CN105316988A - Permeable terrace brick manufacturing method - Google Patents

Permeable terrace brick manufacturing method Download PDF

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Publication number
CN105316988A
CN105316988A CN201410379736.4A CN201410379736A CN105316988A CN 105316988 A CN105316988 A CN 105316988A CN 201410379736 A CN201410379736 A CN 201410379736A CN 105316988 A CN105316988 A CN 105316988A
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Prior art keywords
sand
solvent
adhesive
curing compound
mixing
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CN201410379736.4A
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Inventor
吴远光
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FUJIAN BAIHUA CHEMICAL CO LTD
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FUJIAN BAIHUA CHEMICAL CO LTD
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Priority to CN201410379736.4A priority Critical patent/CN105316988A/en
Publication of CN105316988A publication Critical patent/CN105316988A/en
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Abstract

The invention discloses a permeable terrace brick manufacturing method. The method comprises the steps of weighing sands with different particle sizes and different proportions; stirring the weighed sand, spraying mixed adhesives, and conducting stirring continuously till the adhesives are evenly mixed with the sand; pouring the sand which is obtained after even mixing and contains the adhesives into a floor tile mold, compacting the sand to be flat till solidification, and conducting demolding. Terrace bricks manufactured with the method are light and high in crush resistance, bending resistance and abrasion resistance, and rainwater can permeate through the terrace bricks quickly.

Description

Permeable terrace brick preparation method
Technical field
The present invention relates to a kind of permeable terrace brick preparation method.
Background technology
In recent years, city major part is completely covered by the concrete, and rainwater cannot permeate earthward, can only drain from the lower mouth of a river, and multiple city meets heavy rain and just occurs waterlogging, affects the normal trip of people.The present invention be in order to solve the surface such as existing outdoor solid brick, marble, cement floor, chemical terrace due to closure strong, the shipwreck causing rainfall to bring forms surface flow fast with infiltration.If heavy rain or torrential rain, the surface flow of accumulation, because inlet for stom water is too small, impeded drainage affects normal pass, even may causes urban waterlogging, bring more variation.High permeable terrace brick is a kind of floor tile (porosity more than 30%) of microcellular structure, and rainwater can rapid osmotic on terrace brick surface; Terrace brick itself has certain water function, what the water stored can remain valid again permeates to stratum, back to nature, thus the surface flow problem on road surfaces when can effectively solve more rainy, realize " factory's smokeless, the production automation, harmonious environment, green productive process, purposes ecology ".
With close being all using cement as cementing agent or adopting hollow out, be provided with through hole or adopt each particle masterbatch with through infiltration through hole to sinter to solidify and form of the present invention, they respectively:
The patent No.: 201310751597.9, the preparation method of a kind of local pervious floor tile and local pervious floor tile.A. according to the hollow out pattern of setting, preparation hollow out pattern mould; B, floor tile brick die size being greater than described hollow out pattern mould and hollow out pattern mould are nested mutually, be placed on permanent position, then extruded to the non-seepy material of area filling between floor tile brick die and hollow out pattern mould; C, take out described in floor tile brick die and hollow out pattern mould, and ensure that pierced pattern is complete, form hollow out brick by maintenance; D, fill seepy material to the hollow out position of hollow out brick, through the cementation of overcompaction or seepy material self, make the seepy material fill area at hollow out position and the entirety of hollow out brick form integrative-structure; Possesses the ecological performance of water-permeable and air permeable.
The patent No.: 201110155598.8, a kind of industrial by-products phosphorus slag produces the method for pervious floor tile.A raw material is prepared: get thick phosphorus slag 52%, cement 14%, flyash 4%, stone 30%, the obtained bottom compound of mixing after adding water; Get thin phosphorus slag 75%, cement 25%, the obtained surface layer mixture of mixing after adding water; B is shaping: first the surface layer mixture in the die cavity of block machine and bottom compound vibrated and suppressed, obtaining pervious floor tile base substrate; C maintenance: by pervious floor tile base substrate maintenance 24 hours, i.e. obtained pervious floor tile, with solve existing hardened ground can not penetrating rainwater, affect the problems such as traffic.
Utility model patent number: 200920154880.2, a kind of city road water-permeable floor tile.Be made up of gangue, porous concrete or pottery, comprise floor tile body, the each surface uniform of floor tile is provided with through hole (1), and each through hole (1) running through surrounding side surface is all at least communicated with the through hole (1) always putting on soffit, the Breadth Maximum of through hole (1) is less than 4mm.Described floor tile is a cuboid, and through hole (1) runs through corresponding two surfaces in horizontal, vertical or vertical lines, forms Three Mesh.
Utility model patent number: 200720100674.4, Thief zone water floor tile.Technical essential is that brick body is sintered by each particle masterbatch with through infiltration through hole and forms, and the external surface of each particle masterbatch is rough gully shape structure, also forms infiltration through hole mutually through successively between each adjacent particle masterbatch.After the utility model as above improves prior art, because brick body have employed the particle masterbatch with through water seepage hole, therefore the permeability of prior art brick body is further enhanced.
Above product exist product penetration mechanism simple, with low content of technology, than great, that intensity is poor, water permeable ability is not enough problem.
Summary of the invention
The embodiment of the present invention provides a kind of permeable terrace brick preparation method.
The embodiment of the present invention provide preparation method as follows:
Weigh the sand of different-grain diameter ratio;
Stir described load weighted sand, spray into mixed adhesive simultaneously, continue to stir until described adhesive and described sand Homogeneous phase mixing;
The sand containing adhesive after mixing described in getting, pours in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.The sand of described different-grain diameter ratio is free from foreign meter and not containing any one in the quartz sand of below particle diameter 0.5mm, natural ore particle, river sand, account for 40% according to particle diameter 1-2mm, after the ratio that particle diameter 3-4mm accounts for 60% carries out proportioning mixing, and the pure substance obtained.
Wherein, described adhesive is the mixture of solvent-free epoxy resin and non-solvent epoxy curing compound, or the mixture of polymer polyatomic alcohol and no-solvent polyurethane curing compound.
Wherein, described adhesive, for described solvent-free epoxy resin and non-solvent epoxy curing compound according to 2: 1 mass percent mix.
Or, described adhesive, for described polymer polyatomic alcohol and no-solvent polyurethane curing compound according to 2: 1 mass percent mix.
The preparation process of described adhesive is: stir described solvent-free epoxy resin, adds described non-solvent epoxy curing compound simultaneously, continues to stir until after mixing, slaking 15-30min.
Or the preparation process of described adhesive is: stir described polymer polyatomic alcohol, add described no-solvent polyurethane curing compound simultaneously, continue to stir until after mixing, slaking 15-30min.
Described method is further comprising the steps of:
In described floor brick die, after mixing described in the bottom that thickness accounts for 4/5 adopts, containing solvent-free epoxy resin and non-solvent epoxy curing compound mixture is as the sand of adhesive, and after mixing described in the top employing that thickness accounts for 1/5, containing polymer polyatomic alcohol and no-solvent polyurethane curing compound mixture is as the sand of adhesive.
The embodiment of the present invention has following characteristics relative to prior art:
The product weight prepared is light, resistance to compression flexural strength is higher, abrasion resistance good;
Construction usage is convenient;
Cleaner production (manufacturing process is discharged without waste water,waste gas and industrial residue) can be realized, be laid on the road surfaces such as underloading road surface, sidewalk, view road;
In heavy rain situation, rainwater can rapid osmotic, and enter stratum, back to nature, road surface does not occur surface flow.
Accompanying drawing explanation
Fig. 1 is the flow chart of the permeable terrace brick preparation method that the embodiment of the present invention provides;
Fig. 2 is the structure chart of the permeable terrace brick that the method provided according to the embodiment of the present invention is prepared.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that described herein is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under the prerequisite not making creative work, all belongs to the scope of protection of the invention.
As shown in Figure 1, the present invention obtains permeable terrace brick as follows:
Step S401: the sand weighing different-grain diameter ratio;
Step S402: stir described load weighted sand, spray into mixed adhesive simultaneously, continues to stir until described adhesive and described sand Homogeneous phase mixing;
Step S403: the sand containing adhesive after mixing described in getting, pours in floor brick die;
Step S404: in described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
The sand of described different-grain diameter ratio is free from foreign meter and not containing any one in the quartz sand of below particle diameter 0.5mm, natural ore particle, river sand, account for 40% according to particle diameter 1-2mm, after the ratio that particle diameter 3-4mm accounts for 60% carries out proportioning mixing, and the pure substance obtained.
Wherein, described adhesive is the mixture of solvent-free epoxy resin and non-solvent epoxy curing compound, or the mixture of polymer polyatomic alcohol and no-solvent polyurethane curing compound.
Wherein, described adhesive, for described solvent-free epoxy resin and non-solvent epoxy curing compound according to 2: 1 mass percent mix.
Or, described adhesive, for described polymer polyatomic alcohol and no-solvent polyurethane curing compound according to 2: 1 mass percent mix.
The preparation process of described adhesive is: stir described solvent-free epoxy resin, adds described non-solvent epoxy curing compound simultaneously, continues to stir until after mixing, slaking 15-30min.
Or the preparation process of described adhesive is: stir described polymer polyatomic alcohol, add described no-solvent polyurethane curing compound simultaneously, continue to stir until after mixing, slaking 15-30min.
Described method is further comprising the steps of:
In described floor brick die, after mixing described in the bottom that thickness accounts for 4/5 adopts, containing solvent-free epoxy resin and non-solvent epoxy curing compound mixture is as the sand of adhesive, and after mixing described in the top employing that thickness accounts for 1/5, containing polymer polyatomic alcohol and no-solvent polyurethane curing compound mixture is as the sand of adhesive.
Below specific embodiments of the invention.
Embodiment one:
According to percentage by weight: 3-6 part, non-solvent epoxy curing compound 1.5-3 part, particle diameter 1-3mm dustless high rigidity sand 91-95.5 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
While stir sand, spray into mixed adhesive simultaneously, stir;
Get the sand containing adhesive after mixing, pour in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
Embodiment two:
According to percentage by weight: solvent-free epoxy resin 2-5 part, non-solvent epoxy curing compound 1-2.5 part, 4-6mm dustless high rigidity sand 92.5-97 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
While stir sand, spray into mixed adhesive simultaneously, stir;
Get the sand containing adhesive after mixing, pour in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
Embodiment three:
Polymer polyatomic alcohol 2-5 part, no-solvent polyurethane curing compound 1-2.5 part, 2-6mm dustless high rigidity sand 92.5-97 part, weigh;
Polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into mixed adhesive simultaneously, stir;
Get the sand containing adhesive after mixing, pour in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
Embodiment four:
Polymer polyatomic alcohol 3-6 part, no-solvent polyurethane curing compound 1.5-3 part, 5-10mm dustless high rigidity sand 95.5-91 part, weigh;
Polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into mixed adhesive simultaneously, stir;
Get the sand containing adhesive after mixing, pour in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
Embodiment five:
According to percentage by weight: 3-6 part, non-solvent epoxy curing compound 1.5-3 part, particle diameter 1-3mm dustless high rigidity sand 91-95.5 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
Meanwhile,
Get: polymer polyatomic alcohol 2-5 part, no-solvent polyurethane curing compound 1-2.5 part, 2-6mm dustless high rigidity sand 92.5-97 part, weigh;
And polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into two kinds of mixed adhesives respectively, stir;
Get two kinds mix after containing the sand of adhesive, successively pour in floor brick die;
In described floor brick die, 4/5 of bottom thickness adopts the mixed sand of epoxy resin and curing compound, flattens; Top 1/5 adopts mixed sand compacting, the pressing of polyurethane and curing compound, after curing molding, and the demoulding.
This technique is adopted to be consider that epoxy resin and polyurethane have higher hardness, counter-bending, resistance to compression, anti-wear performance, and epoxy resin weatherability difference cost is lower, polyurethane good weatherability cost is high, take with the use of reaching the object reduced costs, and product is in different environment for use, different ratio and different process can be adopted to produce.
Embodiment six:
According to percentage by weight: 3-6 part, non-solvent epoxy curing compound 1.5-3 part, particle diameter 1-3mm dustless high rigidity sand 91-95.5 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
, get: polymer polyatomic alcohol 3-6 part, no-solvent polyurethane curing compound 1.5-3 part, 5-10mm dustless high rigidity sand 95.5-91 part, weigh meanwhile;
And polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into two kinds of mixed adhesives respectively, stir;
Get two kinds mix after containing the sand of adhesive, successively pour in floor brick die;
In described floor brick die, 4/5 of bottom thickness adopts the mixed sand of epoxy resin and curing compound, flattens; Top 1/5 adopts mixed sand compacting, the pressing of polyurethane and curing compound, after curing molding, and the demoulding.
This technique is adopted to be consider that epoxy resin and polyurethane have higher hardness, counter-bending, resistance to compression, anti-wear performance, and epoxy resin weatherability difference cost is lower, polyurethane good weatherability cost is high, take with the use of reaching the object reduced costs, and product is in different environment for use, different ratio and different process can be adopted to produce.
Embodiment seven:
According to percentage by weight: solvent-free epoxy resin 2-5 part, non-solvent epoxy curing compound 1-2.5 part, 4-6mm dustless high rigidity sand 92.5-97 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
, get: polymer polyatomic alcohol 2-5 part, no-solvent polyurethane curing compound 1-2.5 part, 2-6mm dustless high rigidity sand 92.5-97 part, weigh meanwhile;
And polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into two kinds of mixed adhesives respectively, stir;
Get two kinds mix after containing the sand of adhesive, successively pour in floor brick die;
In described floor brick die, 4/5 of bottom thickness adopts the mixed sand of epoxy resin and curing compound, flattens; Top 1/5 adopts mixed sand compacting, the pressing of polyurethane and curing compound, after curing molding, and the demoulding.
This technique is adopted to be consider that epoxy resin and polyurethane have higher hardness, counter-bending, resistance to compression, anti-wear performance, and epoxy resin weatherability difference cost is lower, polyurethane good weatherability cost is high, take with the use of reaching the object reduced costs, and product is in different environment for use, different ratio and different process can be adopted to produce.
Embodiment eight:
According to percentage by weight: solvent-free epoxy resin 2-5 part, non-solvent epoxy curing compound 1-2.5 part, 4-6mm dustless high rigidity sand 92.5-97 part, weigh;
Solvent-free epoxy resin under agitation slowly adds non-solvent epoxy curing compound, slaking 15-30min;
, get: polymer polyatomic alcohol 3-6 part, no-solvent polyurethane curing compound 1.5-3 part, 5-10mm dustless high rigidity sand 95.5-91 part, weigh meanwhile;
And polymer polyatomic alcohol under agitation slowly adds no-solvent polyurethane curing compound, slaking 15-30min;
While stir sand, spray into two kinds of mixed adhesives respectively, stir;
Get two kinds mix after containing the sand of adhesive, successively pour in floor brick die;
In described floor brick die, 4/5 of bottom thickness adopts the mixed sand of epoxy resin and curing compound, flattens; Top 1/5 adopts mixed sand compacting, the pressing of polyurethane and curing compound, after curing molding, and the demoulding.
This technique is adopted to be consider that epoxy resin and polyurethane have higher hardness, counter-bending, resistance to compression, anti-wear performance, and epoxy resin weatherability difference cost is lower, polyurethane good weatherability cost is high, take with the use of reaching the object reduced costs, and product is in different environment for use, different ratio and different process can be adopted to produce.Prepare adhesive by employing synthetic resin, curing compound, be cured into terrace brick to the mixing sand of different-grain diameter, make product have lightweight, that intensity is high, good porosity (being greater than 30%), rainwater can rapid osmotic.
The present invention by adopting a kind of solventfree resin, solvent-free curing agent, different-grain diameter and the dustless sand of high rigidity, produce a kind of lightweight, intensity is high, water permeable ability is strong, construction usage high permeable terrace brick easily.
The raw materials for production of the embodiment of the present invention adopt solvent-free resin, dustless high strength sand, realize environmentally safe in manufacturing process, discharge without solid waste.Product height pervious floor tile lighter in weight, intensity is large, osmotic effect good (porosity is greater than 30%), and product meets the performance indications of abrasion resistance/mm≤35, compressive strength/MPa >=5.0, bending tensile strength/MPa >=3.0.Be laid on the underloading road in city, sidewalk, view road, on meteorology, in 50-99.9mm/24h heavy rain situation there is not runoff and affect current in road surface, effectively alleviates urban sewerage and drainage pressure, allows rainwater back to nature.Product can also be laid on the place that indoor bathroom etc. needs rapid osmotic, and product has good application value.
Through the above description of the embodiments, those skilled in the art can be well understood to dimension disclosed by the invention and value and is not intended to be used to strictly be limited to described exact value.On the contrary, except as otherwise noted, each such dimension and value are intended to the scope stating described value and be functionally equal to around this value.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should look protection scope of the present invention.

Claims (8)

1. a preparation method for permeable terrace brick, is characterized in that, comprises the following steps:
Weigh the sand of different-grain diameter ratio;
Stir described load weighted sand, spray into mixed adhesive simultaneously, continue to stir until described adhesive and described sand Homogeneous phase mixing;
The sand containing adhesive after mixing described in getting, pours in floor brick die;
In described floor brick die, by the sand compacting containing adhesive after described mixing, pressing, until after curing molding, the demoulding.
2. the preparation method of permeable terrace brick as claimed in claim 1, it is characterized in that, the sand of described different-grain diameter ratio, free from foreign meter and not containing any one in the quartz sand of below particle diameter 0.5mm, natural ore particle, river sand, 40% is accounted for according to particle diameter 1-2mm, after the ratio that particle diameter 3-4mm accounts for 60% carries out proportioning mixing, the pure substance obtained.
3. the preparation method of permeable terrace brick as claimed in claim 1, is characterized in that, described adhesive, is the mixture of solvent-free epoxy resin and non-solvent epoxy curing compound, or the mixture of polymer polyatomic alcohol and no-solvent polyurethane curing compound.
4. the preparation method of permeable terrace brick as claimed in claim 3, is characterized in that, described adhesive, for described solvent-free epoxy resin and non-solvent epoxy curing compound according to 2: 1 mass percent mix.
5. the preparation method of permeable terrace brick as claimed in claim 3, is characterized in that, described adhesive, for described polymer polyatomic alcohol and no-solvent polyurethane curing compound according to 2: 1 mass percent mix.
6. the preparation method of permeable terrace brick as claimed in claim 4, it is characterized in that, the preparation process of described adhesive is: stir described solvent-free epoxy resin, adds described non-solvent epoxy curing compound simultaneously, continue to stir until after mixing, slaking 15-30min.
7. the preparation method of permeable terrace brick as claimed in claim 5, it is characterized in that, the preparation process of described adhesive is: stir described polymer polyatomic alcohol, adds described no-solvent polyurethane curing compound simultaneously, continue to stir until after mixing, slaking 15-30min.
8. the preparation method of permeable terrace brick as claimed in claim 3, it is characterized in that, described method is further comprising the steps of:
In described floor brick die, after mixing described in the bottom that thickness accounts for 4/5 adopts, containing solvent-free epoxy resin and non-solvent epoxy curing compound mixture is as the sand of adhesive, and after mixing described in the top employing that thickness accounts for 1/5, containing polymer polyatomic alcohol and no-solvent polyurethane curing compound mixture is as the sand of adhesive.
CN201410379736.4A 2014-08-05 2014-08-05 Permeable terrace brick manufacturing method Pending CN105316988A (en)

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Cited By (11)

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CN105837087A (en) * 2016-04-08 2016-08-10 杭州阑氏道路工程技术有限公司 A formula of an environmental friendly water-permeable sponge brick and a preparing method of the sponge brick
CN105967729A (en) * 2016-05-17 2016-09-28 重庆路投科技有限公司 Novel pavement water-permeable composite material and preparation method thereof
CN106587723A (en) * 2016-12-14 2017-04-26 方彩燕 Abrasive and durable floor tile
CN107574733A (en) * 2017-08-29 2018-01-12 武汉盛大长青建材有限公司 A kind of imitative stone material water-permeable brick and preparation method thereof
CN108640580A (en) * 2018-06-12 2018-10-12 合肥新骏建材科技有限公司 A kind of resistant to bending preparation method of the resistance to compression of water-permeable brick
CN108675684A (en) * 2016-03-18 2018-10-19 永春福源建材科技有限公司 A kind of foam cement
CN109279815A (en) * 2018-11-07 2019-01-29 同济大学 A kind of antiskid decorative Dank floor tile and preparation method thereof
CN111559899A (en) * 2020-04-29 2020-08-21 青岛理工大学 Recycled material terrace brick and preparation method thereof
CN111943576A (en) * 2020-08-18 2020-11-17 悉地(苏州)勘察设计顾问有限公司 Sponge urban ecological water-permeable pavement brick and preparation method thereof
CN113121153A (en) * 2021-05-24 2021-07-16 北京宝莲纳新材料技术有限公司 Crystal disc and seamless crystal stone floor and preparation method thereof
CN114603870A (en) * 2020-12-08 2022-06-10 嘉兴国秀环保建材有限公司 Resin brick and mold release method for pressing resin brick

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675684A (en) * 2016-03-18 2018-10-19 永春福源建材科技有限公司 A kind of foam cement
CN105837087A (en) * 2016-04-08 2016-08-10 杭州阑氏道路工程技术有限公司 A formula of an environmental friendly water-permeable sponge brick and a preparing method of the sponge brick
CN105967729A (en) * 2016-05-17 2016-09-28 重庆路投科技有限公司 Novel pavement water-permeable composite material and preparation method thereof
CN106587723A (en) * 2016-12-14 2017-04-26 方彩燕 Abrasive and durable floor tile
CN107574733A (en) * 2017-08-29 2018-01-12 武汉盛大长青建材有限公司 A kind of imitative stone material water-permeable brick and preparation method thereof
CN108640580A (en) * 2018-06-12 2018-10-12 合肥新骏建材科技有限公司 A kind of resistant to bending preparation method of the resistance to compression of water-permeable brick
CN109279815A (en) * 2018-11-07 2019-01-29 同济大学 A kind of antiskid decorative Dank floor tile and preparation method thereof
CN109279815B (en) * 2018-11-07 2021-10-08 同济大学 Antiskid decorative water permeable floor tile and preparation method thereof
CN111559899A (en) * 2020-04-29 2020-08-21 青岛理工大学 Recycled material terrace brick and preparation method thereof
CN111943576A (en) * 2020-08-18 2020-11-17 悉地(苏州)勘察设计顾问有限公司 Sponge urban ecological water-permeable pavement brick and preparation method thereof
CN114603870A (en) * 2020-12-08 2022-06-10 嘉兴国秀环保建材有限公司 Resin brick and mold release method for pressing resin brick
CN113121153A (en) * 2021-05-24 2021-07-16 北京宝莲纳新材料技术有限公司 Crystal disc and seamless crystal stone floor and preparation method thereof

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