CN105369622A - 一种丝袜高效防水整理剂及其丝袜生产工艺 - Google Patents

一种丝袜高效防水整理剂及其丝袜生产工艺 Download PDF

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CN105369622A
CN105369622A CN201510822018.4A CN201510822018A CN105369622A CN 105369622 A CN105369622 A CN 105369622A CN 201510822018 A CN201510822018 A CN 201510822018A CN 105369622 A CN105369622 A CN 105369622A
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王晓伟
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Abstract

本发明提供一种丝袜高效防水整理剂，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料10-30％，聚醋酸乙烯酯10-30％，无机硅酸盐2-6％，水34-78％。本发明同时提供一种高效防水丝袜生产工艺，在整理步骤加入高效防水整理剂。本发明优点在于保持丝袜原有的透气性和柔软性的同时，具有持久高效防水效果。

Description

一种丝袜高效防水整理剂及其丝袜生产工艺
技术领域
本发明涉及丝袜领域，特别是涉及一种丝袜高效防水整理剂及其丝袜生产工艺。
背景技术
在日常生活、运动过程中经常会出现水泼落在丝袜上的情况，当水润湿和浸透丝袜时，不仅影响外观，影响身体舒适度，严重时还会印发一些皮肤疾病。而油和污渍等滴落在丝袜上，更是影响丝袜的外观和舒适度，特别是油和污渍透过丝袜直接接触皮肤，容易引发皮肤过敏和皮肤疾病。现有的丝袜都没有拒油拒污功能，而一些拒水丝袜都是在对丝袜进行涂层整理，虽然防水效果良好，但是由于是涂层，使得丝袜的透气性和柔软性几乎消失，严重影响丝袜的穿着效果，且丧失了丝袜的轻薄特点。
中国专利CN203152503U公开了一种防水袜，袜子本体包括一外部防水层以及一与人体皮肤接触的内部保温层。该防水袜设置了双层，其透气性方面存在缺陷，此外，该防水袜并不能够防止油污浸渍。
中国专利CN203121020U公开了一种防水袜，自上而下分为活动防护层、聚氨酯薄膜、纱线。该防水袜存在厚度方面的缺陷，适用于厚型丝袜，但并不适用于轻薄型丝袜，且不具备拒油拒污效果。
中国专利CN103141946A公开了一种防水花边袜，在袜头、袜身和袜筒的外表面涂覆硅层，使得其拥有防水效果，但是穿着舒服度很差，且若此方法用于丝袜，会导致丝袜视觉效果差，丧失丝袜原有的透气性和柔软性。
发明内容
为了解决丝袜防水效果差，防水丝袜透气性和柔软性差的问题，我们提出了一种丝袜高效防水整理剂及其丝袜生产工艺，采用本发明生产的高效防水丝袜，可以在保证高效防水效果的同时，兼顾丝袜的透气性和柔软性。
本发明是通过以下技术方案实现的：
为实现上述目的，本发明提供一种丝袜高效防水整理剂，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料10-30％，聚醋酸乙烯酯10-30％，无机硅酸盐2-6％，水34-78％。聚丙烯酸单体为丙烯酸，工业上主要用丙烯或丙烯醛的催化氧化法生产，它是一种液体，其熔点为12℃，沸点为142℃,具有和乙酸相似的刺激气味。通常多以水溶液状态进行聚合。它在水中的聚合速率受pH的影响很大,在酸性介质中较在碱性介质中为快。聚丙烯酸PAA的水溶液为聚电解质，它的粘度因pH而有异常变化，即在pH>7时粘度异常增加。这是由于聚丙烯酸的羧基电离形成负离子，产生静电排斥，使高分子链在溶液中呈较为舒张的构象所致。聚醋酸乙烯酯。是乙酸乙烯酯(醋酸乙烯酯)的聚合物。英文缩写为PVAc。简称PVAc，醋酸乙烯酯经聚合生成的聚合物。是无定形聚合物，外观透明、溶于苯、丙酮和三氯甲烷等溶剂。
优选地，上述无机硅酸盐为碱金属硅酸盐水溶液和胶体二氧化硅制成。具有良好的耐水、耐碱、耐污染、耐气性能。
本发明同时提供一种高效防水丝袜生产工艺，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；袜胚包括袜口、袜筒、袜脚，袜口采用凸条组织，所述袜筒、袜脚采用平针添纱组织；
(2)染色：控制温度在60-80℃，pH为5-7，采用弱酸性染料和/或中性染料，加入固色剂，将袜胚染色；
(3)整理：将染色后的袜胚水洗3-6分钟，控制温度78-92℃，加入2.5-6.5％上述丝袜高效防水整理剂，处理10-30分钟；
(4)定型：将整理完成的袜胚在袜板上121-165℃蒸汽加热、烘干、整型，得到成品丝袜。
优选地，上述固色剂为季铵盐表面活性剂，与在高效防水污整理剂中功能不同，作为固色剂，季铵盐表面活性剂主要稳定丝袜的着色，保护丝袜颜料不掉色。
与现有技术相比，本发明的有益效果在于：
(1)具有持久高效防水效果；
(2)保持了丝袜原有的透气性和柔软性。
具体实施方式
下面结合实施例，更具体地说明本发明的内容。应当理解，本发明的实施并不局限于下面的实施例，对本发明所做的任何形式上的变通或改变都落入本发明保护范围；且下述实施例中的方法，如无特别说明，均为本领域的常规方法。
实施例1：
一种丝袜高效防水整理剂，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料10％，聚醋酸乙烯酯10％，无机硅酸盐6％，水74％。
一种高效防水丝袜生产工艺，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；
(2)染色：控制温度在70℃，pH为6，采用弱酸性染料和/或中性染料，加入季铵盐表面活性剂，将袜胚染色；
(3)整理：将染色后的袜胚水洗3分钟，控制温度78℃，加入2.5％上述丝袜高效防水整理剂，处理20分钟；
(4)定型：将整理完成的袜胚在袜板上138℃蒸汽加热、烘干、整型，得到成品丝袜。
实施例2：
一种丝袜高效防水整理剂，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料15％，聚醋酸乙烯酯15％，无机硅酸盐3％，水67％。
一种高效防水丝袜生产工艺，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；
(2)染色：控制温度在70℃，pH为6，采用弱酸性染料和/或中性染料，加入季铵盐表面活性剂，将袜胚染色；
(3)整理：将染色后的袜胚水洗5分钟，控制温度80℃，加入4％上述丝袜高效防水整理剂，处理20分钟；
(4)定型：将整理完成的袜胚在袜板上152℃蒸汽加热、烘干、整型，得到成品丝袜。
实施例3：
一种丝袜高效防水整理剂，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料30％，聚醋酸乙烯酯30％，无机硅酸盐6％，水34％。
一种高效防水丝袜生产工艺，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；
(2)染色：控制温度在70℃，pH为6，采用弱酸性染料和/或中性染料，加入季铵盐表面活性剂，将袜胚染色；
(3)整理：将染色后的袜胚水洗5分钟，控制温度90℃，加入6％上述丝袜高效防水整理剂，处理20分钟；
(4)定型：将整理完成的袜胚在袜板上165℃蒸汽加热、烘干、整型，得到成品丝袜。
对比例：
一种丝袜生产工艺，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；
(2)染色：控制温度在70℃，pH为6，采用弱酸性染料和/或中性染料，加入季铵盐表面活性剂，将袜胚染色；
(3)定型：将整理完成的袜胚在袜板上129℃蒸汽加热、烘干、整型，得到成品丝袜。
测试方法：
防水性：采用ISO4920，在控制条件下，定量蒸馏水通过标准喷头以45°喷淋在喷嘴下方150mm处，水喷淋在实验品的紧表面上，产生一个湿样品，将测试后试样表面与标准图卡进行对照评出等级。
透气性：采用YG(B)461型数字式织物透气仪，按照GB/T5453—1997测试丝袜透气性。
柔软度：采用弹性测试，按照FZ/T70006-2004行业标准进行测试，记录横向伸长率和纵向伸长率。
测试结果如下：
由表可知，采用本发明的高效防水丝袜，在透气性和柔软性上与普通丝袜区别不大，而防水性能达到行业较高标准，远远优于普通丝袜的低级标准。

Claims (4)

1.一种丝袜高效防水整理剂，其特征在于，由以下质量百分比的原料组成：纯丙烯酸聚合物乳料10-30％，聚醋酸乙烯酯10-30％，无机硅酸盐2-6％，水34-78％。
2.如权利要求1所述的一种丝袜高效防水整理剂，其特征在于，所述无机硅酸盐为碱金属硅酸盐水溶液和胶体二氧化硅制成。
3.一种高效防水丝袜生产工艺，其特征在于，步骤如下：
(1)编织：将原料送入编织机进行编织，制成袜胚；
(2)染色：控制温度在60-80℃，pH为5-7，采用弱酸性染料和/或中性染料，加入固色剂，将袜胚染色；
(3)整理：将染色后的袜胚水洗3-6分钟，控制温度78-92℃，加入2.5-6.5％上述丝袜高效防水整理剂；
(4)定型：将整理完成的袜胚在袜板上121-165℃蒸汽加热、烘干、整型，得到成品丝袜。
4.如权利要求3所述的一种高效防水丝袜生产工艺，其特征在于，所述固色剂为季铵盐表面活性剂。
CN201510822018.4A 2015-11-24 2015-11-24 一种丝袜高效防水整理剂及其丝袜生产工艺 Pending CN105369622A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109972415A (zh) * 2018-04-04 2019-07-05 卢子强 一种耐久天然纤维纺织品及其制备方法
CN111996812A (zh) * 2020-08-18 2020-11-27 广州溢成印花有限公司 一种仿皮革纹路工艺及其应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109972415A (zh) * 2018-04-04 2019-07-05 卢子强 一种耐久天然纤维纺织品及其制备方法
CN111996812A (zh) * 2020-08-18 2020-11-27 广州溢成印花有限公司 一种仿皮革纹路工艺及其应用

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Application publication date: 20160302