CN105010369A - Pesticide composition containing pyrrole-azole kresoxim-methyl, fludioxonil and fluorine-pyrrole furanone - Google Patents
Pesticide composition containing pyrrole-azole kresoxim-methyl, fludioxonil and fluorine-pyrrole furanone Download PDFInfo
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- CN105010369A CN105010369A CN201510408492.2A CN201510408492A CN105010369A CN 105010369 A CN105010369 A CN 105010369A CN 201510408492 A CN201510408492 A CN 201510408492A CN 105010369 A CN105010369 A CN 105010369A
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- fludioxonil
- pyraclostrobin
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Abstract
The invention discloses a pesticide composition containing pyrrole-azole kresoxim-methyl, fludioxonil and fluorine-pyrrole furanone. The pesticide composition consists of an effective component A, an effective component B, an effective component C and common auxiliary components, wherein the effective component A accounts for 0.1-40 wt% of the composition, the effective component B accounts for 0.1-40wt% of the composition, the effective component C accounts for 1-70wt% of the composition, the effective component A is selected from the pyrrole-azole kresoxim-methyl, the effective component B is selected from the fludioxonil, and the effective component C is selected from the fluorine-pyrrole furanone. The composition for insect disinfestation and sterilization, disclosed by the invention, can effectively prevent and treat various diseases and insect pests of potatoes, has many advantages of being broad in preventing and treating spectrum, slow in resistance development, notable in synergistic effects, low in preventing and treating cost and the like.
Description
Technical field
The present invention relates to composition pesticide and application thereof, specifically with the composition pesticide that pyraclostrobin, fludioxonil and fluorine pyrrole furanone are active ingredient, be applied to the control of damage by disease and insect on potato.
Background technology
Pyraclostrobin (Pyraclostrobin) is methoxy acrylic bactericide, and the mechanism of action is mitochondrial respiratory function inhibitor, there is protection, treat, root out, permeate, strong in inhale and resistance of rainwater washing against effect.Fungicidal spectrum is wide, is widely used in preventing and treating the disease that wheat, barley, soybean, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco, ornamental plants, lawn and other field crops are caused by the fungal pathogens of nearly all types such as sac fungi, basidiomycetes, imperfect fungus and oomycetes.
Fludioxonil (Fludioxonil), inhales benzene pyroles contact killing type bactericide, by the transfer suppressing glucose phosphorylated relevant in right and wrong; and the mycelial growth of Antifungi; finally cause germ dead, the mechanism of action is unique, with existing bactericide without cross resistance.High-efficiency broad spectrum, passes the microbial kind of many cause of diseases such as sac fungi, basidiomycetes, imperfect fungus and soil-borne disease has extraordinary preventive effect.
Fluorine pyrrole furanone (Flupyradifurone), it is novel nicotinamide insecticide, act on the central nervous system of insect, it is the antagonist of insect nAChR, main effective to sucking pest, harmless to honeybee, application restriction of not bloomed, to crop safety.
For the extermination of disease and insect pest agriculturally easily developed immunity to drugs, the use mechanism of action is different, the different pesticide species of control spectrum carries out the selection that mixture is a kind of the best; If reasonable mixture ratio, then can produce significant synergistic effect, make field control effect significantly be better than the effect of each single dose, expanding prevention is composed.Disease and the insect pest of large Tanaka often mix generation, as the damage by disease and insect such as the aphid on potato, tar spot mix generation throughout the year, peasant needs to buy insecticide and bactericide simultaneously, the edge of a field mixes temporarily, random large, is not often Use out of range, cause waste, increase environmental pollution, use quantity not sufficient exactly, impact prevents and treats quality.And part bactericide and insecticide are due to reasons such as chemical reactions, and are not suitable for mixture and use together, mixture is improper also easily causes degradation problem under control efficiency.
Summary of the invention
The object of the invention is for above-mentioned Problems existing, a kind of composition pesticide containing pyraclostrobin and fludioxonil and fluorine pyrrole furanone is provided, for preventing and treating the damage by disease and insect such as Potato Aphid, grub, late blight and tar spot, a drug can parasitosis be double controls, simplify farming, joint medicine cost, reduces environmental pollution, improves and prevent and treat quality.
Technical scheme of the present invention: a kind of composition pesticide containing pyraclostrobin and fludioxonil and fluorine pyrrole furanone, be made up of effective constituents A, B, C and conventional auxiliary element, effective constituents A percentage by weight is in the composition 0.1% ~ 40%, active ingredient B percentage by weight is in the composition 0.1% ~ 40%, active ingredient C percentage by weight is in the composition 1% ~ 70%, effective constituents A is selected from pyraclostrobin, active ingredient B is selected from fludioxonil, and active ingredient C is selected from fluorine pyrrole furanone.
Described auxiliary element comprises emulsifier, dispersant, antifreezing agent, preservative, film forming agent, defoamer, colouring agent etc., it is all composition that is conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by simple test according to recipe requirements.
Composition pesticide of the present invention according to well known to a person skilled in the art method, can be processed into suspension seed-coating agent.
The production technology of described composition pesticide application forms all belongs to existing known technology, does not repeat them here.
Composition pesticide of the present invention, being applicable to the insect pest of control potato disease is aphid, grub, late blight, tar spot.
Composition pesticide described in the invention, can finished product preparation form provide, namely in composition, each material mixes, and the composition of composition also can provide by unit dose form, directly mixes in bucket or tank, be then diluted to desired concn before using.
Composition pesticide provided by the invention, usually adopts dressing methods to use, also can adopt other operation techniques agriculturally applied as required.
Compared with prior art, the invention has the advantages that:
1, pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built have significant synergistic function, the control efficiency significantly improved damage by disease and insect is used than single dose or binary built, expand control spectrum simultaneously, accomplished that a medicine is controlled, damage by disease and insect is planted by Zhiduo County of holding concurrently more.
2, pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built, the service life decreasing Pesticide use amount, reduce use cost, alleviate pollution to environment, delayed the drug-fast generation of damage by disease and insect, extended agricultural chemicals.
Embodiment
In order to understand essence of the present invention better; below in conjunction with embodiment, content of the present invention is described further; but can not limitation of the present invention be considered as; the following stated is only for explaining the present invention; for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
Embodiment one:
Following material is all weight percentage: pyraclostrobin 1%, fludioxonil 3%, fluorine pyrrole furanone 20%, agriculture breast No. 500 10%, lignin sodium iodate 1.5%, Sodium Benzoate 1.5%, polyvinyl acetate 0.5%, silicone oil 1%, glycerine 1.5%, Rosa Damascana 0.5%, add water and complement to 100%.Each component is pre-mixed, then adds in sand mill and grind, after high shear mixing, add film forming agent and colouring agent allotment, 24% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent can be obtained.
This embodiment is for preventing and treating aphid on potato, grub, late blight and tar spot: 24% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent is by 120g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 83.68%, 84.52%, 81.69%, 82.95%; 10% pyraclostrobin 20% fludioxonil suspension seed-coating agent presses 25g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.87%, 1.16%, 53.58%, 58.32%; 25% pyraclostrobin suspension seed-coating agent presses 10g a.i./100kg seed Dressing, after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot be respectively 0.12%, 0.24%, 50.89.%, 39.47%; 25 grams per liter fludioxonil suspension seed-coating agents press 20g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.34%, 0.51%, 49.56%, 54.75%; 50% fluorine pyrrole furanone suspension seed-coating agent presses 150g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 61.39%, 54.67%, 0.94%, 1.13%.Visible, after pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built, synergistic effect is remarkable, lasting period is long, expand control spectrum, to the preventive effect of the damage by disease and insect such as the aphid on potato, grub, late blight and tar spot significantly better than single dose or binary built, obviously reduce when in ternary built medicament, the amount ratio single dose of active ingredient or binary built use, thus alleviate carrying capacity of environment, reduce use cost, meanwhile, in process of the test, do not find that ternary built medicament germinates to seed potato and plant strain growth produces poisoning.
Embodiment two:
Following material is all weight percentage: pyraclostrobin 1%, fludioxonil 1%, fluorine pyrrole furanone 20%, agriculture breast No. 400 10%, lauryl sodium sulfate 1.5%, Sodium Benzoate 1.5%, polyvinyl acetate 0.5%, silicone oil 1%, glycerine 1.5%, rose-red 0.5%, add water and complement to 100%.Each component is pre-mixed, then adds in sand mill and grind, after high shear mixing, add film forming agent and colouring agent allotment, 22% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent can be obtained.
This embodiment is for preventing and treating aphid on potato, grub, late blight and tar spot: 22% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent is by 120g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 85.21%, 81.48%, 83.74%, 84.56%; 10% pyraclostrobin 20% fludioxonil suspension seed-coating agent presses 25g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 1.25%, 0.99%, 56.67%, 54.96%; 25% pyraclostrobin suspension seed-coating agent presses 10g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.36%, 0.69%, 52.47%, 43.47%; 25 grams per liter fludioxonil suspension seed-coating agents press 20g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.96%, 0.83%, 45.54%, 51.43%; 50% fluorine pyrrole furanone suspension seed-coating agent presses 150g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 64.48%, 55.86%, 0.69%, 1.05%.Visible, after pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built, synergistic effect is remarkable, lasting period is long, expand control spectrum, to the preventive effect of the damage by disease and insect such as the aphid on potato, grub, late blight and tar spot significantly better than single dose or binary built, obviously reduce when in ternary built medicament, the amount ratio single dose of active ingredient or binary built use, thus alleviate carrying capacity of environment, reduce use cost, meanwhile, in process of the test, do not find that ternary built medicament germinates to seed potato and plant strain growth produces poisoning.
Embodiment three:
Following material is all weight percentage: pyraclostrobin 1%, fludioxonil 3%, fluorine pyrrole furanone 30%, agriculture breast No. 400 10%, aryl alkyl APEO 1.5%, Sodium Benzoate 1.5%, polyvinyl alcohol 0.5%, silicone oil 1%, glycerine 1.5%, rose-red 0.5%, add water and complement to 100%.Each component is pre-mixed, then adds in sand mill and grind, after high shear mixing, add film forming agent and colouring agent allotment, 34% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent can be obtained.
This embodiment is for preventing and treating aphid on potato, grub, late blight and tar spot: 34% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent is by 120g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 84.91%, 86.28%, 82.53%, 85.92%; 10% pyraclostrobin 20% fludioxonil suspension seed-coating agent presses 25g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.94%, 1.05%, 54.87%, 53.42%; 25% pyraclostrobin suspension seed-coating agent presses 10g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.45%, 0.79%, 52.56%, 47.98%; 25 grams per liter fludioxonil suspension seed-coating agents press 20g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.77%, 0.52%, 43.98%, 50.52%; 50% fluorine pyrrole furanone suspension seed-coating agent presses 150g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 61.78%, 52.34%, 0.71%, 0.46%.Visible, after pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built, synergistic effect is remarkable, lasting period is long, expand control spectrum, to the preventive effect of the damage by disease and insect such as the aphid on potato, grub, late blight and tar spot significantly better than single dose or binary built, obviously reduce when in ternary built medicament, the amount ratio single dose of active ingredient or binary built use, thus alleviate carrying capacity of environment, reduce use cost, meanwhile, in process of the test, do not find that ternary built medicament germinates to seed potato and plant strain growth produces poisoning.
Embodiment four:
Following material is all weight percentage: pyraclostrobin 1%, fludioxonil 1%, fluorine pyrrole furanone 30%, agriculture breast No. 602 10%, polycarboxylate 1.5%, phenmethylol 1.5%, polyvinyl alcohol 0.5%, silicone oil 1%, glycerine 1.5%, water-based rose-red 0.5%, add water and complement to 100%.Each component is pre-mixed, then adds in sand mill and grind, after high shear mixing, add film forming agent and colouring agent allotment, 32% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent can be obtained.
This embodiment is for preventing and treating aphid on potato, grub, late blight and tar spot: 32% pyraclostrobin fludioxonil fluorine pyrrole furanone suspension seed-coating agent is by 120g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 82.18%, 83.35%, 85.81%, 84.25%; 10% pyraclostrobin 20% fludioxonil suspension seed-coating agent presses 25g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.85%, 0.96%, 59.34%, 58.79%; 25% pyraclostrobin suspension seed-coating agent presses 10g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.66%, 0.53%, 56.78%, 49.41%; 25 grams per liter fludioxonil suspension seed-coating agents press 20g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 0.34%, 0.76%, 48.36%, 54.29%; 50% fluorine pyrrole furanone suspension seed-coating agent presses 150g a.i./100kg seed Dressing, and after planting the preventive effect of 40d to the aphid on potato, grub, late blight and tar spot is respectively 65.14%, 55.74%, 0.85%, 0.68%.Visible, after pyraclostrobin, fludioxonil and fluorine pyrrole furanone ternary built, synergistic effect is remarkable, lasting period is long, expand control spectrum, to the preventive effect of the damage by disease and insect such as the aphid on potato, grub, late blight and tar spot significantly better than single dose or binary built, obviously reduce when in ternary built medicament, the amount ratio single dose of active ingredient or binary built use, thus alleviate carrying capacity of environment, reduce use cost, meanwhile, in process of the test, do not find that ternary built medicament germinates to seed potato and plant strain growth produces poisoning.
Embodiment five:
Be the composite synergy type of active ingredient to understand pyraclostrobin, fludioxonil and fluorine pyrrole furanone further, to be that active ingredient is composite to pyraclostrobin, fludioxonil and fluorine pyrrole furanone carried out a large amount of Toxicity Determination tests to the present inventor.
1, the composite Toxicity Determination to Potato Aphid of pyraclostrobin, fludioxonil and fluorine pyrrole furanone.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and calculating the co-toxicity coefficient (CTC) of mixture: co-toxicity coefficient (CTC)>=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 1, pyraclostrobin, fludioxonil and fluorine pyrrole furanone are to the Toxicity Determination result of Potato Aphid
| Medicament | LC 50 | ATI | TTI | CTC |
| Pyraclostrobin (A) | 2916.15 | 100.00 | - | - |
| Fludioxonil (B) | 2243.56 | 129.98 | - | - |
| Fluorine pyrrole furanone (C) | 1.07 | 272537.38 | - | - |
| A:B:C(1:5:30) | 0.96 | 303765.63 | 227135.32 | 133.74 |
| A:B:C(1:5:20) | 0.85 | 343076.47 | 209672.98 | 163.62 |
| A:B:C(1:5:10) | 1.12 | 260370.54 | 170382.73 | 152.82 |
| A:B:C(1:3:30) | 0.84 | 347160.71 | 240488.57 | 144.36 |
| A:B:C(1:3:20) | 0.75 | 388820.00 | 227134.90 | 171.18 |
| A:B:C(1:3:10) | 1.09 | 267536.70 | 194704.55 | 137.41 |
| A:B:C(1:1:30) | 0.72 | 405020.83 | 255510.98 | 158.51 |
| A:B:C(1:1:20) | 0.83 | 351343.37 | 247771.71 | 141.80 |
| A:B:C(1:1:10) | 0.97 | 300634.02 | 227133.65 | 132.36 |
As can be seen from Table 1, when pyraclostrobin, fludioxonil and fluorine pyrrole furanone are composite in a certain proportion of scope, co-toxicity coefficient (CTC) is all greater than 120, shows synergistic function to Potato Aphid; Especially composite with 1:3:20 (by quality), synergistic function is the most remarkable, and co-toxicity coefficient (CTC) is 171.18.Visible, pyraclostrobin, fludioxonil and fluorine pyrrole furanone are composite has reasonability and feasibility.
2, the composite Toxicity Determination to potato black scurf of pyraclostrobin, fludioxonil and fluorine pyrrole furanone
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, and calculating the interactional synergism value of mixture (SR): synergism value (SR) < 0.5 is antagonism; Synergism value (SR)=0.5 ~ 1.5 is additions; Synergism value (SR) > 1.5 is synergistic effects.
Table 2, pyraclostrobin, fludioxonil and fluorine pyrrole furanone are to the Toxicity Determination result of potato black scurf.
| Medicament | EC 50(ob) | EC 50(th) | SR |
| Pyraclostrobin (A) | 3.29 | - | - |
| Fludioxonil (B) | 7.34 | - | - |
| Fluorine pyrrole furanone (C) | 863.16 | - | - |
| A:B:C(1:5:30) | 10.37 | 35.30 | 3.40 |
| A:B:C(1:5:20) | 12.46 | 25.79 | 2.07 |
| A:B:C(1:5:10) | 7.28 | 16.05 | 2.21 |
| A:B:C(1:3:30) | 14.82 | 45.49 | 3.07 |
| A:B:C(1:3:20) | 8.29 | 32.62 | 3.93 |
| A:B:C(1:3:10) | 9.87 | 19.33 | 1.96 |
| A:B:C(1:1:30) | 19.98 | 67.38 | 3.37 |
| A:B:C(1:1:20) | 15.27 | 47.48 | 3.11 |
| A:B:C(1:1:10) | 14.64 | 26.56 | 1.81 |
As can be seen from Table 2, when pyraclostrobin, fludioxonil and fluorine pyrrole furanone are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to potato black scurf; Especially composite with 1:3:20 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 3.93.Visible, pyraclostrobin, fludioxonil and fluorine pyrrole furanone are composite has reasonability and feasibility.
In sum, the present invention adopts pyraclostrobin, fludioxonil and fluorine pyrrole furanone to be the composite ternary complex of active ingredient, obvious synergy, a drug can parasitosis be double controls, and expands control spectrum, compared with existing single dose or binary built preparation, prevention and elimination of disease and pests successful improves, and the lasting period is long, to crop safety, be worth applying in agricultural production.
Claims (4)
1. one kind contains the composition pesticide of pyraclostrobin and fludioxonil and fluorine pyrrole furanone, it is characterized in that: be made up of effective constituents A, B, C and conventional auxiliary element, effective constituents A percentage by weight is in the composition 0.1% ~ 40%, active ingredient B percentage by weight is in the composition 0.1% ~ 40%, active ingredient C percentage by weight is in the composition 1% ~ 70%, effective constituents A is selected from pyraclostrobin, active ingredient B is selected from fludioxonil, and active ingredient C is selected from fluorine pyrrole furanone.
2. a kind of composition pesticide containing pyraclostrobin and fludioxonil and fluorine pyrrole furanone according to claim 1, is characterized in that: its formulation is suspension seed-coating agent.
3. a kind of composition pesticide containing pyraclostrobin and fludioxonil and fluorine pyrrole furanone according to claim 1 is preventing and treating the application in potato disease insect pest.
4. a kind of composition pesticide containing pyraclostrobin and fludioxonil and fluorine pyrrole furanone according to claim 3, is characterized in that: described potato disease insect pest is aphid, grub, late blight, tar spot.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105724433A (en) * | 2016-01-21 | 2016-07-06 | 中国农业科学院郑州果树研究所 | Pesticide composition for bagging pre-treatment of grapes |
| CN107771811A (en) * | 2017-08-24 | 2018-03-09 | 广东和利农种业股份有限公司 | A kind of seed of bitter gourd inorganic agent and its method for handling seed of bitter gourd |
| CN110419537A (en) * | 2019-07-24 | 2019-11-08 | 江门市植保有限公司 | It is a kind of for preventing and treating the composition pesticide of potato disease insect pest |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258195A (en) * | 1997-05-28 | 2000-06-28 | 巴斯福股份公司 | Fungicidal mixtures |
| CN102037968A (en) * | 2011-01-17 | 2011-05-04 | 河北省农林科学院植物保护研究所 | Compound bactericide for mainly treating grey mould of fruits and vegetables |
| CN102365018A (en) * | 2009-03-25 | 2012-02-29 | 拜尔农作物科学股份公司 | Synergistic combinations of active ingredients |
-
2015
- 2015-07-10 CN CN201510408492.2A patent/CN105010369A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258195A (en) * | 1997-05-28 | 2000-06-28 | 巴斯福股份公司 | Fungicidal mixtures |
| CN102365018A (en) * | 2009-03-25 | 2012-02-29 | 拜尔农作物科学股份公司 | Synergistic combinations of active ingredients |
| CN102037968A (en) * | 2011-01-17 | 2011-05-04 | 河北省农林科学院植物保护研究所 | Compound bactericide for mainly treating grey mould of fruits and vegetables |
Non-Patent Citations (1)
| Title |
|---|
| 孙雪等: "多种药剂对水稻纹枯病菌的毒力测定及田间药效", 《农药》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105724433A (en) * | 2016-01-21 | 2016-07-06 | 中国农业科学院郑州果树研究所 | Pesticide composition for bagging pre-treatment of grapes |
| CN105724433B (en) * | 2016-01-21 | 2018-08-24 | 中国农业科学院郑州果树研究所 | A kind of medicament composition of grape bagging pre-treatment |
| CN107771811A (en) * | 2017-08-24 | 2018-03-09 | 广东和利农种业股份有限公司 | A kind of seed of bitter gourd inorganic agent and its method for handling seed of bitter gourd |
| CN107771811B (en) * | 2017-08-24 | 2020-10-09 | 广东和利农种业股份有限公司 | Bitter gourd seed treating agent and method for treating bitter gourd seeds by using same |
| CN110419537A (en) * | 2019-07-24 | 2019-11-08 | 江门市植保有限公司 | It is a kind of for preventing and treating the composition pesticide of potato disease insect pest |
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