CN105507025B - A kind of technique using unusual fruit juice printing and dyeing Animal Skin - Google Patents
A kind of technique using unusual fruit juice printing and dyeing Animal Skin Download PDFInfo
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- CN105507025B CN105507025B CN201510992622.1A CN201510992622A CN105507025B CN 105507025 B CN105507025 B CN 105507025B CN 201510992622 A CN201510992622 A CN 201510992622A CN 105507025 B CN105507025 B CN 105507025B
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- animal skin
- dyestuff
- parts
- fruit juice
- dyeing
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- 241001465754 Metazoa Species 0.000 title claims abstract description 91
- 238000004043 dyeing Methods 0.000 title claims abstract description 48
- 238000007639 printing Methods 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 36
- 235000015203 fruit juice Nutrition 0.000 title claims abstract description 34
- 239000000975 dye Substances 0.000 claims abstract description 79
- 239000002253 acid Substances 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000000706 filtrate Substances 0.000 claims description 23
- 238000006386 neutralization reaction Methods 0.000 claims description 22
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 238000009288 screen filtration Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 235000018553 tannin Nutrition 0.000 claims description 15
- 229920001864 tannin Polymers 0.000 claims description 15
- 239000001648 tannin Substances 0.000 claims description 15
- 238000007598 dipping method Methods 0.000 claims description 11
- 239000012141 concentrate Substances 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 238000002791 soaking Methods 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 8
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims description 6
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 5
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 239000000787 lecithin Substances 0.000 claims description 4
- 235000010445 lecithin Nutrition 0.000 claims description 4
- 229940067606 lecithin Drugs 0.000 claims description 4
- 241001070941 Castanea Species 0.000 claims description 3
- 235000014036 Castanea Nutrition 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- -1 neopelex Chemical compound 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000010985 leather Substances 0.000 abstract description 29
- 235000013311 vegetables Nutrition 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003292 glue Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 235000007763 Castanea pumila Nutrition 0.000 description 6
- 244000025797 Castanea pumila Species 0.000 description 6
- 241000283707 Capra Species 0.000 description 5
- 102000008186 Collagen Human genes 0.000 description 4
- 108010035532 Collagen Proteins 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229920001436 collagen Polymers 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- BOGUPGVJPYQSQC-UHFFFAOYSA-N 2-hexadecyl-1h-pyrrole Chemical group CCCCCCCCCCCCCCCCC1=CC=CN1 BOGUPGVJPYQSQC-UHFFFAOYSA-N 0.000 description 1
- 244000298715 Actinidia chinensis Species 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- 102000008946 Fibrinogen Human genes 0.000 description 1
- 108010049003 Fibrinogen Proteins 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229940012952 fibrinogen Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/007—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated preparing dyes in situ
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of techniques using unusual fruit juice printing and dyeing Animal Skin, include the following steps：A. prepared by Chinese grooseberry dyestuff；B. dyestuff is prepared；C. Animal Skin is handled；D. dye；E. heat is steamed；F. final finishing.The dyeing and printing process of the present invention, can be promoted adhesive force of the vegetable colour on leather, so that leather after printing and dyeing not fugitive color, fade.
Description
Technical field
The present invention relates to leather dyeing and printing process fields, and in particular to a kind of technique using unusual fruit juice printing and dyeing Animal Skin.
Background technology
Printing and dyeing are also referred to as dyeing and finishing.Dye molecule is formed surely after being handled by physical and chemical process with cloth or leather green body
Surely combine.In dyeing process, common chemical synthetic dye can generate substantial amounts of pollution, and cloth or leather after dye transfer
On, can also there be the substance of more multipair human health, be unfavorable for the health of human body.For this purpose, people in dyeing process, send out
Natural dye is showed, predominantly vegetable colour prints and dyes to cloth, leather etc., can either so reach preferable printing and dyeing effect
Fruit also can avoid harmful substance from remaining in leather, cloth, be conducive to the health of human body, while can also reduce and print and dye
The generation of pollutant in journey.But, it has to it says, vegetable colour, the adhesion on leather is poor, is used after printing and dyeing
During, easily generate the situation faded, faded.
The content of the invention
It is an object of the invention to provide a kind of adhesive force that can promote vegetable colour on leather, so that after printing and dyeing
Leather not fugitive color, fade using unusual fruit juice printing and dyeing Animal Skin technique.
To solve the above problems, the technical solution adopted in the present invention is as follows：
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 5-10:1,12-24h is impregnated, with the sieve mistake of 80-100 mesh
Filtrate is collected in filter；Then by filter residue using identical soaking in alcohol, 12-24h with the screen filtration of 80-100 mesh, collects filter
Liquid；Merge the filtrate being collected into twice, concentrate, vacuum drying obtains solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：28-32 parts of Chinese grooseberry dyestuff being obtained by a steps,
40-60 parts of 4-6 parts of tannin extract, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and water；It will be upper
Each component mixes, and homogeneous stirring obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and is neutralized 30-45min, per 5min
Improve pH value 0.4-0.6；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min；
F. final finishing：It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
In the present invention, preferred scheme is that the tannin extract in the step b is chestnut extract.
In the present invention, preferred scheme is that the color fixing agent in step b is cetylpyridinium chloride, hexadecyl pyrrole
At least one of pyridine and crosslinking color fixing agent DE.
In the present invention, preferred scheme is that the surfactant in the b step is lecithin, dodecyl benzene sulfonic acid
At least one of sodium, dioctyl succinate disulfonate acid, Tween-80.
In the present invention, preferred scheme further includes step d1. stamps between the Step d and step e：Using printing machine
Stamp processing is carried out to the Animal Skin by Step d processing, the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-
50%.
In the present invention, preferred scheme is selected from carbonate, the phosphoric acid of alkali metal of alkali metal for the alkali that the step c uses
Salt, sodium hydroxide and potassium hydroxide.
In the present invention, preferred scheme is that the clear water cleaning in the f steps is specially：It is cleaned with clear water by step e
The Animal Skin 30s of processing is cleaned 2-3 times.
In the present invention, preferred scheme is the technique using unusual fruit juice printing and dyeing Animal Skin, including walking as follows
Suddenly：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filter
Liquid；Then by filter residue using identical soaking in alcohol, 14h with the screen filtration of 100 mesh, collects filtrate；Merging is collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
50 parts of 5 parts of glue, 2.3 parts of color fixing agent, 1.1 parts of surfactant, 0.3 part of sodium chloride and water；Upper each component is mixed, homogeneous stirs
It mixes, obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and is neutralized 40min, is carried per 5min
High ph-values 0.4；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 35 DEG C, 30min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 95 DEG C, pressure 1.2kg/cm2Steam under
Heat steams 60min；
F. final finishing：It will be cleaned 2 times with clear water by the Animal Skin of step e processing, shady place air-dries.
Compared with prior art, the invention has the advantages that：
1st, in dyeing and printing process of the invention, it is used as mordant by adding in color fixing agent and containing the tannin extract of tannin, it can
So that the ligands such as hydroxyl, carboxyl contained on phytochrome molecule and in Animal Skin on collagenous fibres molecule it is contained
Hydroxyl forms complicated multicomponent complex so that the active force between the collagenous fibres molecule on phytochrome and Animal Skin increases
Greatly, adhesive force of the vegetable colour on leather is promoted；
2nd, by neutralisation treatment, the free acid on leather is neutralized, enhances collagenous fibres molecule and dyestuff in Animal Skin
Infiltration and combination so that dyeing be more uniformly distributed；In addition, in N-process, pH value is slowly promoted, can further open glue
Passage between fibrinogen molecule so that phytochrome molecule can further penetrate into the depths of animal's leather and collagen fibre
It ties up molecule and forms multicomponent complex, further promote adhesive force of the vegetable colour on leather；
3rd, after dyeing, hot steaming processing is carried out, can speed up the movement of leather surface phytochrome molecule, and by collagen
Gap is further opened between fiber so that phytochrome molecule enters the higher depth of leather so that the phytochrome of leather surface
Molecule is less, and the fixation ability of leather is stronger.
The present invention is described in detail With reference to embodiment.
Specific embodiment
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 5-10:1,12-24h is impregnated, with the sieve mistake of 80-100 mesh
Filtrate is collected in filter；Then by filter residue using identical soaking in alcohol, 12-24h with the screen filtration of 80-100 mesh, collects filter
Liquid；Merge the filtrate being collected into twice, concentrate, vacuum drying obtains solid, i.e. Chinese grooseberry dyestuff；
Chinese grooseberry, also known as Kiwi berry, pulp are green, are that a kind of quality is fresh and tender, full of nutrition, the delicious fruit of flavor；
Wherein containing abundant phytochrome, can be used for printing and dyeing；
B. dyestuff is prepared：Take following component in parts by weight：28-32 parts of Chinese grooseberry dyestuff being obtained by a steps,
40-60 parts of 4-6 parts of tannin extract, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and water；It will be upper
Each component mixes, and homogeneous stirring obtains dyestuff；
Tannin extract in the step, the general name of a kind of complicated native compound.It is also non-wherein in addition to main component tannin
Tannin and insoluble matter include but not limited to chestnut extract, oak tannin extract and larch bark tannin extract；Color fixing agent in the step,
It can be the color fixing agent of field of printing and dyeing, include but not limited to cetylpyridinium chloride and brocide and crosslinking
Color fixing agent DE；Color fixing agent in the step can be the surfactant of field of printing and dyeing, include but not limited to lecithin, ten
Dialkyl benzene sulfonic acids sodium, dioctyl succinate disulfonate acid and Tween-80；
The general adhesive force of phytochrome is relatively low, in dyeing and printing process of the invention, by adding in color fixing agent and containing tannin
Tannin extract as mordant, enable to the ligands such as hydroxyl, carboxyl contained on phytochrome molecule and in Animal Skin
Contained hydroxyl forms complicated multicomponent complex on collagenous fibres molecule so that phytochrome and the collagenous fibres in Animal Skin
Active force increase between molecule, promotes adhesive force of the vegetable colour on leather；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and is neutralized 30-45min, per 5min
Improve pH value 0.4-0.6；
Alkali in the step can be highly basic, weak base or salt of weak acid, include but not limited to carbonate, the alkali of alkali metal
Phosphate, sodium hydroxide and the potassium hydroxide of metal；Animal Skin in the present invention, can be various Animal Skins, including but it is unlimited
In pigskin, ox-hide, sheepskin and fur；
By neutralisation treatment, the free acid on leather is neutralized, enhances collagenous fibres molecule in Animal Skin and dyestuff
Infiltration and combination so that dyeing is more uniformly distributed；In addition, in N-process, pH value is slowly promoted, can further open collagen
Passage between fiber molecule so that phytochrome molecule can further penetrate into depths and the collagenous fibres of animal's leather
Molecule forms multicomponent complex, further promotes adhesive force of the vegetable colour on leather；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min；
After dyeing, hot steaming processing is carried out, can speed up the movement of leather surface phytochrome molecule, and collagen is fine
Gap is further opened between dimension so that phytochrome molecule enters the higher depth of leather so that the phytochrome of leather surface point
Sub less, the fixation ability of leather is stronger；
F. final finishing：It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
In the present invention, preferred scheme further includes step d1. stamps between the Step d and step e：Using printing machine
Stamp processing is carried out to the Animal Skin by Step d processing, the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-
50%.Using the stamp processing environment of above-mentioned temperature and humidity scope, enable to printing quality more preferable.
In the present invention, preferred scheme is that the clear water cleaning in the f steps is specially：It is cleaned with clear water by step e
The Animal Skin 30s of processing is cleaned 2-3 times.
Embodiment 1
Using the technique of unusual fruit juice printing and dyeing Animal Skin, include the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filter
Liquid；Then by filter residue using identical soaking in alcohol, 14h with the screen filtration of 100 mesh, collects filtrate；Merging is collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
50 parts of 5 parts of glue, 2.3 parts of cetylpyridinium chloride, 1.1 parts of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and water；It will be upper
Each component mixes, and homogeneous stirring obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and is neutralized 40min, is carried per 5min
High ph-values 0.4；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 35 DEG C, 30min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 95 DEG C, pressure 1.2kg/cm2Steam under
Heat steams 60min；
F. final finishing：It will be cleaned 2 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 2
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 5:1,12h is impregnated, with the screen filtration of 80 mesh, collects filter
Liquid；Then by filter residue using identical soaking in alcohol, 12h with the screen filtration of 80 mesh, collects filtrate；Merging is collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：28 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
40 parts of 4 parts of glue, 1.5 parts of brocide, 0.8 part of lecithin, 0.2 part of sodium chloride and water；Upper each component is mixed,
Matter stirs, and obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5；Neutralisation treatment is specially：Saleratus is added in the acid solution of dipping and is neutralized 30min, is carried per 5min
High ph-values 0.6；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 30 DEG C, 35min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 80 DEG C, pressure 0.5kg/cm2Steam under
Heat steams 90min；
F. final finishing：It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 3
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 10:1, dipping for 24 hours, with the screen filtration of 100 mesh, is collected
Filtrate；Then filter residue for 24 hours, with the screen filtration of 100 mesh, is collected into filtrate using identical soaking in alcohol；Merging is collected twice
The filtrate arrived concentrates, and vacuum drying obtains solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：32 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
60 parts of 6 parts of glue, 2.5 parts of crosslinking color fixing agent DE, 1.2 parts of dioctyl succinate disulfonate acid, 0.5 part of sodium chloride and water；By upper each group
Divide mixing, homogeneous stirring obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and is neutralized 45min, pH value is improved per 5min
0.42；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 40 DEG C, 25min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 120 DEG C, pressure 1.5kg/cm2Steam under
Heat steams 90min；
F. final finishing：It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 4
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 8:1,18h is impregnated, with the screen filtration of 95 mesh, collects filter
Liquid；Then by filter residue using identical soaking in alcohol, 20h with the screen filtration of 100 mesh, collects filtrate；Merging is collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：31 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
55 parts of 6 parts of glue, 2.3 parts of cetylpyridinium chloride, 1.1 parts of Tween-80,0.4 part of sodium chloride and water；Upper each component is mixed,
Homogeneous stirs, and obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2；Neutralisation treatment is specially：Potassium phosphate is added in the acid solution of dipping and is neutralized 40min, pH is improved per 5min
Value 0.45；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 38 DEG C, 30min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 100 DEG C, pressure 0.8kg/cm2Steam under
Heat steams 80min；
F. final finishing：It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
Embodiment 5
A kind of technique using unusual fruit juice printing and dyeing Animal Skin includes the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, and it is 80% then to add in concentration
Alcohol, the volume of the alcohol and the mass ratio of Chinese grooseberry are 9:1,20h is impregnated, with the screen filtration of 100 mesh, collects filter
Liquid；Then by filter residue using identical soaking in alcohol, 18h with the screen filtration of 100 mesh, collects filtrate；Merging is collected into twice
Filtrate, concentrate, vacuum drying, obtain solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：31 parts of Chinese grooseberry dyestuff being obtained by a steps, evergreen chinquapin
53 parts of 5.5 parts of glue, 2.2 parts of brocide, 0.9 part of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and water；It will
Upper each component mixing, homogeneous stirring obtain dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2.1；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and is neutralized 35min, pH value is improved per 5min
0.6；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 37 DEG C, 30min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 110 DEG C, pressure 1.3kg/cm2Steam under
Heat steams 45min；
F. final finishing：It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
Comparative example 1
A kind of technique using unusual fruit juice printing and dyeing Animal Skin does not include step c and step e as different from Example 1,
Remaining is same as Example 1.
Comparative example 2
A kind of technique using unusual fruit juice printing and dyeing Animal Skin does not include step c as different from Example 1, remaining is
It is same as Example 1.
Comparative example 3
A kind of technique using unusual fruit juice printing and dyeing Animal Skin does not include step e as different from Example 1, remaining is
It is same as Example 1.
Experimental example
8 blocks of goat skins are taken, carry out printing and dyeing processing, Ran Houcong by the dyeing and printing process of embodiment 1-5, comparative example 1-3 respectively
The skin bit of 1 piece of 5cm × 5cm size is cut on goat skin after every piece of printing and dyeing, carries out extraction experiments of stripping, extract liquor selects 25%
Pyridine solution, above-mentioned skin bit is respectively placed in the flask of 50mL, 10mL extract liquors is added in, is then heated to 60 DEG C, it is permanent
Warm 25min, is pulled out, and cleaning is dried, and observes situation of stripping；Concrete outcome refers to the following table 1：
Table 1：It strips situation table by the extraction of stripping of embodiment 1-5, comparative example the 1-3 goat skin handled
| Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| It strips situation | Minute quantity is stripped | Minute quantity is stripped | Minute quantity is stripped | Minute quantity is stripped |
| Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| It strips situation | Minute quantity is stripped | Largely strip | It strips on a small quantity | It strips on a small quantity |
Using above-mentioned goat skin, aforesaid operations are repeated after drying, observe and record required warp of stripping completely on leather
The number for extraction experiments of stripping is crossed, specific data refer to the following table 2：
Table 2：It strips completely data record sheet by embodiment 1-5, comparative example the 1-3 goat skin handled
| Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Number of processes | 7 times | 5 times | 5 times | 4 times |
| Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Number of processes | 4 times | 2 times | 3 times | 3 times |
The dyeing and printing process of the present invention, can be substantially improved vegetable colour in leather it can be seen from the data in upper table 1-2
On adhesive ability so that by printing and dyeing, treated that leather does not allow the situation for being also easy to produce colour fading, fading.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (8)
1. a kind of technique using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that include the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, then adds in the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of Chinese grooseberry are 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh,
Collect filtrate；Then by filter residue using identical soaking in alcohol, 12-24h with the screen filtration of 80-100 mesh, collects filtrate；It closes
And the filtrate being collected into twice, it concentrates, vacuum drying obtains solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：28-32 parts of Chinese grooseberry dyestuff, the tannin extract obtained by a steps
40-60 parts of 4-6 parts, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and water；By upper each group
Divide mixing, homogeneous stirring obtains dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
For 1.5-2.5；Neutralisation treatment is specially：Alkali is added in the acid solution of dipping and is neutralized 30-45min, is improved per 5min
PH value 0.4-0.6；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2Steam
Lower heat steams 30-90min；
F. final finishing：It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
2. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that：In the step b
Tannin extract be chestnut extract.
3. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that：Consolidating in step b
Toner is at least one of cetylpyridinium chloride, brocide and crosslinking color fixing agent DE.
4. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that：In the b step
Surfactant be lecithin, neopelex, dioctyl succinate disulfonate acid, at least one of Tween-80.
5. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that the Step d and e
Step d1. stamps are further included between step：Stamp processing, stamp are carried out to the Animal Skin by Step d processing using printing machine
The environment temperature of processing is 25-35 DEG C, humidity 35-50%.
6. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that：The step c is adopted
Alkali is selected from the carbonate of alkali metal, the phosphate of alkali metal, sodium hydroxide and potassium hydroxide.
7. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that in the f steps
Clear water cleans：The Animal Skin 30s handled by step e is cleaned with clear water, is cleaned 2-3 times.
8. the technique according to claim 1 using unusual fruit juice printing and dyeing Animal Skin, it is characterised in that include the following steps：
A. prepared by Chinese grooseberry dyestuff：Chinese grooseberry pulp is taken, ultramicro grinding obtains unusual fruit juice, then adds in the wine that concentration is 80%
Essence, the volume of the alcohol and the mass ratio of Chinese grooseberry are 7:1,15h is impregnated, with the screen filtration of 100 mesh, collects filtrate；
Then by filter residue using identical soaking in alcohol, 14h with the screen filtration of 100 mesh, collects filtrate；Merge what is be collected into twice
Filtrate concentrates, and vacuum drying obtains solid, i.e. Chinese grooseberry dyestuff；
B. dyestuff is prepared：Take following component in parts by weight：30 parts of Chinese grooseberry dyestuff, the tannin extract 5 obtained by a steps
Part, 2.3 parts of color fixing agent, 1.1 parts of surfactant, 0.3 part of sodium chloride and 50 parts of water；Upper each component is mixed, homogeneous stirring obtains
To dyestuff；
C. Animal Skin is handled：Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
For 1.8；Neutralisation treatment is specially：Sodium acid carbonate is added in the acid solution of dipping and is neutralized 40min, pH is improved per 5min
Value 0.4；
D. dye：Step c will be passed through treated that Animal Skin is immersed within 30s by dyestuff made from b step, 35
At a temperature of DEG C, 30min is impregnated；
E. heat is steamed：To pass through Step d treated Animal Skin temperature be 95 DEG C, pressure 1.2kg/cm2Steam under heat steam
60min；
F. final finishing：It will be cleaned 2 times with clear water by the Animal Skin of step e processing, shady place air-dries.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101289811A (en) * | 2008-06-11 | 2008-10-22 | 李世绪 | Production process for dyeing patterns on pelt |
| CN102443660A (en) * | 2011-04-01 | 2012-05-09 | 李世绪 | Fur tanning-piercing and printing process |
| CN103556506A (en) * | 2013-10-31 | 2014-02-05 | 青铜峡市兴泰皮草有限责任公司 | Colorful Tibet sheepskin fur, suede and glaze leather integrated manufacturing technology |
| CN105088817A (en) * | 2015-08-19 | 2015-11-25 | 际华三五一二皮革服装有限公司 | Manufacturing method for dyeing and printing sheep wool comforter |
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2015
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101289811A (en) * | 2008-06-11 | 2008-10-22 | 李世绪 | Production process for dyeing patterns on pelt |
| CN102443660A (en) * | 2011-04-01 | 2012-05-09 | 李世绪 | Fur tanning-piercing and printing process |
| CN103556506A (en) * | 2013-10-31 | 2014-02-05 | 青铜峡市兴泰皮草有限责任公司 | Colorful Tibet sheepskin fur, suede and glaze leather integrated manufacturing technology |
| CN105088817A (en) * | 2015-08-19 | 2015-11-25 | 际华三五一二皮革服装有限公司 | Manufacturing method for dyeing and printing sheep wool comforter |
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