CN105395374B - A kind of gellan gum sheet microcapsules - Google Patents
A kind of gellan gum sheet microcapsules Download PDFInfo
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- CN105395374B CN105395374B CN201510892713.8A CN201510892713A CN105395374B CN 105395374 B CN105395374 B CN 105395374B CN 201510892713 A CN201510892713 A CN 201510892713A CN 105395374 B CN105395374 B CN 105395374B
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- Prior art keywords
- gellan gum
- microcapsules
- gum sheet
- sheet microcapsules
- solution
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0254—Platelets; Flakes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention discloses a kind of gellan gum sheet microcapsules, belongs to microcapsules technology field；The gellan gum sheet microcapsules, in parts by weight, including following composition：50 ~ 70 parts of gellan gums and 0.1 ~ 1 portion of preservative；The preservative includes the one or more in Sensiva SC50,1,2 ethohexadiols, 1,2 hexylene glycols, Phenoxyethanol, sodium benzoate, potassium benzoate, Buddhist nun's platinum methyl esters, Buddhist nun's platinum propyl ester, Buddhist nun's platinum butyl ester and the different thiophene quinoline ketone of methyl.The present invention passes through the collaboration compatibility effect between each material composition, make the raw material surface tension after compounding less than salting liquids such as sodium chloride, gel is in salt solution face extensions, spread into film out, form gellan gum sheet microcapsules, gellan gum sheet microcapsules of the present invention have property stable, tend to smear out, have good quality.
Description
Technical field
The invention belongs to microcapsules technology field, and in particular to a kind of gellan gum sheet microcapsules.
Background technology
Consumer increasingly pursues natural and effect of cosmetic personal care's product, and as a commodity, not only outward appearance will
Grace is imbued with attraction and natural imagination, and stably and powerful.There are the addition product of addition plant, example currently on the market
Such as petal water, petal mile, perfume, but genuine plant either produces and preserved many stability in cosmetics
The problem of：It is a very big dirt such as the cleaning of the plant material in production process, some plants keep insect, worm's ovum etc.
Dye source, the composition during preservation in plant are soaked out to cause product unstable, and color, which is moved back, to be lost, and easy sensitization of pollen etc. is asked
Topic；The active ingredient that many plants propose uses also has the problem of various stability in cosmetics.
Present microcapsule product is mostly spherical shape, and shape matching is single, does not have sheet microcapsules, and sheet is compared to ball
The microcapsules of shape more save space, can make cosmetic base while with the addition of sheet microcapsules, moreover it is possible to ensure matrix
Addition can not be limited.Prior art does not have the correlative study for preparing sheet microcapsules, and it is because generally to trace it to its cause
Gel solution can shrink balling-up or irregular gel piece due to surface tension, and microcapsules raw material cannot be made to be extended to surrounding
Open, and then the microcapsules of slabbing or strip cannot be done, thus there is it is certain the defects of.
The content of the invention
For deficiencies of the prior art, the technical problems to be solved by the invention are：How a kind of knot is provided
Cold glue sheet microcapsules, break the conventional understanding that microcapsule product in the prior art is spherical shape, and with stability is good, product
The characteristics of of fine quality good.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme that：A kind of gellan gum sheet microcapsules, with weight
Measure part meter, including following composition：50~70 parts of gellan gums and 0.1~1 portion of preservative；It is sweet that the preservative includes ethylhexyl
Oil, 1,2 ethohexadiols, 1,2 hexylene glycols, Phenoxyethanol, sodium benzoate, potassium benzoate, Buddhist nun's platinum methyl esters, Buddhist nun's platinum propyl ester, Buddhist nun's platinum
One or more in the golden different thiophene quinoline ketone of butyl ester and methyl.
Compared with prior art, the present invention has the advantages that：
1st, the present invention is main prepares thin slice using gellan gum chance monovalence or the principle of divalent metal salting liquid generation gel
Shape capsule.But generally gellan gum solution can shrink balling-up or not when run into monovalent metal salting liquid due to surface tension
The gel piece of rule, based on this, the present invention has found to add in raw material of the present invention in gellan gum solution by the research of creativeness
When preservative or surfactant, the material of gel surface tension force can be reduced, these materials for reducing surface tension make knot cold
Sol solution is opened in the surface spreading of monovalent metal salting liquid, while is reacted with salting liquid into class disk gel film, passes through water
Flowing allows these gel film shapes to be made a variation, and obtains sheet microcapsules.
2nd, because single gellan gum diaphragm is more brittle, so the present invention has also compounded some other high polymer materials
Or emollient, by the collaboration compatibility effect between raw material, make obtained sheet microcapsules more flexible or smooth skin sense.
3rd, the collaboration compatibility effect in the present invention between each raw material, makes gellan gum sheet microcapsules of the present invention contain base-material
In easily soften and become easily to smear, skin sense is more preferable.
4th, sheet microcapsules of the present invention can be coated with pigment or active skincare ingredients, bring a variety of experience.
5th, the inventive method can realize a large amount of industrial productions of full automation, and without manual operation, flow pollution is few,
Product quality is high, controllability and favorable reproducibility.
Embodiment
The present invention is described in further detail with reference to embodiment, in the present embodiment unless otherwise instructed, original used
Material is commercially available.
Embodiment 1：
Anti-aging gold gellan gum sheet microcapsules, composition are as shown in table 1 below：
The component prescription table of table 1
Above-mentioned anti-aging gold gellan gum sheet microcapsules are prepared with the following method：
1) gellan gum is configured to the solution that mass concentration is 0.7% with pure water, polyvinyl alcohol is prepared with pure water
Into the solution that mass concentration is 1%, hydroxyethyl cellulose is configured to the solution that mass concentration is 1.5% with pure water, will be saturating
Bright matter acid sodium is configured to the solution that mass concentration is 1% with pure water；
2) after the solution that step 1) is prepared being heated into 60 DEG C, mixed solution is simultaneously incubated, standby；
3) B raw materials in upper table 1 are well mixed；
4) C raw materials in upper table 1 are milled mixing, and be mixed into the mixed B raw materials of step 3), stirred；
5) D raw materials are mixed to join in the mixed material of step 4), obtain mixed material；
6) step 5) mixed material is heated to 75 DEG C, and added in the mixed solution of step 2), carry out homogeneous, and protect
The temperature for holding mixture is 60~70 DEG C, and it is standby to obtain homogeneous thing；
7) the homogeneous thing pump after step 6) vacuum is exported and is added drop-wise on inclined-plane, being trickled on the inclined-plane has matter
The sodium chloride solution that concentration is 2% is measured, obtains anti-aging gold gellan gum sheet microcapsules.
Embodiment 2：
A kind of gellan gum sheet microcapsules, the composition are as shown in table 2 below：
The composition of the gellan gum sheet microcapsules of table 2
| Composition | Parts by weight | |
| A1 | Gellan gum | 70 |
| A2 | Sodium Hyaluronate | 29 |
| B1 | Sensiva SC50 | 0.1 |
| B2 | 1,2 ethohexadiols | 0.3 |
| B3 | Phenoxyethanol | 0.6 |
Above-mentioned gellan gum sheet microcapsules are prepared with the following method：
1) the gellan gum solution that mass concentration is 0.5% is prepared, mass concentration is 1% Sodium Hyaluronate；
2) mixed after the solution that step 1) is prepared being heated into 60 DEG C, insulation is standby；
3) Sensiva SC50 of above-mentioned parts by weight, 1,2 ethohexadiols and Phenoxyethanol are uniformly mixed and heated to 75 DEG C,
Add the mixed solution of step 2) in, carry out homogeneous, and keep mixture temperature be 60~70 DEG C, it is standby to obtain homogeneous thing；
4) the homogeneous thing pump after step 3) vacuum is exported and is added drop-wise on inclined-plane, being trickled on the inclined-plane has matter
The sodium chloride solution that concentration is 2% is measured, obtains gellan gum sheet microcapsules.
Embodiment 3：
Yellow sheet microcapsules, component prescription are as shown in table 3 below：
The yellow sheet microcapsule formula of table 3
| Composition | Parts by weight | |
| A1 | Gellan gum | 70.00 |
| A2 | Sodium Hyaluronate | 29.00 |
| A3 | Iron oxide yellow | 0.30 |
| B1 | Sensiva SC50 | 0.10 |
| B2 | 1,2 ethohexadiols | 0.60 |
Above-mentioned yellow sheet microcapsules are prepared with the following method：
1) the gellan gum solution that mass concentration is 0.5% is prepared, mass concentration is 1% Sodium Hyaluronate；
2) after the solution that step 1) is prepared being heated into 60 DEG C, two kinds of solution is mixed and are incubated, it is standby；
3) B raw materials in upper table 1 are well mixed, and are heated to 75 DEG C, added in the mixed solution of step 2), carried out equal
Matter, and keep mixture temperature be 60~70 DEG C, it is standby to obtain homogeneous thing；
4) the homogeneous thing pump after step 3) vacuum is exported and is added drop-wise on inclined-plane, being trickled on the inclined-plane has matter
The sodium chloride solution that concentration is 2% is measured, obtains yellow sheet microcapsules.
The present invention can also allow sodium chloride brine to produce flowing, avoid colloidal solution dropping point or streamline overlapping, to prepare this
Invention gellan gum sheet microcapsules.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although applicant
The present invention is described in detail with reference to preferred embodiment, it will be understood by those within the art that, to the present invention's
Technical scheme is modified or equivalent substitution, without departing from the objective and scope of technical solution of the present invention, all should cover
Among scope of the presently claimed invention.
Claims (1)
- A kind of 1. gellan gum sheet microcapsules, it is characterised in that in parts by weight, including following composition：70 parts of gellan gums, 29 parts Sodium Hyaluronate, 0.1 part of Sensiva SC50,0.3 part of 1,2 ethohexadiol and 0.6 part of Phenoxyethanol；Prepare with the following method：1）The gellan gum solution that mass concentration is 0.5% is prepared, mass concentration is 1% Sodium Hyaluronate；2）By step 1）The solution of preparation mixes after being heated to 60 DEG C, and insulation is standby；3）By the Sensiva SC50 of above-mentioned parts by weight, 1,2 ethohexadiols and Phenoxyethanol are uniformly mixed and heated to 75 DEG C, are added Step 2）In mixed solution, carry out homogeneous, and keep mixture temperature be 60 ~ 70 DEG C, it is standby to obtain homogeneous thing；4）By step 3）Homogeneous thing pump after equal vacuum is exported and is added drop-wise on inclined-plane, and being trickled on the inclined-plane has quality dense The sodium chloride solution for 2% is spent, obtains gellan gum sheet microcapsules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510892713.8A CN105395374B (en) | 2015-11-27 | 2015-11-27 | A kind of gellan gum sheet microcapsules |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510892713.8A CN105395374B (en) | 2015-11-27 | 2015-11-27 | A kind of gellan gum sheet microcapsules |
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| Publication Number | Publication Date |
|---|---|
| CN105395374A CN105395374A (en) | 2016-03-16 |
| CN105395374B true CN105395374B (en) | 2018-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510892713.8A Active CN105395374B (en) | 2015-11-27 | 2015-11-27 | A kind of gellan gum sheet microcapsules |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114317140A (en) * | 2022-01-24 | 2022-04-12 | 广州立白企业集团有限公司 | Fragrance-enhancing softening detergent composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6391288B1 (en) * | 1999-07-27 | 2002-05-21 | Shiseido Co., Ltd. | Microcapsule and method of making the same |
| CN104490615A (en) * | 2014-12-16 | 2015-04-08 | 重庆小丸科贸有限公司 | Hydrogel microcapsule with pore minimizing efficacy |
-
2015
- 2015-11-27 CN CN201510892713.8A patent/CN105395374B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6391288B1 (en) * | 1999-07-27 | 2002-05-21 | Shiseido Co., Ltd. | Microcapsule and method of making the same |
| CN104490615A (en) * | 2014-12-16 | 2015-04-08 | 重庆小丸科贸有限公司 | Hydrogel microcapsule with pore minimizing efficacy |
Non-Patent Citations (1)
| Title |
|---|
| 锐孔法制备微胶囊技术研究;王显伦;《郑州粮食学院学报》;19951231;第16卷(第4期);第21-26页 * |
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| CN105395374A (en) | 2016-03-16 |
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Address after: 401519 Chongqing Hechuan Industrial Park weir village two Patentee after: Chongqing Xiaowan Biotechnology Co., Ltd. Address before: 401519 Chongqing Hechuan Industrial Park weir village two Patentee before: CHONGQING XIAOWAN TRADE CO., LTD. |