CN105503139A - Stump imitating stool and preparing method thereof - Google Patents

Stump imitating stool and preparing method thereof Download PDF

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Publication number
CN105503139A
CN105503139A CN201510930998.XA CN201510930998A CN105503139A CN 105503139 A CN105503139 A CN 105503139A CN 201510930998 A CN201510930998 A CN 201510930998A CN 105503139 A CN105503139 A CN 105503139A
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CN
China
Prior art keywords
stool
stub
imitative
product
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510930998.XA
Other languages
Chinese (zh)
Inventor
杨卓舒
蒋云辉
陈常文
徐军
李石明
黄宝山
许永剑
林道略
师迎坤
韦佳洪
高兰英
林江元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuoda New Material Technology Group Co Ltd
Original Assignee
Zhuoda New Material Technology Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201510930998.XA priority Critical patent/CN105503139A/en
Publication of CN105503139A publication Critical patent/CN105503139A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a stump imitating stool and a preparing method thereof. The stump imitating stool is prepared from magnesium oxide, magnesium chloride, water, agricultural waste, fly ash, glass fibers and additive. The stump imitating stool can be used as a stool, style design is unique, and materials save energy and are environmentally friendly, resistant to fire and burning, high in strength, light, healthy and capable of achieving a health-preserving effect.

Description

A kind of imitative stub stool and preparation method thereof
Technical field
The invention belongs to stool field, particularly relate to a kind of imitative stub stool and preparation method thereof.
Background technology
Existing stool Technology is the matter input of China, has spread several thousand, and the people this gate technique are also very many.
Existing stool is made as master with timber, also has the stool that the material such as stone material, bamboo, rattan plaited makes, but these materials mankind can resource-constrained, make in wastage of material resource, making processes and easily cause soil erosion and destroy ecotope.
Along with the raising of people's living standard, the requirement for practicality and artistry is more and more higher.But also there is not now the product of stool stub.The product that organic macromolecule unsaturated polyester resin, polyurethane resin material class are produced easily produces outside objectionable impurities, and its product itself does not reach the effect of stool stub yet; The plasticity-such as cement, gypsum of similar inorganic materials is strong and frangible, intensity, the performance such as wear-resisting are not high.
Summary of the invention
Technical assignment of the present invention is mainly for above-mentioned the deficiencies in the prior art, the present invention utilizes fabrication of new materials to go out " imitative stub stool ", can use as stool, not only shape-designing uniqueness, and material energy-saving environmental protection, fire prevention combustion, high-strength light, health care absolutely.
The invention provides a kind of imitative stub stool, with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
Magnesium oxide: 40% ~ 45%
Magnesium chloride: 20% ~ 22%
Water: 20% ~ 22%
Agricultural wastes: 5% ~ 10%
Flyash: 5% ~ 10%
Glass fibre: 1% ~ 3%
Additive: 0.5% ~ 2%.
As preferably, described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150, polyvinyl alcohol one or more.
As preferably, described agricultural wastes are wood chip.
The present invention also provides the preparation method of above-mentioned imitative stub stool, comprises the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add flyash, agricultural wastes, glass fibre and additive, stir, obtain fabric;
Step 2: the fabric be stirred is carried out in product mold whitewash and filling, remove mould product shaping after certain hour;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
As preferably, in step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.
As preferably, in step 2, certain hour is 4-8 hours.
As preferably, in step 1, the weight of flyash and agricultural wastes accounts for 10% ~ 20% of imitative stub stool raw material gross weight.
Advantageous Effects of the present invention is as follows:
(1) the present invention compares with traditional stool, is to utilize New Inorganic Materials to be made through scientific formula, and appearance design is unique, add its practicality and artistry, formed at normal temp solidifies, and does not need through calcining and other complicated technology, energy-conserving and environment-protective, manufacture craft is simple, and cost is low, product strength is high, lightweight, non-friable, nontoxic, tasteless, produce without obnoxious flavour, can be used for indoor and outdoor, beautifying the environment etc. for garden landscape has very high practicality and artistic value.
(2) the present invention utilizes magnesium oxide to combine with magnesium chloride, after fully reacting, produce the gelling material of high strength, solve product weight, flimsy problem, the particular design of product and product surface reach the stub effect of mixing the spurious with the genuine through spraying colored drawing, solve in traditional stool making processes this problem of wasting resource, environmental pollution, the present invention only needs 4-8 hours at shaping time, traditional stool manufacture craft also very complicated, operation is loaded down with trivial details, and the invention solves problems.
(3) the application is in auxiliary material, have selected agricultural wastes and trade waste, glass fibre and additive.Take flyash as the trade waste of representative, its wear resistance for product and intensity play important enhancement; And agricultural wastes can play cohesive action on the one hand, also greatly reduce the weight of product simultaneously; Glass fibre is also the material of important enhancing product strength; In order to better promote mixing and the condensation of raw material, the present invention selects the additive of one or more comprising phosphoric acid, ferrous sulfate, Tai-Ace S 150, polyvinyl alcohol.Therefore, the material energy-saving environmental protection of the application, fire prevention combustion, high-strength light, health care absolutely; Product have lightweight, intensity high, non-friable, nontoxic, tasteless, produce without obnoxious flavour, ambient cure, make simple, low cost and other advantages.
(4) the present invention also has energy-saving and emission-reduction, economizes on resources, lightweight, intensity good, nontoxic, without obnoxious flavour, nonpollution environment, making is simple, cost is low, production efficiency advantages of higher; And the product that the present invention produces meets green, environmental protection, healthy requirement.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Accompanying drawing explanation
Fig. 1 is a kind of stereographic map of imitative stub stool.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, carry out clear, complete description to the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
As shown in Figure 1, the invention provides a kind of imitative stub stool 1, can work as stool use, with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
Magnesium oxide: 40% ~ 45%
Magnesium chloride: 20% ~ 22%
Water: 20% ~ 22%
Agricultural wastes: 5% ~ 10%
Flyash: 5% ~ 10%
Glass fibre: 1% ~ 3%
Additive: 0.5% ~ 2%.
As preferably, described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150, polyvinyl alcohol one or more.
As preferably, described agricultural wastes are wood chip.
The present invention also provides the preparation method of above-mentioned imitative stub stool, comprises the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add flyash, agricultural wastes, glass fibre and additive, stir, obtain fabric;
Step 2: the fabric be stirred is carried out in product mold whitewash and filling, remove mould product shaping after certain hour;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
As preferably, in step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.
As preferably, in step 2, certain hour is 4-8 hours.
As preferably, in step 1, the weight of flyash and agricultural wastes accounts for 10% ~ 20% of imitative stub stool raw material gross weight.
The present invention carries out test result according to regulation in magnesite art general technical specifications GB/T17657-1999:
(1) surface halide accumulation resistance
Being stood up by test specimen or hang into relative humidity is 90%-95%, and temperature is in the thermostat container of 40 DEG C ± 2 DEG C.Enough intervals should be had, to ensure the circulation of air between test specimen.Take out after 72h and observe each surface of product.
(2) apparent density
According in GB/T17657-1999 4.2 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1g/cm 3.
(3) water-intake rate
Should under test conditions, according in GB/T17657-1999 4.6 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1%.
(4) water ratio
Should under test conditions, according in GB/T17657-1999 4.3 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1%.
(5) chlorion stripping quantity
The method that should specify by JG/T301 free chlorine ion content is carried out.
(6) film adhesive
With sharp blade and scale steel ruler, cut in the direction in length and breadth of test specimen the cut channel that 11 stripe pitch are 1mm, cut channel intersects 100 pros in length and breadth.During cutting, blade face must be vertical with base plate, blade becomes 10 ° of-20 ° of angles with bottom surface, firmly will will penetrate the surface of film to base material by evenly all otch, each sharp mouth of blade can only do single test to keep the sharp of blade, and the different sites of same test specimen does three tests.After cutting with banister brush gently along foursquare two diagonal lines each brush 5 times back and forth, and observe with 4 times of magnifying glasses and come off with or without grid, with the test-results that secondary is close, as final test-results.
(7) intensity
Adopt the actual slip of craft articles, cast, vibratory compaction 40mm × 40mm × 160mm prism test specimen 2 groups totally 6 pieces.It is 20 DEG C ± 5 DEG C in temperature, form removal after maintenance 1d in the indoor environment of relative humidity (60 ± 10) %, continue maintenance with this understanding afterwards to 28d, wherein 1 group for measuring ultimate compression strength and folding strength, and measuring method carries out according to the regulation of GB/T17657.
(8) coefficient of softening
Test specimen should temperature 20 DEG C ± 5 DEG C, maintenance 28d in the indoor environment of relative humidity (60 ± 10) %, test specimen is immersed in the water that temperature is (20 ± 5) DEG C, spacing between test specimen is not less than 20mm, the submerged depth of upper surface and the water surface is not less than 20mm, take out after soaking 24h, wipe the moisture of surface of test piece with towel away.According to the folding strength after the regulation immersion of GB/T17671, the ratio of folding strength before what the folding strength and 6.10 calculated after water inlet measured do not soak is test-results, is accurately 0.1.
(9) freezing and thawing test
At room temperature soak test specimen 24h, takes out and wipe swimming of surface, put into the Hanging Basket of the cryogenic freezing case being cooled to-20 DEG C ± 2 DEG C in advance, freezing 4h, takes out the clear water putting into 20 DEG C ± 5 DEG C, melts 4h, for once circulating.Multigelation 28 times, needs to dry before putting into cryogenic freezing case at every turn, observes the surface of test specimen with or without damaged, cracking phenomena.
Advantageous Effects of the present invention is as follows:
(1) the present invention compares with traditional stool, is to utilize New Inorganic Materials to be made through scientific formula, and appearance design is unique, add its practicality and artistry, formed at normal temp solidifies, and does not need through calcining and other complicated technology, energy-conserving and environment-protective, manufacture craft is simple, and cost is low, product strength is high, lightweight, non-friable, nontoxic, tasteless, produce without obnoxious flavour, can be used for indoor and outdoor, beautifying the environment etc. for garden landscape has very high practicality and artistic value.
(2) the present invention utilizes magnesium oxide to combine with magnesium chloride, after fully reacting, produce the gelling material of high strength, solve product weight, flimsy problem, the particular design of product and product surface reach the stub effect of mixing the spurious with the genuine through spraying colored drawing, solve in traditional stool making processes this problem of wasting resource, environmental pollution, the present invention only needs 4-8 hours at shaping time, traditional stool manufacture craft also very complicated, operation is loaded down with trivial details, and the invention solves problems.
(3) the application is in auxiliary material, have selected agricultural wastes and trade waste, glass fibre and additive.Take flyash as the trade waste of representative, its wear resistance for product and intensity play important enhancement; And agricultural wastes can play cohesive action on the one hand, also greatly reduce the weight of product simultaneously; Glass fibre is also the material of important enhancing product strength; In order to better promote mixing and the condensation of raw material, the present invention selects the additive of one or more comprising phosphoric acid, ferrous sulfate, Tai-Ace S 150, polyvinyl alcohol.Therefore, the material energy-saving environmental protection of the application, fire prevention combustion, high-strength light, health care absolutely; Product have lightweight, intensity high, non-friable, nontoxic, tasteless, produce without obnoxious flavour, ambient cure, make simple, low cost and other advantages.
(4) the present invention also has energy-saving and emission-reduction, economizes on resources, lightweight, intensity good, nontoxic, without obnoxious flavour, nonpollution environment, making is simple, cost is low, production efficiency advantages of higher; And the product that the present invention produces meets green, environmental protection, healthy requirement.
Below will be described the present invention by embodiment.
Embodiment 1:
A kind of imitative stub stool, with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
Magnesium oxide: 40%
Magnesium chloride: 20%
Water: 20%
Wood chip: 5%
Flyash: 10%
Glass fibre: 3%
Polyvinyl alcohol: 2%.
A preparation method for above-mentioned imitative stub stool, comprises the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add flyash, wood chip, glass fibre and polyvinyl alcohol according to said ratio, stir, obtain fabric;
Step 2: carried out by the fabric be stirred whitewashing and filling in product mold, removes mould product in 6 hours shaping;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
The product integrated performance index of embodiment 1
Embodiment 2:
A kind of imitative stub stool, with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
Magnesium oxide: 42%
Magnesium chloride: 21%
Water: 21%
Wood chip: 7%
Flyash: 7.5%
Glass fibre: 1%
Ferrous sulfate: 0.5%.
A preparation method for above-mentioned imitative stub stool, comprises the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add flyash, wood chip, glass fibre and ferrous sulfate successively according to said ratio, stir, obtain fabric;
Step 2: carried out by the fabric be stirred whitewashing and filling in product mold, removes mould product in 8 hours shaping;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
The product integrated performance index of embodiment 2
Embodiment 3:
A kind of imitative stub stool, with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
Magnesium oxide: 45%
Magnesium chloride: 20%
Water: 20%
Wood chip: 5%
Flyash: 7%
Glass fibre: 1.5%
Tai-Ace S 150: 1.5%.
A preparation method for the dual-purpose flowerpot of above-mentioned imitative stub, stool, comprises the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add flyash, silicon ash, cavings, glass fibre and Tai-Ace S 150 successively according to said ratio, stir, obtain fabric;
Step 2: carried out by the fabric be stirred whitewashing and filling in product mold, removes mould product in 4 hours shaping;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
The product integrated performance index of embodiment 3
Those skilled in the art, at consideration specification sheets and after putting into practice invention disclosed herein, will easily expect other embodiment of the present invention.The application is intended to contain any modification of the present invention, purposes or adaptations, and these modification, purposes or adaptations are followed general principle of the present invention and comprised the undocumented common practise in the art of the disclosure or conventional techniques means.Specification sheets and embodiment are only regarded as exemplary, and true scope of the present invention and spirit are pointed out by claim.
Should be understood that, the present invention is not limited to precision architecture described above and illustrated in the accompanying drawings, and can carry out various amendment and change not departing from its scope.Scope of the present invention is only limited by appended claim.

Claims (7)

1. an imitative stub stool, is characterized in that: with imitative stub stool raw material total weight, this imitative stub stool is made up of following weight percent raw material:
2. stub stool as claimed in claim 1 imitative, is characterized in that: described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150, polyvinyl alcohol one or more.
3. imitative stub stool as claimed in claim 1 or 2, is characterized in that: described agricultural wastes are wood chip.
4. the preparation method of the imitative stub stool described in claim 1-3, is characterized in that: comprise the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add flyash, agricultural wastes, glass fibre and additive, stir, obtain fabric;
Step 2: the fabric be stirred is carried out in product mold whitewash and filling, remove mould product shaping after certain hour;
Step 3: carry out spraying effect process at product surface, the stub effect making product reach design to want.
5. preparation method as claimed in claim 4, is characterized in that:
In step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.
6. preparation method as claimed in claim 4, is characterized in that:
In step 2, certain hour is 4-8 hours.
7. preparation method as claimed in claim 4, is characterized in that:
In step 1, the weight of flyash and agricultural wastes accounts for 10% ~ 20% of imitative stub stool raw material gross weight.
CN201510930998.XA 2015-12-11 2015-12-11 Stump imitating stool and preparing method thereof Pending CN105503139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510930998.XA CN105503139A (en) 2015-12-11 2015-12-11 Stump imitating stool and preparing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510930998.XA CN105503139A (en) 2015-12-11 2015-12-11 Stump imitating stool and preparing method thereof

Publications (1)

Publication Number Publication Date
CN105503139A true CN105503139A (en) 2016-04-20

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1145342A (en) * 1996-07-02 1997-03-19 丁佑民 Magnesia cement furniture and its prodn. method
CN101117283A (en) * 2006-07-31 2008-02-06 李丽俊 Pseudo stone flower bowl and method for making the same
WO2011111032A1 (en) * 2010-03-10 2011-09-15 Boaz Harpaz Composition for construction elements and improved tiles
CN104926268A (en) * 2015-07-01 2015-09-23 卓达新材料科技集团有限公司 Marble-imitated furniture material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1145342A (en) * 1996-07-02 1997-03-19 丁佑民 Magnesia cement furniture and its prodn. method
CN101117283A (en) * 2006-07-31 2008-02-06 李丽俊 Pseudo stone flower bowl and method for making the same
WO2011111032A1 (en) * 2010-03-10 2011-09-15 Boaz Harpaz Composition for construction elements and improved tiles
CN104926268A (en) * 2015-07-01 2015-09-23 卓达新材料科技集团有限公司 Marble-imitated furniture material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
涂平涛: "《氯氧镁材料技术与应用》", 31 December 2009 *

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Application publication date: 20160420

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