CN107324716A - A kind of resistant water-permeable brick of natural-like stone and preparation method thereof - Google Patents

A kind of resistant water-permeable brick of natural-like stone and preparation method thereof Download PDF

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Publication number
CN107324716A
CN107324716A CN201710437937.9A CN201710437937A CN107324716A CN 107324716 A CN107324716 A CN 107324716A CN 201710437937 A CN201710437937 A CN 201710437937A CN 107324716 A CN107324716 A CN 107324716A
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parts
water
permeable
fine aggregate
resistant
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CN107324716B (en
Inventor
么传杰
常秀丽
韩金涛
齐建忠
兹修超
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Shandong Jinyi Energy Saving Building Material Co Ltd
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Shandong Jinyi Energy Saving Building Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/06Pavings made of prefabricated single units made of units with cement or like binders
    • E01C5/065Pavings made of prefabricated single units made of units with cement or like binders characterised by their structure or component materials, e.g. concrete layers of different structure, special additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention provides a kind of resistant water-permeable brick of natural-like stone and preparation method thereof, resistant water-permeable brick of the invention, including the permeable surface layer of resistant and porous base course, and the permeable surface layer of resistant is prepared by the raw material of following mass fraction:10 15 parts of cement, 0.5 2 parts of aqueous binders, modified 65 75 parts of fine aggregate, 38 parts of 2 4.5 parts of water, 1.5 2 parts of impregnating agent and pigment;The porous base course is prepared by the raw material of following mass fraction:15 25 parts of flyash, 5 10 parts of cement, 10 20 parts of carbide slag, 5 15 parts of clinker, 15 20 parts of building waste, 24 parts of impregnating agent, 38 parts of water.The mass ratio of the permeable surface layer of resistant and porous base course is 1:7.5 8.5, the modified fine aggregate by one or more of fine aggregates in granite fragment, Dali flag, quartz sand, silica sand be modified after obtain.Water-permeable brick of the present invention has the advantages that the imitative stone material that high, wear-resisting fouling resistance rating, good water permeability, intensity are high, cost is low, surface is smooth is attractive in appearance.

Description

A kind of resistant water-permeable brick of natural-like stone and preparation method thereof
Technical field
The present invention relates to resistant water-permeable brick of a kind of natural-like stone and preparation method thereof, belong to building material field.
Background technology
As the important ring in sponge urban construction system, road surface water-permeable brick plays huge effect.In sponge city In the construction spring tide in city, its market prospects is extremely wide.Water-permeable brick has the following advantages that:With good permeable, permeability, Rainwater can be made to rapidly permeate into underground, the supplement soil water and underground water, soil moisture is kept, improve urban ground plant and soil is micro- Biological life condition;Absorbable moisture and heat, adjust the humiture of earth's surface local space, to regulation urban microclimate, delay Solution urban heat land effect plays the role of larger;Municipal drainage and pressure of flood, the pollution to preventing public waters and place can be mitigated Reason sewage has good effect;It is non-slip after not ponding after rain, snow, convenient trip;Surface is in minute asperities, prevents road surface anti- Light, absorbs the noise produced when vehicle is exercised, can improve the comfortableness and security of vehicle pass-through.
At present, in China, most of water-permeable bricks are typically with natural rubble, building waste, slag waste material etc. for main resource. In order that water-permeable brick obtains preferable water penetration, particles used particle diameter can not be too big, if but particle particle diameter it is smaller, prepare Water-permeable brick insufficient strength, often both can not get both for water penetration and intensity.Moreover, the section of waste concrete particle is rougher, Even with the water-permeable brick prepared by the less waste concrete particle of particle diameter out, its water penetration is also not so good.In First Year Change is little, but in sleety weather, when especially running into muddy water, the seam that can be blocked inside water-permeable brick due to the mud in muddy water Gap, substantially reduces water permeability.Water penetration can decline 50% in the 2nd~3 year.And currently common water-permeable brick surface layer it is coarse, dull, Aesthetics is poor.Therefore needing exploitation, water permeability is more preferable, more attractive practical water-permeable brick.
Although lithotome be used for lay square or street, it is sturdy and durable, with society it is growing, country to ore deposit The increasing of mountain resource exploitation supervision and the increasingly anxiety of rock material resource, make the use cost more and more higher of lithotome, It is unpractical to be used for municipal administration consumption using lithotome in majority cities.And the research of permeable imitative Stone brick will overcome with Upper defect, reduces the waste of natural resources, while significantly reducing cost.Therefore, the water penetration of natural-like stone is researched and developed The good water-permeable brick of energy is highly desirable to.
The content of the invention
It is an object of the invention to solve currently common water-permeable brick easily to be blocked by sludge water etc., wear no resistance, permeable effect There is provided resistant water-permeable brick of a kind of natural-like stone and preparation method thereof for the problems such as difference, aesthetics are not enough.The water-permeable brick has resistance to The advantages of imitative stone material that dirty grade is high, wear-resisting, good water permeability, intensity high, cost is low, surface is smooth is attractive in appearance.
To achieve the above object, the technical solution adopted by the present invention is, a kind of resistant water-permeable brick of natural-like stone, including The permeable surface layer of resistant and porous base course, the permeable surface layer of resistant are prepared by the raw material of following mass fraction:10-15 parts of cement, 0.5-2 parts of aqueous binders, modified 65-75 parts of fine aggregate, 3-8 parts of 2-4.5 parts of water, 1.5-2 parts of impregnating agent and pigment;It is described Water-base is prepared by the raw material of following mass fraction:15-25 parts of flyash, 5-10 parts of cement, 10-20 parts of carbide slag, clinker 5- 15 parts, 15-20 parts of building waste, 2-4 parts of impregnating agent, 3-8 parts of water.
The mass ratio of the permeable surface layer of resistant and porous base course is 1:7.5-8.5, preferably 1:8.
The modified fine aggregate by fine aggregate be modified after obtain;The fine aggregate be granite fragment, Dali flag, One or more in quartz sand, silica sand, particle diameter is 40-80 mesh.
It the ratio of each component is in the modified fine aggregate, coagulant:Aqueous binders:Fine aggregate=1:5:800, antioxygen The volume of agent is the 0.1%-0.5% of aqueous binders.
The preparation method of the modified fine aggregate is:Fine aggregate is put into mixer, added a small amount of (30% or so) Aqueous binders be stirred, be gradually added into remaining aqueous binders and antioxidant, stir, be eventually adding rush solidifying Agent continues to stir 5-10 minutes, you can obtain being modified fine aggregate.
The aqueous binders are:SBT-SP103E aqueous epoxy resins.
Preparation technology is as follows:
(1) modified fine aggregate is prepared
Fine aggregate is put into mixer, the aqueous binders for then adding a small amount of (30% or so) are stirred, by Remaining aqueous binders and antioxidant are gradually added, is stirred, coagulant is eventually adding and continues to stir 5-10 minutes, you can Obtain being modified fine aggregate.
(2) the permeable surface layer material of resistant is prepared:First cement, modified fine aggregate, pigment are mixed and mixed thoroughly, add water and Aqueous binders, impregnating agent are stirred with mixer, standby;
(3) porous base course material is prepared:It is first that flyash, cement, carbide slag, clinker, building waste stirring mixing is equal It is even, add water and stirred with impregnating agent with mixer, it is standby;
(4) it is molded:The material feeding fabric material distributing machine of step (2) and step (3) is started into cloth, shaping of vibrating is molded.
(5) it is molded permeable adobe and enters maintenance in curing kilns.
Each raw material and index:
Cement:Strength of cement grade is the portland cement or Portland cement of 42.5 grades and the above.
Pigment:Pigment is inorganic pigment, powdered, and iron oxide is red, yellow, blue, green, black etc..
Flyash:Meet《GBT 1596-2005》For the flyash in cement and concrete.
Carbide slag:Calcium carbide hydrolysis obtains the waste residue using calcium hydroxide as main component after acetylene gas, and water content is 8- 12%.Trace element meets construction main body material technical requirements not less than discharge standard, radioactivity in carbide slurry.
Clinker:Meet《GBT 18046-2008》For the ground granulated blast furnace slag in cement and concrete.
Building waste:Discarded brick, waste concrete block pass through aggregate of the standby particle diameter of crushing mechanism for 3-5mm.
Impregnating agent:The impregnating agent of Beijing Dechang great achievement architectural engineering technology Co., Ltd production, model:DC-C3, with strong Degree is high, bonding force is big, addition is small, cement consumption is few, low cost and other advantages.The workability of pervious bed can be improved using it, is increased High permeability, improves the durability and later strength of water-permeable brick.
Water-permeable brick of the present invention has following technical indicator:
Strength grade CC50, mill hole length 30mm, (15 DEG C) of coefficient of permeability is more than 7.5 × 10-2cm/s;Freezing and thawing test Afterwards, presentation quality is without front ixoderm and defect, no losing fangle, flawless, aberration and layering etc., and loss of strength is less than 14%. About 3%-5% is reduced using water permeability after 3 years.
Water-permeable brick of the present invention has the advantages that:
(1) there is the water permeability of long timeliness
Water-permeable brick of the present invention is by destroying the surface tension of water come permeable, and surface is very fine and close, therefore, is difficult to be blocked up by dust Extremely, the water penetration with long timeliness.
(2) there is high intensity and aesthetics
Fine aggregate is modified using aqueous adhesive, improves the boundary strength of cement and fine aggregate, while enhancing is permeable The surface layer intensity of brick.Therefore, water-permeable brick of the present invention has the outward appearance of the light cleaning of similar lithotome, there is high intensity again And abrasion resistance.
(3) surface layer is pollution-free is not easily blocked
By, the surface smoother of brick modified to fine aggregate, its surface will not form pit or projection, therefore, brick Surface is easily cleaned, and debris is not had and blocks pore.The function of rainwater retaining, water conservation and purified treatment can be reached.Pass through GB/ The stain resistance grade that T9780-2013 evaluates the sample brick is 0 grade, and surface layer is pollution-free.
The resistance to soiling of water-permeable brick surface layer depends primarily on the height and surface defect (pin hole, crackle, pit of its consistency Deng) number, consistency is higher, and surface defect is fewer, and its resistance to soiling is better.Original water-permeable brick, its surface is often relatively thicker It is rough, defect is more and particle inside there is increased number of stomata, this is the basic reason for causing resistance to soiling difference not easy to clean.In the present invention Just because of the fine aggregate using natural material, after being modified, the high surface of smooth, consistency is obtained, therefore with very Good resistance to soiling and property easy to clean.
(4) raw material sources enrich, and preparation technology is simply easily controllable, are adapted to large-scale production, wide market.
Embodiment
Technical scheme and its produced technique effect are further elaborated with reference to specific method, The description below is merely to explain the present invention, but the present invention is not any limitation as in any way, based on present invention teach that being made Any conversion or replacement, belong to protection scope of the present invention.The method of the invention is this area unless otherwise specified Conventional method.Agents useful for same unless otherwise specified, can be obtained from commercial channels.
Embodiment 1
A kind of resistant water-permeable brick of natural-like stone, including the permeable surface layer of resistant and porous base course, the permeable face of resistant Layer is prepared by the raw material of following mass fraction:12 parts of cement, 1 part of aqueous binders, modified 70 parts of fine aggregate, 3 parts of water, impregnating agent 1.5 parts and 5 parts of pigment;The porous base course is prepared by the raw material of following mass fraction:20 parts of flyash, 8 parts of cement, carbide slag 15 parts, 10 parts of clinker, 17 parts of building waste, 3 parts of impregnating agent, 5 parts of water.
The ratio of the permeable surface layer of resistant and porous base course is 1:8.
Preparation technology is as follows:
(1) modified fine aggregate is prepared
According to coagulant:Aqueous binders:Fine aggregate=1:5:800th, the volume of antioxidant is aqueous binders 0.3% ratio, fine aggregate (granite fragment, particle diameter is 40-80 mesh) is put into mixer, then added a small amount of (30%) aqueous binders are stirred, and are gradually added into remaining aqueous binders and antioxidant, are stirred, and are finally added Enter coagulant to continue to stir 5-10 minutes, you can obtain being modified fine aggregate.
(2) the permeable surface layer material of resistant is prepared:Modification fine aggregate, the pigment for first preparing cement, step (1) are mixed and mixed It is even, add water and aqueous binders, impregnating agent are stirred with mixer, it is standby.
(3) porous base course material is prepared:It is first that flyash, cement, carbide slag, clinker, building waste stirring mixing is equal It is even, add water and stirred with impregnating agent with mixer, it is standby.
(4) it is molded:The material feeding fabric material distributing machine of step (2) and step (3) is started into cloth, shaping of vibrating is molded.
(5) it is molded permeable adobe and enters maintenance in curing kilns.
Prepared water-permeable brick has following performance indications:Compression strength 55.0Mpa, mill hole length is 29mm, permeable system (15 DEG C) of number is 7.5 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, no losing fangle, nothing Crackle, aberration and layering etc., loss of strength are 14%.The water-permeable brick is through using after 3 years, (15 DEG C) of coefficient of permeability is 7.1 × 10- 2Cm/s, fouling resistance rating is 0 grade.
Embodiment 2
A kind of resistant water-permeable brick of natural-like stone, including the permeable surface layer of resistant and porous base course, the permeable face of resistant Layer is prepared by the raw material of following mass fraction:10 parts of cement, 0.8 part of aqueous binders, modified 65 parts of fine aggregate, 2.5 parts of water, thoroughly 5 parts of 1.5 parts of aqua and pigment;The porous base course is prepared by the raw material of following mass fraction:15 parts of flyash, 5 parts of cement, electricity 15 parts of rock ballast, 15 parts of clinker, 20 parts of building waste, 3 parts of impregnating agent, 5 parts of water.
The ratio of the permeable surface layer of resistant and porous base course is 1:8.
Preparation technology is as follows:
(1) modified fine aggregate is prepared
According to coagulant:Aqueous binders:Fine aggregate=1:5:800th, the volume of antioxidant is aqueous binders 0.4% ratio, fine aggregate (marble chip, particle diameter is 40-80 mesh) is put into mixer, then added a small amount of (29%) aqueous binders are stirred, and are gradually added into remaining aqueous binders and antioxidant, are stirred, and are finally added Enter coagulant to continue to stir 5-10 minutes, you can obtain being modified fine aggregate.
(2) the permeable surface layer material of resistant is prepared:Modification fine aggregate, the pigment for first preparing cement, step (1) are mixed and mixed It is even, add water and aqueous binders, impregnating agent are stirred with mixer, it is standby.
(3) porous base course material is prepared:It is first that flyash, cement, carbide slag, clinker, building waste stirring mixing is equal It is even, add water and stirred with impregnating agent with mixer, it is standby.
(4) it is molded:The material feeding fabric material distributing machine of step (2) and step (3) is started into cloth, shaping of vibrating is molded.
(5) it is molded permeable adobe and enters maintenance in curing kilns.
Prepared water-permeable brick has following performance indications:Compression strength 53.0Mpa, mill hole length is 31mm, permeable system (15 DEG C) of number is 8.0 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, no losing fangle, nothing Crackle, aberration and layering etc., loss of strength are 13%.The water-permeable brick is through using after 3 years, (15 DEG C) of coefficient of permeability is 7.6 × 10- 2Cm/s, fouling resistance rating is 0 grade.
Embodiment 3
A kind of resistant water-permeable brick of natural-like stone, including the permeable surface layer of resistant and porous base course, the permeable face of resistant Layer is prepared by the raw material of following mass fraction:15 parts of cement, 1.5 parts of aqueous binders, modified 70 parts of fine aggregate, 3.5 parts of water, thoroughly 5 parts of 2 parts of aqua and pigment;The porous base course is prepared by the raw material of following mass fraction:25 parts of flyash, 5 parts of cement, calcium carbide 10 parts of slag, 10 parts of clinker, 15 parts of building waste, 3 parts of impregnating agent, 5 parts of water.
The ratio of the permeable surface layer of resistant and porous base course is 1:8.
Preparation technology is as follows:
(1) modified fine aggregate is prepared
According to coagulant:Aqueous binders:Fine aggregate=1:5:800th, the volume of antioxidant is aqueous binders 0.5% ratio, fine aggregate (granite fragment and marble chip equivalent, particle diameter are 40-80 mesh) is put into mixer, Then the aqueous binders for adding a small amount of (32%) are stirred, and are gradually added into remaining aqueous binders and antioxidant, are stirred Mix uniform, be eventually adding coagulant and continue to stir 5-10 minutes, you can obtain being modified fine aggregate.
(2) the permeable surface layer material of resistant is prepared:Modification fine aggregate, the pigment for first preparing cement, step (1) are mixed and mixed It is even, add water and aqueous binders, impregnating agent are stirred with mixer, it is standby.
(3) porous base course material is prepared:It is first that flyash, cement, carbide slag, clinker, building waste stirring mixing is equal It is even, add water and stirred with impregnating agent with mixer, it is standby.
(4) it is molded:The material feeding fabric material distributing machine of step (2) and step (3) is started into cloth, shaping of vibrating is molded.
(5) it is molded permeable adobe and enters maintenance in curing kilns.
Prepared water-permeable brick has following performance indications:Compression strength 56.5Mpa, mill hole length is 27mm, permeable system (15 DEG C) of number is 7.7 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, no losing fangle, nothing Crackle, aberration and layering etc., loss of strength are 14%.The water-permeable brick is through using after 3 years, (15 DEG C) of coefficient of permeability is 7.4 × 10- 2Cm/s, fouling resistance rating is 0 grade.
Comparative example 1
Method according to embodiment 1 prepares the water-permeable brick of natural-like stone, unlike, fine aggregate is without modification, powder Directly used after broken.
Water-permeable brick prepared by comparative example 1 has following performance indications:Compression strength 46.3Mpa, mill hole length is 33mm, thoroughly (15 DEG C) of water coefficient is 6.6 × 10-2cm/s;After freezing and thawing test, presentation quality is fallen without front ixoderm and defect, no truncation Angle, flawless, aberration and layering etc., loss of strength are 16%.The water-permeable brick is through using after 3 years, (15 DEG C) of coefficient of permeability is 3.0 ×10-2Cm/s, fouling resistance rating is 2 grades.
And the water-permeable brick prepared by embodiment 1 has following performance indications:Compression strength 55.0Mpa, mill cheats length and is 29mm, (15 DEG C) of coefficient of permeability is 7.5 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, nothing Losing fangle, flawless, aberration and layering etc., loss of strength are 14%.The water-permeable brick is after using 3 years, coefficient of permeability (15 DEG C) it is 7.1 × 10-2Cm/s, fouling resistance rating is 0 grade.
Embodiment 1 is can be seen that by being modified to fine aggregate by comparing, and greatly improves the bonding between fine aggregate Intensity, the water-permeable brick of preparation has larger wearability and resistance to soiling, therefore, after use in 3 years, the coefficient of permeability of embodiment 1 Conservation rate is far above comparative example 1.
Comparative example 2
Method according to embodiment 1 prepares the water-permeable brick of natural-like stone, unlike, the aqueous bonding of modified fine aggregate The non-aqueous resins that agent is changed to equal quality are replaced, and reference natural-like stone water-permeable brick is made.
Water-permeable brick prepared by comparative example 2 has following performance indications:Compression strength 47.5Mpa, mill hole length is 32mm, (15 DEG C) of coefficient of permeability is 6.7 × 10-2cm/s;After freezing and thawing test, presentation quality is fallen without front ixoderm and defect, no truncation Angle, flawless, aberration and layering etc., loss of strength are 15%.The water-permeable brick is through using after 3 years, (15 DEG C) of coefficient of permeability is 3.6 ×10-2Cm/s, fouling resistance rating is 2 grades.
And the water-permeable brick prepared by embodiment 1 has following performance indications:Compression strength 55.0Mpa, mill cheats length and is 29mm, (15 DEG C) of coefficient of permeability is 7.5 × 10-2cm/s;After freezing and thawing test, presentation quality is without front ixoderm and defect, nothing Losing fangle, flawless, aberration and layering etc., loss of strength are 14%.The water-permeable brick is after using 3 years, coefficient of permeability (15 DEG C) it is 7.1 × 10-2Cm/s, fouling resistance rating is 0 grade.
By comparing as can be seen that embodiment 1 is different from the only binding agent of comparative example 2, prepared water-permeable brick possesses difference Performance.Through the water-permeable brick for being far above comparative example 1 using its coefficient of permeability of the water-permeable brick of embodiment 1 after 3 years.And comparative example 1 (2 grades) of fouling resistance rating is less than embodiment 1 (0 grade).
The present inventor analysis using non-aqueous resins prepare natural-like stone water permeability coefficient of water permeable brick, resistance to soiling difference Reason is probably that after non-aqueous resins solidify, can cause there is the burr formed after binding agent solidification in brick internal microcellular structure, Burr easily adsorbs the pore of pollutant, so as to cause its water penetration and resistance to soiling poor.
The resistance to of the natural-like stone water-permeable brick prepared in embodiment 1-3 and comparative example 1,2 is evaluated by GB/T9780-2013 Contamination grade, rating is as shown in table 1 below.
Table 1
Stain resistance grade/level Pollution level Perception aberration Gray card grade/level
0 It is pollution-free Without noticeable aberration 5
1 It is very slight There is firm noticeable aberration 4
2 Slightly There is obvious aberration 3
3 It is medium There is apparent aberration 2
4 Seriously There is serious aberration 1
Comparative example 3
Water-permeable brick, the water-permeable brick of the embodiment 1 of application number 201610367940.3 of embodiment 1-3, comparative example 1-2 preparation And the performance indications contrast of commercially available water-permeable brick.As shown in table 2.
Table 2
It is best by comparing the water-permeable brick intensity highest that can be seen that the present invention, anti-pollution characteristic.Water-permeable brick of the present invention due to Surface layer is fine and close, and the compare water-permeable brick of application number 201610367940.3 of water permeability is declined slightly, but the present invention's is permeable Water permeability reduction degree is lower after brick is used 3 years, water permeability reduction about 15%- after water-permeable brick is used 3 years in this application 16%;Water permeability reduction about 3%-5% after water-permeable brick of the present invention is used 3 years.And water-permeable brick compression strength of the present invention is higher, Above all water-permeable brick anti-pollution characteristic of the invention improves 2 grades by comparison.
As can be seen here, water-permeable brick of the present invention is compared with other water-permeable bricks, natural-like stone resistant water-permeable brick of the invention Higher than common water-permeable brick compression strength, resistance to soiling is more preferable, while good water permeability, degree is declined more using water permeability after 3 years It is low, the advantages of permeable time limit is longer.

Claims (8)

1. a kind of resistant water-permeable brick of natural-like stone, it is characterized in that, including the permeable surface layer of resistant and porous base course, the resistant Permeable surface layer is prepared by the raw material of following mass fraction:10-15 parts of cement, 0.5-2 parts of aqueous binders, modified fine aggregate 65- 75 parts, 3-8 parts of 2-4.5 parts of water, 1.5-2 parts of impregnating agent and pigment;The porous base course is prepared by the raw material of following mass fraction: 15-25 parts of flyash, 5-10 parts of cement, 10-20 parts of carbide slag, 5-15 parts of clinker, 15-20 parts of building waste, impregnating agent 2-4 Part, 3-8 parts of water.
2. the resistant water-permeable brick of natural-like stone as claimed in claim 1, it is characterized in that, the permeable surface layer of resistant and permeable The mass ratio of basic unit is 1:7.5-8.5.
3. the resistant water-permeable brick of natural-like stone as claimed in claim 2, it is characterized in that, the permeable surface layer of resistant and permeable The mass ratio of basic unit is 1:8.
4. the resistant water-permeable brick of natural-like stone as claimed in claim 1, it is characterized in that, the modified fine aggregate is by fine aggregate Obtained after being modified;
The fine aggregate is the one or more in granite fragment, Dali flag, quartz sand, silica sand, and particle diameter is 40-80 mesh.
5. the resistant water-permeable brick of natural-like stone as claimed in claim 4, it is characterized in that, each component in the modified fine aggregate Proportioning be, coagulant:Aqueous binders:Fine aggregate=1:5:800, the volume of antioxidant is the 0.1%- of aqueous binders 0.5%.
6. the resistant water-permeable brick of natural-like stone as claimed in claim 5, it is characterized in that, the preparation side of the modified fine aggregate Method is:Fine aggregate is put into mixer, a small amount of aqueous binders is added and is stirred, is gradually added into remaining aqueous viscous Agent and antioxidant are tied, is stirred, coagulant is eventually adding and continues to stir 5-10 minutes, you can obtain being modified fine aggregate.
7. the resistant water-permeable brick of natural-like stone as claimed in claim 1, it is characterized in that, the aqueous binders are:SBT- SP103E aqueous epoxy resins.
8. a kind of method for the resistant water-permeable brick for preparing natural-like stone, it is characterized in that, processing step is as follows:
(1) modified fine aggregate is prepared
Fine aggregate is put into mixer, a small amount of aqueous binders is then added and is stirred, be gradually added into remaining water Property binding agent and antioxidant, stir, being eventually adding coagulant continues to stir 5-10 minutes, you can obtain being modified thin bone Material;
(2) the permeable surface layer material of resistant is prepared:First cement, modified fine aggregate, pigment are mixed and mixed thoroughly, water is added and aqueous Binding agent, impregnating agent are stirred with mixer, standby;
(3) porous base course material is prepared:First flyash, cement, carbide slag, clinker, building waste are uniformly mixed, then Add water and stirred with impregnating agent with mixer, it is standby;
(4) it is molded:The material feeding fabric material distributing machine of step (2) and step (3) is started into cloth, shaping of vibrating is molded;
(5) it is molded permeable adobe and enters maintenance in curing kilns.
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CN108341687A (en) * 2018-04-27 2018-07-31 太原理工大学 A kind of preparation method of high-performance level cloth water-permeable brick
CN108484003A (en) * 2018-01-05 2018-09-04 四川内师检验检测有限责任公司 It is a kind of to utilize building castoff water-permeable brick method
CN109133768A (en) * 2018-07-12 2019-01-04 江苏宏发海绵城市科技有限公司 A kind of odorless stone material of high antibacterial and preparation method thereof
CN109320150A (en) * 2018-11-23 2019-02-12 云南新平恒泰新型材料科技有限公司 A kind of PC stone imitation material water-permeable brick and its preparation process
CN109400040A (en) * 2018-12-19 2019-03-01 阜阳市鑫源建材有限公司 A kind of anti-blocking water-permeable brick and preparation method thereof
CN110272232A (en) * 2018-03-16 2019-09-24 焦作诺尔曼炉业有限公司 A kind of permeable building block in road surface of environmental protection and preparation method thereof
CN110981290A (en) * 2019-11-07 2020-04-10 阜阳市鑫源建材有限公司 Stain-resistant water permeable brick
CN110981402A (en) * 2019-12-25 2020-04-10 齐河艺林景观工程有限公司 High-strength stone-like brick and preparation method thereof
CN111039605A (en) * 2019-12-31 2020-04-21 仁创生态环保科技股份有限公司 Stone-like water permeable brick and preparation method thereof
CN112174582A (en) * 2020-08-26 2021-01-05 北京鼎创科技环保集团有限公司 Method for producing imitation stone from waste granite
CN112876212A (en) * 2021-03-15 2021-06-01 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN113416461A (en) * 2021-08-10 2021-09-21 温州恒福新型建材有限公司 Natural stone imitated stain-resistant water permeable brick and preparation method thereof
CN113501678A (en) * 2021-08-10 2021-10-15 温州恒福新型建材有限公司 Novel stone-imitated ecological water permeable brick and preparation method thereof

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CN107721242A (en) * 2017-11-28 2018-02-23 王德元 A kind of rapid hardening gunite concrete
CN108484003A (en) * 2018-01-05 2018-09-04 四川内师检验检测有限责任公司 It is a kind of to utilize building castoff water-permeable brick method
CN110272232A (en) * 2018-03-16 2019-09-24 焦作诺尔曼炉业有限公司 A kind of permeable building block in road surface of environmental protection and preparation method thereof
CN108341687B (en) * 2018-04-27 2021-03-26 太原理工大学 Preparation method of high-performance layered distribution water permeable brick
CN108341687A (en) * 2018-04-27 2018-07-31 太原理工大学 A kind of preparation method of high-performance level cloth water-permeable brick
CN109133768A (en) * 2018-07-12 2019-01-04 江苏宏发海绵城市科技有限公司 A kind of odorless stone material of high antibacterial and preparation method thereof
CN109320150A (en) * 2018-11-23 2019-02-12 云南新平恒泰新型材料科技有限公司 A kind of PC stone imitation material water-permeable brick and its preparation process
CN109400040A (en) * 2018-12-19 2019-03-01 阜阳市鑫源建材有限公司 A kind of anti-blocking water-permeable brick and preparation method thereof
CN110981290A (en) * 2019-11-07 2020-04-10 阜阳市鑫源建材有限公司 Stain-resistant water permeable brick
CN110981402A (en) * 2019-12-25 2020-04-10 齐河艺林景观工程有限公司 High-strength stone-like brick and preparation method thereof
CN111039605A (en) * 2019-12-31 2020-04-21 仁创生态环保科技股份有限公司 Stone-like water permeable brick and preparation method thereof
CN112174582A (en) * 2020-08-26 2021-01-05 北京鼎创科技环保集团有限公司 Method for producing imitation stone from waste granite
CN112876212A (en) * 2021-03-15 2021-06-01 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN112876212B (en) * 2021-03-15 2021-09-28 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN113416461A (en) * 2021-08-10 2021-09-21 温州恒福新型建材有限公司 Natural stone imitated stain-resistant water permeable brick and preparation method thereof
CN113501678A (en) * 2021-08-10 2021-10-15 温州恒福新型建材有限公司 Novel stone-imitated ecological water permeable brick and preparation method thereof
CN113416461B (en) * 2021-08-10 2021-12-21 温州恒福新型建材有限公司 Natural stone imitated stain-resistant water permeable brick and preparation method thereof
CN113501678B (en) * 2021-08-10 2022-01-07 温州恒福新型建材有限公司 Stone-like ecological water permeable brick and preparation method thereof

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