CN105409991A - Pesticide composition containing zhongshengmycin, pyraclostrobin and fluopyram - Google Patents
Pesticide composition containing zhongshengmycin, pyraclostrobin and fluopyram Download PDFInfo
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- CN105409991A CN105409991A CN201510968685.3A CN201510968685A CN105409991A CN 105409991 A CN105409991 A CN 105409991A CN 201510968685 A CN201510968685 A CN 201510968685A CN 105409991 A CN105409991 A CN 105409991A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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Abstract
The invention discloses a pesticide composition containing zhongshengmycin, pyraclostrobin and fluopyram. The active ingredients are zhongshengmycin, pyraclostrobin and fluopyram. The zhongshengmycin accounts for 0.5-15% by weight of the composition, the pyraclostrobin accounts for 1-20% by weight of the composition, the fluopyramaccounts for 1-20% by weight of the composition, and the balance being auxiliary components which are allowed to use and accepted in pesticides. The pesticide composition disclosed by the invention is mainly used for preventing and treating soil-borne diseases of crops, and has the advantages of being wide in preventing and treating spectrum, relatively slow in developing resistance of pathogen, remarkable in synergistic interaction, good in environmental compatibility, low in preventing and treating cost and the like.
Description
Technical field
The present invention relates to composition pesticide and application thereof, specifically a kind of composition pesticide that is active ingredient with Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides, is mainly used in the control of crops soil-borne disease.
Background technology
Zhongshengmycin (zhongshengmycin): be a kind of novel agricultural antibiotic, has good activity to the bacterial disease of crops and some fungi venereal disease evil, has certain production-increasing function simultaneously.Its mechanism of action is by suppressing the peptide bond of pathogenetic bacteria protein to generate, finally causing bacterial death; There is strong inhibition effect to the sprouting of fungal pathogens spore, cause protoplasm cohesion in hyphal cell, change mycelium shape, play the effect of control fungal disease.
Pyraclostrobin (pyraclostrobin): belong to methoxy acrylic bactericide, the mechanism of action is mitochondrial respiratory function inhibitor, there is protection, treat, root out, permeate, strong in inhale and resistance of rainwater washing against effect.Fungicidal spectrum is wide, is widely used in preventing and treating the disease that wheat, barley, soybean, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco, ornamental plants, lawn and other field crops are caused by the fungal pathogens of nearly all types such as sac fungi, basidiomycetes, imperfect fungus and oomycetes.
Fluorine pyrrole bacterium acid amides (fluopyram): be a kind of pyridine ethyl benzamide series bactericidal agent, suppresses mitochondrial respiratory by hindering the electro transfer of succinate dehydrogenase in respiratory chain.Can be used for preventing and kill off the multiple diseases such as gray mold, powdery mildew, stalk break comprised in 70 various crop of grape, pears and drupe, vegetables and field crop etc.
Soil-borne disease refers to lives in pathogene in soil as fungi, bacterium and nematode etc., the disease that will cause from crop root or stem infringement crop when condition is suitable for.Common soil-borne disease has: the club root of Cruciferae, stalk break, soft rot, the damping off of solanaceous vegetables, the crop such as melon, damping off, epidemic disease, root rot, fusarium wilt and verticillium wilt, the bacterial wilt and root knot nematode disease etc. of tomato, cucumber and sweet (peppery) green pepper.The root of the general damage to crops of soil-borne disease and stem, plant growth early stage, seedling will soon be dead, has a strong impact on crop production once there is disease, seedling root rot or stem rot is rotten dampings off; Plant growth deuterogenesis disease, general time underproduction 20-30%, serious time underproduction 50-60%, even has no harvest.In agricultural production, the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively often mix generation, but, the selectivity that current great majority prevent and treat the medicament of soil-borne disease is comparatively strong, cannot can both reach the object of effectively control to the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively simultaneously.Therefore, the use of single medicament obviously fundamentally can not solve causing harm of various soil-borne disease in crops, is also faced with the problems such as pathogen-resistance increases the weight of, use cost is high, environmental pollution is large.
Summary of the invention
The object of the invention is for above-mentioned Problems existing, a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides is provided, for preventing and treating the soil-borne disease in crops, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively, simplify farming, save medicine cost, decrease environmental pollution, improve control efficiency.
Technical solution of the present invention: a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides, active ingredient is Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides, Zhongshengmycin percentage by weight is in the composition 0.5% ~ 15%, pyraclostrobin percentage by weight is in the composition 1% ~ 20%, fluorine pyrrole bacterium acid amides percentage by weight is in the composition 1% ~ 20%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
Described auxiliary element comprises solvent, emulsifier, wetting agent, dispersant, antifreezing agent, thickener, disintegrant, binding agent, bleeding agent, defoamer, stabilizing agent, macromolecule cyst material, pH adjusting agent, synergist, liquid-carrier and solid carrier etc., it is all composition that is conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by simple test according to recipe requirements.
Composition pesticide of the present invention can be prepared into the multiple application forms being applicable to agriculturally using, and reasonable formulation has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, microcapsule suspending agent and granule.
The production technology of the various application forms of described composition pesticide all belongs to existing known technology, does not repeat them here.
The frequency of administration of the present composition and amount of application change with crops, insect, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Compared with prior art, the invention has the advantages that:
1, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built have significant synergistic function, the control efficiency significantly improved soil-borne disease in crops is used alone than single dose, expand control spectrum, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively.
2, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, the service life decreasing Pesticide use amount, reduce use cost, alleviate pollution to environment, delayed the drug-fast generation of pathogene, extended agricultural chemicals.
Embodiment
In order to understand essence of the present invention better; below in conjunction with embodiment, content of the present invention is described further; but can not limitation of the present invention be considered as; the following stated is only for explaining the present invention; for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
Embodiment one
Following material is all weight percentage: Zhongshengmycin 5%, pyraclostrobin 10%, fluorine pyrrole bacterium acid amides 10%, the many toluene diisocyanates 20% of polymethylene, solvent naphtha S-20010%, dimethyl carbonate 10%, diphenyl phenol polyethenoxy polyethenoxy ether 5%, sodium methylene bis-naphthalene sulfonate 3%, sodium hydroxide 1%, deionized water complements to 100%.By above-mentioned active ingredient, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifier, dispersant, pH adjusting agent, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, can obtain 25% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides microcapsule suspending agent.
This embodiment is for preventing and treating the soil-borne diseases such as fusarium wilt, bacterial wilt and root knot nematode disease on watermelon: 25% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides microcapsule suspending agent is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 93.67%, 91.83% and 95.25%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 44.13%, 76.97% and 13.25%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 78.42%, 39.89% and 22.47%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 63.52%, 34.71% and 72.96%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the fusarium wilt on watermelon, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to watermelon.
Embodiment two
Following material is all weight percentage: Zhongshengmycin 5%, pyraclostrobin 10%, fluorine pyrrole bacterium acid amides 15%, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate 5%, acrylate homopolymer sodium salt 10%, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 5%, polyethylene glycol 2%, xanthans 1%, polyethers emulsion 0.1%, azone 1%, Sodium Benzoate 0.1%, deionized water supplies 100%.By above-mentioned active ingredient, wetting agent, dispersant, antifreezing agent, thickener, defoamer, synergist and preservative sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 30% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium amide suspending agents.
This embodiment is for preventing and treating the soil-borne diseases such as damping off, bacterial wilt and root knot nematode disease on tomato: 30% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium amide suspending agents is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 96.67%, 92.49% and 93.15%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 42.97%, 74.31% and 15.79%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 76.37%, 32.18% and 24.79%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 63.28%, 37.54% and 75.35%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the damping off on tomato, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to tomato.
Embodiment three
Following material is all weight percentage: Zhongshengmycin 9%, pyraclostrobin 15%, fluorine pyrrole bacterium acid amides 21%, trimethylbenzene 10%, fatty acid methyl ester 10%, ethylene oxide-propylene oxide block copolymer 10%, polycarboxylate 5%, the formaldehyde condensation products 5% of methyl naphthalene sulfonic acid sodium, epoxidized soybean oil 1%, glycerine 1%, deionized water supplies 100%.Above-mentioned active ingredient, solvent, emulsifier, dispersant and stabilizing agent are mixed to form oil phase, antifreezing agent dissolves and forms aqueous phase in water, slowly oil phase is added in aqueous phase under clipper effect, and continue to shear about 30 minutes, obtained 45% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides aqueous emulsion.
This embodiment is for preventing and treating the soil-borne diseases such as club root, soft rot and root knot nematode disease on Chinese cabbage: 45% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides aqueous emulsion is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 97.39%, 95.18% and 94.26%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 35.72%, 76.91% and 14.45%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 74.23%, 31.14% and 26.87%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 61.18%, 37.25% and 72.95%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the club root on Chinese cabbage, soft rot and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to Chinese cabbage.
Embodiment four
Following material is all weight percentage: Zhongshengmycin 10%, pyraclostrobin 15%, fluorine pyrrole bacterium acid amides 15%, trimethylbenzene 10%, fatty acid methyl ester 10%, triphen ethyl phenol polyoxyethylene groups ether phosphate 10%, pyrogallic acid 2%, organosilicon 1%, azone 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, 40% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides microemulsion can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as root rot, bacterial wilt and root knot nematode disease on capsicum: 40% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides microemulsion is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 93.49%, 96.53% and 97.18%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 31.42%, 76.36% and 16.55%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 75.85%, 36.27% and 24.11%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 63.35%, 34.81% and 73.89%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the root rot on capsicum, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to capsicum.
Embodiment five
Following material is all weight percentage: Zhongshengmycin 15%, pyraclostrobin 25%, fluorine pyrrole bacterium acid amides 15%, sldium lauryl sulfate 10%, diisobutyl sodium naphthalene sulfonate 10%, PAA and propionamide copolymer 5%, sodium phosphate 5%, white carbon 5%, attapulgite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out granulation, drying, screening, 55% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides water dispersible granules can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as base rot disease, bacterial wilt of ginger and root knot nematode disease on ginger: 55% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides water dispersible granules is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 96.74%, 93.28% and 91.96%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 25.42%, 72.18% and 13.87%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 77.13%, 30.29% and 23.91%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 66.18%, 39.32% and 72.51%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the base rot disease on ginger, bacterial wilt of ginger and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to ginger.
Embodiment six
Following material is all weight percentage: Zhongshengmycin 15%, pyraclostrobin 30%, fluorine pyrrole bacterium acid amides 30%, butyl naphthalene sulfonate 5%, alkyl phenol resin polyoxyethylene ether sulfate 5%, dispersing agent MF 5%, white carbon 5%, kaolin supplies 100%.By above-mentioned, active ingredient, wetting agent, dispersant and filler are mixed, again through air-flow crushing after mechanical crushing, mix, 75% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides wetting powder can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as root black rot, bacterial wilt and root knot nematode disease on tobacco: 75% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides wetting powder is by 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 91.93%, 92.87% and 95.69%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 26.56%, 71.33% and 12.56%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 73.37%, 34.82% and 24.69%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 61.74%, 38.26% and 74.31%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as root black rot, bacterial wilt and the root knot nematode disease on tobacco is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to tobacco.
Embodiment seven
Following material is all weight percentage: Zhongshengmycin 1%, pyraclostrobin 1.5%, fluorine pyrrole bacterium acid amides 2.5%, neopelex 5%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 5%, ethyl cellulose 5%, triphenyl phosphite 3%; kaolin supplies 100%; above-mentioned active ingredient and auxiliary agent are mediated through mixing and water adding; pinch-out granulator is used to pinch out and be shaped; afterwards by particle fluid-bed drying, screening, 5% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides granule can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as verticillium wilt, bacterial wilt and root knot nematode disease on eggplant: 5% Zhongshengmycin pyraclostrobin fluorine pyrrole bacterium acid amides granule spreads fertilizer over the fields process by 150ga.i./ha, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 90.24%, 91.17% and 91.89%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 27.32%, 75.89% and 13.45%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 79.21%, 27.42% and 26.99%; 20% fluorine pyrrole bacterium amide suspending agents presses 150ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 66.25%, 35.81% and 70.36%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the verticillium wilt on eggplant, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to eggplant.
Embodiment eight
In order to understand the synergy type that Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides are active component ternary built further, the present inventor is that active component ternary built has carried out a large amount of Toxicity Determination tests to Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides.
1, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to watermelon blight of fluorine pyrrole bacterium acid amides
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to watermelon blight of table 1, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides
| Medicament | EC 50(ob) | EC 50(th) | SR |
| Zhongshengmycin (A) | 24.93 | - | - |
| Pyraclostrobin (B) | 1.68 | - | - |
| Fluorine pyrrole bacterium acid amides (C) | 2.35 | - | - |
| A:B:C(0.5:1:1) | 0.84 | 2.40 | 2.86 |
| A:B:C(0.5:1:20) | 1.02 | 2.36 | 2.31 |
| A:B:C(0.5:20:1) | 0.96 | 1.74 | 1.81 |
| A:B:C(0.5:20:20) | 1.14 | 1.98 | 1.74 |
| A:B:C(15:1:1) | 4.87 | 10.48 | 2.15 |
| A:B:C(15:1:20) | 1.91 | 3.71 | 1.94 |
| A:B:C(15:20:1) | 1.38 | 2.78 | 2.02 |
| A:B:C(15:20:20) | 1.16 | 2.62 | 2.26 |
As can be seen from Table 1, when Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to watermelon blight; Especially composite with 0.5:1:1 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 2.86.Visible, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides is composite has reasonability and feasibility.
2, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to bacterial wilt of tomato of fluorine pyrrole bacterium acid amides
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to bacterial wilt of tomato of table 2, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides
As can be seen from Table 2, when Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to bacterial wilt of tomato; Especially composite with 0.5:1:1 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 3.02.Visible, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides is composite has reasonability and feasibility.
3, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to tobacco root-knot of fluorine pyrrole bacterium acid amides
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to tobacco root-knot of table 3, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides
| Medicament | EC 50(ob) | EC 50(th) | SR |
| Zhongshengmycin (A) | 81.52 | - | - |
| Pyraclostrobin (B) | 57.49 | - | - |
| Fluorine pyrrole bacterium acid amides (C) | 8.13 | - | - |
| A:B:C(0.5:1:1) | 4.53 | 17.06 | 3.77 |
| A:B:C(0.5:1:20) | 2.97 | 8.66 | 2.91 |
| A:B:C(0.5:20:1) | 17.45 | 45.07 | 2.58 |
| A:B:C(0.5:20:20) | 5.28 | 14.39 | 2.73 |
| A:B:C(15:1:1) | 16.78 | 52.40 | 3.12 |
| A:B:C(15:1:20) | 5.69 | 13.53 | 2.38 |
| A:B:C(15:20:1) | 15.39 | 54.97 | 3.57 |
| A:B:C(15:20:20) | 10.21 | 18.38 | 1.80 |
As can be seen from Table 3, when Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to tobacco root-knot; Especially composite with 0.5:1:1 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 3.77.Visible, Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides is composite has reasonability and feasibility.
In sum, a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides provided by the invention, obvious synergy, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively.Compared with existing single dose, the soil-borne disease successful in control crops improves, and the lasting period is long, to crop safety, is worth applying in agricultural production.
Claims (3)
1. one kind contains the composition pesticide of Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides, it is characterized in that: active ingredient is Zhongshengmycin, pyraclostrobin and fluorine pyrrole bacterium acid amides, Zhongshengmycin percentage by weight is in the composition 0.5% ~ 15%, pyraclostrobin percentage by weight is in the composition 1% ~ 20%, fluorine pyrrole bacterium acid amides percentage by weight is in the composition 1% ~ 20%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
2. a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides according to claim 1, is characterized in that: its formulation can be the one in suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, microcapsule suspending agent and granule.
3. a kind of application of composition pesticide in control crops soil-borne disease containing Zhongshengmycin and pyraclostrobin and fluorine pyrrole bacterium acid amides according to claim 1.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109769846A (en) * | 2019-03-13 | 2019-05-21 | 湖南速博生物技术有限公司 | A kind of seed treatment |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302026A (en) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing pyraclostrobin and antibiotic compounds |
| CN103518724A (en) * | 2012-07-06 | 2014-01-22 | 陕西美邦农药有限公司 | Bactericidal composition containing fluopyram and methoxyacrylate |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302026A (en) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing pyraclostrobin and antibiotic compounds |
| CN103518724A (en) * | 2012-07-06 | 2014-01-22 | 陕西美邦农药有限公司 | Bactericidal composition containing fluopyram and methoxyacrylate |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109769846A (en) * | 2019-03-13 | 2019-05-21 | 湖南速博生物技术有限公司 | A kind of seed treatment |
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