CN101928118A - High-porosity epoxy resin pervious concrete - Google Patents
High-porosity epoxy resin pervious concrete Download PDFInfo
- Publication number
- CN101928118A CN101928118A CN2009100870333A CN200910087033A CN101928118A CN 101928118 A CN101928118 A CN 101928118A CN 2009100870333 A CN2009100870333 A CN 2009100870333A CN 200910087033 A CN200910087033 A CN 200910087033A CN 101928118 A CN101928118 A CN 101928118A
- Authority
- CN
- China
- Prior art keywords
- pervious concrete
- epoxy resin
- porosity
- epoxy
- aggregate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011380 pervious concrete Substances 0.000 title claims abstract description 35
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 17
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 17
- 239000002893 slag Substances 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 6
- 239000010959 steel Substances 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims description 30
- 229920005989 resin Polymers 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 9
- -1 aliphatic cyclic amine Chemical class 0.000 claims description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000006004 Quartz sand Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical group CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 2
- 150000008431 aliphatic amides Chemical class 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000004568 cement Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229960005191 ferric oxide Drugs 0.000 description 2
- 239000001062 red colorant Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Epoxy Resins (AREA)
Abstract
The invention provides high-porosity epoxy resin pervious concrete, which comprises the following components in part by mass: 100 parts of epoxy resin, 0-50 parts of reactive diluent, 20-80 parts of curing agent, 2,000-10,000 parts of aggregate and 0-30 parts of dye. The invention has the beneficial effects that (1) the pervious concrete with porosity of greater than 40% is prepared by using the epoxy resin as gel material; (2) the pervious concrete the maximum breaking strength of which is 12 MPa can be prepared, which can bear relatively large impact load and prevent the aggregate from falling compared with the cement-based pervious concrete; (3) when the steel slag is used as the aggregate, the steel slag can be used without special treatment; and (4) the pervious concrete with various colors can be prepared by adding the dye.
Description
Technical field
The present invention relates to a kind of pervious concrete, relating to a kind of specifically is the pervious concrete of gelling material with Resins, epoxy.
Background technology
Along with improving constantly of the level of urbanization, increasing urban ground is covered by closely knit fluid-tight concrete, has caused rainwater to permeate the ground like this, has influenced replenishing of urban groundwater when forming surface gathered water again, causes disruption of ecological balance.Pervious concrete is a kind of new concrete that is born for the watertightness that remedies normal concrete, and it is a kind of ecological environment-friendly type concrete, and what it was different with normal concrete is both to have had certain compression strength, has water-permeable and air permeable again.Chinese invention patent CN101190833A discloses a kind of pervious concrete and preparation method thereof, and this method is gelling material with cement, is aggregate with natural gravel or slag waste material.
Slag is a kind of waste residue that produces in the steelmaking process, because wherein contain free calcium oxide overbumt, after gelling material is hardened, generates calcium hydroxide with the water reaction, causes structure later stage volume to produce and expands, and can cause structural damage; Because the hardness of slag is very big, crushing and grinding gets up very difficult on the other hand, and the utilization of slag is as the roadbed bed course mostly at present, is not utilized widely.Pile up like a mountain for the slag of each steel mill at present, not only taken land resources, also causes the havoc of environmental pollution and natural landscape.
Chinese invention patent CN101050092A discloses a kind of preparation method of cement concrete with water permeability, has adopted slag as aggregate, but slag must adopt purifying, pulverizing and stage treatment.Chinese invention patent CN1891654A discloses a kind of slag that utilizes as the pervious concrete that gathers materials, but the free calcium oxide in the slag is had requirement, and content can not be greater than 5%, and this has just determined that its steel slag utilization face is very narrow.
The preparation of general pervious concrete is to be gelling material with cement, its porosity is generally below 20%, though good ultimate compression strength is arranged, but because cement is very weak to the cementability of aggregate, so the pervious concrete folding strength of preparing is lower, come off being impacted or can occur aggregate in use for some time, thereby cause the road surface uneven.Simultaneously,, therefore utilize the pervious concrete of cement production, adjust very difficulty of color because cement itself is coloured.
Summary of the invention
The objective of the invention is to propose a kind of employing Resins, epoxy is that gelling material prepares pervious concrete, its porosity can reach more than 40%, because Resins, epoxy all has very high bonding strength to aggregates such as cobble, rubble, slags, therefore prepared pervious concrete is except ultimate compression strength is higher, folding strength is also higher, bonding firm between aggregate and the aggregate, can bear higher shock load.Simultaneously, because used Resins, epoxy is transparent, therefore only need to add the pervious concrete that different pigment can prepare different colours.When using the slag aggregate, because water resistance is fine after the epoxy resin cure, the free calcium oxide of slag inside is not met water and can't be expanded, so slag need not special processing and promptly may be used among the present invention.
A kind of high-porosity epoxy resin pervious concrete of the present invention is made up of Resins, epoxy, reactive thinner, solidifying agent, aggregate, pigment, and its each constituent mass umber proportioning is:
Resins, epoxy: 100 parts
Reactive thinner: 0～50 part
Solidifying agent: 20～80 parts
Aggregate: 2000～10000 parts
Pigment: 0～30 part.
In the above-mentioned pervious concrete, described Resins, epoxy is liquid-state epoxy resins such as dihydroxyphenyl propane or Bisphenol F; Described reactive thinner is single epoxy group(ing) or bis-epoxy base reactive thinner; Described solidifying agent is transparent liquid epoxy curing agents such as polymeric amide, aliphatic cyclic amine or aliphatic amide; Described aggregate is quartz sand, cobble, rubble or steel slag particle; Described pigment is versicolor used for epoxy resin pigment.
Beneficial effect of the present invention is: (1) is that gelling material is prepared porosity greater than 40% pervious concrete with Resins, epoxy; (2) can prepare the pervious concrete that folding strength is up to 12MPa, compare, can bear bigger shock load, and aggregate can not come off with the cement based pervious concrete; When (3) utilizing slag as aggregate, slag need not special processing and can use; (4) by adding pigment, can prepare versicolor pervious concrete.
Embodiment
The present invention will be further described below in conjunction with specific embodiment, can prepare the pervious concrete of different performance, different colours according to the proportioning of following each embodiment.Following each embodiment only is used to the present invention is described but not limitation of the present invention.
Embodiment 1
Choose E44 Resins, epoxy 100kg, aliphatic cyclic amine solidifying agent 20kg, aggregate 5mm～15mm rubble 5000kg.Earlier Resins, epoxy and solidifying agent are mixed, add aggregate again and be stirred to all aggregate surfaces all by till the Resins, epoxy covering.Prepared pervious concrete porosity 41%, 28d folding strength 12MPa, color is the color of rubble itself.
Embodiment 2
Choose E51 Resins, epoxy 100kg, single epoxy group(ing) reactive thinner 20kg, polyamide curing agent 30kg, aggregate 5mm～15mm slag 7000kg.Earlier Resins, epoxy, reactive thinner, solidifying agent are mixed, add aggregate again and be stirred to all aggregate surfaces all by till the Resins, epoxy covering.Because used Resins, epoxy viscosity is lower, added simultaneously reactive thinner again, therefore (viscosity of Resins, epoxy is low more can to add more aggregate, it is thin more at the resin molding that aggregate surface forms, the needed amount of epoxy of identical aggregate is just few more, in other words, be exactly that the Resins, epoxy of same amount can add more aggregate).Prepared pervious concrete porosity 43%, 28d folding strength 8.5MPa.
Embodiment 3
Choose E44 Resins, epoxy 100kg, bis-epoxy base reactive thinner 50kg, fatty amine curing agent 80kg, aggregate 3mm～5mm quartz sand 2000kg, 400 order ferric oxide red colorant 20kg.Earlier Resins, epoxy, reactive thinner, solidifying agent are mixed, add ferric oxide red colorant again and stir, then add aggregate and be stirred to all aggregate surfaces all by till the Resins, epoxy covering.Prepared pervious concrete is red, porosity 45%, 28d folding strength 7.5MPa.
Embodiment 4
Choose bisphenol F epoxy resin 100kg, aliphatic cyclic amine solidifying agent 30kg, aggregate 5mm～15mm cobble 6500kg.Earlier Resins, epoxy and solidifying agent are mixed, add aggregate again and be stirred to all aggregate surfaces all by till the Resins, epoxy covering.Prepared pervious concrete porosity 41%, 28d folding strength 10.5MPa, color is the color of cobble itself.
Claims (6)
1. a high-porosity epoxy resin pervious concrete is characterized in that, comprises following component and be by the mass fraction proportioning:
Resins, epoxy: 100 parts
Reactive thinner: 0～50 part
Solidifying agent: 20～80 parts
Aggregate: 2000～10000 parts
Pigment: 0～30 part.
2. high-porosity epoxy resin pervious concrete according to claim 1 is characterized in that, described Resins, epoxy is dihydroxyphenyl propane or Bisphenol F liquid-state epoxy resin.
3. high-porosity epoxy resin pervious concrete according to claim 2 is characterized in that, described reactive thinner is single epoxy group(ing) or bis-epoxy base reactive thinner.
4. high-porosity epoxy resin pervious concrete according to claim 3 is characterized in that, described solidifying agent is polymeric amide, aliphatic cyclic amine or aliphatic amide transparent liquid epoxy curing agent.
5. according to arbitrary described high-porosity epoxy resin pervious concrete among the claim 1-4, it is characterized in that described aggregate is quartz sand, cobble, rubble or steel slag particle.
6. high-porosity epoxy resin pervious concrete according to claim 5 is characterized in that, described pigment is versicolor used for epoxy resin pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910087033 CN101928118B (en) | 2009-06-22 | 2009-06-22 | High-porosity epoxy resin pervious concrete |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910087033 CN101928118B (en) | 2009-06-22 | 2009-06-22 | High-porosity epoxy resin pervious concrete |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101928118A true CN101928118A (en) | 2010-12-29 |
| CN101928118B CN101928118B (en) | 2013-03-27 |
Family
ID=43367607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910087033 Expired - Fee Related CN101928118B (en) | 2009-06-22 | 2009-06-22 | High-porosity epoxy resin pervious concrete |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101928118B (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102424548A (en) * | 2011-09-19 | 2012-04-25 | 宁波曙翔铁路设备制造有限公司 | Anchoring material |
| CN103253893A (en) * | 2013-04-12 | 2013-08-21 | 同济大学 | Pavement thin layer rapid repair material |
| CN103496887A (en) * | 2013-09-13 | 2014-01-08 | 天津大学 | Epoxy resin zirconium tungstate concrete and preparation method thereof |
| CN103922642A (en) * | 2014-03-28 | 2014-07-16 | 中冶建筑研究总院有限公司 | Large-mixing amount steel slag epoxy grouting material for low-temperature construction as well as preparation method and application thereof |
| CN105316988A (en) * | 2014-08-05 | 2016-02-10 | 福建百花化学股份有限公司 | Permeable terrace brick manufacturing method |
| CN106116259A (en) * | 2016-06-23 | 2016-11-16 | 中设设计集团股份有限公司 | A kind of colored Self-leveling porous footpath face material and preparation method |
| CN106495563A (en) * | 2016-10-19 | 2017-03-15 | 山西省交通科学研究院 | A kind of environmental protection freeze-thawing resistant type porous pavement pavement material and preparation method thereof |
| CN107352905A (en) * | 2017-07-21 | 2017-11-17 | 江苏燕宁新材料科技发展有限公司 | A kind of pervious concrete |
| CN107572885A (en) * | 2017-08-21 | 2018-01-12 | 福建省正丰数控科技有限公司 | It is a kind of to utilize the method for making steel tailings casting bed piece |
| CN107759131A (en) * | 2017-08-21 | 2018-03-06 | 福建省正丰数控科技有限公司 | It is a kind of to utilize the bed piece for making steel tailings casting |
| CN107759172A (en) * | 2017-11-09 | 2018-03-06 | 安徽工业大学 | A kind of aqueous epoxy resins are modified pervious concrete material |
| CN108178576A (en) * | 2017-12-30 | 2018-06-19 | 孙祎 | The preparation method of ceramic tile is imitated in a kind of resistance to compression |
| CN108609917A (en) * | 2018-06-07 | 2018-10-02 | 安徽匠星联创新材料科技有限公司 | A kind of epoxy resin pervious ground surface material and preparation method thereof |
| CN109401709A (en) * | 2018-11-19 | 2019-03-01 | 福州皇家地坪有限公司 | Compound permeable terrace material |
| CN109896777A (en) * | 2019-04-23 | 2019-06-18 | 哈尔滨工业大学 | A kind of preparation method of road epoxy resin concrete |
| CN110204251A (en) * | 2019-06-14 | 2019-09-06 | 吉林建筑大学 | A kind of neo-epoxy resin concrete material and preparation method thereof |
| CN110357538A (en) * | 2019-08-01 | 2019-10-22 | 西安新意达建筑制品有限公司 | A kind of regeneration self-compacting concrete and preparation method thereof |
| CN111041925A (en) * | 2018-10-12 | 2020-04-21 | 仁创生态环保科技股份有限公司 | On-site-made water permeable ground and preparation method thereof |
| CN113250033A (en) * | 2021-06-04 | 2021-08-13 | 张浩燃 | Construction process of modified permeable terrace |
| CN113563010A (en) * | 2021-08-13 | 2021-10-29 | 长安大学 | Steel slag asphalt mixture and preparation method thereof |
| CN113880500A (en) * | 2021-10-29 | 2022-01-04 | 武汉理工大学 | High-stability tailing sand-based epoxy resin water-permeable material and preparation method thereof |
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| CN1274626C (en) * | 2004-04-13 | 2006-09-13 | 中国水利水电第十一工程局勘测设计院 | Epoxy resin mortar and preparation method |
| CN101186468A (en) * | 2007-12-27 | 2008-05-28 | 王军 | Epoxy modified unsaturated resin concrete for road and bridge |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1994955A (en) * | 2005-12-26 | 2007-07-11 | 秦升益 | Weatherable water-permeable material and its uses |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102424548A (en) * | 2011-09-19 | 2012-04-25 | 宁波曙翔铁路设备制造有限公司 | Anchoring material |
| CN103253893A (en) * | 2013-04-12 | 2013-08-21 | 同济大学 | Pavement thin layer rapid repair material |
| CN103253893B (en) * | 2013-04-12 | 2015-06-10 | 同济大学 | Pavement thin layer rapid repair material |
| CN103496887A (en) * | 2013-09-13 | 2014-01-08 | 天津大学 | Epoxy resin zirconium tungstate concrete and preparation method thereof |
| CN103922642B (en) * | 2014-03-28 | 2017-02-01 | 中冶建筑研究总院有限公司 | Large-mixing amount steel slag epoxy grouting material for low-temperature construction as well as preparation method and application thereof |
| CN103922642A (en) * | 2014-03-28 | 2014-07-16 | 中冶建筑研究总院有限公司 | Large-mixing amount steel slag epoxy grouting material for low-temperature construction as well as preparation method and application thereof |
| CN105316988A (en) * | 2014-08-05 | 2016-02-10 | 福建百花化学股份有限公司 | Permeable terrace brick manufacturing method |
| CN106116259A (en) * | 2016-06-23 | 2016-11-16 | 中设设计集团股份有限公司 | A kind of colored Self-leveling porous footpath face material and preparation method |
| CN106495563A (en) * | 2016-10-19 | 2017-03-15 | 山西省交通科学研究院 | A kind of environmental protection freeze-thawing resistant type porous pavement pavement material and preparation method thereof |
| CN107352905A (en) * | 2017-07-21 | 2017-11-17 | 江苏燕宁新材料科技发展有限公司 | A kind of pervious concrete |
| CN107352905B (en) * | 2017-07-21 | 2020-02-11 | 江苏燕宁新材料科技发展有限公司 | Pervious concrete |
| CN107572885A (en) * | 2017-08-21 | 2018-01-12 | 福建省正丰数控科技有限公司 | It is a kind of to utilize the method for making steel tailings casting bed piece |
| CN107759131A (en) * | 2017-08-21 | 2018-03-06 | 福建省正丰数控科技有限公司 | It is a kind of to utilize the bed piece for making steel tailings casting |
| CN107759172A (en) * | 2017-11-09 | 2018-03-06 | 安徽工业大学 | A kind of aqueous epoxy resins are modified pervious concrete material |
| CN108178576A (en) * | 2017-12-30 | 2018-06-19 | 孙祎 | The preparation method of ceramic tile is imitated in a kind of resistance to compression |
| CN108609917B (en) * | 2018-06-07 | 2021-01-05 | 安徽匠星联创新材料科技有限公司 | Epoxy resin water permeable pavement material and preparation method thereof |
| CN108609917A (en) * | 2018-06-07 | 2018-10-02 | 安徽匠星联创新材料科技有限公司 | A kind of epoxy resin pervious ground surface material and preparation method thereof |
| CN111041925A (en) * | 2018-10-12 | 2020-04-21 | 仁创生态环保科技股份有限公司 | On-site-made water permeable ground and preparation method thereof |
| CN109401709A (en) * | 2018-11-19 | 2019-03-01 | 福州皇家地坪有限公司 | Compound permeable terrace material |
| CN109896777A (en) * | 2019-04-23 | 2019-06-18 | 哈尔滨工业大学 | A kind of preparation method of road epoxy resin concrete |
| CN109896777B (en) * | 2019-04-23 | 2021-11-05 | 哈尔滨工业大学 | Preparation method of epoxy resin concrete for roads |
| CN110204251A (en) * | 2019-06-14 | 2019-09-06 | 吉林建筑大学 | A kind of neo-epoxy resin concrete material and preparation method thereof |
| CN110357538B (en) * | 2019-08-01 | 2021-09-24 | 西安新意达建筑制品有限公司 | Regenerated self-compacting concrete and preparation method thereof |
| CN110357538A (en) * | 2019-08-01 | 2019-10-22 | 西安新意达建筑制品有限公司 | A kind of regeneration self-compacting concrete and preparation method thereof |
| CN113250033A (en) * | 2021-06-04 | 2021-08-13 | 张浩燃 | Construction process of modified permeable terrace |
| CN113563010A (en) * | 2021-08-13 | 2021-10-29 | 长安大学 | Steel slag asphalt mixture and preparation method thereof |
| CN113880500A (en) * | 2021-10-29 | 2022-01-04 | 武汉理工大学 | High-stability tailing sand-based epoxy resin water-permeable material and preparation method thereof |
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