CN105482595A - Environment-friendly exterior wall latex coating and preparing method thereof - Google Patents

Environment-friendly exterior wall latex coating and preparing method thereof Download PDF

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Publication number
CN105482595A
CN105482595A CN201610011444.4A CN201610011444A CN105482595A CN 105482595 A CN105482595 A CN 105482595A CN 201610011444 A CN201610011444 A CN 201610011444A CN 105482595 A CN105482595 A CN 105482595A
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China
Prior art keywords
parts
environment
exterior wall
emulsion
friendly exterior
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Pending
Application number
CN201610011444.4A
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Chinese (zh)
Inventor
王宇
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TONGCHENG HUIQI INDUSTRY AND TRADE Co Ltd
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TONGCHENG HUIQI INDUSTRY AND TRADE Co Ltd
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Priority to CN201610011444.4A priority Critical patent/CN105482595A/en
Publication of CN105482595A publication Critical patent/CN105482595A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to an environment-friendly exterior wall latex coating and a preparing method thereof. The environment-friendly exterior wall latex coating is prepared from, by weight, 0-2 parts of preservative, 0-2 parts of mildew preventive, 0.5-2 parts of PH regulator, 150-170 parts of titanium dioxide, 1-5 parts of hydroxyethyl cellulose, 5-8 parts of dispersing agent, 1-5 parts of defoamer, 1-5 parts of wetting agent, 90-110 parts of wollastonite in powder, 180-220 parts of heavy calcium powder, 10-20 parts of propylene glycol, 5-10 parts of coalescing agent, 60-70 parts of styrene-acrylic emulsion, 220-240 parts of elastic emulsion, 0-5 parts of ammonia water, 1-5 parts of thickener, 0-5 parts of colorant and 160-180 parts of deionized water. The environment-friendly exterior wall latex coating is environmentally friendly and has high weather resistance, water resistance and adhesive force, and the quality of the environment-friendly exterior wall latex coating meets the national standard.

Description

A kind of environment-friendly exterior wall emulsion paint and preparation method thereof
Technical field
The present invention relates to a kind of environment-friendly exterior wall emulsion paint and preparation method thereof, belong to building coating technical field.
Background technology
Exterior wall latex paint take macromolecule emulsion as a class coating of film forming matter, is that base-material adds the formulated class water-borne coatings of pigment, filler and various auxiliary agent with synthetic resin emulsion.The major function of exterior wall latex paint is decoration and architecture protection object plane, makes buildings appearance neat and artistic, thus reaches the object of beautifying urban environment, can play the effect of architecture protection beyond the region of objective existence wall simultaneously, extend its work-ing life.
Exterior wall latex paint also exists poor water resistance in the market, weathering resistance is poor, the shortcoming that adhesive ability is not strong, for a long time being exposed to the phenomenons such as air floating coat easily occurs ftractureing, peels off, shedding, variable color, makes it lose original ornamental and protectiveness.Meanwhile, existing exterior wall latex paint because of containing formaldehyde or benzene solvent etc. polluted air, affect environmental quality.
Summary of the invention
The object of the invention is to: a kind of environmental protection is provided, simultaneously good weatherability, water-tolerant, environment-friendly exterior wall emulsion paint that sticking power is high and preparation method thereof.
In order to realize foregoing invention object, the invention provides following technical scheme:
A kind of environment-friendly exterior wall emulsion paint, comprise the raw material of following weight part: sanitas 0-2 part, mould inhibitor 0-2 part, PH adjusting agent 0.5-2 part, titanium dioxide 150-170 part, Natvosol 1-5 part, dispersion agent 5-8 part, defoamer 1-5 part, wetting agent 1-5 part, wollastonite powder 90-110 part, dicalcium powder 180-220 part, propylene glycol 10-20 part, film coalescence aid 5-10 part, benzene emulsion 60-70 part, elastic emulsion 220-240 part, ammoniacal liquor 0-5 part, thickening material 1-5 part, tinting material 0-5 part, deionized water 160-180 part.
Preferably, described environment-friendly exterior wall emulsion paint, comprises the raw material of following weight part: sanitas 1 part, mould inhibitor 1 part, PH adjusting agent 1 part, titanium dioxide 160 parts, Natvosol 3 parts, dispersion agent 6 parts, defoamer 2 parts, wetting agent 2 parts, wollastonite powder 100 parts, dicalcium powder 200 parts, propylene glycol 15 parts, film coalescence aid 8 parts, benzene emulsion 65 parts, elastic emulsion 230 parts, ammoniacal liquor 1 part, thickening material 2 parts, tinting material 3 parts, deionized water 170 parts.
Preferably, described tinting material be iron oxide black, tomato red, curcumine, indigo and aluminium color lake one or more.
Preferably, described elastic emulsion is acrylic ester elastic emulsion.
Preferably, described PH conditioning agent is the one in sodium carbonate, sodium bicarbonate.
Preferably, described Natvosol model is 30000S.
Preferably, a kind of preparation method of environment-friendly exterior wall emulsion paint, concrete steps are as follows:
(1) by ionized water, sanitas, mould inhibitor, PH adjusting agent, titanium dioxide, Natvosol, dispersion agent, defoamer, wetting agent adds in dispersion machine, high speed dispersion 10-20 minute under rotating speed is 1300-1350 rev/min of condition;
(2) then wollastonite powder is added, dicalcium powder, propylene glycol, film coalescence aid, high speed dispersion 30-40 minute under rotating speed is 1300-1350 rev/min of condition;
(3) finally add defoamer, benzene emulsion, after stirring under rotating speed is 300-500 rev/min of condition, then add elastic emulsion, ammoniacal liquor, thickening material, tinting material, rotating speed is adjusted to 300-500 rev/min and stirs and can fillingly dispatch from the factory.
Preferably, the mass ratio of the defoamer in step (1) and step (3) is 1:1.
Beneficial effect of the present invention is: environment-friendly exterior wall emulsion paint provided by the invention environmental protection, and quality meets national standard, and meanwhile, good weatherability, water-tolerant, sticking power are high.
Embodiment
Embodiment 1
A kind of environment-friendly exterior wall emulsion paint, comprises the raw material of following weight part: sanitas 0.5 part, mould inhibitor 0.5 part, PH adjusting agent 0.5 part, titanium dioxide 150 parts, Natvosol 1 part, dispersion agent 5 parts, defoamer 1 part, wetting agent 1 part, wollastonite powder 90 parts, dicalcium powder 180 parts, propylene glycol 10 parts, film coalescence aid 5 parts, benzene emulsion 60 parts, elastic emulsion 220 parts, ammoniacal liquor 1 part, thickening material 1 part, tinting material 1 part, deionized water 160 parts.
The preparation method of above-mentioned environment-friendly exterior wall emulsion paint, concrete steps are as follows:
(1) by ionized water, sanitas, mould inhibitor, PH adjusting agent, titanium dioxide, Natvosol, dispersion agent, defoamer, wetting agent adds in dispersion machine, high speed dispersion 10 minutes under rotating speed is 1300 revs/min of conditions;
(2) then wollastonite powder is added, dicalcium powder, propylene glycol, film coalescence aid, high speed dispersion 30 minutes under rotating speed is 1300 revs/min of conditions;
(3) finally add defoamer, benzene emulsion, after stirring under rotating speed is 300 revs/min of conditions, then add elastic emulsion, ammoniacal liquor, thickening material, tinting material, rotating speed is adjusted to 300 revs/min and stirs and can fillingly dispatch from the factory.
Wherein, the mass ratio of the defoamer in step (1) and step (3) is 1:1.
Embodiment 2
A kind of environment-friendly exterior wall emulsion paint, comprises the raw material of following weight part: sanitas 1 part, mould inhibitor 1 part, PH adjusting agent 1 part, titanium dioxide 160 parts, Natvosol 3 parts, dispersion agent 6 parts, defoamer 2 parts, wetting agent 2 parts, wollastonite powder 100 parts, dicalcium powder 200 parts, propylene glycol 15 parts, film coalescence aid 8 parts, benzene emulsion 65 parts, elastic emulsion 230 parts, ammoniacal liquor 1 part, thickening material 2 parts, tinting material 3 parts, deionized water 170 parts.
The preparation method of above-mentioned environment-friendly exterior wall emulsion paint, concrete steps are as follows:
(1) by ionized water, sanitas, mould inhibitor, PH adjusting agent, titanium dioxide, Natvosol, dispersion agent, defoamer, wetting agent adds in dispersion machine, high speed dispersion 15 minutes under rotating speed is 1325 revs/min of conditions;
(2) then wollastonite powder is added, dicalcium powder, propylene glycol, film coalescence aid, high speed dispersion 35 minutes under rotating speed is 1325 revs/min of conditions;
(3) finally add defoamer, benzene emulsion, after stirring under rotating speed is 400 revs/min of conditions, then add elastic emulsion, ammoniacal liquor, thickening material, tinting material, rotating speed is adjusted to 400 revs/min and stirs and can fillingly dispatch from the factory.
Wherein, the mass ratio of the defoamer in step (1) and step (3) is 1:1.
Embodiment 3
A kind of environment-friendly exterior wall emulsion paint, comprises the raw material of following weight part: sanitas 2 parts, mould inhibitor 2 parts, PH adjusting agent 2 parts, titanium dioxide 170 parts, Natvosol 5 parts, dispersion agent 8 parts, defoamer 5 parts, wetting agent 5 parts, wollastonite powder 110 parts, dicalcium powder 220 parts, propylene glycol 20 parts, film coalescence aid 10 parts, benzene emulsion 70 parts, elastic emulsion 240 parts, ammoniacal liquor 5 parts, thickening material 5 parts, tinting material 5 parts, deionized water 180 parts.
The preparation method of above-mentioned environment-friendly exterior wall emulsion paint, concrete steps are as follows:
(1) by ionized water, sanitas, mould inhibitor, PH adjusting agent, titanium dioxide, Natvosol, dispersion agent, defoamer, wetting agent adds in dispersion machine, high speed dispersion 20 minutes under rotating speed is 1350 revs/min of conditions;
(2) then wollastonite powder is added, dicalcium powder, propylene glycol, film coalescence aid, high speed dispersion 40 minutes under rotating speed is 1350 revs/min of conditions;
(3) finally add defoamer, benzene emulsion, after stirring under rotating speed is 500 revs/min of conditions, then add elastic emulsion, ammoniacal liquor, thickening material, tinting material, rotating speed is adjusted to 500 revs/min and stirs and can fillingly dispatch from the factory.
Wherein, the mass ratio of the defoamer in step (1) and step (3) is 1:1.
In embodiment 1-3: tinting material be iron oxide black, tomato red, curcumine, indigo and aluminium color lake one or more; Elastic emulsion is acrylic ester elastic emulsion; PH conditioning agent is the one in sodium carbonate, sodium bicarbonate; Natvosol model is 30000S.

Claims (8)

1. an environment-friendly exterior wall emulsion paint, it is characterized in that: the raw material comprising following weight part: sanitas 0-2 part, mould inhibitor 0-2 part, PH adjusting agent 0.5-2 part, titanium dioxide 150-170 part, Natvosol 1-5 part, dispersion agent 5-8 part, defoamer 1-5 part, wetting agent 1-5 part, wollastonite powder 90-110 part, dicalcium powder 180-220 part, propylene glycol 10-20 part, film coalescence aid 5-10 part, benzene emulsion 60-70 part, elastic emulsion 220-240 part, ammoniacal liquor 0-5 part, thickening material 1-5 part, tinting material 0-5 part, deionized water 160-180 part.
2. environment-friendly exterior wall emulsion paint according to claim 1, is characterized in that: the raw material comprising following weight part: sanitas 1 part, mould inhibitor 1 part, PH adjusting agent 1 part, titanium dioxide 160 parts, Natvosol 3 parts, dispersion agent 6 parts, defoamer 2 parts, wetting agent 2 parts, wollastonite powder 100 parts, dicalcium powder 200 parts, propylene glycol 15 parts, film coalescence aid 8 parts, benzene emulsion 65 parts, elastic emulsion 230 parts, ammoniacal liquor 1 part, thickening material 2 parts, tinting material 3 parts, deionized water 170 parts.
3. environment-friendly exterior wall emulsion paint according to claim 1, is characterized in that: described tinting material be iron oxide black, tomato red, curcumine, indigo and aluminium color lake one or more.
4. environment-friendly exterior wall emulsion paint according to claim 1, is characterized in that: described elastic emulsion is acrylic ester elastic emulsion.
5. environment-friendly exterior wall emulsion paint according to claim 1, is characterized in that: described PH conditioning agent is the one in sodium carbonate, sodium bicarbonate.
6. environment-friendly exterior wall emulsion paint according to claim 1, is characterized in that: described Natvosol model is 30000S.
7. a preparation method for environment-friendly exterior wall emulsion paint, is characterized in that: concrete steps are as follows:
(1) by ionized water, sanitas, mould inhibitor, PH adjusting agent, titanium dioxide, Natvosol, dispersion agent, defoamer, wetting agent adds in dispersion machine, high speed dispersion 10-20 minute under rotating speed is 1300-1350 rev/min of condition;
(2) then wollastonite powder is added, dicalcium powder, propylene glycol, film coalescence aid, high speed dispersion 30-40 minute under rotating speed is 1300-1350 rev/min of condition;
(3) finally add defoamer, benzene emulsion, after stirring under rotating speed is 300-500 rev/min of condition, then add elastic emulsion, ammoniacal liquor, thickening material, tinting material, rotating speed is adjusted to 300-500 rev/min and stirs and can fillingly dispatch from the factory.
8. the preparation method of environment-friendly exterior wall emulsion paint according to claim 7, is characterized in that: the mass ratio of the defoamer in step (1) and step (3) is 1:1.
CN201610011444.4A 2016-01-05 2016-01-05 Environment-friendly exterior wall latex coating and preparing method thereof Pending CN105482595A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557890A (en) * 2004-01-18 2004-12-29 大庆油田创业集团有限公司 Nano titanium dioxide composite water-based building paint having high weathering-resistance
CN101270247A (en) * 2007-03-23 2008-09-24 宝山钢铁股份有限公司 Water-proof emulsion for coal pile in the open air
CN101338163A (en) * 2008-08-12 2009-01-07 山西天时涂料装饰有限公司 Elastic emulsion paint and method for preparing same
CN101857752A (en) * 2010-05-28 2010-10-13 中华制漆（深圳）有限公司 Aqueous exterior wall coating material with high solid content and low viscosity
CN104861790A (en) * 2015-04-28 2015-08-26 安徽顺驰电缆有限公司 Acrylic acid waterproof coating
CN104893440A (en) * 2015-04-29 2015-09-09 安徽嘉木橡塑工业有限公司 Acrylic acid waterproof material preparation process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557890A (en) * 2004-01-18 2004-12-29 大庆油田创业集团有限公司 Nano titanium dioxide composite water-based building paint having high weathering-resistance
CN101270247A (en) * 2007-03-23 2008-09-24 宝山钢铁股份有限公司 Water-proof emulsion for coal pile in the open air
CN101338163A (en) * 2008-08-12 2009-01-07 山西天时涂料装饰有限公司 Elastic emulsion paint and method for preparing same
CN101857752A (en) * 2010-05-28 2010-10-13 中华制漆（深圳）有限公司 Aqueous exterior wall coating material with high solid content and low viscosity
CN104861790A (en) * 2015-04-28 2015-08-26 安徽顺驰电缆有限公司 Acrylic acid waterproof coating
CN104893440A (en) * 2015-04-29 2015-09-09 安徽嘉木橡塑工业有限公司 Acrylic acid waterproof material preparation process

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Application publication date: 20160413