Background technology
At present, do not see being that the technology that the animal fur of representative carries out stamp really belongs to exception with sheep known for its fine thick wool skin, beaver rabbit skin.Wherein, the dyeing and printing process of fur forms the printing and dyeing flower naturally and has greatly improved the ornamental of fur owing to can on fur, print and dye specific color to form pattern in specific zone, has received the increasing attention of industry.The printing technology of fur comprises that pre-treatment, tanning penetrate, print and dye and spend three big steps.Tanning is carried out the chemical industry processing to rawhide exactly, makes rawhide be converted into bark.
Yet, since the printing and dyeing flower need be on fur specific region hair side printing and dyeing flower, how with dye liquor be limited in fur the specific region, make printing and dyeing flower liquid contact with fur, dissolve in, fixing, form printing and dyeing and spend, just become a difficult problem that perplexs industry.In addition, the purpose of common process for tanning is to have an effect through tanning agent and collagen, and the character of the dermatotome of fur is changed, and plate matter is not too soft, is not easy to dress.Yet this process for tanning does not consider that tanned dermatotome absorbs the poor ability of dye liquor, finally makes painted efficient not high.
Summary of the invention
In view of this, be necessary to provide a kind of fur tanning that can improve printing and dyeing flower efficient to penetrate technology and tanning fur thereof.
A kind of fur tanning penetrates technology; Be used for tanning and penetrate fur; Comprise pre-treatment, enzyme bating step; Comprise also successively that after the enzyme bating step plate matter penetrates and tanning step and comprehensive reduction step, this plate matter penetrate and the tanning step in add to the tanning agent of this fur and the aspartic protease that consumption is no more than the enzyme bating step, to improve the ability that dye liquor in the follow-up printing and dyeing flower process absorbs and penetrate dermatotome.
A kind of tanning fur; The tanning of this fur penetrates technology and comprises: pre-treatment, enzyme bating step; Comprise also successively that after the enzyme bating step plate matter penetrates and tanning step and comprehensive reduction step; This plate matter penetrate and the tanning step in add to the tanning agent of this fur and the aspartic protease that consumption is no more than the enzyme bating step, dye liquor absorbs the ability that penetrates dermatotome in the follow-up printing and dyeing flower process to improve.
Compared with prior art; Fur tanning of the present invention penetrates technology and penetrates and the tanning step through this plate matter; Use proteolytic enzyme and white tanning agent simultaneously, greatly improved the ability that owse decomposes interfibrillar substance in the dermatotome, make that the spacing of corium fabric increases in the dermatotome; Absorb dye liquor thereby improved dermatotome, and make dye liquor penetrate the ability of dermatotome.In follow-up dyeing and printing process; The ability that penetrates dermatotome owing to dye liquor is stronger; Pass through with the specific region; This just makes has considerable dye liquor to be limited on the specific region of dermatotome in the dyeing process, contacts with the specific region fur and carries out the painted time thereby effectively prolonged in the dyeing process dye liquor.Because the prolongation of dyeing time, dyeing efficient is able to promote naturally.
Embodiment
Do bright specifically through embodiment to the present invention below:
Embodiment one
The sheep known for its fine thick wool skin is carried out pre-treatment to present embodiment and tanning penetrates.Pretreatment process comprises that rawhide returns that aquatic foods, pelt board matter are fixed, pickling and four steps of green-shaving.Tanning penetrates that operation comprises enzyme bating, plate matter penetrates and tanning, comprehensively reduce three steps.Below respectively above-mentioned steps is described in detail:
1, rawhide returns aquatic foods.Rawhide is soaked as in the water 24 hours.Add enzyme-containing detergent afterwards and wash skin.Enzyme-containing detergent can improve the perviousness of the enzyme of hair matter, plate matter in the follow-up process for tanning and penetrate dynamics.
2, pelt board matter is fixed.30 sheep known for its fine thick wool skins are put into 140L underground water.Add 60.0-71.4g/L salt, the 65.0-85.7g/L Sodium sulfate anhydrous.min(99) transfers to 1.5-2.0 with pH value, 25 ℃-30 ℃ of constant temperature, and every separated 1h stirs once.Treatment time is 20 to 24 hours.This pelt board matter fixing step can strengthen the tensile strength of fur.For further improving pelt board matter fixed mass; Can also in the solution of pelt board matter fixing step, add salt, Sodium sulfate anhydrous.min(99) again, be 75g/L with the concentration adjustment of salt, is 90g/L with the concentration adjustment of Sodium sulfate anhydrous.min(99); Add 0.2ml/L sulfuric acid again, pH value is transferred to 1.5-2.0.38 ℃-40 ℃ of constant temperature, the treatment time is 12 to 24 hours.
3, green-shaving.In order to improve the ability that dye liquor penetrates fur, utilize water shovel machine that the plate matter of the fur after fixing through pelt board matter is carried out skiving, remove oil reservoir, the pachydermia portion of plate matter.The thickness of skiving doubles than traditional skiving thickness, and the thickness of pruning accounts for 10% to 20% of dermatotome total thickness.
4, enzyme bating.Fur behind the shaving is put into 140L underground water, and the adding model is 537 homemade aspartic protease 5U/mL, salt 35.7g/L, and Sodium sulfate anhydrous.min(99) 42.9g/L, sulfuric acid 1.9ml/L transfers to 3-3.5 with pH value, constant temperature 38-40 ℃.Treatment time is 12 to 24 hours.
5, plate matter penetrates and tanning.Fur after the enzyme bating processing is pulled out, put into 140L underground water, the adding model is 537 homemade aspartic protease 0.3-5U/mL; Model is the white tanning agent 2-4ml/L of PU-08; Soda ash 4.0-5.7g/L, salt 25.0-35.7g/L, Sodium sulfate anhydrous.min(99) 35.0-42.9g/L; PH value is transferred to 3-3.5, constant temperature 38-42 ℃.Treatment time is 44 to 48 hours.
6, comprehensive reduction.Fur after the tanning processing is pulled out, put into 140L underground water, 38 ℃ of constant temperature add 2.9g/L salt, the 3.6g/L Sodium sulfate anhydrous.min(99), and the 3.6g/L sulfate of ammoniac, 1.4g/L alum, 0.2ml/L sulfuric acid transfers to 3-3.5 with pH value.Treatment time is 12 to 24 hours.
After the comprehensive reduction, fur is pulled out, promptly accomplished whole tanning after drying, drying and penetrated technology, the operation of post-treatment such as the pattern that can be used to print and dye.
In the above-mentioned course of processing, this pelt board matter fixing step can improve the tensile strength or the elasticity of fur, thereby makes follow-up green-shaving step can compare the prior art more dermatotome of pruning, thereby improves the penetrativity of dye liquor.This plate matter penetrates and the tanning step is used aspartic protease and white tanning agent simultaneously; Make molecule in the solution, lake participate in reaction; Disintegration, decompose the grease fat system in the dermatotome, greatly improved the ability that owse decomposes interfibrillar substance in the dermatotome, make that the spacing of corium fabric increases in the dermatotome; Thereby improved dermatotome absorption dye liquor, and made dye liquor penetrate the ability of dermatotome.This plate matter penetrate and the tanning step in, the directly dye liquor absorption and penetrate the ability of dermatotome in the follow-up dyeing of influence of the consumption of this aspartic protease, the consumption of aspartic protease is many more, the spacing of corium fabric is just big more in the dermatotome; But, if the acidic protein enzyme dosage is too much, for example having surpassed the consumption in the enzyme bating step, defectives such as dermatotome, depilation then possibly be damaged.So in the present embodiment, the consumption of aspartic protease is the 6%-100% of the consumption in the enzyme bating step.
In follow-up printing and dyeing flower process; The ability that penetrates dermatotome owing to dye liquor is stronger; The dye liquor that contacts with the specific region fur will effectively be adsorbed on dermatotome that this fur links to each other on; And constantly to dermatotome infiltration, this just makes has considerable dye liquor to be limited on the specific region of dermatotome in the dyeing process, contacts with the specific region fur and prints and dyes the time spent thereby effectively prolonged in the printing and dyeing flower process dye liquor.Because the prolongation that printing and dyeing are taken time, dyeing efficient is able to promote naturally.
Understandable, the prescription of above-mentioned pre-treatment, enzyme bating and comprehensive reduction step and condition can also be selected other fur circle prescription or condition commonly used for use, and can not influence reaching of the object of the invention to the character of the fur of processing.This plate matter penetrate and the tanning step in can also select the aspartic protease of other models for use, wherein, the consumption of aspartic protease exceeds with the consumption that is no more than in the enzyme bating step.This plate matter penetrate and the tanning step in can also select other types for use tanning agent to replace white tanning agent, as long as this tanning agent can be accomplished the tanning to fur.
Obviously, those skilled in the art can carry out various changes and modification to the embodiment among the present invention and not break away from the spirit and scope of the present invention.Like this, if these in the embodiment of the invention are revised within the scope that belongs to claim of the present invention with modification and be equal to, then the embodiment among the present invention also is intended to comprise these changes and modification interior.