CN104211852A - Preparation method of acrylate emulsion for waterborne printing ink - Google Patents
Preparation method of acrylate emulsion for waterborne printing ink Download PDFInfo
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- CN104211852A CN104211852A CN201410480603.6A CN201410480603A CN104211852A CN 104211852 A CN104211852 A CN 104211852A CN 201410480603 A CN201410480603 A CN 201410480603A CN 104211852 A CN104211852 A CN 104211852A
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Abstract
The invention provides a preparation method of acrylate emulsion for waterborne printing ink. The preparation method comprises the following steps: (a) selecting materials for later use; (b) preparing pre-emulsion; (c) preparing the acrylate emulsion. The preparation method disclosed by the invention is reasonable in process arrangement, scientific and efficient in process and moderate in cost; the prepared acrylate emulsion has excellent performances such as good stability, moderate viscosity, low water absorption rate, high adhesion power and the like, and can effectively improve the performances of the printing ink, such as adhesion property, water resistance, after-tack resistance and the like.
Description
Technical field
The present invention relates to a kind of preparation method of acrylic ester emulsion, relate in particular to a kind of stability high, the preparation method of the used for water color ink acrylic ester emulsion that water tolerance and sticking power are good, belongs to technical field of ink.
Background technology
Ink is the important materials for printing, and it is by printing on pattern, the present stock of literal table.Ink is generally comprised of pigment, low-melting ink vehicle, solvent and auxiliary agent etc., and these compositions mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Ink is widely used in the various printings such as books and periodicals, packing and decorating, building decoration, and along with social demand increases, ink kind and output is respective extension and growth also.Packages printing industry mainly adopts solvent type ink at present, solvent type ink all can discharge a large amount of poisonous organic substances in preparation and printing process, these materials are contaminate environment not only, infringement HUMAN HEALTH, and there is disaster hidden-trouble in production, transportation and storage process.With respect to traditional solvent type ink, the water color ink of environmental protection, low toxicity has become the main development direction of ink industry.
The quality of water color ink depends primarily on the quality of its low-melting ink vehicle, and the advantages such as at present, Emulsion acrylic resin is high with its stability, good luster, good weatherability and good rheological property are widely used as low-melting ink vehicle in water color ink is produced.But the shortcomings such as not high, the anti-after tackiness of the many existence and stabilities of ink of Emulsion acrylic resin preparation is at present poor, water tolerance is bad, poor adhesive force, therefore need carry out necessary modification to Emulsion acrylic resin.In existing technology to the method for modifying of acrylic ester emulsion mainly contain monomer modified, resin is composite modified, inoganic particle modified etc.
Summary of the invention
For the demand, the invention provides a kind of preparation method of used for water color ink acrylic ester emulsion, this preparation method's science, efficient, cost is moderate, the excellent properties such as the acrylic ester emulsion making has good stability, modest viscosity, water-intake rate is low, sticking power is high, can greatly improve sticking power and the water tolerance of the water color ink of preparation.
The present invention is a kind of preparation method of used for water color ink acrylic ester emulsion, and this preparation method comprises the steps: that a) selection is got the raw materials ready, b) preparation pre-emulsion, c) preparing propone acid esters emulsion.
In a preferred embodiment of the present invention, in described step a), the main component of this acrylic ester emulsion is: compound emulsifying agent, glycidyl methacrylate, mix monomer, vinylformic acid, buffer reagent, initiator and deionized water; Compound emulsifying agent is formed by Nonionic Polymerizable emulsifying agent ER-30 and anionic polymerisable emulsifier SE-10 mixed preparing; Mix monomer obtains after fully being mixed by methyl methacrylate, vinylbenzene and butyl acrylate; Buffer reagent is selected sodium bicarbonate, and initiator is selected ammonium persulphate.
In a preferred embodiment of the present invention, in described step b), process for preparation is as follows: first, according to portion rate, deionized water, compound emulsifying agent, vinylformic acid and buffer reagent are imported to uniform stirring in stirred vessel and extremely dissolve completely, whipping temp is controlled at 20 ℃ of left and right, makes mixing solutions; Then, mix monomer is slowly splashed in mixing solutions, and stir with the rotating speed of 800-860r/min, churning time is controlled at 30-35 minute, and agitation vat temperature maintains 25 ℃ of left and right; Finally, cooling at normal temperatures, produce pre-emulsion.
In a preferred embodiment of the present invention, in described step c), preparation process is as follows: first, get 1/10 pre-emulsion in reactor, reactor is heated to 80 ℃; Then, in reactor, slowly add and be about 1/3 initiator, constantly stir until there is blue light; Then, add remaining pre-emulsion, initiator and glycidyl methacrylate, constant temperature polyreaction 1-1.2 hour, makes acrylic ester emulsion; Finally, acrylic ester emulsion is cooled to room temperature, with sodium hydroxide solution, regulates its pH value after 7-8, filter discharging.
The present invention has disclosed a kind of preparation method of used for water color ink acrylic ester emulsion, this preparation method's procedure arrangement is reasonable, preparation process science, efficient, cost is moderate, the excellent properties such as the acrylic ester emulsion making has good stability, modest viscosity, water-intake rate is low, sticking power is high, can effectively improve the sticking power of ink, the water-fast and anti-performance such as after-tack.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation:
Fig. 1 is embodiment of the present invention used for water color ink acrylic ester emulsion preparation method's process figure.
Embodiment
Below in conjunction with accompanying drawing, preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Fig. 1 is embodiment of the present invention used for water color ink acrylic ester emulsion preparation method's process figure; This preparation method comprises the steps: that a) selection is got the raw materials ready, b) preparation pre-emulsion, c) preparing propone acid esters emulsion.
Embodiment 1
The concrete preparation process of the used for water color ink acrylic ester emulsion that the present invention mentions is as follows:
A) selection is got the raw materials ready, and the main component of this acrylic ester emulsion and portion rate thereof are: 3 parts of compound emulsifying agents, 5 parts of glycidyl methacrylate, 86 parts of mix monomers, 1 part, vinylformic acid, 0.5 part of buffer reagent, 0.6 part of initiator, 100 parts of deionized waters; Wherein, compound emulsifying agent is formed by Nonionic Polymerizable emulsifying agent ER-30 and anionic polymerisable emulsifier SE-10 mixed preparing, both mass ratio 2:1; Mix monomer, by 28 parts of methyl methacrylates, 14 parts of vinylbenzene and 44 parts of butyl acrylates, obtains after fully mixing; Buffer reagent is selected sodium bicarbonate, and initiator is selected ammonium persulphate;
B) preparation pre-emulsion, process for preparation is as follows: first, according to portion rate, deionized water, compound emulsifying agent, vinylformic acid and buffer reagent are imported to uniform stirring in stirred vessel and extremely dissolve completely, whipping temp is controlled at 20 ℃ of left and right, makes mixing solutions; Then, mix monomer is slowly splashed in mixing solutions, and stir with the rotating speed of 820r/min, churning time was controlled at about 30 minutes, and agitation vat temperature maintains 25 ℃ of left and right; Finally, cooling at normal temperatures, produce pre-emulsion;
C) preparing propone acid esters emulsion, preparation process is as follows: first, get 1/10 pre-emulsion in reactor, reactor is heated to 80 ℃; Then, in reactor, slowly add and be about 1/3 initiator, constantly stir until there is blue light; Then, add remaining pre-emulsion, initiator and glycidyl methacrylate, constant temperature polyreaction 1 hour, makes acrylic ester emulsion; Finally, acrylic ester emulsion is cooled to room temperature, with sodium hydroxide solution, regulates its pH value after 7-8, filter discharging.
Embodiment 2
The concrete preparation process of the used for water color ink acrylic ester emulsion that the present invention mentions is as follows:
A) selection is got the raw materials ready, and the main component of this acrylic ester emulsion and portion rate thereof are: 4 parts of compound emulsifying agents, 6 parts of glycidyl methacrylate, 87 parts of mix monomers, 2 parts, vinylformic acid, 0.6 part of buffer reagent, 0.7 part of initiator, 105 parts of deionized waters; Wherein, compound emulsifying agent is formed by Nonionic Polymerizable emulsifying agent ER-30 and anionic polymerisable emulsifier SE-10 mixed preparing, both mass ratio 2:1; Mix monomer, by 28 parts of methyl methacrylates, 14 parts of vinylbenzene and 45 parts of butyl acrylates, obtains after fully mixing; Buffer reagent is selected sodium bicarbonate, and initiator is selected ammonium persulphate;
B) preparation pre-emulsion, process for preparation is as follows: first, according to portion rate, deionized water, compound emulsifying agent, vinylformic acid and buffer reagent are imported to uniform stirring in stirred vessel and extremely dissolve completely, whipping temp is controlled at 20 ℃ of left and right, makes mixing solutions; Then, mix monomer is slowly splashed in mixing solutions, and stir with the rotating speed of 840r/min, churning time was controlled at about 30 minutes, and agitation vat temperature maintains 25 ℃ of left and right; Finally, cooling at normal temperatures, produce pre-emulsion;
C) preparing propone acid esters emulsion, preparation process is as follows: first, get 1/10 pre-emulsion in reactor, reactor is heated to 80 ℃; Then, in reactor, slowly add and be about 1/3 initiator, constantly stir until there is blue light; Then, add remaining pre-emulsion, initiator and glycidyl methacrylate, constant temperature polyreaction 1.2 hours, makes acrylic ester emulsion; Finally, acrylic ester emulsion is cooled to room temperature, with sodium hydroxide solution, regulates its pH value after 7-8, filter discharging.
The present invention has disclosed a kind of preparation method of used for water color ink acrylic ester emulsion, be characterized in: this preparation method's procedure arrangement is reasonable, preparation process science, efficient, cost is moderate, the excellent properties such as the acrylic ester emulsion making has good stability, modest viscosity, water-intake rate is low, sticking power is high, can effectively improve the sticking power of ink, the water-fast and anti-performance such as after-tack.
The above; it is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; the variation that can expect without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (4)
1. a preparation method for used for water color ink acrylic ester emulsion, is characterized in that, this preparation method comprises the steps: that a) selection is got the raw materials ready, b) preparation pre-emulsion, c) preparing propone acid esters emulsion.
2. the preparation method of used for water color ink acrylic ester emulsion according to claim 1, it is characterized in that, in described step a), the main component of this acrylic ester emulsion is: compound emulsifying agent, glycidyl methacrylate, mix monomer, vinylformic acid, buffer reagent, initiator and deionized water; Compound emulsifying agent is formed by Nonionic Polymerizable emulsifying agent ER-30 and anionic polymerisable emulsifier SE-10 mixed preparing; Mix monomer obtains after fully being mixed by methyl methacrylate, vinylbenzene and butyl acrylate; Buffer reagent is selected sodium bicarbonate, and initiator is selected ammonium persulphate.
3. the preparation method of used for water color ink acrylic ester emulsion according to claim 1, it is characterized in that, in described step b), process for preparation is as follows: first, according to portion rate, deionized water, compound emulsifying agent, vinylformic acid and buffer reagent are imported to uniform stirring in stirred vessel and extremely dissolve completely, whipping temp is controlled at 20 ℃ of left and right, makes mixing solutions; Then, mix monomer is slowly splashed in mixing solutions, and stir with the rotating speed of 800-860r/min, churning time is controlled at 30-35 minute, and agitation vat temperature maintains 25 ℃ of left and right; Finally, cooling at normal temperatures, produce pre-emulsion.
4. the preparation method of used for water color ink acrylic ester emulsion according to claim 1, is characterized in that, in described step c), preparation process is as follows: first, get 1/10 pre-emulsion in reactor, reactor is heated to 80 ℃; Then, in reactor, slowly add and be about 1/3 initiator, constantly stir until there is blue light; Then, add remaining pre-emulsion, initiator and glycidyl methacrylate, constant temperature polyreaction 1-1.2 hour, makes acrylic ester emulsion; Finally, acrylic ester emulsion is cooled to room temperature, with sodium hydroxide solution, regulates its pH value after 7-8, filter discharging.
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| CN201410480603.6A CN104211852A (en) | 2014-09-19 | 2014-09-19 | Preparation method of acrylate emulsion for waterborne printing ink |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905465A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | A kind of manufacture method of resin, the resin and the aqueous ink using the resin |
| CN107141393A (en) * | 2017-05-17 | 2017-09-08 | 云南中烟工业有限责任公司 | A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof |
| CN107266625A (en) * | 2017-07-25 | 2017-10-20 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water inkwood fat and preparation method thereof |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN116215128A (en) * | 2023-03-17 | 2023-06-06 | 广东特地陶瓷有限公司 | Digital spray printing negative ion stained paper, preparation method thereof and decal negative ion ceramic product |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030045609A1 (en) * | 1996-12-24 | 2003-03-06 | University Of Southern Mississippi | Process for forming latex polymers |
| CN1621460A (en) * | 2004-10-20 | 2005-06-01 | 太原理工大学 | Aqueous non-oriented silicon steel sheet paint |
| CN103360561A (en) * | 2013-07-02 | 2013-10-23 | 广东海顺新材料科技有限公司 | Polyurethane modified acrylic emulsion, preparation method of acrylic emulsion and prepared artificial stone |
-
2014
- 2014-09-19 CN CN201410480603.6A patent/CN104211852A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030045609A1 (en) * | 1996-12-24 | 2003-03-06 | University Of Southern Mississippi | Process for forming latex polymers |
| CN1621460A (en) * | 2004-10-20 | 2005-06-01 | 太原理工大学 | Aqueous non-oriented silicon steel sheet paint |
| CN103360561A (en) * | 2013-07-02 | 2013-10-23 | 广东海顺新材料科技有限公司 | Polyurethane modified acrylic emulsion, preparation method of acrylic emulsion and prepared artificial stone |
Non-Patent Citations (1)
| Title |
|---|
| 张松等: "水性油墨用丙烯酸酯乳液的制备及应用", 《包装工程》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905465A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | A kind of manufacture method of resin, the resin and the aqueous ink using the resin |
| CN107141393A (en) * | 2017-05-17 | 2017-09-08 | 云南中烟工业有限责任公司 | A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof |
| CN107266625A (en) * | 2017-07-25 | 2017-10-20 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water inkwood fat and preparation method thereof |
| CN107266625B (en) * | 2017-07-25 | 2019-06-21 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water inkwood rouge and preparation method thereof |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN110951004B (en) * | 2019-12-04 | 2021-12-17 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN116215128A (en) * | 2023-03-17 | 2023-06-06 | 广东特地陶瓷有限公司 | Digital spray printing negative ion stained paper, preparation method thereof and decal negative ion ceramic product |
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Application publication date: 20141217 |