CN105255589A

CN105255589A - Detergent essence added with peonile

Info

Publication number: CN105255589A
Application number: CN201410258217.2A
Authority: CN
Inventors: 冯天笑
Original assignee: Tianjin Double Horse Flavor & Fragrance New Technology Co Ltd
Current assignee: Tianjin Double Horse Flavor & Fragrance New Technology Co Ltd
Priority date: 2014-06-12
Filing date: 2014-06-12
Publication date: 2016-01-20

Abstract

The present invention discloses a detergent essence added with peonile, wherein the detergent essence comprises, by mass, 0.45% of eucalyptus essential oil, 0.44% of ethyl-2-methylbutyrate, 4.655% of diethyl phthalate, 3.55% of phenylethyl acetate, 1.9% of p-tert-butylcyclohexyl acetate, 0.6% of hexyl acetate, 22.6% of hexyl salicylate, 4.2% of tricyclodecenyl acetate, 0.8% of methyl nonyl acetaldehyde, 16.7% of lily aldehyde, 0.03% of undecanal, 1.8% of methylionone, 0.075% of stemone, 1.4% of beta-ionone, 3.1% of isomethylionone, 0.24% of alpha-damascone, 12% of isoesuper, 1.76% of evertal, 6.7% of dihydromyrcenol, 0.2% of nerol, 1.9% of citronellol, 1.5% of linalool, 1% of geraniol, 1.5% of 4-methyl-3-decene-5-ol, 1.8% of eugenol, 0.7% of ambrox, 0.01% of camphor, 0.07% of ethyl lemonile, 0.04% of 2-pentylcyclopentanone, 4.3% of peonile, and the like. According to the present invention, the ultra-long aroma lasting effect of the peonile and the Ambergris in the tail aroma can be perfectly matched.

Description

Add the detergent essence of tree peony nitrile

Technical field

The present invention relates to laundry detergent perfume formulation field, more particularly, relate to a kind of laundry detergent essence adding tree peony nitrile.

Background technology

Existing various laundry detergent essence ubiquity odor type is more old, thick punching, not graceful, the defect that fragrance remaining time is short, along with the quality requirements that rapid growth and the human consumer of laundry detergent consumption market increase day by day, need the more some more fresh and new change of detergent essence odor type, need fragrance more graceful, the most important thing is the fragrance remaining time after also obviously will increasing clothes washing.

Summary of the invention

Technical problem to be solved by this invention overcomes the deficiencies in the prior art, provides a kind of detergent essence of adding tree peony nitrile.

Chinese name: tree peony nitrile.

English name: Peonile.

Chemical name: 2-sub-tetrahydrobenzene-2-benzyl cyanide.

CASNo.：10461-98-0。

Appearance character: colourless to weak yellow liquid is also likely xln.

Tree peony nitrile has the strong fragrance of a flower and with the delicate fragrance of Flos Pelargonii, grapefruit and orange peel sample, to debate on fragrant paper lasting more than 30 days, belong to one of very lasting spices of lasting, except fragrance superior, also there is splendid chemical stability, in the multiple family expenses fine chemicals of pH value 2-10.5, all there is good performance.

The present invention adds the detergent essence of tree peony nitrile, is made up of by described mass percent following component:

Constituent mass per-cent %

Eucalyptus quintessence oil 0.45

Ethyl 2-methylbutyrate 0.44

Diethyl phthalate 4.655

Wintergreen oil 0.1

Orchidae 0.6

Phenylethyl ethanoate 3.55

Phanteine 0.4

Styroyl acetate 0.3

Vertenex 1.9

Hexyl acetate 0.6

N-Hexyl salicylate 22.6

Verdy acetate 4.2

Methyl nonyl acetaldehyde 0.8

α-methyl-p-tert.-butyl phenylpropionaldehyde 16.7

The undecyl aldehyde 0.03

Methylionone 1.8

Greenolivetone 0.075

Alpha, beta-lonone 1.4

Isoraldeine 3.1

α-damascone 0.24

Ambrotone 12

Evertal 1.76

Dihydromyrcenol 6.7

Vernol 0.2

Geraniol 1.9

Phantol 1.5

Geraniol 1

4-methyl-3-decene-5-alcohol 1.5

Eugenol 1.8

P-cresyl methyl ether 0.16

Phenyl ether 0.7

Tonka bean camphor 0.6

Borneol 0.02

Ambrox 0.7

Vanirone 0.05

β-naphthol methyl ether 0.6

Isoeugenol 0.3

Rose oxide 0.15

Camphor 0.01

Ethyl lemonile 0.07

2-amyl group cyclopentanone 0.04

Tree peony nitrile 4.3.

Head of the present invention is fragrant fragrant based on blue or green fragrant flower, the blue or green perfume material of growing such as tree peony nitrile, eucalyptus quintessence oil, styroyl acetate, evertal, verdy acetate, dihydromyrcenol, wintergreen oil (Methyl Salicylate) has been selected to arrange in pairs or groups, initiative does auxiliary with fruit flavour type raw materials such as ethyl lemonile, ethyl 2-methylbutyrate, hexyl acetate and modifies, and makes more plentiful many rhythms of the fragrant fragrance of head, more soft and moist.

Body note of the present invention is based on n-Hexyl salicylate (the own ester of salicylic acid), α-methyl-p-tert.-butyl phenylpropionaldehyde, methylionone, isoraldeine, set off with spices such as vernol, rose oxide, phantols again, fragrance is presented as with fragrance of a flower such as rhododendron, the lily of the valley, sweet osmanthus for nominative is adjusted, and take flores aurantii, rose as the perfect compound fragrance of a flower of auxiliary style.

Bottom note of the present invention is based on the grane ambra of a large amount of ambrotones, ambrox, amber, the banksia rose.It is worth mentioning that, ambrox is one of most important composition of natural grane ambra, and its application makes the fragrance of essence finer and smoother and graceful, meaningful long.

Tree peony nitrile in the present invention, mainly apply the strong and feature of fragrance with grapefruit, orange peel of its fragrance, can significantly embody in head perfume (or spice), perfume material can be grown with the green grass or young crops in head perfume (or spice) to coordinate well, the floral character floral of tree peony nitrile can reveal strong and interesting fragrance of a flower aroma effect with the multiple compound fragrance of a flower ligand in body note again, finally utilize the aroma retaining effect of tree peony nitrile overlength perfectly to coordinate with the grane ambra in bottom note, synthesis reveals tree peony nitrile carries throughout in the present invention, has irreplaceable effect.

Embodiment

Below in conjunction with experimental example, the present invention is described in further detail.

The present invention adds the detergent essence of tree peony nitrile, composed of the following components:

Constituent mass: g

Eucalyptus quintessence oil 0.45

Ethyl 2-methylbutyrate 0.44

Diethyl phthalate 4.655

Wintergreen oil 0.1

Orchidae 0.6

Phenylethyl ethanoate 3.55

Phanteine 0.4

Styroyl acetate 0.3

Vertenex 1.9

Hexyl acetate 0.6

N-Hexyl salicylate 22.6

Verdy acetate 4.2

Methyl nonyl acetaldehyde 0.8

α-methyl-p-tert.-butyl phenylpropionaldehyde 16.7

The undecyl aldehyde 0.03

Methylionone 1.8

Greenolivetone 0.075

Alpha, beta-lonone 1.4

Isoraldeine 3.1

α-damascone 0.24

Ambrotone 12

Evertal 1.76

Dihydromyrcenol 6.7

Vernol 0.2

Geraniol 1.9

Phantol 1.5

Geraniol 1

4-methyl-3-decene-5-alcohol 1.5

Eugenol 1.8

P-cresyl methyl ether 0.16

Phenyl ether 0.7

Tonka bean camphor 0.6

Borneol 0.02

Ambrox 0.7

Vanirone 0.05

β-naphthol methyl ether 0.6

Isoeugenol 0.3

Rose oxide 0.15

Camphor 0.01

Ethyl lemonile 0.07

2-amyl group cyclopentanone 0.04

Tree peony nitrile 4.3

Add up to 100g.

The present invention utilizes above component preparation process as follows: above component adds in container in strict accordance with proportioning raw materials, then stirs with agitator, can suitably heat, and accelerate its mixing, but temperature is no more than 40 DEG C.

Experimental verification: take the present invention as experimental subjects, the change of essence aromatic style and the effect of tree peony nitrile are added and are not added in contrast.

Attached formula: in table one, in table, A formula is the detergent essence of adding tree peony nitrile; B formula is not for add tree peony nitrile and the detergent essence replaced with dipropylene glycol (daily chemical essence commonly uses tasteless weighting agent).

Experiment conclusion:

(1) the fragrant paper lasting several months more than is distinguished

(2) carry out crowd's sampling, organize 21 Ren Pingxiang groups, before and after adding tree peony nitrile to experiment detergent essence, comparing result is in table two and table three.

Tree peony nitrile not only can strengthen the head perfume of essence as can be seen here, essence is sent out more strongly more thoroughly, improves flavouring essence quality, obviously can also increase the fragrance remaining time of essence.

Table one

Table two

Table three

	A sample washing composition finished product	B sample washing composition finished product	Without obviously difference
				No. 1	√
No. 2	√
				No. 3	√
No. 4	√
				No. 5	√
No. 6	√
				No. 7	√
No. 8	√
				No. 9	√
No. 10	√
				No. 11	√
No. 12	√
				No. 13		√
No. 14	√
				No. 15	√
No. 16	√
				No. 17	√
No. 18	√
				No. 19	√
No. 20	√
				No. 21	√

Note: beat " √ " for thinking that essence fragrance is good, perfume breath is strong and lasting is lasting.

The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims

1. add a detergent essence for tree peony nitrile, it is characterized in that, be made up of by described mass percent following component:

Constituent mass per-cent %

Eucalyptus quintessence oil 0.45

Ethyl 2-methylbutyrate 0.44

Diethyl phthalate 4.655

Wintergreen oil 0.1

Orchidae 0.6

Phenylethyl ethanoate 3.55

Phanteine 0.4

Styroyl acetate 0.3

Vertenex 1.9

Hexyl acetate 0.6

N-Hexyl salicylate 22.6

Verdy acetate 4.2

Methyl nonyl acetaldehyde 0.8

α-methyl-p-tert.-butyl phenylpropionaldehyde 16.7

The undecyl aldehyde 0.03

Methylionone 1.8

Greenolivetone 0.075

Alpha, beta-lonone 1.4

Isoraldeine 3.1

α-damascone 0.24

Ambrotone 12

Evertal 1.76

Dihydromyrcenol 6.7

Vernol 0.2

Geraniol 1.9

Phantol 1.5

Geraniol 1

4-methyl-3-decene-5-alcohol 1.5

Eugenol 1.8

P-cresyl methyl ether 0.16

Phenyl ether 0.7

Tonka bean camphor 0.6

Borneol 0.02

Ambrox 0.7

Vanirone 0.05

β-naphthol methyl ether 0.6

Isoeugenol 0.3

Rose oxide 0.15

Camphor 0.01

Ethyl lemonile 0.07

2-amyl group cyclopentanone 0.04

Tree peony nitrile 4.3.