CN105506985A - 一种大豆蛋白纤维纺织品整理液 - Google Patents

一种大豆蛋白纤维纺织品整理液 Download PDF

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CN105506985A
CN105506985A CN201610012817.XA CN201610012817A CN105506985A CN 105506985 A CN105506985 A CN 105506985A CN 201610012817 A CN201610012817 A CN 201610012817A CN 105506985 A CN105506985 A CN 105506985A
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soybean protein
protein fiber
textile finishing
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CN105506985B (zh
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孟灵灵
黄新民
毕红军
王春霞
柏欣
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KUNSHAN DONGLE NEW MATERIAL TECHNOLOGY Co.,Ltd.
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Yangcheng Institute of Technology
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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Abstract

本发明公开了一种大豆蛋白纤维纺织品整理液，该整理液由以下重量份的组分组成：水解蚕丝蛋白10-15份、茶多酚1-2份、茶树精油2-4份、牛奶4-6份、天然芝麻油5-7份、纯净水80-100份、维生素C？2-4份、抗菌抑制剂1-2份、复合DNA修复剂2-4份、月桂醇聚醚硫酸铵5-8份。该整理液保持大豆蛋白纤维纺织品在洗涤后pH值平衡，不仅对大豆蛋白纤维无刺激,还可利用蚕丝蛋白水解获得小分子蚕丝丝素蛋白肽，其含有18种氨基酸，其中甘氨酸、丙氨酸和丝氨酸，通过月桂醇聚醚硫酸铵接枝到大豆蛋白纤维纺织品大豆蛋白纤维主链上，形成修复膜，能够有效修复大豆蛋白纤维纺织品在洗涤过程中受到的损伤。

Description

一种大豆蛋白纤维纺织品整理液
技术领域
本发明涉及纺织品领域，尤其涉及一种大豆蛋白纤维纺织品整理液。
背景技术
大豆蛋白纤维属于再生植物蛋白纤维类，是以榨过油的大豆豆粕为原料，利用生物工程技术，提取出豆粕中的球蛋白，通过添加功能性助剂，与腈基、羟基等高聚物接枝、共聚、共混，制成一定浓度的蛋白质纺丝液，改变蛋白质空间结构，经湿法纺丝而成。不仅有羊绒般的柔软手感，蚕丝般的柔和光泽，棉的保暖性和良好的亲肤性等优良性能，还有明显的抑菌功能，被誉为“新世纪的健康舒适纤维”。但是大豆蛋白纤维属酸性，而目前的洗涤液大多数属于碱性，在碱性的条件下洗涤，大豆蛋白纤维纺织品的纤维表面会出现损伤，宏观上表现出手感变得粗糙，出现褶皱等现象，从而严重影响了产品的品质，如何确保在洗涤的过程中保持大豆蛋白纤维纺织品质成为行业的难点问题。
发明内容
针对现有技术中存在的上述缺陷，本发明旨在提供一种清洁效果好、对大豆蛋白纤维纺织品大豆蛋白纤维具有修复作用的整理液。
为了实现上述目的，本发明提供的一种大豆蛋白纤维纺织品整理液，由以下重量份的组分组成：水解蚕丝蛋白10-15份、茶多酚1-2份、茶树精油2-4份、牛奶4-6份、天然芝麻油5-7份、纯净水80-100份、维生素C2-4份、抗菌抑制剂1-2份、复合DNA修复剂2-4份、月桂醇聚醚硫酸铵5-8份。
所述水解蚕丝蛋白为小分子蚕丝丝素蛋白肽。
所述水解蚕丝蛋白为纯度99％以上、分子量小于1000道尔顿的小分子蚕丝丝素蛋白肽。
所述抗菌抑制剂为羟苯甲酯、羟苯丙酯、甲基氯异噻唑啉酮、甲基异噻唑啉酮中的一种或它们的混合物。
与现有技术比较，本发明采用了小分子蚕丝丝素蛋白肽，其主成分为纯度99％以上、分子量小于1000道尔顿的小分子蚕丝丝素蛋白肽，加上其它辅助成份的添加，保持大豆蛋白纤维纺织品在洗涤后pH值平衡，不仅对大豆蛋白纤维无刺激,还可利用蚕丝蛋白水解获得小分子蚕丝丝素蛋白肽，其含有18种氨基酸，其中甘氨酸、丙氨酸和丝氨酸，通过月桂醇聚醚硫酸铵接枝到大豆蛋白纤维纺织品大豆蛋白纤维主链上，形成修复膜，能够有效修复大豆蛋白纤维纺织品在洗涤过程中受到的损伤。
具体实施方式
实施例1：
一种大豆蛋白纤维纺织品整理液，其特征在于由以下重量份的组分组成：水解蚕丝蛋白15份、茶多酚2份、茶树精油4份、牛奶6份、天然芝麻油7份、纯净水80份、维生素C4份、羟苯甲酯1份、羟苯丙酯1份、复合DNA修复剂4份、月桂醇聚醚硫酸铵8份。
其中，复合DNA修复剂为现有技术，不再赘述，下同。
其中，水解蚕丝蛋白为纯度99％以上、分子量小于1000道尔顿的小分子蚕丝丝素蛋白肽，下同。其制备方法在发明人同日申请的发明中有具体记载，包含以下步骤：
(1)去蛹：选取优质的桑蚕丝茧，煮沸，切开将死蛹剥除；
(2)风选：用风扇吹，将密度比茧轻的杂物吹走；
(3)粉碎：用粉碎机械将去蛹的茧粉碎为直径5mm以下；
(4)脱胶：将茧片置于0.7-1％的弱碱溶液中煮沸35-40min，并同时用强力搅拌设备搅拌，取出茧片用水漂洗几次，烘干；
(5)水解：将茧片置于盛放浓度为1-1.3％的KCl和/或MgCl2水溶液的密闭容器中升温，在0.5-0.6Mpa、130-140℃的条件下使蚕丝丝素蛋白溶解；
(6)过滤：对混合物进行过滤，得到未溶部分的胶状固态物和滤液；
(7)透析：将滤液置于透析袋中用水透析纯化，以除去KCl和/或MgCl2以及其它小分子杂质，从而制得蚕丝丝素蛋白溶液；
(8)酶解：将未溶部分的胶状固态物用清洁水冲净，与上一步骤制得的蚕丝丝素蛋白溶液混合，加入总重量1.2-2％的蛋白酶进行酶解，PH值为6-7，温度32-37℃，时间7-10h；
(9)灭酶：酶解结束后升温到70-80℃，保温20-30分钟灭酶，得到纯度大于90％、相对分子质量小于1000道尔顿的小分子蚕丝丝素蛋白肽溶液；
(10)纳滤：用相对分子质量为1000道尔顿的纳滤膜去除掉大分子蚕丝丝素蛋白肽，得到小分子蚕丝丝素蛋白肽溶液；
(11)干燥：利用喷雾干燥快速干燥，得到纯度大于99％、相对分子质量小于1000道尔顿的小分子蚕丝丝素蛋白肽。
该整理液的pH值为5.6，大豆蛋白纤维纺织品在洗涤后通过整理液处理后，保持大豆蛋白纤纤维pH值平衡，整理液中的甘氨酸、丙氨酸和丝氨酸等氨基酸，通过月桂醇聚醚硫酸铵接枝到大豆蛋白纤维纺织品大豆蛋白纤维主链上，形成修复膜，有效修复了大豆蛋白纤维纺织品在洗涤过程中受到的损伤，使处理后的大豆蛋白纤纤维纺织品具有崭新的感觉。
实施例2：
一种大豆蛋白纤维纺织品整理液，其特征在于由以下重量份的组分组成：水解蚕丝蛋白10份、茶多酚1份、茶树精油2份、牛奶4份、天然芝麻油5份、纯净水100份、维生素C2份、甲基异噻唑啉酮1份、复合DNA修复剂2份、月桂醇聚醚硫酸铵5份。
实施例3：
一种大豆蛋白纤维纺织品整理液，其特征在于由以下重量份的组分组成：水解蚕丝蛋白12份、茶多酚2份、茶树精油3份、牛奶5份、天然芝麻油6份、纯净水85份、维生素C3份、羟苯甲酯0.5份、羟苯丙酯0.5份、甲基氯异噻唑啉酮0.5份、复合DNA修复剂3份、月桂醇聚醚硫酸铵6份。

Claims (4)

1.一种大豆蛋白纤维纺织品整理液，其特征在于：由以下重量份的组分组成：水解蚕丝蛋白10-15份、茶多酚1-2份、茶树精油2-4份、牛奶4-6份、天然芝麻油5-7份、纯净水80-100份、维生素C2-4份、抗菌抑制剂1-2份、复合DNA修复剂2-4份、月桂醇聚醚硫酸铵5-8份。
2.根据权利要求1所述的大豆蛋白纤维纺织品整理液，其特征在于：所述水解蚕丝蛋白为小分子蚕丝丝素蛋白肽。
3.根据权利要求2所述的大豆蛋白纤维纺织品整理液，其特征在于：所述水解蚕丝蛋白为纯度99％以上、分子量小于1000道尔顿的小分子蚕丝丝素蛋白肽。
4.根据权利要求3所述的大豆蛋白纤维纺织品整理液，其特征在于：所述抗菌抑制剂为羟苯甲酯、羟苯丙酯、甲基氯异噻唑啉酮、甲基异噻唑啉酮中的一种或它们的混合物。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105902406A (zh) * 2016-05-27 2016-08-31 广州中科国典环境科技有限公司 具有护肤功效的复合蛋白肽及其水凝胶和制备方法
CN109957868A (zh) * 2019-04-03 2019-07-02 广州哥伦布科技发展有限公司 一种抗菌面料、其制备方法及其应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0571073A (ja) * 1991-09-06 1993-03-23 Kanebo Ltd 絹フイブロイン−高吸水性樹脂加工布帛及びその製造方法
CN201290815Y (zh) * 2008-09-26 2009-08-19 徐国文 一种新型护垫
CN101974850A (zh) * 2010-10-18 2011-02-16 南通曙光染织有限公司 一种生态免烫真丝绸面料制备方法
CN102002854A (zh) * 2010-12-06 2011-04-06 中原工学院 一种多功能织物整理剂及其制备方法和棉织物整理方法
CN103696244A (zh) * 2013-11-29 2014-04-02 南通市通州区大达麻纺织有限公司 一种织物防螨整理剂
CN104434748A (zh) * 2014-11-03 2015-03-25 杨磊 蚕丝蛋白胶原面膜
CN104762821A (zh) * 2015-03-25 2015-07-08 苏州威尔德工贸有限公司 一种蚕丝织物的免烫整理方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0571073A (ja) * 1991-09-06 1993-03-23 Kanebo Ltd 絹フイブロイン−高吸水性樹脂加工布帛及びその製造方法
CN201290815Y (zh) * 2008-09-26 2009-08-19 徐国文 一种新型护垫
CN101974850A (zh) * 2010-10-18 2011-02-16 南通曙光染织有限公司 一种生态免烫真丝绸面料制备方法
CN102002854A (zh) * 2010-12-06 2011-04-06 中原工学院 一种多功能织物整理剂及其制备方法和棉织物整理方法
CN103696244A (zh) * 2013-11-29 2014-04-02 南通市通州区大达麻纺织有限公司 一种织物防螨整理剂
CN104434748A (zh) * 2014-11-03 2015-03-25 杨磊 蚕丝蛋白胶原面膜
CN104762821A (zh) * 2015-03-25 2015-07-08 苏州威尔德工贸有限公司 一种蚕丝织物的免烫整理方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105902406A (zh) * 2016-05-27 2016-08-31 广州中科国典环境科技有限公司 具有护肤功效的复合蛋白肽及其水凝胶和制备方法
CN105902406B (zh) * 2016-05-27 2018-12-04 广州中科国典环境科技有限公司 具有护肤功效的复合蛋白肽及其水凝胶和制备方法
CN109957868A (zh) * 2019-04-03 2019-07-02 广州哥伦布科技发展有限公司 一种抗菌面料、其制备方法及其应用

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