CN105504711A - 一种3d打印用聚己内酯改性微球 - Google Patents
一种3d打印用聚己内酯改性微球 Download PDFInfo
- Publication number
- CN105504711A CN105504711A CN201510985065.0A CN201510985065A CN105504711A CN 105504711 A CN105504711 A CN 105504711A CN 201510985065 A CN201510985065 A CN 201510985065A CN 105504711 A CN105504711 A CN 105504711A
- Authority
- CN
- China
- Prior art keywords
- polycaprolactone
- microballoon
- printing
- molybdenum boride
- prints
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004632 polycaprolactone Substances 0.000 title claims abstract description 92
- 229920001610 polycaprolactone Polymers 0.000 title claims abstract description 92
- 238000010146 3D printing Methods 0.000 title claims abstract description 21
- 239000004005 microsphere Substances 0.000 title abstract 4
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 20
- 239000012764 mineral filler Substances 0.000 claims description 18
- -1 glycerin fatty acid ester Chemical class 0.000 claims description 17
- 239000003112 inhibitor Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 239000013543 active substance Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 12
- 238000001291 vacuum drying Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002425 crystallisation Methods 0.000 claims description 6
- 230000008025 crystallization Effects 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 235000019359 magnesium stearate Nutrition 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical class CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 235000019260 propionic acid Nutrition 0.000 claims description 4
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000011325 microbead Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 26
- 230000004048 modification Effects 0.000 description 13
- 238000012986 modification Methods 0.000 description 13
- 230000035939 shock Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229920000747 poly(lactic acid) Polymers 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920002961 polybutylene succinate Polymers 0.000 description 2
- 239000004631 polybutylene succinate Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000006362 organocatalysis Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000000399 orthopedic effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
检测项目 | 纯聚己内酯微球 | 聚己内酯微球改性材料 |
热变形温度(℃) | 60 | 963 --> |
冲击强度(J/m) | 15 | 56 |
拉伸强度(MPa) | 18 | 31 |
基本流动能(mJ) | 33.5 | 22.3 |
检测项目 | 纯聚己内酯微球 | 聚己内酯微球改性材料 |
热变形温度(℃) | 60 | 98 |
冲击强度(J/m) | 15 | 68 |
拉伸强度(MPa) | 18 | 29 |
基本流动能(mJ) | 33.5 | 19.2 |
检测项目 | 纯聚己内酯微球 | 聚己内酯微球改性材料 |
热变形温度(℃) | 60 | 102 |
冲击强度(J/m) | 15 | 63 |
拉伸强度(MPa) | 18 | 33 |
基本流动能(mJ) | 33.5 | 21.8 |
检测项目 | 纯聚己内酯微球 | 聚己内酯微球改性材料 |
热变形温度(℃) | 60 | 110 |
冲击强度(J/m) | 15 | 61 |
拉伸强度(MPa) | 18 | 32 |
基本流动能(mJ) | 33.5 | 21.3 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510985065.0A CN105504711B (zh) | 2015-12-25 | 2015-12-25 | 一种3d打印用聚己内酯改性微球 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510985065.0A CN105504711B (zh) | 2015-12-25 | 2015-12-25 | 一种3d打印用聚己内酯改性微球 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105504711A true CN105504711A (zh) | 2016-04-20 |
CN105504711B CN105504711B (zh) | 2018-01-30 |
Family
ID=55713036
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510985065.0A Expired - Fee Related CN105504711B (zh) | 2015-12-25 | 2015-12-25 | 一种3d打印用聚己内酯改性微球 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105504711B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107641303A (zh) * | 2017-09-14 | 2018-01-30 | 北京化工大学 | 一种低温fdm型3d打印材料、制备及应用 |
US10316184B2 (en) | 2016-12-30 | 2019-06-11 | Nano And Advanced Materials Institute Limited | Low printing temperature filaments for 3D printing |
CN110559489A (zh) * | 2019-09-25 | 2019-12-13 | 广州益诚生物科技有限公司 | 一种注射填充物 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8071007B1 (en) * | 2000-09-20 | 2011-12-06 | Osteopore International Pte. Ltd. | Three-dimensional bioresorbable scaffolds for tissue engineering applications |
CN103980682A (zh) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 一种3d打印聚己内酯材料及其制备方法 |
-
2015
- 2015-12-25 CN CN201510985065.0A patent/CN105504711B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8071007B1 (en) * | 2000-09-20 | 2011-12-06 | Osteopore International Pte. Ltd. | Three-dimensional bioresorbable scaffolds for tissue engineering applications |
CN103980682A (zh) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 一种3d打印聚己内酯材料及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10316184B2 (en) | 2016-12-30 | 2019-06-11 | Nano And Advanced Materials Institute Limited | Low printing temperature filaments for 3D printing |
CN107641303A (zh) * | 2017-09-14 | 2018-01-30 | 北京化工大学 | 一种低温fdm型3d打印材料、制备及应用 |
CN110559489A (zh) * | 2019-09-25 | 2019-12-13 | 广州益诚生物科技有限公司 | 一种注射填充物 |
Also Published As
Publication number | Publication date |
---|---|
CN105504711B (zh) | 2018-01-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105713362B (zh) | 一种用于3d打印的组合物、含有其的3d打印材料及其制备方法、应用及3d打印设备 | |
CN105524398A (zh) | 一种用于3d打印的abs快速成型材料及其制备方法 | |
CN108948500B (zh) | 用于3d打印的含聚氨酯改性粉末橡胶的聚乙烯混合物的制备方法 | |
CN105647137A (zh) | 一种3d打印聚乳酸/皮粉复合材料及其制备方法 | |
CN105504813A (zh) | 一种用于3d打印的球形聚苯硫醚粉末材料及其制备方法 | |
CN105504749B (zh) | 一种3d打印用聚碳酸酯复合材料及其制备方法 | |
CN101698728B (zh) | 光亮型可注塑木塑复合材料及制备方法 | |
CN105504711A (zh) | 一种3d打印用聚己内酯改性微球 | |
CN105623029B (zh) | 复合补强剂、pc/pbt合金及应用 | |
CN107903487A (zh) | 一种3d打印发泡鞋材及其制备方法 | |
CN104231626B (zh) | 一种选择性激光烧结用聚苯硫醚粉末材料及其制备方法 | |
CN105504759A (zh) | 一种3d打印用abs复合材料及其制备方法 | |
CN103554691B (zh) | 一种汽车内饰制品 | |
CN110144092A (zh) | 一种环保硬质pvc改性材料及其制备方法 | |
CN107189423A (zh) | 基于fdm3d打印的减磨材料及其制备方法和增强该材料制品减磨性能的方法 | |
CN105778212B (zh) | 一种玻璃纤维/热塑性塑料颗粒及其制备方法 | |
CN109206709B (zh) | 用于3d打印的含氟化石墨烯改性的粉末橡胶聚乙烯混合物的制备方法 | |
CN106633411A (zh) | 一种可3d打印的聚丙烯复合材料及制备方法 | |
CN110330756A (zh) | 一种低温低翘曲的asa 3d打印线材及其制备方法 | |
CN105524449A (zh) | 一种3d打印用聚苯醚复合粉体及其制备方法 | |
CN112210187A (zh) | 一种复合塑料及其制备方法 | |
CN109181067B (zh) | 用于3d打印的含氟化石墨烯的聚乙烯混合物的制备方法 | |
CN106832827B (zh) | 一种用于3d打印的热稳定性聚乳酸材料及其制备方法 | |
CN109825065A (zh) | 一种传感器外壳的制备工艺 | |
CN108467580A (zh) | 一种3d低温打印材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20170719 Address after: 510640 Guangdong City, Tianhe District Province, No. five, road, public education building, unit 371-1, unit 2401 Applicant after: Guangdong Gaohang Intellectual Property Operation Co., Ltd. Address before: Qingyang District of Chengdu City, Sichuan province 610091 Dragon Industrial Port East Road 4 Applicant before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd. |
|
TA01 | Transfer of patent application right | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Yu Guangbin Inventor after: Zhuo Shi Inventor after: Mao Hancheng Inventor after: Ke Shunqi Inventor before: Chen Qing Inventor before: Ye Renhai Inventor before: Chen Bing |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20171128 Address after: 150000 Harbin, Heilongjiang, Nangang District Road, No. 52 Applicant after: Harbin University of Science and Technology Address before: 510640 Guangdong City, Tianhe District Province, No. five, road, public education building, unit 371-1, unit 2401 Applicant before: Guangdong Gaohang Intellectual Property Operation Co., Ltd. |
|
TA01 | Transfer of patent application right | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180130 Termination date: 20181225 |
|
CF01 | Termination of patent right due to non-payment of annual fee |