CN105421113B - A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice - Google Patents
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice Download PDFInfo
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- CN105421113B CN105421113B CN201510992623.6A CN201510992623A CN105421113B CN 105421113 B CN105421113 B CN 105421113B CN 201510992623 A CN201510992623 A CN 201510992623A CN 105421113 B CN105421113 B CN 105421113B
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- skin
- mangosteen
- dyestuff
- animal skin
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- 240000006053 Garcinia mangostana Species 0.000 title claims abstract description 92
- 235000017048 Garcinia mangostana Nutrition 0.000 title claims abstract description 92
- 241001465754 Metazoa Species 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims abstract description 36
- 235000011389 fruit/vegetable juice Nutrition 0.000 title claims abstract description 35
- 239000000975 dye Substances 0.000 claims abstract description 80
- 239000000706 filtrate Substances 0.000 claims abstract description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000007639 printing Methods 0.000 claims abstract description 24
- 238000009288 screen filtration Methods 0.000 claims abstract description 22
- 239000000284 extract Substances 0.000 claims abstract description 17
- 238000000227 grinding Methods 0.000 claims abstract description 11
- 238000002791 soaking Methods 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 11
- 238000001291 vacuum drying Methods 0.000 claims abstract description 11
- 239000012141 concentrate Substances 0.000 claims abstract description 10
- 238000012545 processing Methods 0.000 claims description 33
- 238000006386 neutralization reaction Methods 0.000 claims description 32
- 239000002253 acid Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 235000018553 tannin Nutrition 0.000 claims description 15
- 229920001864 tannin Polymers 0.000 claims description 15
- 239000001648 tannin Substances 0.000 claims description 15
- 238000007598 dipping method Methods 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 8
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 5
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 239000000787 lecithin Substances 0.000 claims description 4
- 235000010445 lecithin Nutrition 0.000 claims description 4
- 229940067606 lecithin Drugs 0.000 claims description 4
- 241001070941 Castanea Species 0.000 claims description 3
- 235000014036 Castanea Nutrition 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- -1 neopelex Chemical compound 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010985 leather Substances 0.000 abstract description 30
- 238000004043 dyeing Methods 0.000 abstract description 27
- 230000008569 process Effects 0.000 abstract description 10
- 235000013311 vegetables Nutrition 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 240000007471 Garcinia livingstonei Species 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003292 glue Substances 0.000 description 7
- 244000025797 Castanea pumila Species 0.000 description 6
- 235000007763 Castanea pumila Nutrition 0.000 description 6
- 241000283707 Capra Species 0.000 description 5
- 102000008186 Collagen Human genes 0.000 description 4
- 108010035532 Collagen Proteins 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229920001436 collagen Polymers 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- BOGUPGVJPYQSQC-UHFFFAOYSA-N 2-hexadecyl-1h-pyrrole Chemical group CCCCCCCCCCCCCCCCC1=CC=CN1 BOGUPGVJPYQSQC-UHFFFAOYSA-N 0.000 description 1
- 241000546193 Clusiaceae Species 0.000 description 1
- 241000593508 Garcinia Species 0.000 description 1
- 235000000885 Garcinia xanthochymus Nutrition 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 230000004345 fruit ripening Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C15/00—Apparatus for chemical treatment or washing of hides, skins, or leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of technique using mangosteen skin juice printing and dyeing Animal Skin, comprise the following steps：A. mangosteen skin dyestuff extracts：Mangosteen skin is taken, then ultramicro grinding adds the alcohol that concentration is 80%, the volume of the alcohol and the mass ratio of mangosteen skin are 5 10:1,12 24h are impregnated, with the screen filtration of 80 100 mesh, collect filtrate；Then filter residue is used into identical soaking in alcohol, 12 24h, with the screen filtration of 80 100 mesh, collects filtrate；Merge the filtrate being collected into twice, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；B. dyestuff is prepared；C. Animal Skin is handled；D. dye；E. heat is steamed；F. final finishing.The dyeing and printing process of the present invention, adhesive force of the vegetable colour on leather can be lifted, cause the leather after printing and dyeing not fugitive color, fade.
Description
Technical field
The present invention relates to leather dyeing and printing process field, and in particular to a kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice.
Background technology
Printing and dyeing are also referred to as dyeing and finishing.Dye molecule is formed surely after being handled by physical and chemical process with cloth or leather base substrate
Surely combine.In dyeing process, common chemical synthetic dye can produce substantial amounts of pollution, and cloth or leather after dye transfer
On, can also there is the material of more multipair human health, be unfavorable for the health of human body.Therefore, people in dyeing process, send out
Natural dye is showed, predominantly vegetable colour is printed and dyed to cloth, leather etc., can either so reach preferably printing and dyeing effect
Fruit, also harmful substance can be avoided to remain in leather, cloth, be advantageous to the health of human body, while can also reduce and print and dye
The generation of pollutant in journey.But, it has to say, vegetable colour, the tack on leather is poor, is used after printing and dyeing
During, easily produce the situation faded, faded.
Mangosteen, original name：Mangosteen (scientific name：Garcinia mangostana L.) Guttiferae, Garcinia dungarunga, branch
More and intensive, interaction is to life, the significantly vertical lin bars of sprig tool.Blade heavy leather matter, having gloss, ellipse or ellipticity square are circular,
Top is short tapering, base portion wide wedge shape or subcircular, aubergine during fruit maturation, has yellowish-brown patch, smooth, originates in Ma Lugu,
Asia and African torrid areas are cultivated extensively；China Taiwan, Fujian, Guangdong and Yunnan are also introduced a fine variety or planted experimentally.For famous heat
Band fruit, can eat raw or preserved fruit processed.Wherein mangosteen skin contains abundant phytochrome, can be used for printing and dyeing；
Therefore, research how using mangosteen skin juice printing and dyeing Animal Skin seem necessary.
The content of the invention
It is an object of the invention to provide a kind of adhesive force that can lift vegetable colour on leather, cause after printing and dyeing
Leather not fugitive color, fade using mangosteen skin juice print and dye Animal Skin technique.
To solve the above problems, the technical solution adopted in the present invention is as follows：
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh,
Collect filtrate；Then filter residue is used into identical soaking in alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate；Close
And the filtrate being collected into twice, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：Mangosteen skin dyestuff 28-32 parts for being obtained by a steps,
Tannin extract 4-6 parts, color fixing agent 1.5-2.5 parts, surfactant 0.8-1.2 parts, sodium chloride 0.2-0.5 parts and water 40-60 parts；Will be upper
Each component mixing is stated, homogeneous stirring, obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and carries out neutralisation treatment 30-45min, per 5min
Improve pH value 0.4-0.6；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min；
F. final finishing：Animal Skin by step e processing is cleaned with clear water, shady place air-dries.
In the present invention, preferable scheme is that the tannin extract in the step b is chestnut extract.
In the present invention, preferable scheme is that the color fixing agent in step b is cetylpyridinium chloride, hexadecyl pyrrole
At least one of pyridine and crosslinking color fixing agent DE.
In the present invention, preferable scheme is that the surfactant in the b step is lecithin, DBSA
At least one of sodium, dioctyl succinate disulfonate acid, Tween-80.
In the present invention, preferable scheme also includes step d1. stamps between the Step d and step e：Using printing machine
Stamp processing is carried out to the Animal Skin by Step d processing, the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-
50%.
In the present invention, preferable scheme is carbonate, the phosphoric acid of alkali metal that the alkali that the step c uses is selected from alkali metal
Salt, sodium hydroxide and potassium hydroxide.
In the present invention, preferable scheme is that the clear water cleaning in the f steps is specially：Cleaned with clear water and pass through step e
The Animal Skin 30s of processing, clean 2-3 times.
In the present invention, preferable scheme is the technique of the Animal Skin of being printed and dyed using mangosteen skin juice, including following step
Suddenly：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filtrate；
Then filter residue is used into identical soaking in alcohol, 14h, with the screen filtration of 100 mesh, collects filtrate；Merge what is be collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
50 parts of 5 parts of glue, 2.3 parts of color fixing agent, 1.1 parts of surfactant, 0.3 part of sodium chloride and water；Above-mentioned each component is mixed, homogeneous stirs
Mix, obtain dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and carries out neutralisation treatment 40min, is carried per 5min
High ph-values 0.4；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 35 DEG C, 30min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 95 DEG C, pressure 1.2kg/cm2Steam under
Heat steams 60min；
F. final finishing：Animal Skin by step e processing is cleaned 2 times with clear water, shady place air-dries.
Compared with prior art, the invention has the advantages that：
1st, in dyeing and printing process of the invention, it is used as mordant by adding color fixing agent and containing the tannin extract of tannin, can
So that the ligand such as hydroxyl contained on phytochrome molecule, carboxyl and with Animal Skin on collagenous fibres molecule it is contained
Hydroxyl forms the multicomponent complex of complexity so that the active force between the collagenous fibres molecule on phytochrome and Animal Skin increases
Greatly, adhesive force of the vegetable colour on leather is lifted；
2nd, by neutralisation treatment, the free acid on leather is neutralized, strengthens collagenous fibres molecule and dyestuff in Animal Skin
Infiltration and combination so that dyeing be more uniformly distributed；In addition, in N-process, pH value is slowly lifted, can further open glue
Passage between fibrillation molecule so that phytochrome molecule can further penetrate into depths and the collagen fibre of animal's leather
Tie up molecule and form multicomponent complex, further lift adhesive force of the vegetable colour on leather；
3rd, after dyeing, hot steaming processing is carried out, can speed up the motion of leather surface phytochrome molecule, and by collagen
Gap is further opened between fiber so that phytochrome molecule enters the higher depth of leather so that the phytochrome of leather surface
Molecule is less, and the fixation ability of leather is stronger.
With reference to embodiment, the present invention is described in detail.
Embodiment
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh,
Collect filtrate；Then filter residue is used into identical soaking in alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate；Close
And the filtrate being collected into twice, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：Mangosteen skin dyestuff 28-32 parts for being obtained by a steps,
Tannin extract 4-6 parts, color fixing agent 1.5-2.5 parts, surfactant 0.8-1.2 parts, sodium chloride 0.2-0.5 parts and water 40-60 parts；Will be upper
Each component mixing is stated, homogeneous stirring, obtains dyestuff；
Tannin extract in the step, the general name of a kind of complicated native compound.It is also non-wherein in addition to main component tannin
Tannin and insoluble matter, including but not limited to chestnut extract, oak tannin extract and larch bark tannin extract；Color fixing agent in the step,
Can be the color fixing agent of field of printing and dyeing, including but not limited to cetylpyridinium chloride and brocide and crosslinking
Color fixing agent DE；Color fixing agent in the step, can be the surfactant of field of printing and dyeing, including but not limited to lecithin, ten
Dialkyl benzene sulfonic acids sodium, dioctyl succinate disulfonate acid and Tween-80；
The general adhesive force of phytochrome is relatively low, in dyeing and printing process of the invention, by adding color fixing agent and containing tannin
Tannin extract as mordant, enable to the ligands such as hydroxyl contained on phytochrome molecule, carboxyl and with Animal Skin
Contained hydroxyl forms the multicomponent complex of complexity on collagenous fibres molecule so that phytochrome and the collagenous fibres in Animal Skin
Active force increase between molecule, adhesive force of the lifting vegetable colour on leather；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and carries out neutralisation treatment 30-45min, per 5min
Improve pH value 0.4-0.6；
Alkali in the step, can be highly basic, weak base or salt of weak acid, the including but not limited to carbonate of alkali metal, alkali
Phosphate, sodium hydroxide and the potassium hydroxide of metal；Animal Skin in the present invention, can be various Animal Skins, including it is but unlimited
In pigskin, ox-hide, sheepskin and fur；
By neutralisation treatment, the free acid on leather is neutralized, strengthens collagenous fibres molecule in Animal Skin and dyestuff
Infiltration and combination so that dyeing is more uniformly distributed；In addition, in N-process, pH value is slowly lifted, can further open collagen
Passage between fiber molecule so that phytochrome molecule can further penetrate into depths and the collagenous fibres of animal's leather
Molecule forms multicomponent complex, further lifts adhesive force of the vegetable colour on leather；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min；
After dyeing, hot steaming processing is carried out, can speed up the motion of leather surface phytochrome molecule, and collagen is fine
Gap is further opened between dimension so that phytochrome molecule enters the higher depth of leather so that the phytochrome of leather surface point
Sub less, the fixation ability of leather is stronger；
F. final finishing：Animal Skin by step e processing is cleaned with clear water, shady place air-dries.
In the present invention, preferable scheme also includes step d1. stamps between the Step d and step e：Using printing machine
Stamp processing is carried out to the Animal Skin by Step d processing, the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-
50%.Using said temperature and the stamp processing environment of humidity range, enable to printing quality more preferable.
In the present invention, preferable scheme is that the clear water cleaning in the f steps is specially：Cleaned with clear water and pass through step e
The Animal Skin 30s of processing, clean 2-3 times.
Embodiment 1
Using the technique of mangosteen skin juice printing and dyeing Animal Skin, comprise the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filtrate；
Then filter residue is used into identical soaking in alcohol, 14h, with the screen filtration of 100 mesh, collects filtrate；Merge what is be collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
50 parts of 5 parts of glue, 2.3 parts of cetylpyridinium chloride, 1.1 parts of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and water；Will be upper
Each component mixing is stated, homogeneous stirring, obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and carries out neutralisation treatment 40min, is carried per 5min
High ph-values 0.4；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 35 DEG C, 30min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 95 DEG C, pressure 1.2kg/cm2Steam under
Heat steams 60min；
F. final finishing：Animal Skin by step e processing is cleaned 2 times with clear water, each 30s, shady place air-dries.
Embodiment 2
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 5:1,12h is impregnated, with the screen filtration of 80 mesh, collects filtrate；So
Filter residue is used into identical soaking in alcohol afterwards, 12h, with the screen filtration of 80 mesh, collects filtrate；Merge the filter being collected into twice
Liquid, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：28 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
40 parts of 4 parts of glue, 1.5 parts of brocide, 0.8 part of lecithin, 0.2 part of sodium chloride and water；Above-mentioned each component is mixed,
Homogeneous stirs, and obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5；Neutralisation treatment is specially：Saleratus is added in the acid solution of dipping and carries out neutralisation treatment 30min, is carried per 5min
High ph-values 0.6；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 30 DEG C, 35min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 80 DEG C, pressure 0.5kg/cm2Steam under
Heat steams 90min；
F. final finishing：Animal Skin by step e processing is cleaned 3 times with clear water, each 30s, shady place air-dries.
Embodiment 3
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 10:1,24h is impregnated, with the screen filtration of 100 mesh, collects filtrate；
Then filter residue is used into identical soaking in alcohol, 24h, with the screen filtration of 100 mesh, collects filtrate；Merge what is be collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：32 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
60 parts of 6 parts of glue, 2.5 parts of crosslinking color fixing agent DE, 1.2 parts of dioctyl succinate disulfonate acid, 0.5 part of sodium chloride and water；Will be above-mentioned each
Component mixes, and homogeneous stirring, obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and carries out neutralisation treatment 45min, pH value is improved per 5min
0.42；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 40 DEG C, 25min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 120 DEG C, pressure 1.5kg/cm2Steam under
Heat steams 90min；
F. final finishing：Animal Skin by step e processing is cleaned 3 times with clear water, each 30s, shady place air-dries.
Embodiment 4
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 8:1,18h is impregnated, with the screen filtration of 95 mesh, collects filtrate；So
Filter residue is used into identical soaking in alcohol afterwards, 20h, with the screen filtration of 100 mesh, collects filtrate；Merge the filter being collected into twice
Liquid, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：31 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
55 parts of 6 parts of glue, 2.3 parts of cetylpyridinium chloride, 1.1 parts of Tween-80,0.4 part of sodium chloride and water；Above-mentioned each component is mixed
Close, homogeneous stirring, obtain dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2；Neutralisation treatment is specially：Potassium phosphate is added in the acid solution of dipping and carries out neutralisation treatment 40min, pH is improved per 5min
Value 0.45；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 38 DEG C, 30min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 100 DEG C, pressure 0.8kg/cm2Steam under
Heat steams 80min；
F. final finishing：Animal Skin by step e processing is cleaned with clear water, shady place air-dries.
Embodiment 5
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, is comprised the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of mangosteen skin are 9:1,20h is impregnated, with the screen filtration of 100 mesh, collects filtrate；
Then filter residue is used into identical soaking in alcohol, 18h, with the screen filtration of 100 mesh, collects filtrate；Merge what is be collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：31 parts of mangosteen skin dyestuff being obtained by a steps, evergreen chinquapin
53 parts of 5.5 parts of glue, 2.2 parts of brocide, 0.9 part of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and water；Will
Above-mentioned each component mixing, homogeneous stirring, obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2.1；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and carries out neutralisation treatment 35min, pH value is improved per 5min
0.6；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 37 DEG C, 30min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 110 DEG C, pressure 1.3kg/cm2Steam under
Heat steams 45min；
F. final finishing：Animal Skin by step e processing is cleaned with clear water, shady place air-dries.
Comparative example 1
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, does not include step c and step e as different from Example 1,
Remaining is same as Example 1.
Comparative example 2
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, does not include step c, remaining is equal as different from Example 1
It is same as Example 1.
Comparative example 3
A kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, does not include step e, remaining is equal as different from Example 1
It is same as Example 1.
Experimental example
8 blocks of goat skins are taken, carry out printing and dyeing processing, Ran Houcong by embodiment 1-5, comparative example 1-3 dyeing and printing process respectively
The skin bit of 1 piece of 5cm × 5cm size is cut on goat skin after every piece of printing and dyeing, carries out extraction experiments of stripping, extract selects 25%
Pyridine solution, above-mentioned skin bit is respectively placed in 50mL flask, 10mL extracts is added, is then heated to 60 DEG C, it is permanent
Warm 25min, is pulled out, cleaning, is dried, and observes situation of stripping；Concrete outcome refers to table 1 below：
Table 1：Stripped situation table by the extraction of stripping of embodiment 1-5, comparative example the 1-3 goat skin handled
| Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Strip situation | Very small amount is stripped | Very small amount is stripped | Very small amount is stripped | Very small amount is stripped |
| Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Strip situation | Very small amount is stripped | Largely strip | Largely strip | Strip on a small quantity |
Using above-mentioned goat skin, aforesaid operations are repeated after drying, observes and records required warp of being stripped completely on leather
The number for extraction experiments of stripping is crossed, specific data refer to table 2 below：
Table 2：Stripped completely data logger by embodiment 1-5, comparative example the 1-3 goat skin handled
| Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Number of processes | 8th time | 6th time | 7th time | The 5th |
| Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Number of processes | The 4th | 2nd time | 2nd time | 3rd time |
The dyeing and printing process of the present invention, can be substantially improved vegetable colour in leather it can be seen from the data in upper table 1-2
On adhesive ability so that the leather after printing and dyeing are handled does not allow the situation for being also easy to produce colour fading, fading.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (8)
1. a kind of technique for Animal Skin of being printed and dyed using mangosteen skin juice, it is characterised in that comprise the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the alcohol that concentration is 80%, institute
The mass ratio of the volume and mangosteen skin of stating alcohol is 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh, collects filter
Liquid；Then filter residue is used into identical soaking in alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate；Merge twice
The filtrate being collected into, concentrate, vacuum drying, obtain solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：Mangosteen skin dyestuff 28-32 parts for being obtained by a steps, tannin extract
4-6 parts, color fixing agent 1.5-2.5 parts, surfactant 0.8-1.2 parts, sodium chloride 0.2-0.5 parts and water 40-60 parts；Will be above-mentioned each
Component mixes, and homogeneous stirring, obtains dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
For 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and carries out neutralisation treatment 30-45min, is improved per 5min
PH value 0.4-0.6；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2Steam
Lower heat steams 30-90min；
F. final finishing：Animal Skin by step e processing is cleaned with clear water, shady place air-dries.
2. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that：In the step b
Tannin extract be chestnut extract.
3. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that：Consolidating in step b
Toner is at least one of cetylpyridinium chloride, brocide and crosslinking color fixing agent DE.
4. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that：In the b step
Surfactant be lecithin, neopelex, dioctyl succinate disulfonate acid, at least one of Tween-80.
5. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that the Step d and e
Also include step d1. stamps between step：Stamp processing, stamp are carried out to the Animal Skin by Step d processing using printing machine
The environment temperature of processing is 25-35 DEG C, humidity 35-50%.
6. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that：The step c is adopted
Alkali is selected from the carbonate of alkali metal, the phosphate of alkali metal, sodium hydroxide and potassium hydroxide.
7. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that in the f steps
Clear water cleans：The Animal Skin 30s handled by step e is cleaned with clear water, is cleaned 2-3 times.
8. the technique of Animal Skin according to claim 1 of being printed and dyed using mangosteen skin juice, it is characterised in that comprise the following steps：
A. prepared by mangosteen skin dyestuff：Mangosteen skin is taken, ultramicro grinding, obtains mangosteen skin juice, then adds the alcohol that concentration is 80%, institute
The mass ratio of the volume and mangosteen skin of stating alcohol is 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filtrate；Then will
Filter residue uses identical soaking in alcohol, 14h, with the screen filtration of 100 mesh, collects filtrate；Merge the filtrate being collected into twice, it is dense
Contracting, vacuum drying, obtains solid, i.e. mangosteen skin dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of mangosteen skin dyestuff, the tannin extract 5 obtained by a steps
Part, 2.3 parts of color fixing agent, 1.1 parts of surfactant, 0.3 part of sodium chloride and 50 parts of water；Above-mentioned each component is mixed, homogeneous stirring,
Obtain dyestuff；
C. Animal Skin is handled：Animal Skin after tanning of learning from else's experience processing carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
For 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and carries out neutralisation treatment 40min, pH is improved per 5min
Value 0.4；
D. dye：Animal Skin after step c is handled is immersed within 30s by dyestuff made from b step, 35
At a temperature of DEG C, 30min is impregnated；
E. heat is steamed：By the Animal Skin after Step d is handled temperature be 95 DEG C, pressure 1.2kg/cm2Steam under heat steam
60min；
F. final finishing：Animal Skin by step e processing is cleaned 2 times with clear water, shady place air-dries.
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