CN105420427B - A kind of technique using strawberry juice printing and dyeing Animal Skin - Google Patents
A kind of technique using strawberry juice printing and dyeing Animal Skin Download PDFInfo
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- CN105420427B CN105420427B CN201510982218.6A CN201510982218A CN105420427B CN 105420427 B CN105420427 B CN 105420427B CN 201510982218 A CN201510982218 A CN 201510982218A CN 105420427 B CN105420427 B CN 105420427B
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C15/00—Apparatus for chemical treatment or washing of hides, skins, or leather
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
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Abstract
The present invention relates to a kind of techniques using strawberry juice printing and dyeing Animal Skin, include the following steps:A. strawberry juice dyestuff is prepared;B. dye solution is prepared;C. Animal Skin is handled;D. it dyes;E. heat is steamed;F. final finishing.The dyeing and printing process of the present invention, can be promoted adhesive force of the strawberry juice dyestuff in Animal Skin, so that Animal Skin after printing and dyeing not fugitive color, fade.
Description
Technical field
The present invention relates to leather technology field field of printing and dyeing, and in particular to a kind of work using strawberry juice printing and dyeing Animal Skin
Skill.
Background technology
Printing and dyeing are also referred to as dyeing and finishing.Dye molecule is formed surely after being handled by physical and chemical process with cloth or leather green body
Surely it combines.Plant printing and dyeing refers to using the extraction pigment such as flower, grass, tree, wood, leaf, stem, fruit, kind, skin, root of nature to spinning
Fabric is painted, and this method is known as " vegetation dye " in ancient times.Early in the Neolithic Age, people begin to use natural plant to contaminate
Material.It has been found that the root of flowers and fruits, stem, leaf, skin can extract dye liquor with warm water immersion all over the mountains and plains.
During vegetable colour prints and dyes Animal Skin, dye molecule is by hydrogen bond and belongs to water key and the glue in Animal Skin
Original combines, to increase the binding force of vegetable colour and animal's leather.
The main component of strawberry pigment is pelargonin -3-O- glucosides, and No. CAS is 18466-51-8, is a kind of
Preferable red stain, can be as the coloring of food, beverage toy for children etc..But because strawberry pigment is soluble easily in water, ethyl alcohol etc.
Substance, so, strawberry pigment print and dye Animal Skin there may be dyeing loosely, washing property it is poor the problems such as.
Invention content
The defects of to overcome the prior art, dyes profit secured, that washing fastness is high the purpose of the present invention is to provide a kind of
With the technique of strawberry juice printing and dyeing Animal Skin.
To achieve the above object, the technical solution adopted in the present invention is as follows:
A kind of technique using strawberry juice printing and dyeing Animal Skin includes the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh, collects filtrate;Then will
Filter residue is impregnated using identical absolute ethyl alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate;Merging is collected twice
The filtrate arrived concentrates, and vacuum drying obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:28-32 parts of strawberry juice dyestuff, the tannin extract obtained by a steps
40-60 parts of 4-6 parts, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and water;It will be above-mentioned each
Component mixes, and homogeneous stirring obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5;Neutralisation treatment is specially:Alkali is added in the acid solution of dipping and is neutralized 30-45min, per 5min
Improve pH value 0.4-0.6;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 30-40 DEG C, impregnate 25-35min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min;
F. final finishing:It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
Preferably, the tannin extract in the b step is chestnut extract.
Preferably, the color fixing agent in b step is cetylpyridinium chloride, brocide and crosslinking fixation
At least one of agent DE.
Preferably, the surfactant in the b step is lecithin, neopelex, dioctyl succinate
At least one of disulfonate acid, Tween-80.
Preferably, a patterning step is further included between the Step d and step e:Using printing machine to by Step d
The Animal Skin of reason carries out stamp processing, and the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-50%.
Preferably, the alkali that the step c uses is selected from the carbonate of alkali metal, the phosphate of alkali metal, sodium hydroxide
And potassium hydroxide.
Preferably, the clear water cleaning in the f steps is specially:The Animal Skin handled by step e is cleaned with clear water
30s is cleaned 2-3 times.
The above-mentioned technique using strawberry juice printing and dyeing Animal Skin includes the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 7:1,12h is impregnated, with the screen filtration of 80 mesh, collects filtrate;Then filter residue is used into phase
Same absolute ethyl alcohol dipping, 12-24h with the screen filtration of 80 mesh, collect filtrate;Merge the filtrate being collected into twice, concentrate,
Vacuum drying, obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:28 parts of strawberry juice dyestuff, the tannin extract 4 obtained by a steps
Part, 1.5 parts of brocide, 0.8 part of lecithin, 0.2 part of sodium chloride and 40 parts of water;Above-mentioned each component is mixed,
Matter stirs, and obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 30min, is carried per 5min
High ph-values 0.6;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 30 DEG C, impregnate 35min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80 DEG C, pressure 0.5kg/cm2Steam under
Heat steams 90min;
F. final finishing:It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
The present invention is described in further detail with reference to specific embodiment.
Specific embodiment
A kind of technique using strawberry juice printing and dyeing Animal Skin includes the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh, collects filtrate;Then will
Filter residue is impregnated using identical absolute ethyl alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate;Merging is collected twice
The filtrate arrived concentrates, and vacuum drying obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:28-32 parts of strawberry juice dyestuff, the tannin extract obtained by a steps
40-60 parts of 4-6 parts, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and water;It will be above-mentioned each
Component mixes, and homogeneous stirring obtains dye solution;
Tannin extract in the step, the general name of a kind of complicated native compound.It is also non-wherein in addition to main component tannin
Tannin and insoluble matter, including but not limited to chestnut extract, oak tannin extract and larch bark tannin extract;Color fixing agent in the step,
Can be the color fixing agent of field of printing and dyeing, including but not limited to cetylpyridinium chloride and brocide and crosslinking
Color fixing agent DE;Color fixing agent in the step can be the surfactant of field of printing and dyeing, including but not limited to lecithin, ten
Dialkyl benzene sulfonic acids sodium, dioctyl succinate disulfonate acid and Tween-80;
The general adhesive force of phytochrome is relatively low, in dyeing and printing process of the invention, by adding in color fixing agent and containing tannin
Tannin extract as mordant, enable to the ligands such as hydroxyl, carboxyl contained on phytochrome molecule and in Animal Skin
Contained hydroxyl forms complicated multicomponent complex on collagenous fibres molecule so that phytochrome and the collagenous fibres in Animal Skin
Active force increase between molecule, promotes adhesive force of the vegetable colour in Animal Skin;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5-2.5;Neutralisation treatment is specially:Alkali is added in the acid solution of dipping and is neutralized 30-45min, per 5min
Improve pH value 0.4-0.6;
Alkali in the step can be highly basic, weak base or salt of weak acid, the including but not limited to carbonate of alkali metal, alkali
Phosphate, sodium hydroxide and the potassium hydroxide of metal;Animal Skin in the present invention, can be various Animal Skins, including but it is unlimited
In pigskin, ox-hide, sheepskin and fur;
By neutralisation treatment, the free acid in Animal Skin is neutralized, enhances collagenous fibres molecule and dyestuff in Animal Skin
Molecule interpenetrates power and binding force so that dyeing is more uniformly distributed;In addition, in N-process, pH value is slowly promoted, it can
Further open the channel between collagenous fibres molecule so that phytochrome molecule can further penetrate into animal skin
Depths and collagenous fibres molecule form multicomponent complex, further promote adhesive force of the vegetable colour in Animal Skin;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 30-40 DEG C, impregnate 25-35min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2
Steam under heat steam 30-90min;
After dyeing, hot steaming processing is carried out, can speed up the movement of Animal Skin plants on surface pigment molecular, and by collagen
Gap is further opened between fiber so that phytochrome molecule enters the higher depth of Animal Skin so that the plant on Animal Skin surface
Pigment molecular is less, and the fixation ability of Animal Skin is stronger;
F. final finishing:It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
In the present invention, preferred scheme further includes a patterning step between the Step d and step e:Using printing machine
Stamp processing is carried out to the Animal Skin by Step d processing, the environment temperature that stamp is handled is 25-35 DEG C, humidity 35-
50%.Using the stamp processing environment of above-mentioned temperature and humidity range, enable to printing quality more preferable.
In the present invention, preferred scheme is that the clear water cleaning in the f steps is specially:It is cleaned with clear water by step e
The Animal Skin 30s of processing is cleaned 2-3 times.
Embodiment 1
Using the technique of strawberry juice printing and dyeing Animal Skin, include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 7:1,12h is impregnated, with the screen filtration of 80 mesh, collects filtrate;Then filter residue is used into phase
Same absolute ethyl alcohol dipping, 12-24h with the screen filtration of 80 mesh, collect filtrate;Merge the filtrate being collected into twice, concentrate,
Vacuum drying, obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:28 parts of strawberry juice dyestuff, the tannin extract 4 obtained by a steps
Part, 1.5 parts of brocide, 0.8 part of lecithin, 0.2 part of sodium chloride and 40 parts of water;Above-mentioned each component is mixed,
Matter stirs, and obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.8;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 30min, is carried per 5min
High ph-values 0.6;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 30 DEG C, impregnate 35min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80 DEG C, pressure 0.5kg/cm2Steam under
Heat steams 90min;
F. final finishing:It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 2
Using the technique of strawberry juice printing and dyeing Animal Skin, include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 7:1,12h is impregnated, with the screen filtration of 100 mesh, collects filtrate;Then filter residue is used into phase
Same absolute ethyl alcohol dipping, 14h with the screen filtration of 100 mesh, collect filtrate;Merge the filtrate being collected into twice, concentrate, very
Sky is dry, obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:30 parts of strawberry juice dyestuff, the tannin extract 5 obtained by a steps
Part, 2.3 parts of brocide, 1.1 parts of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and 40 parts of water;It will be above-mentioned each
Component mixes, and homogeneous stirring obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 1.5;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 30min, is carried per 5min
High ph-values 0.4;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 30 DEG C, impregnate 30min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80 DEG C, pressure 0.5kg/cm2Steam under
Heat steams 60min;
F. final finishing:It will be cleaned 2 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 3
Using the technique of strawberry juice printing and dyeing Animal Skin, include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 10:1, dipping for 24 hours, with the screen filtration of 100 mesh, collects filtrate;Then filter residue is used
Identical absolute ethyl alcohol dipping, 14h with the screen filtration of 100 mesh, collect filtrate;Merge the filtrate being collected into twice, concentrate,
Vacuum drying, obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:30 parts of strawberry juice dyestuff, the tannin extract 5 obtained by a steps
40 parts of part, 2.5 parts of crosslinking color fixing agent DE, 1.1 parts of dioctyl succinate disulfonate acid, 0.3 part of sodium chloride and water;By above-mentioned each group
Divide mixing, homogeneous stirring obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2.5;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 30min, is carried per 5min
High ph-values 0.42;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 40 DEG C, impregnate 25min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 120 DEG C, pressure 1.5kg/cm2Steam under
Heat steams 90min;
F. final finishing:It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
Embodiment 4
Using the technique of strawberry juice printing and dyeing Animal Skin, include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 9:1,20h is impregnated, with the screen filtration of 100 mesh, collects filtrate;Then filter residue is used into phase
Same absolute ethyl alcohol dipping 18h, with the screen filtration of 100 mesh, collects filtrate;Merge the filtrate being collected into twice, concentration, vacuum
It is dry, obtain solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:30 parts of strawberry juice dyestuff, the tannin extract 6 obtained by a steps
Part, 2.2 parts of brocide, 1.3 parts of lecithin, 0.3 part of sodium chloride and 40 parts of water;Above-mentioned each component is mixed,
Matter stirs, and obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 40min, is improved per 5min
PH value 0.45;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 38 DEG C, impregnate 30min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 100 DEG C, pressure 0.8kg/cm2Steam under
Heat steams 80min;
F. final finishing:It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
Embodiment 5
Using the technique of strawberry juice printing and dyeing Animal Skin, include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the absolute ethyl alcohol
Volume and the mass ratio of strawberry are 8:1,20h is impregnated, with the screen filtration of 100 mesh, collects filtrate;Then filter residue is used into phase
Same absolute ethyl alcohol dipping 18h, with the screen filtration of 100 mesh, collects filtrate;Merge the filtrate being collected into twice, concentration, vacuum
It is dry, obtain solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:31 parts of strawberry juice dyestuff, the tannin extract 5.5 obtained by a steps
Part, 2.2 parts of brocide, 1.3 parts of lecithin, 0.3 part of sodium chloride and 40 parts of water;Above-mentioned each component is mixed,
Matter stirs, and obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution that acidleach uses
PH value is 2;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 35min, is improved per 5min
PH value 0.6;
D. it dyes:Step c will be passed through, and treated that Animal Skin is immersed within 30s by dye solution made from b step
In, at a temperature of 37 DEG C, impregnate 30min;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 110 DEG C, pressure 1.3kg/cm2Steam under
Heat steams 80min;
F. final finishing:It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
Comparative example 1
A kind of technique using strawberry juice printing and dyeing Animal Skin, as different from Example 1, not including step c and step e;
Comparative example 2
A kind of technique using strawberry juice printing and dyeing Animal Skin, as different from Example 1, not including step c;
Comparative example 3
A kind of technique using strawberry juice printing and dyeing Animal Skin, as different from Example 1, not including step e.
Detect embodiment
8 blocks of goat skins are taken, carry out printing and dyeing processing, Ran Houcong by the dyeing and printing process of embodiment 1-5, comparative example 1-3 respectively
The skin bit of 1 piece of 5cm × 5cm size is cut on goat skin after every piece of printing and dyeing, carries out extraction experiments of stripping, extract liquor selects 25%
Pyridine solution, above-mentioned skin bit is respectively placed in the flask of 50mL, 10mL extract liquors is added in, is then heated to 60 DEG C, it is permanent
Warm 25min, is pulled out, and cleaning is dried, and observes situation of stripping;Concrete outcome refers to the following table 1:
Table 1:It strips situation table by the extraction of stripping of embodiment 1-5, comparative example the 1-3 goat skin handled
Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
It strips situation | Minute quantity is stripped | Minute quantity is stripped | Minute quantity is stripped | Minute quantity is stripped |
Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
It strips situation | Minute quantity is stripped | Largely strip | It strips on a small quantity | It strips on a small quantity |
Using above-mentioned goat skin, aforesaid operations are repeated after drying, are observed and recorded required for stripping completely in Animal Skin
By the number for extraction experiments of stripping, specific data refer to the following table 2:
Table 2:It strips completely data record sheet by embodiment 1-5, comparative example the 1-3 goat skin handled
Experimental group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
Number of processes | 9th time | 8th time | 8th time | 6th time |
Experimental group | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
Number of processes | 6th time | The 4th | 6th time | 6th time |
The dyeing and printing process of the present invention, can be substantially improved vegetable colour in animal it can be seen from the data in upper table 1-2
Adhesive ability on skin so that treated that Animal Skin does not allow the situation for being also easy to produce colour fading, fading by printing and dyeing.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed range.
Claims (6)
1. a kind of technique using strawberry juice printing and dyeing Animal Skin includes the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the volume of the absolute ethyl alcohol
Mass ratio with strawberry is 5-10:1,12-24h is impregnated, with the screen filtration of 80-100 mesh, collects filtrate;Then by filter residue
It is impregnated using identical absolute ethyl alcohol, 12-24h, with the screen filtration of 80-100 mesh, collects filtrate;Merge what is be collected into twice
Filtrate concentrates, and vacuum drying obtains solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:28-32 parts of strawberry juice dyestuff, the tannin extract 4-6 obtained by a steps
Part, 1.5-2.5 parts of color fixing agent, 0.8-1.2 parts of surfactant, 0.2-0.5 parts of sodium chloride and 40-60 parts of water;By upper each component
Mixing, homogeneous stirring, obtains dye solution;The color fixing agent is brocide;The surfactant is lecithin
Or dioctyl succinate disulfonate acid;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
For 1.5-2.5;Neutralisation treatment is specially:Alkali is added in the acid solution of dipping and is neutralized 30-45min, is improved per 5min
PH value 0.4-0.6;
D. it dyes:Step c will be passed through treated that Animal Skin is immersed within 30s by dye solution made from b step,
At a temperature of 30-40 DEG C, 25-35min is impregnated;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80-120 DEG C, pressure 0.5-1.5kg/cm2Steam
Lower heat steams 30-90min;
F. final finishing:It will be cleaned by the Animal Skin of step e processing with clear water, shady place air-dries.
2. the technique according to claim 1 using strawberry juice printing and dyeing Animal Skin, it is characterised in that:In the b step
Tannin extract is chestnut extract.
3. the technique according to claim 1 using strawberry juice printing and dyeing Animal Skin, which is characterized in that the Step d is walked with e
A patterning step is further included between rapid:Stamp processing, stamp processing carry out the Animal Skin by Step d processing using printing machine
Environment temperature be 25-35 DEG C, humidity 35-50%.
4. the technique according to claim 1 using strawberry juice printing and dyeing Animal Skin, it is characterised in that:The step c uses
Alkali be selected from the carbonate of alkali metal, the phosphate of alkali metal, sodium hydroxide and potassium hydroxide.
5. the technique according to claim 1 using strawberry juice printing and dyeing Animal Skin, which is characterized in that in the f steps
Clear water cleans:The Animal Skin 30s handled by step e is cleaned with clear water, is cleaned 2-3 times.
6. the technique according to claim 1 using strawberry juice printing and dyeing Animal Skin, it is characterised in that include the following steps:
A. strawberry juice dyestuff is prepared:Strawberry pulp is taken, then ultramicro grinding adds in absolute ethyl alcohol, the volume of the absolute ethyl alcohol
Mass ratio with strawberry is 7:1,12h is impregnated, with the screen filtration of 80 mesh, collects filtrate;Then by filter residue using identical
Absolute ethyl alcohol impregnates, 12-24h, with the screen filtration of 80 mesh, collects filtrate;Merge the filtrate being collected into twice, concentration, vacuum
It is dry, obtain solid, i.e. strawberry juice dyestuff;
B. dye solution is prepared:Following component is taken according to weight:4 parts of 28 parts of strawberry juice dyestuff, tannin extract, the bromine obtained by a steps
Change 40 parts of 1.5 parts of cetyl pyridinium, 0.8 part of lecithin, 0.2 part of sodium chloride and water;Above-mentioned each component is mixed, homogeneous stirs
It mixes, obtains dye solution;
C. Animal Skin is handled:Learning from else's experience tanning treated, Animal Skin carries out acidleach, neutralisation treatment, the acid solution pH value that acidleach uses
It is 1.8;Neutralisation treatment is specially:Saleratus is added in the acid solution of dipping and is neutralized 30min, pH is improved per 5min
Value 0.6;
D. it dyes:Step c will be passed through treated that Animal Skin is immersed within 30s by dye solution made from b step,
At a temperature of 30 DEG C, 35min is impregnated;
E. heat is steamed:To pass through Step d treated Animal Skin temperature be 80 DEG C, pressure 0.5kg/cm2Steam under heat steam
90min;
F. final finishing:It will be cleaned 3 times with clear water by the Animal Skin of step e processing, each 30s, shady place air-dries.
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