CN109694215A - A kind of water-permeable brick and preparation method thereof using solid waste preparation - Google Patents

A kind of water-permeable brick and preparation method thereof using solid waste preparation Download PDF

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Publication number
CN109694215A
CN109694215A CN201910060257.9A CN201910060257A CN109694215A CN 109694215 A CN109694215 A CN 109694215A CN 201910060257 A CN201910060257 A CN 201910060257A CN 109694215 A CN109694215 A CN 109694215A
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CN
China
Prior art keywords
water
permeable
parts
slag
permeable brick
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Pending
Application number
CN201910060257.9A
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Chinese (zh)
Inventor
常秀丽
李海泉
华雷广
赵自远
孙春磊
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Shandong Jinyi City Construction Ltd By Share Ltd
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Shandong Jinyi City Construction Ltd By Share Ltd
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Priority to CN201910060257.9A priority Critical patent/CN109694215A/en
Publication of CN109694215A publication Critical patent/CN109694215A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/22Pavings made of prefabricated single units made of units composed of a mixture of materials covered by two or more of groups E01C5/008, E01C5/02 - E01C5/20 except embedded reinforcing materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of water-permeable bricks and preparation method thereof using solid waste preparation, water-permeable brick surface layer is prepared as cementitious matter using resinous material, industrial residue, industrial waste etc. is used to prepare porous base course as coarse-fine aggregate, the technical indicators such as the adhesive strength of surface layer, weatherability are further promoted using materials such as the curing agent of good hydrophilic property, ecological ground-slag, meter Shi, light stabilizers simultaneously, prepare the environment friendly pervious brick of a kind of high-weatherability, good water permeability.Its flexural strength >=4.5Mpa of water-permeable brick, mill hole length≤32mm, (15 DEG C) of coefficient of permeability are greater than 7.8 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, no losing fangle, flawless, color difference and layering etc., and loss of strength≤15%, after being used 4 years, water penetration declines≤5%, and production cost substantially reduces, and raw material are easy to get, ecological, environmental protective.

Description

A kind of water-permeable brick and preparation method thereof using solid waste preparation
Technical field
The present invention relates to a kind of water-permeable bricks and preparation method thereof using solid waste preparation, are related to construction material neck Domain.
Background technique
A large amount of stackings of solid waste, not only seriously destroy ecological environment, endanger human health, but also are to money A kind of waste in source.With the quickening of China's modernization construction and production paces, building waste, industrial waste increasingly increase.It builds The main composition of building refuse includes soil, dregs, mortar, masonry, broken concrete etc., and industrial residue substantial amounts are many kinds of, Complicated component handles relative difficulty.It piles up for a long time, can not only occupy a large amount of soil, can also cause dirt to ecological environment Dye.
Currently, most of water-permeable bricks are all the main skies by between sandstone using natural rubble as main resource in China Gap realizes pervious function, and the water-permeable brick compression strength is generally relatively low, and water penetration is little in First Year variation, but in sleet sky Gas when encountering muddy water, since the mud in muddy water can block the gap inside water-permeable brick, substantially reduces water permeability, influences Road traffic, some roads even just lose pervious function less than year completely.
Resin-bonded water-permeable brick simple production process, but price is high, and influences its service life due to the aging of resin, Cement base water-permeable brick, raw material are mainly the natural resources such as sandstone, need largely to exploit natural soft-clay, are unfavorable for ecological environment Protection.
Summary of the invention
The present invention overcomes above-mentioned the deficiencies in the prior art, provide a kind of water-permeable brick using solid waste preparation and its Preparation method, the present invention prepare water-permeable brick surface layer as cementitious matter using resinous material, are made with industrial residue, industrial waste etc. Porous base course is prepared for coarse-fine aggregate, while using materials such as the curing agent of good hydrophilic property, ecological ground-slag, meter Shi, light stabilizers The technical indicators such as adhesive strength, weatherability for further promoting surface layer, through reasonable design mixture proportion, prepare a kind of high-weatherability, The environment friendly pervious brick of good water permeability, and production cost is low.
A kind of water-permeable brick prepared using solid waste, including permeable surface layer and porous base course, the permeable surface layer are pressed Component and parts by weight are as follows:
It is 4-8 parts of resin, 40-60 parts of meter Shi, ecological ground-slag 15-25 parts, 3-6 parts of water, 3.5-7.4 parts of curing agent, anti-oxidant 0.1-0.5 parts and pigment 3-8 parts of agent;
The component and parts by weight of the porous base course are as follows:
5 parts of cement, ecological ground-slag 20-30 parts, 15-20 parts of building waste, 30-45 parts of grain slag, permeable reinforcing agent 2-5 parts, 3-8 parts of water.
It is raw material using the solid waste such as building waste and industrial residue, waste material, prepares resin water-permeable brick, reach useless The purpose of object comprehensive utilization, solution contaminated land environment, reduction natural resource utilizing;The conducts such as industrial residue, building waste Coarse aggregate replaces sandstone, and ecological ground-slag replaces cement etc. as cementitious material, passes through the optimum mix of aggregate and cementitious material Realize permeable and flexural strength optimal combination;In order to improve water penetration, the weatherability of product, using resinous material as face The cementing material of layer, is added suitable curing agent, suitable light stabilizer is added in Lai Tigao water penetration, and the weather-proof of brick can be improved Property technical indicator, while the persistence of color can be enhanced.
Further, the resin is one of epoxy resin, polyurethane resin.
Further, the rice stone grain diameter is 20-40 mesh.
Further, the ecological ground-slag is metal smelt waste residue, through fine powder made of grinding, fineness 20%.
Further, the building waste be the substances such as discarded concrete, waste bricks etc. quality than mixture, warp Partial size is 5-25mm after broken.
Further, the curing agent is amine curing agent, is one of polyamines such as polyamide, phenolic aldehyde amine.
Further, the antioxidant is antioxidant 1010.
Further, the pigment is iron oxide red, Huang, black etc..
Further, the permeable reinforcing agent is powdery, the production of Beijing Dechang great achievement architectural engineering technology Co., Ltd Permeable reinforcing agent, model DC-C3 has that intensity is high, bonding force is big, additive amount is small, cement consumption is few, at low cost etc. excellent Point.The workability of pervious bed can be improved using it, enhance water penetration, improve the durability and later strength of water-permeable brick.
A method of it prepares by the water-permeable brick of above-mentioned formula composition, includes the following steps:
1) it prepares permeable surface material: meter Shi and ecological ground-slag, water successively being added according to aforementioned proportion, stirred evenly, Obtain mixture 1;
Epoxy resin, polyamide, antioxidant 1010, pigment are successively mixed into addition according to aforementioned proportion, stirred evenly, Obtain mixture 2;
The mixture 1 and mixture 2 of acquisition mix, and stir evenly, obtain permeable surface material;
2) grain slag, ecological ground-slag, building waste, permeable reinforcing agent and water are sequentially added according to aforementioned proportion, mixing is stirred It mixes uniformly, obtains permeable base materials
3) permeable surface material and permeable base materials are placed according to the ratio of mass ratio 1:9-11 with secondary material distributing Molding is prepared in 2001 full automatic production equipment of jaguar of system.
The utility model has the advantages that
(1) first by meter Shi and ecological ground-slag, the mixture 1 that water pretreatment obtains, it is possible to increase resin is bonding with mixture 1 Intensity greatly promotes wearability and water penetration.
(2) the porous and water imbibition of grain slag, ecological ground-slag, building waste itself, can avoid permeable gap hole by dust or Mud blocking, enhances the resistance to soiling and water permeable ability of environment friendly pervious brick, light-weight, and intensity is high, good water permeability.
(3) production cost substantially reduces, and raw material are easy to get, ecological, environmental protective.
(4) its flexural strength >=4.5Mpa of the water-permeable brick prepared, mill hole length≤32mm, coefficient of permeability (15 DEG C) are big In 7.8 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, no losing fangle, flawless, color Difference and layering etc., loss of strength≤15%.After being used 4 years, water penetration decline≤5%.
Specific embodiment
Embodiment 1:
A kind of water-permeable brick prepared using solid waste, including permeable surface layer and porous base course, the permeable surface layer by It is prepared by the raw material of following mass fraction: 6 parts of epoxy resin, 20 parts of ecological ground-slag, and 50 parts of meter Shi, 4 parts of water, 5 parts of polyamide, antioxygen 10100.2 parts and 5 parts of pigment of agent;The porous base course is prepared by the raw material of following mass fraction: 30 parts of ecological ground-slag, cement 5 parts, 35 parts of grain slag, 17 parts of building waste, 3 parts, 5 parts of water of the permeable reinforcing agent agent of DC-C3 type.
1) it prepares permeable surface material: meter Shi and ecological ground-slag, water successively being added according to aforementioned proportion, stirred evenly, Obtain mixture 1;
Epoxy resin, polyamide, antioxidant 1010, pigment are successively mixed into addition according to aforementioned proportion, stirred evenly, Obtain mixture 2;
The mixture 1 and mixture 2 of acquisition mix, and stir evenly, obtain permeable surface material;
2) water-permeable brick base material is prepared: by grain slag, ecological ground-slag, building waste, permeable reinforcing agent and water according to above-mentioned Ratio sequentially adds, and is mixed evenly, and obtains permeable base materials;
3) permeable surface material and permeable base materials are placed according to the ratio of mass ratio 1:11 with secondary material distributing system Molding is prepared in 2001 full automatic production equipment of jaguar of system, preparation process: permeable base materials cloth -- striking off ----vibration Dynamic molding --- permeable surface material cloth ----strike off ----vibration moulding --- -- demoulding --- -- steam curing --- packing --- Natural curing ----finished product.
Prepared water-permeable brick has following performance indicator: flexural strength 5.0Mpa, and mill hole length is 29mm, coefficient of permeability (15 DEG C) are 7.9 × 10-2cm/s;After freezing and thawing test, presentation quality is split without front ixoderm and defect, no losing fangle, nothing Line, color difference and layering etc., loss of strength 13%.After the water-permeable brick is used 4 years, (15 DEG C) of coefficient of permeability are 7.6 × 10- 2cm/s。
Embodiment 2:
A kind of water-permeable brick prepared using solid waste, including permeable surface layer and porous base course, the permeable surface layer by Prepared by the raw material of following mass fraction: 4 parts of polyurethane, 25 parts of ecological ground-slag is 53 parts of meter Shi, 5 parts of water, 4 parts of phenolic aldehyde amine, anti-oxidant 10100.5 parts and 7 parts of pigment of agent;The porous base course is prepared by the raw material of following mass fraction: 25 parts of ecological ground-slag, cement 5 Part, 40 parts of grain slag, 20 parts of building waste, 2 parts, 4 parts of water of the permeable reinforcing agent agent of DC-C3 type.
1) it prepares permeable surface material: meter Shi and ecological ground-slag, water successively being added according to aforementioned proportion, stirred evenly, Obtain mixture 1;
Polyurethane, phenolic aldehyde amine, antioxidant 1010, pigment are successively mixed into addition according to aforementioned proportion, stirs evenly, obtains To mixture 2;
The mixture 1 and mixture 2 of acquisition mix, and stir evenly, obtain permeable surface material;
2) permeable base materials are prepared: by grain slag, ecological ground-slag, building waste, permeable reinforcing agent and water according to above-mentioned ratio Example sequentially adds, and is mixed evenly, and obtains water-permeable brick base material;
3) permeable surface material and permeable base materials are placed according to the ratio of mass ratio 1:11 with secondary material distributing system Molding is prepared in 2001 full automatic production equipment of jaguar of system, preparation process: permeable base materials cloth -- striking off ----vibration Dynamic molding --- permeable surface material cloth ----strike off ----vibration moulding --- -- demoulding --- -- steam curing --- packing --- Natural curing ----finished product.
Prepared water-permeable brick has following performance indicator: flexural strength 4.8Mpa, and mill hole length is 30mm, coefficient of permeability (15 DEG C) are 8 × 10-2cm/s;After freezing and thawing test, presentation quality without front ixoderm and defect, no losing fangle, flawless, Color difference and layering etc., loss of strength 14%.After the water-permeable brick is used 4 years, (15 DEG C) of coefficient of permeability are 7.7 × 10-2cm/s。
Comparative example 1:
The water-permeable brick prepared according to the method for embodiment 1, unlike, ecological ground-slag replaces with cement.
Water-permeable brick prepared by comparative example 1 has following performance indicator: flexural strength 4.5Mpa, and mill hole length is 31mm, thoroughly (15 DEG C) of water coefficient are 7.9 × 10-2cm/s;After freezing and thawing test, presentation quality is fallen without front ixoderm and defect, no truncation Angle, flawless, color difference and layering etc., loss of strength 14%.After the water-permeable brick is used 4 years, (15 DEG C) of coefficient of permeability are 7.2 ×10-2cm/s。
Compared with Example 1, ecological ground-slag is replaced by ordinary cement, and the flexural strength of product decreases, mill hole length Degree becomes larger, and wearability reduces, and frost resistance is declined, and coefficient of permeability is also declined, and ordinary cement unit price is 450 yuan/ton, and The unit price of ecological ground-slag is 200 yuan/ton, and cost is significantly raised.Either technical indicator or economic indicator, ecological ground-slag generation There is apparent advantage for cement.
Comparative example 2:
The water-permeable brick prepared according to the method for embodiment 1, unlike: meter Shi and ecological ground-slag, water are not mixed first Object 1, but be directly mixed evenly with resin, prepare permeable surface layer.
Prepared water-permeable brick has following performance indicator: flexural strength 4.8Mpa, and mill hole length is 35mm, coefficient of permeability (15 DEG C) are 6.2 × 10-2cm/s;After freezing and thawing test, presentation quality is split without front ixoderm and defect, no losing fangle, nothing Line, color difference and layering etc., loss of strength 16%.After the water-permeable brick is used 4 years, (15 DEG C) of coefficient of permeability are 5.7 × 10- 2cm/s。
Compared with Example 1, the flexural strength of product decreases, and mill hole length obviously becomes larger, and wearability reduces, freeze proof Property is decreased obviously, and coefficient of permeability is decreased obviously.The viscous of resin and mixture 1 can be obviously improved after ecological ground-slag and the pretreatment of rice stone Intensity is connect, wearability is obviously improved, and water penetration increases.

Claims (10)

1. a kind of water-permeable brick prepared using solid waste, including permeable surface layer and porous base course, the group of the permeable surface layer Point and parts by weight are as follows:
4-8 parts of resin, 40-60 parts of meter Shi, ecological ground-slag 15-25 parts, 3-6 parts of water, 3.5-7.4 parts of curing agent, antioxidant 0.1-0.5 parts and pigment 3-8 parts;
The component and parts by weight of the porous base course are as follows:
5 parts of cement, ecological ground-slag 20-30 parts, 15-20 parts of building waste, 30-45 parts of grain slag, permeable reinforcing agent 2-5 parts, water 3-8 Part.
2. water-permeable brick according to claim 1, which is characterized in that the resin is epoxy resin, in polyurethane resin One kind.
3. water-permeable brick according to claim 1, which is characterized in that the rice stone grain diameter is 20-40 mesh.
4. water-permeable brick according to claim 1, which is characterized in that the ecological ground-slag is metal smelt waste residue, fineness For less than 20%.
5. water-permeable brick according to claim 1, which is characterized in that the building waste is discarded concrete, discarded brick Block etc. quality than mixture, partial size 5-25mm.
6. water-permeable brick according to claim 1, which is characterized in that the curing agent is polynary amine curing agent.
7. water-permeable brick according to claim 1, which is characterized in that the antioxidant is antioxidant 1010.
8. water-permeable brick according to claim 1, which is characterized in that the pigment be iron oxide red, Huang, it is black in one Kind.
9. water-permeable brick according to claim 1, which is characterized in that the permeable reinforcing agent is powdery, and Beijing Dechang is big The production of industry architectural engineering technology Co., Ltd, model DC-C3.
10. a kind of method of the water-permeable brick as described in preparation any one of claim 1-9, which comprises the steps of:
1) ecological ground-slag being crushed as 20-40 mesh, meter Shi and ecological ground-slag, water are successively added according to aforementioned proportion, it stirs evenly, Obtain mixture 1;
Resin, curing agent, antioxidant 1010, pigment are successively mixed into addition according to aforementioned proportion, stirs evenly, is mixed Object 2;
The mixture 1 and mixture 2 of acquisition mix, and stir evenly, obtain permeable surface material;
2) grain slag, ecological ground-slag, building waste, permeable reinforcing agent and water are sequentially added according to aforementioned proportion, is mixed equal It is even, obtain permeable base materials;
3) permeable surface material and permeable base materials are placed in production equipment according to the ratio of mass ratio 1:9-11 and are prepared into Type.
CN201910060257.9A 2019-01-22 2019-01-22 A kind of water-permeable brick and preparation method thereof using solid waste preparation Pending CN109694215A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110903053A (en) * 2019-11-07 2020-03-24 阜阳市鑫源建材有限公司 Method for preparing water permeable brick from construction waste
CN110981308A (en) * 2019-12-18 2020-04-10 四川德胜绿色新材料科技有限公司 Preparation method of light ash concrete hollow partition board
CN115417621A (en) * 2022-08-11 2022-12-02 中国电建集团西北勘测设计研究院有限公司 Method for preparing water permeable brick by using waste rubber and construction waste and application of water permeable brick

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110903053A (en) * 2019-11-07 2020-03-24 阜阳市鑫源建材有限公司 Method for preparing water permeable brick from construction waste
CN110981308A (en) * 2019-12-18 2020-04-10 四川德胜绿色新材料科技有限公司 Preparation method of light ash concrete hollow partition board
CN115417621A (en) * 2022-08-11 2022-12-02 中国电建集团西北勘测设计研究院有限公司 Method for preparing water permeable brick by using waste rubber and construction waste and application of water permeable brick

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