation method thereof | |
| CN103044615B (en) | A kind of Hydroxy acrylic resin for reflective film and preparation method thereof | |
| CN110669181A (en) | Preparation method of novel acrylate emulsion for wood paint | |
| CN103013043B (en) | Heat-insulating flame-retarding pulverized fuel ash decorative plate and production method thereof | |
| CN104479523A (en) | Highly hydrophobicuv (ultraviolet) leather surface treating agent and preparation method thereof | |
| CN109206705A (en) | A kind of preparation method of luminescence generated by light low density polyethylene (LDPE) conversion film | |
| CN103880338A (en) | Preparation method of coal ash thermal insulation-decoration integrated plate | |
| WO2014002505A1 (en) | Methacrylic resin composition, molded product of same, and method for producing same | |
| CN109096672A (en) | A kind of heat-resistant fireproof organic glass | |
| CN102964792A (en) | Modified polycarbonate composition and LED (light-emitting diode) full-color screen module mask prepared therefrom | |
| CN101787102A (en) | Method for preparing white latex by utilizing polystyrene waste | |
| CN107935456A (en) | A kind of the hydrophobicity artificial stone and its preparation process of the enhancing of response type silicon powder | |
| CN104211852A (en) | Preparation method of acrylate emulsion for waterborne printing ink | |
| CN103555460B (en) | Reactive dye anti-staining soaping agent and preparation method thereof | |
| CN106543616A (en) | A kind of high-quality acrylic board of heat-resistant, wear-resistant and preparation method thereof | |
| CN106243896A (en) | A kind of environment-friendly and high-performance water-repellent paint | |
| CN102115507A (en) | PVB (polyvinyl butyal) resin powder and environment-friendly semi-continuous synthetic method and application thereof | |
| CN104530430A (en) | High-tenacity flame-retardant bismaleimide resin and preparation method thereof | |
| CN108003535A (en) | A kind of high tenacity acryl plates and preparation method thereof | |
| CN107955310A (en) | A kind of high intensity acryl plates and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170426 |