CN105482596A - 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸 - Google Patents

一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸 Download PDF

Info

Publication number
CN105482596A
CN105482596A CN201510831389.9A CN201510831389A CN105482596A CN 105482596 A CN105482596 A CN 105482596A CN 201510831389 A CN201510831389 A CN 201510831389A CN 105482596 A CN105482596 A CN 105482596A
Authority
CN
China
Prior art keywords
polylactic acid
acrylic resin
emulsion
wallpaper
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510831389.9A
Other languages
English (en)
Inventor
李华令
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Suoya Decorative Materials Co Ltd
Original Assignee
Anhui Suoya Decorative Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Suoya Decorative Materials Co Ltd filed Critical Anhui Suoya Decorative Materials Co Ltd
Priority to CN201510831389.9A priority Critical patent/CN105482596A/zh
Publication of CN105482596A publication Critical patent/CN105482596A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开了一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸，该墙纸使用的涂层浆料中采用的树脂粘接剂为醋酸纤维素共聚改性水性丙烯酸树脂乳液，这种树脂乳液性能稳定，不含甲醛等慢性挥发性有毒化合物，所形成的涂层爽滑有弹性，具备防水、防污、抗菌等功能，含有纳米活性炭纤维的浮石-聚乳酸多孔纤维可有效改善涂层的透气性，同时改善涂层的力学性能，赋予墙纸对空气的净化能力，这种新型墙纸经久耐用，环保经济，特色鲜明，应用价值极大。

Description

一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
技术领域
本发明涉及墙纸技术领域，尤其涉及一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸。
背景技术
墙纸又名壁纸,因其具有色彩多样，图案丰富，豪华气派、安全环保、施工方便、价格适宜等优势在家装中应用越来越广泛,常见墙纸大是以纯纸、无纺布等材料作为基材，在其表面涂覆树脂浆料，经高温塑化、印制压花等工序制成。
目前市场上最常见的涂层浆料主要是由PVC树脂及填料组成，这种涂层材料虽然具有美观耐用防水等优点，然而其透气性差，且含有有机类溶剂，长时间使用会污染室内空气，随着人们环保意识的提高，对壁纸的环保性要求也越来越高，这无疑需要使用新的涂层材料取代PVC树脂。近年来市场上涌现出一批环保的水性树脂涂层材料，这类材料虽然不含挥发性有机溶剂，然而其在透气性、塑化温度、附加功能性以及与基材的贴合性等方面仍存在不足。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸。
本发明是通过以下技术方案实现的：
一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸，该墙纸是由无纺布基材和涂覆于基材表面的涂层浆料经过干燥、塑化、压花后制成，所述的涂层浆料由以下重量份的原料制成：复合水性丙烯酸树脂乳液80-100、聚乳酸切片8-10、浮石微粉3-5、纳米活性炭纤维1-2、乙烯基双硬脂酸酰胺0.1-0.2、硅烷偶联剂kh5500.1-0.2。
所述的涂层浆料制备方法为：
（1）浮石-聚乳酸多孔纤维制备：先将浮石微粉、纳米活性炭纤维、聚乳酸切片、乙烯基双硬脂酸酰胺、硅烷偶联剂kh550搅拌混合均匀后进行熔融纺丝，制成长度为60-100μm，直径为30-50μm的多孔短纤维；
（2）将浮石-聚乳酸多孔纤维投入复合水性丙烯酸树脂乳液中，搅拌混合30-50min后加入其它剩余物料，强力搅拌混合4-5h，随后静置放置30-40min后即得。
所述的复合水性丙烯酸树脂乳液由以下重量份的原料制成：纳米二氧化硅0.5-0.8、醋酸纤维素4-5、N，N-二甲基甲酰胺12-15、丙烯酸丁酯18-25、甲基丙烯酸甲酯15-20、丙烯酸10-15、过硫酸铵5-8、乳化剂OP-102-3、十二烷基硫酸钠1-3、氨水适量、去离子水50-60，制备方法为：
（1）先将醋酸纤维素投入N，N-二甲基甲酰胺中，搅拌至其完全溶解，随后将纳米二氧化硅投入溶液中，密闭超声搅拌分散3-4h，得掺混纳米二氧化硅的醋酸纤维素溶液备用；
（2）将乳化剂OP-10、十二烷基硫酸钠投入反应釜中，随后加入10-15重量份的去离子水，搅拌至完全溶解后，投入步骤（1）制备的物料及丙烯酸丁酯、甲基丙烯酸甲酯、丙烯酸，升温至70-75℃，搅拌混合2-3h，得预乳化液备用；
（3）种子乳液制备：将过硫酸铵和适量的氨水溶于余量的去离子水中，调节溶液pH值为6.0-7.5，并加热至65-75℃，然后分别取2/3重量份的该溶液与1/4重量份步骤（2）制备的预乳化液，同时滴加到反应容器中，滴加速度为45-60滴/min，待反应体系呈蓝色荧光时停止滴加，得种子乳液；
（4）所得种子乳液静置15-20min后重新滴加剩余量的过硫酸铵溶液及预乳化液，滴加结束后在70-75℃条件下恒温50-60min，随后加热至75-80℃，恒温条件下强力搅拌混合1.5-2h，随后停止搅拌，待乳液自然冷却至50℃以下时用氨水调节溶液pH值为7.0，随后过滤出料即得。
本发明墙纸使用的涂层浆料中采用的树脂粘接剂为醋酸纤维素共聚改性水性丙烯酸树脂乳液，这种树脂乳液性能稳定，不含甲醛等慢性挥发性有毒化合物，所形成的涂层爽滑有弹性，具备防水、防污、抗菌等功能，含有纳米活性炭纤维的浮石-聚乳酸多孔纤维可有效改善涂层的透气性，同时改善涂层的力学性能，赋予墙纸对空气的净化能力，这种新型墙纸经久耐用，环保经济，特色鲜明，应用价值极大。
具体实施方式
该实施例墙纸是由无纺布基材和涂覆于基材表面的涂层浆料经过干燥、塑化、压花后制成，其中涂层浆料由以下重量份的原料制成：复合水性丙烯酸树脂乳液80、聚乳酸切片8、浮石微粉3、纳米活性炭纤维1、乙烯基双硬脂酸酰胺0.1、硅烷偶联剂kh5500.1。
该涂层浆料制备方法为：
（1）浮石聚乳酸多孔纤维制备：先将浮石微粉、纳米活性炭纤维、聚乳酸切片、乙烯基双硬脂酸酰胺、硅烷偶联剂kh550搅拌混合均匀后进行熔融纺丝，制成长度为60μm，直径为30μm的多孔短纤维；
（2）将浮石聚乳酸多孔纤维投入复合水性丙烯酸树脂乳液中，搅拌混合30min后加入其它剩余物料，强力搅拌混合4h，随后静置放置30min后即得。
其中复合水性丙烯酸树脂乳液由以下重量份的原料制成：纳米二氧化硅0.5、醋酸纤维素4、N，N-二甲基甲酰胺12、丙烯酸丁酯18、甲基丙烯酸甲酯15、丙烯酸10、过硫酸铵5、乳化剂OP2、十二烷基硫酸钠1、氨水适量、去离子水50，制备方法为：
（1）先将醋酸纤维素投入N，N-二甲基甲酰胺中，搅拌至其完全溶解，随后将纳米二氧化硅投入溶液中，密闭超声搅拌分散3h，得掺混纳米二氧化硅的醋酸纤维素溶液备用；
（2）将乳化剂OP、十二烷基硫酸钠投入反应釜中，随后加入10重量份的去离子水，搅拌至完全溶解后，投入步骤（1）制备的物料及丙烯酸丁酯、甲基丙烯酸甲酯、丙烯酸，升温至70℃，搅拌混合2h，得预乳化液备用；
（3）种子乳液制备：将过硫酸铵和适量的氨水溶于余量的去离子水中，调节溶液pH值为6.0，并加热至65℃，然后分别取2/3重量份的该溶液与1/4重量份步骤（2）制备的预乳化液，同时滴加到反应容器中，滴加速度为45滴/min，待反应体系呈蓝色荧光时停止滴加，得种子乳液；
（4）所得种子乳液静置15min后重新滴加剩余量的过硫酸铵溶液及预乳化液，滴加结束后在70℃条件下恒温50min，随后加热至75℃，恒温条件下强力搅拌混合1.5h，随后停止搅拌，待乳液自然冷却至50℃以下时用氨水调节溶液pH值为7.0，随后过滤出料即得。
将涂层浆料涂覆在无纺布基纸表面，控制涂布量为15g/m2，待其干燥后在135℃条件下塑化压花，冷却成型后对产品依据相关标准进行性能测试，测试结果为:
甲醛去除率:
0h：35.5%；24h：60.5%；48h：85.5%；72h：90.8%；96h:95.4%；120h:98.5%。
回潮率：0.45%；透气度：12.4L/（m2s）；抗张强度：3230N/m，耐破度：158.5KPa。
抗菌防霉性：对金黄色葡萄球菌抑菌率可达96.0%；对大肠杆菌抑菌率可达97.5%；对黑曲霉、球毛壳菌、绿粘帚菌的抑菌等级为0级。
该实施例制备的墙纸符合GB18585-2001的规定，不含有国家规定的禁止使用的重金属锑、砷、钡、镉、铬、铅、汞、硒，不含有甲醛、不含有氯乙烯单体。

Claims (3)

1.一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸，该墙纸是由无纺布基材和涂覆于基材表面的涂层浆料经过干燥、塑化、压花后制成，其特征在于，所述的涂层浆料由以下重量份的原料制成：复合水性丙烯酸树脂乳液80-100、聚乳酸切片8-10、浮石微粉3-5、纳米活性炭纤维1-2、乙烯基双硬脂酸酰胺0.1-0.2、硅烷偶联剂kh5500.1-0.2。
2.如权利要求1所述的一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸，其特征在于，所述的涂层浆料制备方法为：
（1）浮石-聚乳酸多孔纤维制备：先将浮石微粉、纳米活性炭纤维、聚乳酸切片、乙烯基双硬脂酸酰胺、硅烷偶联剂kh550搅拌混合均匀后进行熔融纺丝，制成长度为60-100μm，直径为30-50μm的多孔短纤维；
（2）将浮石-聚乳酸多孔纤维投入复合水性丙烯酸树脂乳液中，搅拌混合30-50min后加入其它剩余物料，强力搅拌混合4-5h，随后静置放置30-40min后即得。
3.如权利要求1或2所述的一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸，其特征在于，所述的复合水性丙烯酸树脂乳液由以下重量份的原料制成：纳米二氧化硅0.5-0.8、醋酸纤维素4-5、N，N-二甲基甲酰胺12-15、丙烯酸丁酯18-25、甲基丙烯酸甲酯15-20、丙烯酸10-15、过硫酸铵5-8、乳化剂OP-102-3、十二烷基硫酸钠1-3、氨水适量、去离子水50-60，制备方法为：
（1）先将醋酸纤维素投入N，N-二甲基甲酰胺中，搅拌至其完全溶解，随后将纳米二氧化硅投入溶液中，密闭超声搅拌分散3-4h，得掺混纳米二氧化硅的醋酸纤维素溶液备用；
（2）将乳化剂OP-10、十二烷基硫酸钠投入反应釜中，随后加入10-15重量份的去离子水，搅拌至完全溶解后，投入步骤（1）制备的物料及丙烯酸丁酯、甲基丙烯酸甲酯、丙烯酸，升温至70-75℃，搅拌混合2-3h，得预乳化液备用；
（3）种子乳液制备：将过硫酸铵和适量的氨水溶于余量的去离子水中，调节溶液pH值为6.0-7.5，并加热至65-75℃，然后分别取2/3重量份的该溶液与1/4重量份步骤（2）制备的预乳化液，同时滴加到反应容器中，滴加速度为45-60滴/min，待反应体系呈蓝色荧光时停止滴加，得种子乳液；
（4）所得种子乳液静置15-20min后重新滴加剩余量的过硫酸铵溶液及预乳化液，滴加结束后在70-75℃条件下恒温50-60min，随后加热至75-80℃，恒温条件下强力搅拌混合1.5-2h，随后停止搅拌，待乳液自然冷却至50℃以下时用氨水调节溶液pH值为7.0，随后过滤出料即得。
CN201510831389.9A 2015-11-25 2015-11-25 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸 Pending CN105482596A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510831389.9A CN105482596A (zh) 2015-11-25 2015-11-25 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510831389.9A CN105482596A (zh) 2015-11-25 2015-11-25 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸

Publications (1)

Publication Number Publication Date
CN105482596A true CN105482596A (zh) 2016-04-13

Family

ID=55669882

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510831389.9A Pending CN105482596A (zh) 2015-11-25 2015-11-25 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸

Country Status (1)

Country Link
CN (1) CN105482596A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107503164A (zh) * 2017-08-22 2017-12-22 安徽银兔装饰材料有限公司 无缝长纤无纺布基墙布及其制备方法
CN107524017A (zh) * 2017-08-22 2017-12-29 安徽银兔装饰材料有限公司 无缝短纤无纺布基墙布及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605679A (zh) * 2012-03-15 2012-07-25 广东银洋树脂有限公司 一种墙纸
CN104452476A (zh) * 2014-12-12 2015-03-25 广东玉兰装饰材料有限公司 一种金沙墙纸及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102605679A (zh) * 2012-03-15 2012-07-25 广东银洋树脂有限公司 一种墙纸
CN104452476A (zh) * 2014-12-12 2015-03-25 广东玉兰装饰材料有限公司 一种金沙墙纸及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107503164A (zh) * 2017-08-22 2017-12-22 安徽银兔装饰材料有限公司 无缝长纤无纺布基墙布及其制备方法
CN107524017A (zh) * 2017-08-22 2017-12-29 安徽银兔装饰材料有限公司 无缝短纤无纺布基墙布及其制备方法

Similar Documents

Publication Publication Date Title
CN105505079A (zh) 一种含沸石粉-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105421086A (zh) 一种含茶多酚-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105442335A (zh) 一种含改性丙烯酸树脂乳液涂层的高韧性墙纸
CN105297438A (zh) 一种含凹凸棒土-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105274855A (zh) 一种含改性丙烯酸树脂乳液涂层的耐火保温型墙纸
CN101250244B (zh) 一种聚合物空心微球及其制备方法
CN102619127B (zh) 一种环保高适印性无纺壁纸原纸
WO2019015365A1 (zh) 多功能高强复合织物涂层剂、涂层及其制备方法与应用
CN103613700B (zh) 一种Pickering乳液聚合法制备聚丙烯酸酯/纳米ZnO复合涂料印花粘合剂的方法
CN105505091A (zh) 一种含多孔碳化硅-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105295626A (zh) 一种含复合改性水性丙烯酸树脂乳液涂层的珠光型阻燃墙纸
CN105804352B (zh) 自带胶黏剂的环保墙布及其制备方法
CN104479596A (zh) 水基环保型拼板胶及其制备方法
CN105506987A (zh) 一种含疏水性硅藻土-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN103172785A (zh) 高吸水性自交联环氧基丙烯酸酯共聚物及其制备和应用
CN105273555A (zh) 一种含改性丙烯酸树脂乳液涂层的除湿杀菌型墙纸
CN105482596A (zh) 一种含浮石-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105295628A (zh) 一种含改性丙烯酸树脂乳液涂层的高耐磨损墙纸
CN105295627A (zh) 一种含改性丙烯酸树脂乳液涂层的净味墙纸
CN105440858A (zh) 一种含改性丙烯酸树脂乳液涂层的高抗菌保温型墙纸
CN103215825B (zh) 石头纸壁纸印花粘合剂及其制备方法
CN105298073A (zh) 一种含纳米碳酸钙晶须-聚乳酸多孔纤维改性丙烯酸树脂乳液涂层的墙纸
CN105421087A (zh) 一种含改性丙烯酸树脂乳液涂层的防静电保健型墙纸
CN102758380B (zh) 一种用于纯纸和无纺纸生产的表面微涂布剂及其制备方法
CN105316938B (zh) 一种制备醋酸纤维素纳米纤维复合材料的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160413