CN105435723A - Toilet soap containing pomegranate polyphenol microcapsule and preparation method of pomegranate polyphenol microcapsule - Google Patents
Toilet soap containing pomegranate polyphenol microcapsule and preparation method of pomegranate polyphenol microcapsule Download PDFInfo
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- CN105435723A CN105435723A CN201510832613.6A CN201510832613A CN105435723A CN 105435723 A CN105435723 A CN 105435723A CN 201510832613 A CN201510832613 A CN 201510832613A CN 105435723 A CN105435723 A CN 105435723A
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- polyphenol
- punica granatum
- microcapsules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses toilet soap containing a pomegranate polyphenol microcapsule and a preparation method of the pomegranate polyphenol microcapsule and relates to the technical fields of extraction of active substances in agricultural product processing waste and application of the active substances in daily chemical products. An EC (ethyl cellulose) material is adopted as an embedding material for preparation of the pomegranate polyphenol microcapsule, the biological activity of the pomegranate polyphenol microcapsule is effectively protected, oxygenolysis is avoided, and the pomegranate polyphenol storage period is greatly prolonged. The prepared toilet soap containing the pomegranate polyphenol microcapsule has mild performance and a little skin irritation, and pomegranate polyphenol in the pomegranate polyphenol microcapsule can have effects of antibacterial performance, antioxidant and the like.
Description
Technical field
The present invention relates to the extraction of active material in processing of farm products discarded object and the applied technical field in cosmetics of everyday use, more specifically, relate to a kind of pomegranate pomace and prepare the method for Punica granatum L. polyphenol microcapsules and the application on perfumed soap.
Background technology
Pomegranate is subject to liking of people with its abundant nutritive value and good health care, the market demand of its converted products particularly juice of my pomegranate is very large, by Mechanized Processing mode, 1 ton of pomegranate can be squeezed out fruit juice about 300L, but the byproduct (pomegranate pomace) of its processing fails to be utilized effectively, usually as ox feed or the garbage disposal of low value.
Research shows, pomegranate pomace contains abundant Punica granatum L. polyphenol, Punica granatum L. polyphenol is the general name that a class has polyphenol hydroxyl compound, comprises the multiple compounds such as Ellagitannins, nutgall tannin, ellagic acid, gallic acid, catechin, anthocyanidin, chlorogenic acid and forulic acid.Many experiments show, Punica granatum L. polyphenol has many-sided biologically active; Comprise antioxidation; Anti-aging effects; Anti-cancer and cancer-preventing effect; Study of anti-atherogenic effect; To Shigella shigae, Escherichia coli and staphylococcus aureus, gonococcus and genital herpes virus inhibitory action; T suppression cell inner virus is bred; Direct kill virus and prevention virus absorption onto cell; Hypotensive and effect such as prevention cardiovascular and cerebrovascular disease etc.
The extracting method of polyphenol substance generally has hot water extraction method, solvent extraction method, diluted alkaline alcohol or alkaline water extraction method, ultrasonic extraction, microwave loss mechanisms and supercritical CO
2extraction method.Solvent method utilizes polyphenol substance easily molten or water soluble, methyl alcohol, ethanol, acetone etc., Punica granatum L. polyphenol material directly can be extracted from extract.The recovery rate of the method is relatively high, is convenient to purify, refine and carry out comprehensive study, and therefore solvent method is a kind of effective Punica granatum L. polyphenol extracting method, and wherein alcohol extract products obtained therefrom is nontoxic, pollution-free, safer.
The phenolic hydroxyl group activity that polyphenols contains due to its molecule is very strong, easily (high temperature, moisture and illumination etc.) affected by environment, be oxidized, be polymerized and the reaction such as condensation loses its biologic applications such as anti-oxidant, antibacterial, the polyphenol of the solid powdery also easy moisture absorption simultaneously, these shortcomings and problem limit and have impact on the application of polyphenols.
Microcapsules refer to that one has polymeric shell wall and miniature vessel or packing material, are by solid, liquid or gas entrapment, seal up for safekeeping in a kind of microencapsulation, its content controlled release under given conditions.Ethyl cellulose (EC) material, as embedded material, has the series of advantages such as intensity is high, chemical stability good, anti-decomposability strong, nontoxic to organism, cheap.A lot of experiment shows that ethyl cellulose prepares microcapsules, and can play good protective effect (prevent its oxidation or decompose) to its content, its content also can better be discharged in aqueous simultaneously.
The active material that juice of my pomegranate, granatum and pomegranate seed are extracted adds in cosmetics of everyday use by existing a lot of research now, the perfumed soap with physiologically active, hand cleanser, facial mask and mildy wash etc. are prepared, but the character such as oxidizable Sum decomposition due to Punica granatum L. polyphenol limits its application, utilize ethyl cellulose by Punica granatum L. polyphenol microencapsulation at present, have not been reported for the preparation of perfumed soap.
Summary of the invention
The invention provides a kind of Punica granatum L. polyphenol microcapsules preparation method and with a kind of preparation method of the microcapsules perfumed soap prepared containing the method.
A preparation method for Punica granatum L. polyphenol microcapsules, carries out according to following step:
(1) ethyl cellulose being dissolved in cyclohexane solvent (mass volume ratio is 10 ~ 25mg/mL), in flask, heating stirring and refluxing to all dissolving;
(2) get Punica granatum L. polyphenol powder and slowly add ethyl cellulose solution (mass volume ratio is 75 ~ 150mg/mL), constant temperature rapid stirring (300 ~ 700rpm) 15 ~ 30min at 50 ~ 70 DEG C, then slow cooling is to room temperature, ethyl cellulose solubility is declined and with Punica granatum L. polyphenol subparticle for core cohesion is separated out, forms ethyl cellulose Punica granatum L. polyphenol microcapsules;
(3) pour out product, suction filtration, deionized water drip washing, vacuum drying 24h, obtains Punica granatum L. polyphenol microscapsule powder.
In such scheme, Punica granatum L. polyphenol can derive from the extract of water, ethanol or the ethanol water of each component of pomegranate (as granatum, pomegranate seed, juice of my pomegranate).
Containing a microcapsules perfumed soap prepared by said method, the raw material containing following weight parts:
Punica granatum L. polyphenol microcapsules 0.25 ~ 2.5 part,
Natural soap base 65 ~ 80 parts,
18 ~ 23.75 parts, water,
Cocamidopropyl propyl amide amine oxide 0 ~ 5 part,
N-laurel acyl amino acid sodium 0 ~ 5 part,
Chelating agent 0 ~ 1 part.
Described natural soap base for any one in olive oil soap base, soybean oil soap base, peanut oil soap base and corn oil soap base or wherein severally can to mix.
Described chelating agent can be disodium ethylene diamine tetraacetate (EDETATE SODIUM), MDGA trisodium (NTA trisodium) and hydroxyethyl diamine tetraacethyl trisodium salt (HEDTA trisodium) one or more compositions wherein, and preferred sequestrant component is NTA trisodium.
In addition, in the present invention, can also with reference to the composition in conventional toilet soaps, a small amount of interpolation (0.02 ~ 1 weight portion) other functional components, as antioxidant, antiseptic, pigment, essence and brightening agent etc., to strengthen the performance of perfumed soap.
A preparation method containing microcapsules perfumed soap prepared by said method, carries out according to following step:
(1) mediate: the raw material taking said components in proportion joins soapmaking kneader, and kneading stirs.
(2) grind: the material after kneading is stirred enters grinding mill, carries out process of milling.
(3) press strip: after the process that makes to mill, soap body enters vacuum plodder, carries out press strip process shaping.
The present invention passes through Punica granatum L. polyphenol microencapsulation, effectively maintain the biologically active of polyphenol, solve polyphenol easily to lump in the application, be oxidized and the shortcoming of poor stability, the ethyl cellulose wall material used has the series of advantages such as intensity is high, chemical stability good, anti-decomposability strong, nontoxic to organism, cheap, and obtained microcapsules easily make content Punica granatum L. polyphenol effectively be discharged in water environment.Punica granatum L. polyphenol perfumed soap performance prepared by the present invention is gentle, little to skin irritatin, and its Punica granatum L. polyphenol contained more can play the effects such as antibacterial, antioxidant.
Below by embodiment, technical scheme of the present invention is described in further detail.
Detailed description of the invention
Term used in the present invention, unless otherwise specified, generally has the implication that those of ordinary skill in the art understand usually.Below in conjunction with specific embodiment, and comparable data describes the present invention in further detail.Should be understood that these embodiments are just further described the present invention, can not be interpreted as limiting the scope of the present invention, the technician in this field can make some nonessential improvement and adjustment according to the content of foregoing invention to the present invention.
Below in an example, the various process do not described in detail and method are conventional methods as known in the art.Source, the trade name of agents useful for same and be necessary to list its constituent person, all indicate when occurring first, identical reagent used if no special instructions thereafter, all identical with the content indicated first.
Embodiment 1: the extracting method of Punica granatum L. polyphenol:
(1) pulverized by the pomegranate pomace of drying, cross 20 mesh sieves, adding weight is its water of 50 times, 25 DEG C, stir 30min under 600rpm;
(2) the centrifugal 20min of 5000rpm, gets supernatant;
(3) by supernatant through molecular cut off be the ultrafiltration membrance filter of 10kDa, collect filtered solution;
(4) by filtered solution spraying dry, i.e. obtained Punica granatum L. polyphenol.
Embodiment 2: the extracting method of Punica granatum L. polyphenol:
(1) by pomegranate pomace crushed after being dried, cross 20 mesh sieves, adding weight is its 20%(volume ratio of 50 times) ethanol water, 40 DEG C, stir 20min under 600rpm;
(2) the centrifugal 20min of 5000rpm, gets supernatant;
(3) by supernatant through molecular cut off be the ultrafiltration membrance filter of 10kDa, collect filtered solution;
(4) 40 DEG C of low-pressure distillations be concentrated into that volume is original volume 1/2;
(5) by concentrate spraying dry, i.e. obtained Punica granatum L. polyphenol.
Embodiment 3: prepared by Punica granatum L. polyphenol microcapsules:
(1) ethyl cellulose being dissolved in cyclohexane solvent (mass volume ratio is 10mg/mL), in flask, heating stirring and refluxing to all dissolving;
(2) get Punica granatum L. polyphenol powder and slowly add ethyl cellulose solution (mass volume ratio is 75mg/mL), constant temperature rapid stirring (700rpm) 15min at 50 DEG C, then slow cooling is to room temperature, ethyl cellulose solubility is declined and with Punica granatum L. polyphenol subparticle for core cohesion is separated out, forms ethyl cellulose Punica granatum L. polyphenol microcapsules;
(3) pour out product, suction filtration, deionized water drip washing, vacuum drying 24h, obtains microscapsule powder.
Embodiment 4: prepared by Punica granatum L. polyphenol microcapsules:
(1) ethyl cellulose being dissolved in cyclohexane solvent (mass volume ratio is 25mg/mL), in flask, heating stirring and refluxing to all dissolving;
(2) get Punica granatum L. polyphenol powder and slowly add ethyl cellulose solution (mass volume ratio is 150mg/mL), constant temperature rapid stirring (300rpm) 30min at 70 DEG C, then slow cooling is to room temperature, ethyl cellulose solubility is declined and with Punica granatum L. polyphenol subparticle for core cohesion is separated out, forms ethyl cellulose Punica granatum L. polyphenol microcapsules;
(3) pour out product, suction filtration, deionized water drip washing, vacuum drying 24h, obtains microscapsule powder.
Embodiment 5 ~ 8: the preparation of Punica granatum L. polyphenol microcapsules perfumed soap:
(1) raw material is taken: take Punica granatum L. polyphenol microcapsules, soap base, water, cocamidopropyl propyl amide amine oxide, N-laurel acyl amino acid sodium and chelating agent NTA trisodium with reference to table one.
(2) mediate: the raw material taking said components in proportion joins soapmaking kneader, and kneading stirs.
(3) grind: the material after kneading is stirred enters grinding mill, carries out process of milling.
(4) press strip: after the process that makes to mill, soap body enters vacuum plodder, carries out press strip process shaping.
Table one Punica granatum L. polyphenol microcapsules perfumed soap composition (unit: part)
| Composition | Punica granatum L. polyphenol microcapsules | Soap base | Water | Cocamidopropyl propyl amide amine oxide | N-laurel acyl amino acid sodium | NTA trisodium |
| Embodiment 5 | 2.5 | 80(soybean oil soap base) | 17.5 | 0 | 0 | 0 |
| Embodiment 6 | 0.25 | 65(olive oil soap base) | 23.75 | 5 | 5 | 1 |
| Embodiment 7 | 0.5 | 78(peanut oil soap base) | 18 | 2 | 1 | 0.5 3 --> |
| Embodiment 8 | 1 | 70(corn oil soap base) | 23 | 2.5 | 2.5 | 1 |
Claims (7)
1. a preparation method for Punica granatum L. polyphenol microcapsules, is characterized in that carrying out according to following step:
(1) ethyl cellulose being dissolved in cyclohexane solvent (mass volume ratio is 10 ~ 25mg/mL), in flask, heating stirring and refluxing to all dissolving;
(2) get Punica granatum L. polyphenol powder and slowly add ethyl cellulose solution (mass volume ratio is 75 ~ 150mg/mL), constant temperature rapid stirring (300 ~ 700rpm) 15 ~ 30min at 50 ~ 70 DEG C, then slow cooling is to room temperature, ethyl cellulose solubility is declined and with Punica granatum L. polyphenol subparticle for core cohesion is separated out, forms ethyl cellulose Punica granatum L. polyphenol microcapsules;
(3) pour out product, suction filtration, deionized water drip washing, vacuum drying 24h, obtains Punica granatum L. polyphenol microscapsule powder.
2. the preparation method of a kind of Punica granatum L. polyphenol microcapsules according to claim 1, is characterized in that Punica granatum L. polyphenol can derive from the extract of water, ethanol or the ethanol water of each component of pomegranate (as granatum, pomegranate seed, juice of my pomegranate).
3. the microcapsules perfumed soap containing a kind of Punica granatum L. polyphenol microcapsules according to claim 1, the raw material containing following weight parts:
Punica granatum L. polyphenol microcapsules 0.25 ~ 2.5 part,
Natural soap base 65 ~ 80 parts,
18 ~ 23.75 parts, water,
Cocamidopropyl propyl amide amine oxide 0 ~ 5 part,
N-laurel acyl amino acid sodium 0 ~ 5 part,
Chelating agent 0 ~ 1 part.
4. the microcapsules perfumed soap of a kind of Punica granatum L. polyphenol microcapsules according to claim 3, is characterized in that described natural soap base for any one in olive oil soap base, soybean oil soap base, peanut oil soap base and corn oil soap base or wherein severally can to mix.
5. the microcapsules perfumed soap of a kind of Punica granatum L. polyphenol microcapsules according to claim 3, it is characterized in that described chelating agent can be disodium ethylene diamine tetraacetate (EDETATE SODIUM), MDGA trisodium (NTA trisodium) and hydroxyethyl diamine tetraacethyl trisodium salt (HEDTA trisodium) one or more compositions wherein, preferred sequestrant component is NTA trisodium.
6. the microcapsules perfumed soap of a kind of Punica granatum L. polyphenol microcapsules according to claim 3, it is characterized in that with reference to the composition in conventional toilet soaps, a small amount of interpolation (0.02 ~ 1 weight portion) other functional components, as antioxidant, antiseptic, pigment, essence and brightening agent etc., to strengthen the performance of perfumed soap.
7. the preparation method of the microcapsules perfumed soap of a kind of Punica granatum L. polyphenol microcapsules according to claim 3, is characterized in that carrying out according to following step:
(1) mediate: the raw material taking said components in proportion joins soapmaking kneader, and kneading stirs;
(2) grind: the material after kneading is stirred enters grinding mill, carries out process of milling;
(3) press strip: after the process that makes to mill, soap body enters vacuum plodder, carries out press strip process shaping.
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| CN201510832613.6A CN105435723A (en) | 2015-11-26 | 2015-11-26 | Toilet soap containing pomegranate polyphenol microcapsule and preparation method of pomegranate polyphenol microcapsule |
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| CN201510832613.6A CN105435723A (en) | 2015-11-26 | 2015-11-26 | Toilet soap containing pomegranate polyphenol microcapsule and preparation method of pomegranate polyphenol microcapsule |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109620773A (en) * | 2019-01-10 | 2019-04-16 | 澳宝化妆品（惠州）有限公司 | A kind of hair-washing composition of the berry extract containing pomegranate |
| CN110663857A (en) * | 2019-09-25 | 2020-01-10 | 浙江清华长三角研究院 | Green radish flavor dietary fiber effervescent powder and preparation method thereof |
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| CN101428069A (en) * | 2008-12-08 | 2009-05-13 | 广东省农业科学院蚕业与农产品加工研究所 | Process for producing mulberry leaf polyphenol, microcapsule and uses thereof |
| WO2009107861A1 (en) * | 2008-02-29 | 2009-09-03 | 株式会社スリーボンド | Microcapsule and microcapsule-containing curable resin composition |
| CN102940598A (en) * | 2012-12-05 | 2013-02-27 | 大连创达技术交易市场有限公司 | Pomegranate face cream |
| CN104694292A (en) * | 2013-12-09 | 2015-06-10 | 霍兆健 | Purely-natural plant soap |
| CN104940294A (en) * | 2015-06-16 | 2015-09-30 | 青岛博恩高科生物技术有限公司 | Preparation method for punicosides, and method for preparing punicosides microcapsule containing punicosides, prepared according to preparation method, and microcapsule |
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2015
- 2015-11-26 CN CN201510832613.6A patent/CN105435723A/en active Pending
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| WO2009107861A1 (en) * | 2008-02-29 | 2009-09-03 | 株式会社スリーボンド | Microcapsule and microcapsule-containing curable resin composition |
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| CN102940598A (en) * | 2012-12-05 | 2013-02-27 | 大连创达技术交易市场有限公司 | Pomegranate face cream |
| CN104694292A (en) * | 2013-12-09 | 2015-06-10 | 霍兆健 | Purely-natural plant soap |
| CN104940294A (en) * | 2015-06-16 | 2015-09-30 | 青岛博恩高科生物技术有限公司 | Preparation method for punicosides, and method for preparing punicosides microcapsule containing punicosides, prepared according to preparation method, and microcapsule |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109620773A (en) * | 2019-01-10 | 2019-04-16 | 澳宝化妆品（惠州）有限公司 | A kind of hair-washing composition of the berry extract containing pomegranate |
| CN109620773B (en) * | 2019-01-10 | 2021-05-28 | 澳宝化妆品（惠州）有限公司 | Shampoo composition containing pomegranate fruit extract |
| CN110663857A (en) * | 2019-09-25 | 2020-01-10 | 浙江清华长三角研究院 | Green radish flavor dietary fiber effervescent powder and preparation method thereof |
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Application publication date: 20160330 |