CN103789462A - Compound-enzyme soaking agent used for leather making - Google Patents
Compound-enzyme soaking agent used for leather making Download PDFInfo
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- CN103789462A CN103789462A CN201210431754.3A CN201210431754A CN103789462A CN 103789462 A CN103789462 A CN 103789462A CN 201210431754 A CN201210431754 A CN 201210431754A CN 103789462 A CN103789462 A CN 103789462A
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Abstract
The invention discloses a compound-enzyme soaking agent used for leather making. The compound-enzyme soaking agent comprises following components by weight: 1 part of a compound enzyme preparation, 1-5 parts of a surfactant, 2-10 parts of urea, 1-5 parts of a pH regulator and 10-50 parts of a diluent. The compound-enzyme soaking agent is capable of accelerating grease decomposition and water penetration, accelerating removal of interfibrillar substances, shortening the soaking time, largely reducing the using amount of sodium chloride and the using amount of the surfactant, and significantly reducing pollution of neutral salts in the soaking processes of leather making.
Description
Technical field
The present invention relates to leather chemicals technical field, particularly relate to a kind of process hides containing compound enzymic preparation immersion agent.
Background technology
In leather production, immersion is that first operation is also a critical process.Due to anticorrosion and preservation, there is dehydration to some extent in raw material skin.Its interfibrillar substance of raw material skin after dehydration shrinks, and collegen filament are bonded together, and this hinders the infiltration of water and chemical, thereby has influence on the quality of process hides processing.The abundant backwater of raw material skin, will be the infiltration of chemical and giving security of chemical reaction in subsequent manufacturing processes.Traditional process hides immersion process time is long, in order to accelerate immersion process, guarantees that whole skin evenly soaks, and conventionally need to add Soaking and promote immersion.The Soaking using in tradition process hides mostly is the materials such as acid, alkali, neutral salt, tensio-active agent, these Soakings exist interfibrillar substance and remove few, the defect that backwater is inhomogeneous, and the use of a large amount of acid, alkali, salt is also one of main source of the most unmanageable neutral salt pollution in leather-making waste water.
Summary of the invention
The technical problem that the present invention mainly solves is to provide the agent of soaking of a kind of process hides prozyme, in the immersion process of process hides, not only can accelerate the decomposition of grease, the infiltration of water, accelerate removing of interfibrillar substance, shorten soaking time, and greatly reduced the consumption of sodium-chlor, tensio-active agent, reduce significantly the pollution of neutral salt.
For solving the problems of the technologies described above, the technical solution used in the present invention is: the agent of soaking of a kind of process hides prozyme is provided, and described process hides is made up of the component of following mass parts with prozyme immersion agent:
1 part of compound enzymic preparation;
1～5 part, tensio-active agent;
2～10 parts, urea;
1～5 part of pH adjusting agent;
10～50 parts of thinners.
Preferably, described compound enzymic preparation by 1 million international units/gram or 5 million international units/gram alkaline lipase, 5 million international units/gram Sumizyme MP, 5 million international units/gram neutral protease and 5 million international units/gram composite the forming of saccharifying enzyme.
Preferably, the alkaline lipase enzyme work in described prozyme immersion agent be 50～450 international unit/gram, proteinase activity be 100～2000 international unit/gram, glucoamylase enzyme work be 50～500 international unit/gram.
Preferably, described alkaline lipase derives from animal, plant or microorganism.
More preferably, described alkaline lipase is green micro-health Leveking-01 alkaline lipase.
Preferably, described Sumizyme MP derives from animal, plant or microorganism.
More preferably, described Sumizyme MP is the one in green micro-health Leveking-PF01 Sumizyme MP, 2709 Sumizyme MPs or 209 Sumizyme MPs.
Preferably, described neutral protease derives from animal, plant or microorganism.
More preferably, described neutral protease is A.S1.398 proteolytic enzyme or 166 proteolytic enzyme.
Preferably, described saccharifying enzyme derives from animal, plant or microorganism.
More preferably, described saccharifying enzyme is green micro-health Leveking-001 saccharifying enzyme.
Preferably, described tensio-active agent is at least one in sodium lauryl sulphate, sodium laurylsulfonate, Lei meter Bang, fatty alcohol polyoxyethylene ether sulfate, polyoxyethylene alkyl ether sulfate salt and fatty alcohol-polyoxyethylene ether.
Preferably, described pH adjusting agent is at least one in sodium carbonate, sodium bicarbonate and ammonium sulfate.
Preferably, described thinner is at least one in sodium sulfate, sodium-chlor, starch, segregation phosphoric acid salt, diatomite and kaolin.
Beneficial effect of the present invention: be different from that existing process hides soaking time is long, neutral salt is seriously polluted, interfibrillar substance is removed not enough situation, utilization of the present invention includes the process hides immersion agent of compound enzymic preparation, in the immersion process of process hides, by single-minded, the efficient catalytic performance of prozyme, not only can accelerate the decomposition of grease, the infiltration of water, accelerate the removal of interfibrillar substance, shorten soaking time, and greatly reduced the consumption of sodium-chlor, tensio-active agent, significantly reduce the pollution of neutral salt.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
Embodiment 1
Take respectively 1 million international units/gram 1.5 parts of green micro-health Leveking-01 alkaline lipases, 5 million international units/gram 1.5 parts of green micro-health Leveking-PF01 Sumizyme MPs, 5 million international units/gram 1.0 parts, green micro-health Leveking-001 saccharifying enzyme, 5 million international units/gram 1.0 parts of A.S1.398 neutral proteases, above zymin is mixed, obtain compound enzymic preparation.
Take respectively 1.0 parts of compound enzymic preparations, 2.0 parts of sodium lauryl sulphate, 5.0 parts, urea, 1.0 parts, sodium carbonate, 16 parts of W-Gums, 5.0 parts of segregation sodium phosphates, 10.0 parts, sodium sulfate, after mixing the prozyme agent of soaking for process hides.Lipase activity in this prozyme immersion agent be 75 international unit/gram, proteinase activity be 625 international unit/gram, glucoamylase enzyme work is 250 international unit/good.
This prozyme immersion agent is applied to the immersion of goatskin wet salted hide, its application art parameter and immersion effect are as follows:
Application art:
Goatskin batching, weighs after deburring, as following operation materials foundation.
Immersion processing parameter:
Water: 200%; Temperature: 25 ℃; Prozyme immersion agent: 0.5%; Sodium carbonate: 0.2%; Time: 6 hours.
Immersion operation: directly add prozyme immersion agent, sodium carbonate from drum door, rotate 60 minutes, survey pH:9.0～9.5; Stop 60 minutes; Turn 20 minutes, stop 40 minutes; Turn 20 minutes, stop 40 minutes; Turn 20 minutes, stop 40 minutes; Turn 5 minutes, stop 55 minutes.Discharge opeing, enters subsequent processing.
Immersion effect: the abundant backwater of raw hide, skin heart softness, without falling hair, slipping a mao phenomenon.When immersion finishes, in body lotion, polysaccharide content is 1.2mg/mL, and total protein content is 3.5mg/mL.Compare with routine immersion, interfibrillar substance removes 30% more, and soaking time is saved 8 hours.
Embodiment 2:
Take respectively 1 million international units/gram 5.0 parts of green micro-health Leveking-01 alkaline lipases, 5 million international units/gram 3.0 parts of 2709 Sumizyme MPs, 5 million international units/gram 1.0 parts, green micro-health Leveking-001 saccharifying enzyme, 5 million international units/gram 1.0 parts of 166 neutral proteases, above zymin is mixed, obtain compound enzymic preparation.
Take respectively 1.0 parts of compound enzymic preparations, 2.0 parts of sodium laurylsulfonates, 8.0 parts, urea, 2.0 parts, sodium carbonate, 15 parts of W-Gums, 2.0 parts of kaolin, 2.0 parts of segregation sodium phosphates, 8.0 parts, sodium sulfate, after mixing the prozyme agent of soaking for process hides.Lipase activity in this prozyme immersion agent be 125 international unit/gram, proteinase activity be 500 international unit/gram, glucoamylase enzyme work be 125 international unit/gram.
This prozyme immersion agent is applied to the pre-immersion of cattle hide wet salted hide, its application art parameter and immersion effect are as follows:
Application art:
Cattle hide batching, weighs after deburring, as following operation materials foundation.
Immersion processing parameter:
Water: 200%; Temperature: 25 ℃; Contain enzyme immersion agent: 0.4%; Sodium carbonate: 0.3%; JFC:0.2%; Time: 8 hours.
Immersion operation: directly add prozyme immersion agent, JFC, sodium carbonate from drum door, rotate 30 minutes, survey pH:9.0～9.5; Stop 30 minutes; Turn 30 minutes, stop 30 points; Turn 10 minutes, stop 50 minutes; Turn 10 minutes, stop 50 minutes; Turn 10 minutes, stop 40 minutes; Turn 5 minutes, stop 55 minutes; Turn 5 minutes, stop 55 minutes; Turn 5 minutes, stop 55 minutes.Discharge opeing, enters subsequent processing.
Immersion effect: the abundant backwater of raw hide, skin heart softness is pure white, and otch is without gold zone, without falling hair, slip a mao phenomenon.In immersion body lotion, polysaccharide content is 1.3mg/mL, and total protein content is 4.8mg/mL.Compared with conventional preimpregnation water conservancy project skill, interfibrillar substance removes 20% more, and time shorten 6 hours in advance soaks.
Embodiment 3:
Take respectively 1 million international units/gram 3.0 parts of green micro-health Leveking-01 alkaline lipases, 5 million international units/gram 2.0 parts of green micro-health Leveking-PF01 Sumizyme MPs, 5 million international units/gram 2.0 parts, green micro-health Leveking-001 saccharifying enzyme, 5 million international units/gram 3.0 parts of 166 neutral proteases, above zymin is mixed, obtain compound enzymic preparation.
Take respectively 1.0 parts of compound enzymic preparations, 1.0 parts of Lei meter Bang, 2.0 parts, urea, 1.0 parts, sodium carbonate, 8.0 parts of W-Gums, 1.0 parts of segregation sodium phosphates, 3.0 parts, diatomite, 3.0 parts, sodium sulfate, after mixing the prozyme agent of soaking for process hides.Lipase activity in this prozyme immersion agent be 150 international unit/gram, proteinase activity be 1250 international unit/gram, glucoamylase enzyme live 500 international unit/gram.
This prozyme immersion agent is applied to the immersion of Corii Bubali wet salted hide, its application art parameter and immersion effect are as follows:
Application art:
Corii Bubali batching, weighs after deburring, as following operation materials foundation.
Immersion processing parameter:
Water: 200%; Temperature: 25 ℃; Contain enzyme immersion agent: 0.8%; JFC:0.2%; Sodium carbonate: 0.2%; Time: 16 hours.
Immersion operation: directly add prozyme immersion agent, JFC, sodium carbonate from drum door, rotate 60 minutes, survey pH:9.0～9.5; Stop 60 minutes; Turn 20 minutes, stop 40 minutes; Turn 20 minutes, stop 40 minutes; Turn 20 minutes, stop 40 minutes; Turn 5 minutes, stop 55 minutes; Turn 5 minutes, stop 55 minutes; Stopping drum spends the night.Within second day, rotate 30 minutes, discharge opeing, enters subsequent processing.
Immersion effect: the abundant backwater of raw hide, otch is without gold zone, and skin heart softness, without falling hair, slip a mao phenomenon.In immersion body lotion, polysaccharide content is 1.8mg/mL, and total protein content is 5.2mg/mL.Compared with conventional preimpregnation water conservancy project skill, interfibrillar substance removes 35% more.
Embodiment 4:
Take respectively 5 million international units/gram 1.8 parts of green micro-health Leveking-01 alkaline lipases, 5 million international units/gram 5.0 parts of green micro-health Leveking-PF01 Sumizyme MPs, 5 million international units/gram 0.2 part, green micro-health Leveking-001 saccharifying enzyme, 5 million international units/gram 3.0 parts of 166 neutral proteases, above zymin is mixed, obtain compound enzymic preparation.
Take respectively 1.0 parts of compound enzymic preparations, 1.0 parts of paregal Os, 3.0 parts, urea, 5.0 parts, sodium carbonate, 4.0 parts of W-Gums, 1.0 parts of segregation sodium phosphates, 2.0 parts, diatomite, 3.0 parts, sodium sulfate, after mixing the prozyme agent of soaking for process hides.Lipase activity in this prozyme immersion agent be 450 international unit/gram, proteinase activity be 2000 international unit/gram, glucoamylase enzyme work be 50 international unit/gram.
This prozyme immersion agent is applied to the immersion of pigskin wet salted hide, its application art parameter and immersion effect are as follows:
Application art:
Pigskin batching, weighs after deburring, fleshing, as following operation materials foundation.
Immersion processing parameter:
Water: 150%; Temperature: 25 ℃; Prozyme immersion agent: 0.6%; Nonionic grease-removing agent: 0.3%; Sodium carbonate: 0.2%; Time: 6 hours.
Immersion operation: directly add prozyme immersion agent, grease-removing agent, sodium carbonate from drum door, rotate 60 minutes, survey pH:9.0～9.5; Be rotated further 90 minutes.Discharge opeing, enters subsequent processing.
Immersion effect: the abundant backwater of raw hide, otch oyster white, without gold zone, skin heart softness, without falling hair, slipping a mao phenomenon.In immersion body lotion, polysaccharide content is 2.2mg/mL, and total protein content is 6.8mg/mL.Compared with conventional preimpregnation water conservancy project skill, interfibrillar substance removes 38% more, and grease is sloughed rate increases by 20%.
Embodiment 5:
Take respectively 1 million international units/gram 3.5 parts of green micro-health Leveking-01 alkaline lipases, 5 million international units/gram 1.0 parts of 209 Sumizyme MPs, 5 million international units/gram 5.1 parts, saccharifying enzyme, 5 million international units/gram 0.4 part of A.S 1.398 neutral protease, above zymin is mixed, obtain compound enzymic preparation.
Take respectively 1.0 parts of compound enzymic preparations, 5.0 parts of paregal Os, 10.0 parts, urea, 4.0 parts, sodium carbonate, 30.0 parts of W-Gums, 2.0 parts of segregation sodium phosphates, 10.0 parts, diatomite, 8.0 parts, sodium sulfate, after mixing the prozyme agent of soaking for process hides.Lipase activity in this prozyme immersion agent be 50 international unit/gram, proteinase activity be 100 international unit/gram, glucoamylase enzyme work be 364 international unit/gram.
This prozyme immersion agent is applied to the immersion of goatskin dry-salted hide, its application art parameter and immersion effect are as follows:
Application art:
Goatskin batching, deburring, weighs, as following operation materials foundation.
Immersion processing parameter:
Water: 200%; Temperature: 25 ℃; Contain enzyme immersion agent: 0.3%; JFC:0.2%; Sodium carbonate: 0.2%; Time: 14 hours.
Immersion operation: directly add prozyme immersion agent, JFC, sodium carbonate from drum door, rotate 30 minutes, survey pH:9.0～9.5; Stop 30 minutes; Rotate 30 minutes, stop 30 minutes, turn 20 minutes, stop 40 minutes; Turn 20 minutes, stop 40 minutes; Turn 5 minutes, stop 55 minutes; Turn 5 minutes, stop 55 minutes; Turn 5 minutes, stop 55 minutes.Stop drum and spend the night, morning rotates 30 minutes, and discharge opeing, enters subsequent processing.
Immersion effect: the abundant backwater of raw hide, skin heart softness, without falling hair, slipping a mao phenomenon.In immersion body lotion, polysaccharide content is 1.5mg/mL, and total protein content is 4.2mg/mL.Compared with conventional preimpregnation water conservancy project skill, interfibrillar substance removes 35% more.
Those skilled in the art do not depart from essence of the present invention and spirit, can there is various deformation scheme to realize the present invention, the foregoing is only the better feasible embodiment of the present invention, not thereby limit to interest field of the present invention, the equivalent texture change that all utilizations specification sheets of the present invention is done, within being all contained in interest field of the present invention.
Claims (10)
1. the prozyme agent of soaking for process hides, is characterized in that, described process hides is made up of the component of following mass parts with prozyme immersion agent:
1 part of compound enzymic preparation;
1～5 part, tensio-active agent;
2～10 parts, urea;
1～5 part of pH adjusting agent;
10～50 parts of thinners.
2. the prozyme agent of soaking for process hides as claimed in claim 1, it is characterized in that, described compound enzymic preparation by 1 million international units/gram or 5 million international units/gram alkaline lipase, 5 million international units/gram Sumizyme MP, 5 million international units/gram neutral protease and 5 million international units/gram composite the forming of saccharifying enzyme.
3. the prozyme agent of soaking for process hides as claimed in claim 2, it is characterized in that, the alkaline lipase enzyme work in described prozyme immersion agent be 50～450 international unit/gram, proteinase activity be 100～2000 international unit/gram, glucoamylase enzyme work be 50～500 international unit/gram.
4. the prozyme agent of soaking for process hides as claimed in claim 3, is characterized in that, described alkaline lipase derives from animal, plant or microorganism.
5. the prozyme agent of soaking for process hides as claimed in claim 3, is characterized in that, described Sumizyme MP derives from animal, plant or microorganism.
6. the prozyme agent of soaking for process hides as claimed in claim 3, is characterized in that, described neutral protease derives from animal, plant or microorganism.
7. the prozyme agent of soaking for process hides as claimed in claim 3, is characterized in that, described saccharifying enzyme derives from animal, plant or microorganism.
8. the prozyme agent of soaking for process hides as claimed in claim 1, it is characterized in that, described tensio-active agent is at least one in sodium lauryl sulphate, sodium laurylsulfonate, Lei meter Bang, fatty alcohol polyoxyethylene ether sulfate, polyoxyethylene alkyl ether sulfate salt and fatty alcohol-polyoxyethylene ether.
9. prozyme immersion profit for process hides as claimed in claim 1, is characterized in that, described pH adjusting agent is at least one in sodium carbonate, sodium bicarbonate and ammonium sulfate.
10. the prozyme agent of soaking for process hides as claimed in claim 1, is characterized in that, described thinner is at least one in sodium sulfate, sodium-chlor, starch, segregation phosphoric acid salt, diatomite and kaolin.
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| CN201210431754.3A CN103789462B (en) | 2012-11-02 | 2012-11-02 | Process hides prozyme soaks agent |
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| CN201210431754.3A CN103789462B (en) | 2012-11-02 | 2012-11-02 | Process hides prozyme soaks agent |
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| CN103789462B CN103789462B (en) | 2015-10-07 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105132600A (en) * | 2015-08-21 | 2015-12-09 | 四川大学 | Method for regulating selectivity function of protease to collagen and elastin in animal skin |
| CN105886488A (en) * | 2016-04-08 | 2016-08-24 | 四川大学 | Enzymatic soaking agent compound and application thereof |
| CN107619889A (en) * | 2017-11-06 | 2018-01-23 | 齐河力厚化工有限公司 | A kind of leather soaking enzyme preparation |
| CN116103451A (en) * | 2023-03-30 | 2023-05-12 | 精艺裘皮制品股份有限公司 | Multi-working-procedure effective synergistic beach sheepskin harmless tanning method |
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| US4484924A (en) * | 1982-07-03 | 1984-11-27 | Rohm Gmbh | Process for producing unhaired, storable hides and skins |
| CN101235421A (en) * | 2008-02-02 | 2008-08-06 | 四川大学 | Animal fur clean depilation and fur fiber loosing method for preparing leather and application thereof |
| CN101265506A (en) * | 2008-05-08 | 2008-09-17 | 四川大学 | Ashless and alkali sulfide free depilation liming treatment method for preparing leather from goatskin |
| CN101525609A (en) * | 2009-03-23 | 2009-09-09 | 陕西科技大学 | Composite soaking enzyme preparation |
| CN102344975A (en) * | 2010-07-30 | 2012-02-08 | 隆昌县阳州制革有限公司 | Clean tanning hair removal expansion method |
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2012
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Patent Citations (6)
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| US4314801A (en) * | 1979-11-03 | 1982-02-09 | Rohm Gmbh | Soaking method |
| US4484924A (en) * | 1982-07-03 | 1984-11-27 | Rohm Gmbh | Process for producing unhaired, storable hides and skins |
| CN101235421A (en) * | 2008-02-02 | 2008-08-06 | 四川大学 | Animal fur clean depilation and fur fiber loosing method for preparing leather and application thereof |
| CN101265506A (en) * | 2008-05-08 | 2008-09-17 | 四川大学 | Ashless and alkali sulfide free depilation liming treatment method for preparing leather from goatskin |
| CN101525609A (en) * | 2009-03-23 | 2009-09-09 | 陕西科技大学 | Composite soaking enzyme preparation |
| CN102344975A (en) * | 2010-07-30 | 2012-02-08 | 隆昌县阳州制革有限公司 | Clean tanning hair removal expansion method |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105132600A (en) * | 2015-08-21 | 2015-12-09 | 四川大学 | Method for regulating selectivity function of protease to collagen and elastin in animal skin |
| CN105886488A (en) * | 2016-04-08 | 2016-08-24 | 四川大学 | Enzymatic soaking agent compound and application thereof |
| CN107619889A (en) * | 2017-11-06 | 2018-01-23 | 齐河力厚化工有限公司 | A kind of leather soaking enzyme preparation |
| CN107619889B (en) * | 2017-11-06 | 2020-09-01 | 齐河力厚化工有限公司 | Leather soaking enzyme preparation |
| CN116103451A (en) * | 2023-03-30 | 2023-05-12 | 精艺裘皮制品股份有限公司 | Multi-working-procedure effective synergistic beach sheepskin harmless tanning method |
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Effective date of registration: 20170615 Address after: 247100 Shuanglong Road 1, Chizhou economic and Technological Development Zone, Anhui, China Patentee after: Anhui Lvweikang Biological Technology Co. Ltd. Address before: 8, Guangdong, Zhejiang Province, Nanshan District, Dragon Ball Avenue, dragon ball, three road, 518000 continents, plant floor, Shenzhen Patentee before: Luweikang Bio-Engineering Co., Ltd., Shenzhen City |