CN105403657A - 一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 - Google Patents
一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 Download PDFInfo
- Publication number
- CN105403657A CN105403657A CN201510740768.7A CN201510740768A CN105403657A CN 105403657 A CN105403657 A CN 105403657A CN 201510740768 A CN201510740768 A CN 201510740768A CN 105403657 A CN105403657 A CN 105403657A
- Authority
- CN
- China
- Prior art keywords
- barrel
- gas
- sample
- circulation conduit
- hydrogen phosphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title claims abstract description 71
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000012360 testing method Methods 0.000 title claims abstract description 18
- 239000002861 polymer material Substances 0.000 title abstract description 6
- 230000000979 retarding effect Effects 0.000 title abstract description 3
- 238000010521 absorption reaction Methods 0.000 claims abstract description 70
- 239000007789 gas Substances 0.000 claims abstract description 54
- 238000010438 heat treatment Methods 0.000 claims abstract description 40
- 238000009833 condensation Methods 0.000 claims abstract description 39
- 230000005494 condensation Effects 0.000 claims abstract description 39
- 238000002479 acid--base titration Methods 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 61
- 239000007788 liquid Substances 0.000 claims description 44
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
- 238000009413 insulation Methods 0.000 claims description 24
- 239000003063 flame retardant Substances 0.000 claims description 18
- 238000009434 installation Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 238000010998 test method Methods 0.000 claims description 12
- 238000004064 recycling Methods 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 239000012774 insulation material Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000004148 unit process Methods 0.000 claims description 3
- 238000012956 testing procedure Methods 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 8
- 238000004448 titration Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000012086 standard solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 2
- 238000004737 colorimetric analysis Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002730 mercury Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000003822 preparative gas chromatography Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229960002523 mercuric chloride Drugs 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510740768.7A CN105403657B (zh) | 2014-05-28 | 2014-05-28 | 一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510740768.7A CN105403657B (zh) | 2014-05-28 | 2014-05-28 | 一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 |
CN201410232019.9A CN103994944B (zh) | 2014-05-28 | 2014-05-28 | 一种红磷阻燃聚合物材料的磷化氢释放量的测试装置和方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410232019.9A Division CN103994944B (zh) | 2014-05-28 | 2014-05-28 | 一种红磷阻燃聚合物材料的磷化氢释放量的测试装置和方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105403657A true CN105403657A (zh) | 2016-03-16 |
CN105403657B CN105403657B (zh) | 2017-06-13 |
Family
ID=51309169
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510740768.7A Active CN105403657B (zh) | 2014-05-28 | 2014-05-28 | 一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 |
CN201410232019.9A Active CN103994944B (zh) | 2014-05-28 | 2014-05-28 | 一种红磷阻燃聚合物材料的磷化氢释放量的测试装置和方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410232019.9A Active CN103994944B (zh) | 2014-05-28 | 2014-05-28 | 一种红磷阻燃聚合物材料的磷化氢释放量的测试装置和方法 |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN105403657B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107656009A (zh) * | 2017-10-31 | 2018-02-02 | 苏州市苏测检测技术有限公司 | 食品快速检测装置 |
CN108469501A (zh) * | 2018-06-14 | 2018-08-31 | 云南江磷集团股份有限公司 | 快速测定赤磷稳定性的方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104297187B (zh) * | 2014-10-30 | 2016-08-24 | 东北林业大学 | 一种在实验室中模拟红磷类阻燃剂的阻燃材料加工过程并吸收磷化氢的方法 |
CN112710619A (zh) * | 2019-10-25 | 2021-04-27 | 北京利达科信环境安全技术有限公司 | 水质在线监测仪 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62204157A (ja) * | 1986-03-05 | 1987-09-08 | Mitsui Toatsu Chem Inc | ホスフインの簡便な定量分析法 |
JPH02141660A (ja) * | 1988-11-24 | 1990-05-31 | Toshiba Corp | 分析方法 |
CN101281178A (zh) * | 2008-04-03 | 2008-10-08 | 南京大学 | 一种痕量磷化氢气体的定量检测方法及富集装置 |
CN101493393A (zh) * | 2009-03-02 | 2009-07-29 | 谱尼测试科技(北京)有限公司 | 一种重量法对电子产品中红磷含量进行测定的方法 |
CN102393429A (zh) * | 2011-10-26 | 2012-03-28 | 南京大学 | 一种气相色谱配合柱前两次冷阱富集法检测水样中痕量磷化氢气体的方法 |
CN202512095U (zh) * | 2012-02-29 | 2012-10-31 | 华南理工大学 | 一种磷化氢气体分析测定装置 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1128001C (zh) * | 2000-09-29 | 2003-11-19 | 四川天一科技股份有限公司 | 从黄磷尾气中脱除磷、磷化物、硫化物并回收磷的方法 |
US7838304B2 (en) * | 2006-01-18 | 2010-11-23 | Arkray, Inc. | Liquid reagent of color former and method of stabilizing the same |
CN200986540Y (zh) * | 2006-08-29 | 2007-12-05 | 李立华 | 一种电脑全自动凯氏定氮仪 |
CN102539624B (zh) * | 2012-01-04 | 2015-02-04 | 上海蓝星聚甲醛有限公司 | 一种聚甲醛热稳定性的测定方法 |
CN103274921B (zh) * | 2013-05-24 | 2014-06-25 | 湖北吉星化工集团有限责任公司 | 一种利用黄磷尾气制取甲酸钙的装置及方法 |
-
2014
- 2014-05-28 CN CN201510740768.7A patent/CN105403657B/zh active Active
- 2014-05-28 CN CN201410232019.9A patent/CN103994944B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62204157A (ja) * | 1986-03-05 | 1987-09-08 | Mitsui Toatsu Chem Inc | ホスフインの簡便な定量分析法 |
JPH02141660A (ja) * | 1988-11-24 | 1990-05-31 | Toshiba Corp | 分析方法 |
CN101281178A (zh) * | 2008-04-03 | 2008-10-08 | 南京大学 | 一种痕量磷化氢气体的定量检测方法及富集装置 |
CN101493393A (zh) * | 2009-03-02 | 2009-07-29 | 谱尼测试科技(北京)有限公司 | 一种重量法对电子产品中红磷含量进行测定的方法 |
CN102393429A (zh) * | 2011-10-26 | 2012-03-28 | 南京大学 | 一种气相色谱配合柱前两次冷阱富集法检测水样中痕量磷化氢气体的方法 |
CN202512095U (zh) * | 2012-02-29 | 2012-10-31 | 华南理工大学 | 一种磷化氢气体分析测定装置 |
Non-Patent Citations (2)
Title |
---|
吴满昌等: "黄磷尾气中总磷及磷化氢的测定", 《环境污染与防治》 * |
魏燕富等: "PH3工业废气治理的研究进展", 《材料导报》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107656009A (zh) * | 2017-10-31 | 2018-02-02 | 苏州市苏测检测技术有限公司 | 食品快速检测装置 |
CN107656009B (zh) * | 2017-10-31 | 2024-05-14 | 广东上益食品有限公司 | 食品快速检测装置 |
CN108469501A (zh) * | 2018-06-14 | 2018-08-31 | 云南江磷集团股份有限公司 | 快速测定赤磷稳定性的方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103994944A (zh) | 2014-08-20 |
CN105403657B (zh) | 2017-06-13 |
CN103994944B (zh) | 2016-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103472061B (zh) | 一种烟气中三氧化硫的在线检测装置及方法 | |
CN105403657A (zh) | 一种测试红磷阻燃聚合物材料中磷化氢释放量的方法 | |
CN103091194A (zh) | 二氧化碳含量测定装置 | |
CN102253232B (zh) | 水中溶解性总磷的自动分析仪及其分析方法 | |
CN202793851U (zh) | 高温高压反应釜的汽液取样装置 | |
CN111044670B (zh) | 铵型及铵型混合粉末离子交换树脂的阳离子交换容量测试方法 | |
CN203732348U (zh) | 一种环境水中碳-14测量的制样装置 | |
CN206270239U (zh) | 一种烟气中氮氧化物含量测量的紫外分析仪 | |
CN203858177U (zh) | 一种红磷阻燃聚合物材料的磷化氢释放量的测试装置 | |
CN105223307A (zh) | 一种用于钒铁合金中硅元素容量法的检测方法 | |
CN105044275A (zh) | 偏磷酸铝中氧化铝含量的测试方法 | |
CN109358012A (zh) | 一种水质氨氮快速检测装置及方法 | |
CN110044835B (zh) | 三氧化硫在线分析系统及方法 | |
CN210123399U (zh) | 三氧化硫在线分析系统 | |
CN109765275B (zh) | 一种室外快速在线检测原油硫化氢含量的方法、装置 | |
CN203365290U (zh) | 一种简易的化工腐蚀试验装置 | |
CN114660229A (zh) | 工业硝酸铵中有机化合物含量测定方法及其装置 | |
CN203299029U (zh) | 采用气体吸收反应管的分析测定装置 | |
CN104764854B (zh) | 一种测定锰碳合金中碳含量的装置和方法 | |
CN204462133U (zh) | 一种高炉煤气混合气态酸浓度干式检测装置及其取样装置 | |
CN202869981U (zh) | 恒温蒸气发生进样系统 | |
CN113984958A (zh) | 一种安全壳内气体可燃性分析系统 | |
CN204630801U (zh) | 一种气体取样加热回送装置 | |
CN111307744A (zh) | 一种测量烟气中汞的装置 | |
CN105738246A (zh) | 用于核电站安全壳事故后水蒸汽在线取样的装置和方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210907 Address after: Room 109, no.1866, Bohai 12th Road, Port Economic Zone, Binhai New Area, Tianjin 300452 Patentee after: Tianjin Bohua Xinchuang Technology Co.,Ltd. Address before: 300072 Tianjin City, Nankai District Wei Jin Road No. 92 Patentee before: Tianjin University |
|
TR01 | Transfer of patent right | ||
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160316 Assignee: TIANJIN HONGTAI HUAKAI TECHNOLOGY CO.,LTD. Assignor: Tianjin Bohua Xinchuang Technology Co.,Ltd. Contract record no.: X2023980049319 Denomination of invention: A method for testing the release of phosphine in red phosphorus flame retardant polymer materials Granted publication date: 20170613 License type: Common License Record date: 20231130 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160316 Assignee: TIANJIN TIAN YUAN ELECTRICAL MATERIALS CO.,LTD. Assignor: Tianjin Bohua Xinchuang Technology Co.,Ltd. Contract record no.: X2024980003329 Denomination of invention: A method for testing the release of phosphine in red phosphorus flame retardant polymer materials Granted publication date: 20170613 License type: Common License Record date: 20240322 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160316 Assignee: TIANJIN ZHUOBAO TECHNOLOGY Co.,Ltd. Assignor: Tianjin Bohua Xinchuang Technology Co.,Ltd. Contract record no.: X2024980004073 Denomination of invention: A method for testing the release of phosphine in red phosphorus flame retardant polymer materials Granted publication date: 20170613 License type: Common License Record date: 20240409 |