CN105504987A - Compound activated mineral environment-friendly ink - Google Patents

Compound activated mineral environment-friendly ink Download PDF

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Publication number
CN105504987A
CN105504987A CN201610093679.2A CN201610093679A CN105504987A CN 105504987 A CN105504987 A CN 105504987A CN 201610093679 A CN201610093679 A CN 201610093679A CN 105504987 A CN105504987 A CN 105504987A
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weight part
oil
traditional chinese
essential oil
weight
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史玉桂
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Priority to CN201610093679.2A priority Critical patent/CN105504987A/en
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Priority to CN201610735633.6A priority patent/CN106349801A/en
Priority to CN201610723030.4A priority patent/CN106336721A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/16—Writing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/06—Printing inks based on fatty oils
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Abstract

The invention discloses compound activated mineral environment-friendly ink. The ink has the anion releasing and antimicrobial effects, is fragrant, refreshing and capable of relieving pressure, has the health-care effects of refreshing a user, restoring consciousness and eliminating fatigue and has very wide application prospects.

Description

A kind of built reactive mineral substance Environment-friendlyink ink
Technical field
The present invention relates to a kind of built reactive mineral substance Environment-friendlyink ink.
Background technology
Ink can be used for routine office work or textile printing field, but traditional general ink does not have refreshes oneself and produces the health-care effects such as negative ion, user's use when long produces taediumvitae, due to the function singleness of conventional inks, can not meet the multi-demands of people.
Summary of the invention
For the deficiency that prior art exists, the user that the present invention is ink provides a kind of smell pure and fresh, has the ink of stimulating effect and negative ion health effect, and it not only can release air negative ion for a long time, purifies air, is beneficial to HUMAN HEALTH; Also there are certain suppression, killing action to the multiple germs such as staphylococcus, intestinal bacteria, gram-positive bacteria and fungi; Simultaneously fragrant odour, pure and freshly soothes the spirit, pressure of releiving, also can expelling mosquito, can not produce detrimentally affect, have application prospect widely to human body.
The object of the invention is to be achieved through the following technical solutions:
A kind of built reactive mineral substance Environment-friendlyink ink, it is characterized in that: be made up of according to parts by weight following component: dispersible pigment color paste 23 weight part, dihydroxyphenyl propane 19 weight part, glycerine 4.5 weight part, anhydrous sodium sulphate 2.3 weight part, trolamine 2.7 weight part, triethylamine 3.3 weight part, acetone 3.6 weight part, two thiocarbamate 0.25 weight part, active mineral matter powder 1.7 weight part, surfactant blend 1.2 weight part, sustained release dosage 0.55 weight part, essential oil of traditional Chinese medicine 3.85 weight part, deionized water 62 weight part, the pigment of described mill base is high-carbon black pigment, the median size of described dispersible pigment color paste is 75nm, described active mineral matter powder is germanite, fluorite, tourmalinite, zinc spinel is by weight the mixture of 2.5:3:3.7:2, wherein tourmalinite is dravite and the elbaite mixture by weight 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine is prepared from as follows,
S1, get Triquetrous Tadehagi Herb 35 weight part and clean, naturally dry, be then placed in 90 DEG C of frying pans and fry extremely savory effusion, then Air washer 17 weight part, be placed in constant temperature oven less than 60 DEG C oven dry, water content≤6.5%;
S2, the leaf of bamboo 14.5 weight part to be cleaned, puts into salt solution and soak 3.5 hours, the salt water yield by 3.7 times of immersions spice quality, put into pot and steam thoroughly, taking-up, dry, the concentration of salt solution is 27%;
S3, by Semen Pharbitidis 15.5 weight part, lavandula angustifolia 12 weight part, Hupeh Anemone Herb 4.5 weight part, Stigma Croci 1 weight part, Japanese Honeysuckle 1 weight part, sweet marjoram 0.75 weight part decon, drops in supper micron mill and is crushed to 60 orders together with the made bulk drug of step S1 and S2, obtained bulk drug powder, for subsequent use;
S4, dropped into by bulk drug powder obtained in step S3 in the extraction kettle of supercritical carbon dioxide extraction apparatus, regulate extracting pressure 27.65MPa, extraction temperature 45.10 DEG C, carbon dioxide flow is 0.6m 3/ h, dynamic extraction 2.5h, directly collect volatile oil A at separating still outlet triangular flask, for subsequent use;
S5, by Cortex ulmi pumilae 8.5 weight part, agalloch eaglewood 2.5 weight part, camphorwood 15.5 weight part, calamus 4.5 weight part, peppermint 1 weight part, the root of large-flowered skullcap 1 weight part is cleaned and is dried, and drops in supper micron mill together and is crushed to 70 orders, then add deionized water and soak 6 hours, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, obtained Traditional Chinese drug mixture, for subsequent use;
S6, the Traditional Chinese drug mixture obtained by step S5 decoct 2 hours in 80 DEG C, and collect distillate, and add extracted with diethyl ether, the volume ratio of distillate and ether is 2:1, gets upper oil phase, then adds anhydrous sodium sulfate drying, and namely obtained volatile oil B, for subsequent use;
S7, by made for step S4 and S6 volatile oil A and volatile oil B mixing mix well obtained mixing oil, add Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil while stirring successively again, abundant stirring 35 minutes, leave standstill 30 minutes, abundant stirring is mixed well, and filtering and impurity removing obtains essential oil of traditional Chinese medicine, wherein, the mass ratio of described mixing oil and Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, in the bulk drug powder of step S3, wild marjoram oil 1.3 weight part and pyrethre 1.5 weight part is also included.
In a preferred embodiment, in the Traditional Chinese drug mixture of step S5, also include borneol 0.6 weight part and lotus leaf 0.4 weight part.
In a preferred embodiment, in the essential oil of traditional Chinese medicine of step S7, Oil of Eucalyptus 0.3 weight part is also included.
Equipment involved in the present invention, raw material and method, be equipment, raw material and method that the industry usually uses, do not repeat them here.
Wherein each essential oil component must and tensio-active agent, sustained release dosage fully mixes, to reach slow release effect, the addition of each essential oil and negative ion natural mineral matter powder must be appropriate, not only antibiotic and sterilizing, mood can also be stabilized, so there is the effect in front to not normal psychological condition, can purify, pacify soul, indignation and beaten sensation can be alleviated, make people can even-tempered and good-humouredly in the face of life, because its energy centre of equilibrium is neural, so helpful to alarmed and dejected state, also significantly tranquil and function of releiving is had, goodish easypro putting is had to console with spirit to insomniac, for pacify hot-tempered enter or moody temper have goodish effect, can increase work efficiency.
The present invention is with reference to modern Chinese herbal medicine pharmacological research, and from the drug screening of existing Chinese medicine with repeatedly verify, give full play to each group of weight part and act synergistically, wherein each traditional Chinese medicinal components brief introduction is as follows.
Triquetrous Tadehagi Herb is pulse family beggar-ticks plant.Possess the effects such as clearing heat and detoxicating, the long-pending dampness removing that disappears, desinsection are anticorrosion, can be used for preventing heatstroke, treatment cold, fever, swelling and pain in the throat, ephritis etc.
The leaf of bamboo: there is excellent Green Tea Extract, anti-oxidant, antifatigue, expansion capillary vessel, dredging microcirculation, activation brain, promote memory, improving water flood, anticancer, beautify the effects such as skin.According to research reports, the impact of the bone marrow toxicity that its natural biological flavones rises anticancer efficacy-enhancing ingredient and immunological function repression, on the impact of patients with coronary heart disease microcirculation, platelet function and the hemorrhage improvement of cardiac muscle.
Semen Pharbitidis: cold in nature, bitter; Poisonous, water pouring defaecation, drink is washed in dissolving phlegm, and desinsection is attacked long-pending.For oedema turgor, constipation and anuresis, phlegm and retained fluid is gathered, and the circulation of vital energy in the wrong direction is breathed with cough, abdominal pain due to worm stagnation
Lavandula angustifolia can remove ant, except roach, except mite, when being placed under wardrobe, pillow, not only mothball can be replaced, the fragrance of one people that oozes can also be left, research finds, lavandula angustifolia has obvious anti-microbial effect, and the phantol contained in lavandula angustifolia is the antibacterial main component of lavandula angustifolia, and it can suppress the growth of 17 kinds of bacteriums (comprising gram-negative bacteria and gram-positive bacteria), 10 kinds of fungies.
Hupeh Anemone Herb: 1. " Shaanxi herbal medicine ": " bitter, cool, slightly poisonous." 2. " herbal medicine is commonly used in Sichuan ": " and toil, temperature, slightly poisonous." removing toxic substances, apocenosis myogenic, the Sweeling-eliminating medicine powder stasis of blood, has and kills maggot, wriggler, eliminate indigestion, detumescence, and the loose stasis of blood, controls stubborn dermatitis, the favus of the scalp, malaria, infantile malnutrition, dysentery, and carbuncle furuncle sore swells, scrofula, wound.
Stigma Croci: have powerful physiologically active, its column cap as medicinal in Asia and Europe, have calmness, eliminates the phlegm, spasmolysis, is used as calm, carminative abroad, promoting blood circulation and removing blood stasis, removing pattogenic heat from the blood and toxic material from the body, resolving stagnation for tranquilization.Maculae caused by violent heat pathogen, melancholy ruffian are vexed, palpitation with fear is gone mad.
Japanese Honeysuckle: its effect is mainly clearing heat and detoxicating, to pharmacological components such as chlorogenic acid, luteolin glycosides, certain restraining effect is all had to streptococcus aureus, Hemolytic streptococcus, intestinal bacteria, dysentery bacterium, vibrio cholerae, Corynebacterium diphtheriae, paratyphosum Bacterium etc., also effective to streptococcus pneumoniae, meningococcus, Pseudomonas aeruginosa, tubercule bacillus, also can strengthening immunity.
Sweet marjoram: the depressed and addictive disease of mood can be improved, especially effective to liberal-mindedness and vigorous endurance stress symptom, can vasodilation, hypotensive, alleviate and burden, help to eliminate palpitaition, have excellent nerve to pacify and calm function.
Cortex ulmi pumilae: be dry bark or the root skin of Ulmaceae is sweet, flat, nontoxic; Li Shui, treating stranguria, detumescence, for urinary obstruction, stranguria with turbid discharge, oedema, ulcer carbuncle on the back, erysipelas, mange.
Agalloch eaglewood: " Compendium of Materia Medica " records that wood has strong antibacterial efficacy, fragrance enters spleen, clear god regulates the flow of vital energy, tonifying the five internal organs, relieving cough and reducing sputum, warm stomach temperature spleen, analgesic therapy of ventilating, can be used as medicine is first-class medicinal material superfine product.
Camphorwood: aiphyllium, bark tawny, has irregular longitudinal crack, on the south main product the Changjiang river and southwestern various places.Cut down trees winter and split broken or be sawn into bulk, to dry or air-dry.Timber bulk is not of uniform size, and surface red is brown to burgundy, the visible annual ring in transverse section.Matter is heavily hard.Have strong camphor fragrance, taste is refrigerant, has pungent sense, and warm in nature, taste is pungent; Sensiblely can ward off dirty, warming middle-JIAO to relieve pain, dampness removing desinsection.
Calamus: its flower, stem aromatic flavour, have have one's ideas straightened out, eliminate the phlegm, effect of loose wind, epidemic disease of can dispelling intelligence development, to improve the health, spices or mosquito-repelling can be made.
Peppermint: be the dry aerial parts of labiate peppermint, dispelling wind and heat pathogens, the clear sharp head, relieve sore throat promoting eruption, soothing the liver promoting the circulation of qi.
The root of large-flowered skullcap: antibacterial, antiviral, has restraining effect to multiple gram positive organism, gram-negative bacteria, pathogenic dermatophytes, suppresses influenza virus, hepatitis B virus.
Flos Rosae Rugosae quintessence oil: there is antibacterial, sterilization, promote the sexual maturity, calm, mend the effects such as body, have and smooth mood, improve mood, calm nerves anxiety and pressure, woman can be made to produce impression actively and positively to oneself, and its natural fragrance enters after human body through olfactory nerve, people's spiritual happiness, satisfied can be made, alleviate anxiety, depression, pressure, help for sleep, enhance metabolism, sanguimotor effect.
P-Cymene: all have anti-microbial effect to 10 kinds of Gram-positive aerophils such as anthrax bacillus, Alpha-hemolytic streptococcus, B-Streptococcus hemolyticus, diphtheria corynebacterium, bacillus pseudodiphthericus, lung diplococcoid, streptococcus aureus, Staphylococcus citreus, white Portugal Portugal coccus, Bacillus subtilus, also have bacteriostatic action for multiple pathomycete.
Geranium Essential: there is hemostasis, vasoconstriction, asthma, liver and expelling toxin, gallbladdergallstonecholetithiasis, kidney toxin expelling, urinary stone disease, diuresis, sore muscle, oily skin, aging skin activates, bleb, ochrodermia, fat-reducing, promotes to scab, eczema, to burn sunburn, tinea, menstruation has some setbacks, engorgement of breasts inflammation, alleviate melancholy uneasy, there is deodorizing, antibacterial, the effect of sterilization.
Tea tree ethereal oil: for air cleaning, elimination of off flavor, deodorizing, insect protected is dust-proof to be hidden from, and to Candida albicans, the contour disease carrying germ of staphylococcus has kill activity, effectively can resist 26 kinds of dermatophytes, 32 kinds of Candida albicanss and 22 kinds of little sporeformer, be potent antibiotic essential oil.
Cypress essential oil: have amber taste charming as wooden and face cream, rheumatism, antibacterial, spasmolytic, suppression sweating, convergence, promotion scab, except underarm odor, diuresis, bring down a fever, stop blooding, sharp liver, desinsection, rehabilitation, calmness, astringing to arrest bleeding, benefit body, vasoconstriction.Ginseng Extract, angry mood of releiving, alleviates heart anxiety and pressure, purifies one's soul.
Wild marjoram oil: the herb of Labiatae origanum wild marjoram ORIGZNUMVUL-GAREL., have another name called the symbol name such as the ground that stops dysentery grass, wild catmint, there is heat-clearing, dampness elimination, drive away summer heat, induce sweat, regulate the flow of vital energy extremely strong sterilization, bacteriostatic action, the volatile oil extracted from wild marjoram, commonly causing enteritis bacterium and shigella flexneri to 31 kinds, is the pure Chinese medicine additive most with broad-spectrum antimicrobial.
Pyrethre: the general designation of chrysanthemum artemisia (Tanacetum) several plants, removing dampness and killing parasites, kills crab louse, head louse, body louse, flea, effect except mosquito desinsection.
Borneol: pungent is bitter, cool.There is inducing resuscitation of having one's ideas straightened out, the loose poison of heat-clearing, improving acuity of vision and removing nebula.Cure mainly pyreticosis unconsciousness due to high fever, apoplexy coma due to blocking of the respiratory system shies epilepsy, and summer-heat and damp hoodwinks key clearly, and larynx numbness is deaf, and aphtha tooth swells, sore carbuncle infantile malnutrition due to digestive disturbances or intestinalparasites hemorrhoid, conjunctival congestion with pain and swelling of the eye, pterygium.
Lotus leaf: be the leaf of nymphaeaceae plant lotus, has the effect of clearing heat and detoxicating, cool blood, hemostasis.There are the effects such as clearing summer-heat and damp, sending up the lucid YANG, cooling blood for hemostasis.
Oil of Eucalyptus: the most common and purposes one of essential oil the most widely, has good health-care effect, help to focus one's attention on.Effectively can alleviate sinus infection, influenza, bronchitis, cold nasal obstruction and other respiratory system diseases.Have good antibacterial and sterilization idiocratic, in some certain food, Oil of Eucalyptus is also as fragrance component.Carry this essential oil at whilst on tour, effectively can resist mosquito bite and insect bite, treatment skin measles.It is good anophelifuge.Mix with water and can become a kind of simple and effective sterilizing agent.
Beneficial effect of the present invention:
The present invention provides a kind of smell pure and fresh for user, has the ink of stimulating effect and negative ion health effect, and it not only can release air negative ion for a long time, purifies air, is beneficial to HUMAN HEALTH; Also there are certain suppression, killing action to the multiple germs such as staphylococcus, intestinal bacteria, gram-positive bacteria and fungi; Simultaneously fragrant odour, pure and freshly soothes the spirit, pressure of releiving, also can expelling mosquito, can not produce detrimentally affect, be applicable to each age groups to human body, its appropriate add other function ingredients after still can keep original effect and quality.
1, tourmalinite is a kind of silicate minerals, its chemical formula is Na (Mg, Fe, Mn, Li, Al) 3Al6 (Si6O18) (Bo3) 3 (OH, F) 4, it contacts with water molecules under electrostatic field, just water molecules can be ionized into hydrogen ion (H+) and hydroxide ion (OH-), hydroxide ion and water molecules form basic hydroxide group negative ion (H2OOH-), be " negative aeroion ", current scientific research proves: negative ion can not only facilitate human body to synthesize and vitamin storage, the physiological activity of strengthening and human activin, very important impact is had on the vital movement of human body and other biological, be called as " air VITAMIN ".The indoor objectionable impurities of negative ion active adsorption, as the construction and decoration such as formaldehyde, toluene objectionable impurities, not only self does not increase pollution, and Cress room air, fundamentally eliminates construction and decoration syndromes, ensures that HUMAN HEALTH is unaffected.
2, the traditional Chinese medicine ingredients contained in the present invention, not only has certain suppression, killing action to the multiple germs such as staphylococcus, tubercule bacillus, Pseudomonas aeruginosa, gram-negative bacteria and gram-positive bacteria and fungi; Simultaneously fragrant odour, character is gentle, pure and freshly soothes the spirit, and helps hormone secretion, the effect of anxiety of releiving, also has certain mosquito-repelling effect, more crucially simultaneously, life-time service the present invention can not produce detrimentally affect to human body, is applicable to each age groups, has application prospect widely.
Embodiment
Embodiment.
A kind of built reactive mineral substance Environment-friendlyink ink, it is characterized in that: be made up of according to parts by weight following component: dispersible pigment color paste 23 weight part, dihydroxyphenyl propane 19 weight part, glycerine 4.5 weight part, anhydrous sodium sulphate 2.3 weight part, trolamine 2.7 weight part, triethylamine 3.3 weight part, acetone 3.6 weight part, two thiocarbamate 0.25 weight part, active mineral matter powder 1.7 weight part, surfactant blend 1.2 weight part, sustained release dosage 0.55 weight part, essential oil of traditional Chinese medicine 3.85 weight part, deionized water 62 weight part, the pigment of described mill base is high-carbon black pigment, the median size of described dispersible pigment color paste is 75nm, described active mineral matter powder is germanite, fluorite, tourmalinite, zinc spinel is by weight the mixture of 2.5:3:3.7:2, wherein tourmalinite is dravite and the elbaite mixture by weight 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine is prepared from as follows,
S1, get Triquetrous Tadehagi Herb 35 weight part and clean, naturally dry, be then placed in 90 DEG C of frying pans and fry extremely savory effusion, then Air washer 17 weight part, be placed in constant temperature oven less than 60 DEG C oven dry, water content≤6.5%;
S2, the leaf of bamboo 14.5 weight part to be cleaned, puts into salt solution and soak 3.5 hours, the salt water yield by 3.7 times of immersions spice quality, put into pot and steam thoroughly, taking-up, dry, the concentration of salt solution is 27%;
S3, by Semen Pharbitidis 15.5 weight part, lavandula angustifolia 12 weight part, Hupeh Anemone Herb 4.5 weight part, Stigma Croci 1 weight part, Japanese Honeysuckle 1 weight part, sweet marjoram 0.75 weight part decon, drops in supper micron mill and is crushed to 60 orders together with the made bulk drug of step S1 and S2, obtained bulk drug powder, for subsequent use;
S4, dropped into by bulk drug powder obtained in step S3 in the extraction kettle of supercritical carbon dioxide extraction apparatus, regulate extracting pressure 27.65MPa, extraction temperature 45.10 DEG C, carbon dioxide flow is 0.6m 3/ h, dynamic extraction 2.5h, directly collect volatile oil A at separating still outlet triangular flask, for subsequent use;
S5, by Cortex ulmi pumilae 8.5 weight part, agalloch eaglewood 2.5 weight part, camphorwood 15.5 weight part, calamus 4.5 weight part, peppermint 1 weight part, the root of large-flowered skullcap 1 weight part is cleaned and is dried, and drops in supper micron mill together and is crushed to 70 orders, then add deionized water and soak 6 hours, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, obtained Traditional Chinese drug mixture, for subsequent use;
S6, the Traditional Chinese drug mixture obtained by step S5 decoct 2 hours in 80 DEG C, and collect distillate, and add extracted with diethyl ether, the volume ratio of distillate and ether is 2:1, gets upper oil phase, then adds anhydrous sodium sulfate drying, and namely obtained volatile oil B, for subsequent use;
S7, by made for step S4 and S6 volatile oil A and volatile oil B mixing mix well obtained mixing oil, add Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil while stirring successively again, abundant stirring 35 minutes, leave standstill 30 minutes, abundant stirring is mixed well, and filtering and impurity removing obtains essential oil of traditional Chinese medicine, wherein, the mass ratio of described mixing oil and Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, in the bulk drug powder of step S3, wild marjoram oil 1.3 weight part and pyrethre 1.5 weight part is also included.
In a preferred embodiment, in the Traditional Chinese drug mixture of step S5, also include borneol 0.6 weight part and lotus leaf 0.4 weight part.
In a preferred embodiment, in the essential oil of traditional Chinese medicine of step S7, Oil of Eucalyptus 0.3 weight part is also included.
Use air ion static method of testing tests the ink in this above-described embodiment, and negative ion burst size is at 430-650/m 3, and sustained release negative aeroion, be more conducive to purifying air for a long time, reach the basic demand of health of people.
Reference examples.
Colour carbon black 20g, phenol 11g, glycerine 4g, benzotriazole 3g, trolamine 1g, triethylamine 3g, sodium bicarbonate 5g, polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant 1.5g, sustained release dosage 0.4g, sweet marjoram essential oil 0.6g, wheat malt essential oil 0.5g, Herba Lysimachiae foenumgraeci quintessence oil 0.5g, RADIX PAEONIAE ALBA essential oil 0.4g, cypress essential oil 0.4g, eucalyptus quintessence oil 0.4g, P-Cymene 0.4g, Peppermint essential oil 0.4g, deionized water 75g.
Use air ion static method of testing tests the ink in this above-mentioned reference examples, and negative ion burst size is at 0/m 3, not there is the function of release air negative ion.
(1) carry out acute toxicity test to obtained essential oil of traditional Chinese medicine, result is as follows:
1. Mouse oral acute toxicity test: the LD50 of Mouse oral essential oil of traditional Chinese medicine is 383.55g/kg, 95% be crediblely limited to 294.68g/kg ~ 499.31g/kg.And the toxicity criterion of air freshener is: the anxious malicious LD50 >=5g/kg of Mouse oral, is judged to be nontoxic.The LD50 of this essential oil of traditional Chinese medicine, higher than 76 times of nontoxic standard, is therefore judged to be nontoxic.
2. chmice acute toxicity on inhalation test: it is 24863.99g/m3 that chmice acute sucks the LC50 of essential oil of traditional Chinese medicine, 95% be crediblely limited to 16837.34g/m3 ~ 33387.46g/m3.And the toxicity criterion of air freshener is: chmice acute sucks (2h) LC50 > 10000mg/m3, the nontoxic level in true border.The LC50 of this essential oil of traditional Chinese medicine, higher than 2486 times of nontoxic standard, is therefore judged to be nontoxic.
Obtained essential oil of traditional Chinese medicine is through inspection, and its fragrance, color and luster, refractive index, relative density, arsenic content, heavy metal content, pH value all meet the requirement of national standard.
(2) check above-mentioned ink performance test result as table 1:
(3) to the test improving the mental status.
Main method is that ink uses volunteer's experiment, recruit 60 people, use the ink in above-mentioned 2 kinds of embodiments respectively, by SCL-90 questionnaire (i.e. " Self-reporting inventory-SCL90 ", one of foremost Mental health test scale in the world), followed the tracks of by the use of continuous 1 week, judge the actual efficacy effect of the present invention in refreshing oneself, wherein 3 people are noninductive is subject to; 7 people experience general; 1 people thinks that this product is invalid for stimulating effect; Have 49 people to feed back this product and have effect of refreshing oneself preferably, the power that can warn is concentrated, and efficient is 81.67%.
(4) repelling effect test.
Repelling effect according to common ink of the prior art and above-described embodiment ink inside carries out contrast test, and test data is in table 2.
Conclusion: the ink in the embodiment of the present invention has good repelling effect.
The foregoing is only preferred embodiment of the present invention; not in order to limit the present invention; for those of ordinary skill in the field; can also make other changes in different forms on the basis of the above description; here exhaustive without the need to also giving all embodiments; within the spirit and principles in the present invention all, any amendment made, equivalent replacement, improvement etc., be still included within protection scope of the present invention.

Claims (1)

1. a built reactive mineral substance Environment-friendlyink ink, it is characterized in that: be made up of according to parts by weight following component: dispersible pigment color paste 23 weight part, dihydroxyphenyl propane 19 weight part, glycerine 4.5 weight part, anhydrous sodium sulphate 2.3 weight part, trolamine 2.7 weight part, triethylamine 3.3 weight part, acetone 3.6 weight part, two thiocarbamate 0.25 weight part, active mineral matter powder 1.7 weight part, surfactant blend 1.2 weight part, sustained release dosage 0.55 weight part, essential oil of traditional Chinese medicine 3.85 weight part, deionized water 62 weight part, the pigment of described mill base is high-carbon black pigment, the median size of described dispersible pigment color paste is 75nm, described active mineral matter powder is germanite, fluorite, tourmalinite, zinc spinel is by weight the mixture of 2.5:3:3.7:2, wherein tourmalinite is dravite and the elbaite mixture by weight 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine is prepared from as follows,
S1, get Triquetrous Tadehagi Herb 35 weight part and clean, naturally dry, be then placed in 90 DEG C of frying pans and fry extremely savory effusion, then Air washer 17 weight part, be placed in constant temperature oven less than 60 DEG C oven dry, water content≤6.5%;
S2, the leaf of bamboo 14.5 weight part to be cleaned, puts into salt solution and soak 3.5 hours, the salt water yield by 3.7 times of immersions spice quality, put into pot and steam thoroughly, taking-up, dry, the concentration of salt solution is 27%;
S3, by Semen Pharbitidis 15.5 weight part, lavandula angustifolia 12 weight part, Hupeh Anemone Herb 4.5 weight part, Stigma Croci 1 weight part, Japanese Honeysuckle 1 weight part, sweet marjoram 0.75 weight part decon, drops in supper micron mill and is crushed to 60 orders together with the made bulk drug of step S1 and S2, obtained bulk drug powder, for subsequent use;
S4, dropped into by bulk drug powder obtained in step S3 in the extraction kettle of supercritical carbon dioxide extraction apparatus, regulate extracting pressure 27.65MPa, extraction temperature 45.10 DEG C, carbon dioxide flow is 0.6m 3/ h, dynamic extraction 2.5h, directly collect volatile oil A at separating still outlet triangular flask, for subsequent use;
S5, by Cortex ulmi pumilae 8.5 weight part, agalloch eaglewood 2.5 weight part, camphorwood 15.5 weight part, calamus 4.5 weight part, peppermint 1 weight part, the root of large-flowered skullcap 1 weight part is cleaned and is dried, and drops in supper micron mill together and is crushed to 70 orders, then add deionized water and soak 6 hours, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, obtained Traditional Chinese drug mixture, for subsequent use;
S6, the Traditional Chinese drug mixture obtained by step S5 decoct 2 hours in 80 DEG C, and collect distillate, and add extracted with diethyl ether, the volume ratio of distillate and ether is 2:1, gets upper oil phase, then adds anhydrous sodium sulfate drying, and namely obtained volatile oil B, for subsequent use;
S7, by made for step S4 and S6 volatile oil A and volatile oil B mixing mix well obtained mixing oil, add Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil while stirring successively again, abundant stirring 35 minutes, leave standstill 30 minutes, abundant stirring is mixed well, and filtering and impurity removing obtains essential oil of traditional Chinese medicine, wherein, the mass ratio of described mixing oil and Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
CN201610093679.2A 2016-02-19 2016-02-19 Compound activated mineral environment-friendly ink Pending CN105504987A (en)

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CN106009535A (en) * 2016-05-23 2016-10-12 魏国营 Decomposition type environment-friendly lighting lampshade
CN106084988A (en) * 2016-06-17 2016-11-09 苍南县宝丰印业有限公司 A kind of multifunctional water-based ink
CN106122850A (en) * 2016-05-23 2016-11-16 魏国营 Decorative accessory of LED lamp

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CN107828277A (en) * 2017-11-09 2018-03-23 江苏淮阴华新纸品有限公司 A kind of environment-friendly type aqueous ink and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009534A (en) * 2016-05-23 2016-10-12 魏国营 Multifunctional environment-friendly lampshade structure
CN106009535A (en) * 2016-05-23 2016-10-12 魏国营 Decomposition type environment-friendly lighting lampshade
CN106122850A (en) * 2016-05-23 2016-11-16 魏国营 Decorative accessory of LED lamp
CN106084988A (en) * 2016-06-17 2016-11-09 苍南县宝丰印业有限公司 A kind of multifunctional water-based ink

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Application publication date: 20160420