CN108675684A - A kind of foam cement - Google Patents

A kind of foam cement Download PDF

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Publication number
CN108675684A
CN108675684A CN201810603346.9A CN201810603346A CN108675684A CN 108675684 A CN108675684 A CN 108675684A CN 201810603346 A CN201810603346 A CN 201810603346A CN 108675684 A CN108675684 A CN 108675684A
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China
Prior art keywords
parts
epoxy resin
foam cement
ground
acid epoxy
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810603346.9A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yongchun Fuyuan Building Materials Technology Co Ltd
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Yongchun Fuyuan Building Materials Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201810603346.9A priority Critical patent/CN108675684A/en
Publication of CN108675684A publication Critical patent/CN108675684A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D27/00Foundations as substructures
    • E02D27/32Foundations for special purposes
    • E02D27/44Foundations for machines, engines or ordnance
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D3/00Improving or preserving soil or rock, e.g. preserving permafrost soil
    • E02D3/12Consolidating by placing solidifying or pore-filling substances in the soil
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Agronomy & Crop Science (AREA)
  • Soil Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention belongs to soft soil foundation field, specially foam cement, the foam cement includes the substance of following parts by weight:20 30 parts of modified acroleic acid epoxy resin, 3 parts of phosphatase 11,3 10 parts of zinc powder, 38 parts of water, 10 13 parts of glycerine, 8 10 parts of polyvinyl alcohol, 30 60 parts of Iron-ore Slag, 15 30 parts of ceramic microsphere, wherein modified acroleic acid epoxy resin are 1,4,5,8 naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is obtained by the reaction.It can be done directly on the foundation that weak soil carries out lathe ground on the ground, reduce construction volume and human cost.

Description

A kind of foam cement
The application is application No. is 2016101552179, and the applying date is on 03 18th, 2016, and invention and created name is A kind of divisional application of the patent of " lathe ground for being established on the ground in weak soil ".
Technical field
The invention belongs to soft soil foundation field, specially a kind of lathe grounds for being established on the ground in weak soil.
Background technology
Heavy machine tool is widely used in fields such as the machinery in China, space flight, national defence, the energy, is China's equipment The representative product of manufacturing industry.But domestic heavy machine tool presently, there are one of main problem precisely due to heavy machine The huge quality of bed volume is very big, and ground is difficult the requirement for meeting lathe load-bearing, and the ground in especially many areas is partially soft, in order to make Obtaining heavy machine tool at work can be steady, generally requires to carry out consolidation process to ground, such as Chinese patent CN103469783A " a kind of soft soil foundation reinforcing method ", the reinforcement means include using weak soil compacting equipment, the weak soil compacting equipment:Nip drum Machine and two sets of rail pressure devices;The reinforcement means includes the following steps:A drafts of soft soil foundation is determined first;Setting Four fixed foundation points;By nip drum machine setting in compacting initial position;Make the front stretching of two sets of rail pressure devices respectively Mechanism and rear telescoping mechanism alternating movement, the nip drum machine accordingly move forward and backward, to be compacted to the soft soil foundation, Until practical drafts meets the requirement of overall reduction.For another example Chinese patent CN1957143A " reinforcement means of soft soil foundation ", In the inside of the ground of consolidated subsoil peripheral portion, vertical drainage part is set, forms vertical row supply passageway, is supplied in the vertical row The inside of access pours into the water with sealing part, and by above-mentioned vertical supply passageway, the water with sealing part is supplied to reinforcing The inside of the ground of ground peripheral portion, the sealing part being circulated into above-mentioned vertical supply passageway are spread in vertical confession with flow To the periphery of access, sealing region is formed, effect is:Consolidated subsoil peripheral portion is hindered by the sealing region that sealing part is formed Ground inside underground water movement, can inhibit the consolidated subsoil periphery of the forced drainage of the underground water with consolidated subsoil The decline of the underground water of the inside of the ground in portion can effectively inhibit the consolidated subsoil peripheral portion of the reinforcing with soft soil foundation The sedimentation of ground.
The above method is to carry out compacting or the firm ground of drain reinforcing method foundation to soft soil foundation, great in constructing amount, Program is complex, and labour cost is higher, and the ground established is unable to antidetonation resistance to compression, and service life is short.
Invention content
In order to solve the above technical problem, the present invention provides a kind of lathe grounds for being established on the ground in weak soil, can The foundation that weak soil carries out lathe ground on the ground is directly acted on, construction volume and human cost are reduced.
To realize the above-mentioned technical purpose, the specific technical solution that the present invention takes be using foam cement construction and At the foam cement includes the substance of following parts by weight:
20-30 parts of modified acroleic acid epoxy resin,
- 3 parts of phosphatase 11,
3-10 parts of zinc powder,
3-8 parts of water,
10-13 parts of glycerine,
8-10 parts of polyvinyl alcohol,
30-60 parts of Iron-ore Slag,
15-30 parts of ceramic microsphere, wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy Resin in molar ratio 1:1 is obtained by the reaction.
Technical solution as an improvement of the present invention further includes 1-3 parts of catalyst, and the catalyst is heteropoly acid, miscellaneous more The sodium salt or aluminium phosphate molecular sieve of acid.
The mass concentration of technical solution as an improvement of the present invention, phosphoric acid is 60%-85%.
Technical solution as an improvement of the present invention further includes 3-8 parts of coupling agent.
Technical solution as an improvement of the present invention, the coupling agent are preferably silane coupling agent.
Technical solution as an improvement of the present invention, it is to use to establish lathe ground on the ground in weak soil:By modified acroleic acid Epoxy resin, polyvinyl alcohol, glycerine, ceramic microsphere, Iron-ore Slag, zinc powder, water, phosphoric acid are uniformly mixed construction in order.
Advantageous effect
A kind of lathe ground honeycombed cement provided by the invention, in ingredient comprising resin of the benzene ring structure with carboxyl with Polyalcohol, the big calorimetric discharged during zinc powder, Iron-ore Slag and phosphatase reaction generate the passivating film with anticorrosion structure Under the action of can generate the organic substance with rigid structure and flexible structure, and the organic substance generated is that polarity is organic Object, can adsorb hydrone in weak soil to cement it is porous in, and then improve the intensity of cement.Simultaneously as first by metallics It is uniformly mixed with resin so that during phosphoric acid is subsequently added, metal generates the hydrogen discharged during passivating film with phosphoric acid Gas can be uniformly distributed in entire cement ground so that cement ground has even porous structure.And porous structure has centainly Water imbibition therefore can make full use of weak soil groundwater resources, realize the consolidation of ground, and prolongedly with the time Base only can be consolidated increasingly;And simultaneously, after construction building, ground be honeycombed cement ground, can have it is shockproof, insulate against sound and The propagation of Isolation stress.
Specific implementation mode
It is clearer for the purpose and technical solution that make the embodiment of the present invention, below in conjunction with the embodiment of the present invention to this hair Bright technical solution is clearly and completely described.Obviously, described embodiment is a part of the embodiment of the present invention, and The embodiment being not all of.Based on described the embodiment of the present invention, those of ordinary skill in the art are without creative labor The every other embodiment obtained under the premise of dynamic, shall fall within the protection scope of the present invention.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art Language and scientific terminology) there is meaning identical with the general understanding of the those of ordinary skill in fields of the present invention.Should also Understand, those terms such as defined in the general dictionary, which should be understood that, to be had and the meaning in the context of the prior art The consistent meaning of justice, and unless defined as here, will not be with idealizing or the meaning of too formal be explained.
It is to use to establish lathe ground on the ground in weak soil:By modified acroleic acid epoxy resin, polyvinyl alcohol, glycerine, pottery Porcelain microballoon, Iron-ore Slag, zinc powder, water, phosphoric acid are uniformly mixed construction in order.
Embodiment 1
The foam cement includes the substance of following parts by weight:
20 parts of modified acroleic acid epoxy resin,
3 parts of phosphoric acid,
3 parts of zinc powder,
8 parts of water,
10 parts of glycerine,
10 parts of polyvinyl alcohol,
30 parts of Iron-ore Slag,
30 parts of ceramic microsphere,
3 parts of silane coupling agent,
1 part of heteropoly acid,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 60%.
Implementation result
The compression strength that the cement ground built up can bear is 300kpa.
Embodiment 2
The foam cement includes the substance of following parts by weight:
30 parts of modified acroleic acid epoxy resin,
Phosphatase 11 part,
10 parts of zinc powder,
3 parts of water,
13 parts of glycerine,
8 parts of polyvinyl alcohol,
60 parts of Iron-ore Slag,
15 parts of ceramic microsphere,
8 parts of silane coupling agent,
1 part of heteropoly acid,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 85%.
Implementation result
The compression strength that the cement ground built up can bear is 280kpa.
Embodiment 3
The foam cement includes the substance of following parts by weight:
26 parts of modified acroleic acid epoxy resin,
2 parts of phosphoric acid,
7 parts of zinc powder,
5 parts of water,
12 parts of glycerine,
9 parts of polyvinyl alcohol,
46 parts of Iron-ore Slag,
18 parts of ceramic microsphere,
4 parts of silane coupling agent,
2 parts of aluminium phosphate molecular sieve,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 75%.
Implementation result
The compression strength that the cement ground built up can bear is 270kpa.
Embodiment 4
The foam cement includes the substance of following parts by weight:
28 parts of modified acroleic acid epoxy resin,
2 parts of phosphoric acid,
7 parts of zinc powder,
7 parts of water,
12 parts of glycerine,
9 parts of polyvinyl alcohol,
50 parts of Iron-ore Slag,
24 parts of ceramic microsphere,
6 parts of silane coupling agent,
2 parts of phosphorus crow heteropoly acid sodium,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 65%.
Implementation result
The compression strength that the cement ground built up can bear is 300kpa.
Embodiment 5
The foam cement includes the substance of following parts by weight:
20 parts of modified acroleic acid epoxy resin,
3 parts of phosphoric acid,
3 parts of zinc powder,
3 parts of water,
12 parts of glycerine,
8 parts of polyvinyl alcohol,
44 parts of Iron-ore Slag,
22 parts of ceramic microsphere,
5 parts of silane coupling agent,
1 part of aluminium phosphate molecular sieve,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 70%.
Implementation result
The compression strength that the cement ground built up can bear is 310kpa.
Embodiment 6
The foam cement includes the substance of following parts by weight:
26 parts of modified acroleic acid epoxy resin,
2 parts of phosphoric acid,
7 parts of zinc powder,
6 parts of water,
12 parts of glycerine,
9 parts of polyvinyl alcohol,
40 parts of Iron-ore Slag,
24 parts of ceramic microsphere,
5 parts of silane coupling agent,
2 parts of aluminium phosphate molecular sieve,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 75%.
Implementation result
The compression strength that the cement ground built up can bear is 280kpa.
Embodiment 7
The foam cement includes the substance of following parts by weight:
29 parts of modified acroleic acid epoxy resin,
2 parts of phosphoric acid,
8 parts of zinc powder,
6 parts of water,
12 parts of glycerine,
9 parts of polyvinyl alcohol,
38 parts of Iron-ore Slag,
25 parts of ceramic microsphere,
5 parts of titanate coupling agent,
2 parts of phosphorus crow heteropoly acid,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 80%.
Implementation result
The compression strength that the cement ground built up can bear is 270kpa.
Embodiment 8
The foam cement includes the substance of following parts by weight:
20 parts of modified acroleic acid epoxy resin,
3 parts of phosphoric acid,
3 parts of zinc powder,
3 parts of water,
10 parts of glycerine,
8 parts of polyvinyl alcohol,
30 parts of Iron-ore Slag,
15 parts of ceramic microsphere,
3 parts of aluminium phosphate molecular sieve,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 65%.
Implementation result
The compression strength that the cement ground built up can bear is 210kpa.
Embodiment 9
The foam cement includes the substance of following parts by weight:
30 parts of modified acroleic acid epoxy resin,
Phosphatase 11 part,
9 parts of zinc powder,
7 parts of water,
12 parts of glycerine,
9 parts of polyvinyl alcohol,
39 parts of Iron-ore Slag,
24 parts of ceramic microsphere,
Wherein modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 is anti- It should obtain.
The mass concentration of phosphoric acid is 69%.
Implementation result
The compression strength that the cement ground built up can bear is 191kpa.
It these are only embodiments of the present invention, the description thereof is more specific and detailed, but can not therefore be interpreted as pair The limitation of the scope of the claims of the present invention.It should be pointed out that for those of ordinary skill in the art, not departing from the present invention Under the premise of design, various modifications and improvements can be made, these are all belonged to the scope of protection of the present invention.

Claims (5)

1. a kind of foam cement, which is characterized in that the foam cement includes the substance of following parts by weight:
20-30 parts of modified acroleic acid epoxy resin,
- 3 parts of phosphatase 11,
3-10 parts of zinc powder,
3-8 parts of water,
10-13 parts of glycerine,
8-10 parts of polyvinyl alcohol,
30-60 parts of Iron-ore Slag,
15-30 parts of ceramic microsphere,
Wherein, modified acroleic acid epoxy resin be 1,4,5,8- naphthalenetetracarbacidic acidics and acrylic acid epoxy resin in molar ratio 1:1 reaction It obtains.
2. a kind of foam cement according to claim 1, which is characterized in that further include 1-3 parts of catalyst, the catalyst For heteropoly acid, the sodium salt or aluminium phosphate molecular sieve of heteropoly acid.
3. foam cement according to claim 1, which is characterized in that the mass concentration of phosphoric acid is 60%-85%.
4. a foam cement according to claim 1, which is characterized in that further include 3-8 parts of coupling agent.
5. a kind of foam cement according to claim 4, which is characterized in that the coupling agent is preferably silane coupling agent.
CN201810603346.9A 2016-03-18 2016-03-18 A kind of foam cement Withdrawn CN108675684A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810603346.9A CN108675684A (en) 2016-03-18 2016-03-18 A kind of foam cement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201810603346.9A CN108675684A (en) 2016-03-18 2016-03-18 A kind of foam cement
CN201610155217.9A CN105801159B (en) 2016-03-18 2016-03-18 A kind of lathe ground for being established on the ground in weak soil

Related Parent Applications (1)

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CN201610155217.9A Division CN105801159B (en) 2016-03-18 2016-03-18 A kind of lathe ground for being established on the ground in weak soil

Publications (1)

Publication Number Publication Date
CN108675684A true CN108675684A (en) 2018-10-19

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CN201610155217.9A Active CN105801159B (en) 2016-03-18 2016-03-18 A kind of lathe ground for being established on the ground in weak soil

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1950311A (en) * 2004-04-30 2007-04-18 郭尚运 Foaming chemical grout
CN103351112A (en) * 2013-07-04 2013-10-16 陕西理工学院 Preparing method for high-strength light multihole construction waste composite
CN104176981A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Environmental-protection paving material
CN104176980A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Environment-friendly pressure-proof pavement material
CN105316988A (en) * 2014-08-05 2016-02-10 福建百花化学股份有限公司 Permeable terrace brick manufacturing method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013019642A2 (en) * 2011-07-29 2013-02-07 Calera Corporation Cement and concrete with reinforced material
RU2552730C2 (en) * 2013-04-26 2015-06-10 Евгений Николаевич Ястремский Dry mixture for making composite foam concrete

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1950311A (en) * 2004-04-30 2007-04-18 郭尚运 Foaming chemical grout
CN104176981A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Environmental-protection paving material
CN104176980A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Environment-friendly pressure-proof pavement material
CN103351112A (en) * 2013-07-04 2013-10-16 陕西理工学院 Preparing method for high-strength light multihole construction waste composite
CN105316988A (en) * 2014-08-05 2016-02-10 福建百花化学股份有限公司 Permeable terrace brick manufacturing method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
方来荣等: "《怎样生产和使用新型化学建筑材料》", 30 June 1993, 中国建筑工业出版社 *

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