CN103922642B - Large-mixing amount steel slag epoxy grouting material for low-temperature construction as well as preparation method and application thereof - Google Patents

Large-mixing amount steel slag epoxy grouting material for low-temperature construction as well as preparation method and application thereof Download PDF

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CN103922642B
CN103922642B CN201410130801.XA CN201410130801A CN103922642B CN 103922642 B CN103922642 B CN 103922642B CN 201410130801 A CN201410130801 A CN 201410130801A CN 103922642 B CN103922642 B CN 103922642B
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parts
grouting
powder
epoxy
epoxy resin
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CN103922642A (en
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任恩平
杨晓光
高汉青
陈夙
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Beijing New Vision Building Construction Technology Co Ltd
Central Research Institute of Building and Construction Co Ltd MCC Group
China Jingye Engineering Corp Ltd
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Beijing New Vision Building Construction Technology Co Ltd
Central Research Institute of Building and Construction Co Ltd MCC Group
China Jingye Engineering Corp Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention provides a large-mixing amount steel slag epoxy grouting material for low-temperature construction. The material is suitable for basic grouting of equipment having a vibration requirement, and particularly for grouting under a low-temperature environment. The large-mixing amount steel slag epoxy grouting material is prepared from the following raw materials in parts by mass: 2-4 parts of a binder, 1 part of a curing component and 15-20 parts of a powder material, wherein the binder consists of epoxy resin, a diluent, a flexibilizer and a coupling agent; the curing agent consists of a curing agent and a catalyst; the powder material consists of steel slag powder and steel slag aggregates. The large-mixing amount steel slag epoxy grouting material provided by the invention has the beneficial effects that (1) the material can be used under a low-temperature environment at the temperature of 0-5 DEG C; (2) the grouting material has the advantages of good fluidity, good thermal stability, good volume stability and the like; (3) the grouting material can be used for realizing full and compact grouting without vibration; (4) by adopting a large quantity of industrial wastes, namely steel slag, the grouting material disclosed by the invention is energy-saving and environment-friendly.

Description

Large dosage slag epoxy grouting material for low-temperature construction and preparation method thereof and Application
Technical field
The invention belongs to building material technology application, it is related to a kind of large dosage slag epoxy for low-temperature construction and fills Pulp material and its preparation method and application, compared with common epoxy grouting material, this material has steel slag content greatly it is adaptable to have The equipment Foundations grouting that vibration requires, reinforcing grouting especially under low temperature environment.
Background technology
Grouting material, since the nineties in 20th century at home popularization and application, has been widely used in numerous large and medium-sized enterprise In equipment installation, bolt anchoring, and the strengthening and rebuilding engineering of building structure, its range is also gradually from single metallurgical row Industry is extended to the industries such as municipal administration, environmental protection, electric power, harbour comprehensively.
The spies such as epoxy resin has that adhesion strength is high, can solidify in room temperature, high mechanical properties and corrosion resistance and good Point, is therefore widely used in the multiple fields such as electronics, machinery, building as binding agent, coating, grouting material etc..Asphalt mixtures modified by epoxy resin Lipid grouting material is current using the chemical classes grouting material more larger than wide, amount ratio.Such material has shock resistance Good toughness, can absorb vibrational energy, thus is widely used in the grouting of electronics material equipment Foundations and reinforcing.But asphalt mixtures modified by epoxy resin Solidification under low-temperature construction environment for the fat is slow, has had a strong impact on efficiency of construction, and then limits under low-temperature construction environment The application of epoxiess chemical grouting material.
Because epoxy resin oneself viscosity ratio is larger, the binding agent as grouting material generally needed to be added activity dilution Agent.Furfural-acetone system dilution effect is good, is the diluent more commonly used.Chinese patent literature 87105255.5, 01107590.2 and 201010598220.0 etc. discloses a series of asphalt mixtures modified by epoxy resin with furfural-acetone system as reactive diluent Lipid grouting material, these materials have excellent mechanical property, but furfural-acetone class reactive diluent high volatility, poison Property is larger, using being increasingly subject to strict restriction.Chinese patent literature cn102070873a employs (+)-2,3-Epoxy-1-propanol ethers chemical combination Thing have developed a kind of epoxide resin grouting material of environmental protection flexible as diluent, this material small toxicity, excellent in mechanical performance, material Material pliability is good, but (+)-2,3-Epoxy-1-propanol ethers compound is expensive, substantially increases the use cost of epoxy grouting material.In State patent documentation cn102898075a disclose a kind of high-strength consolidate epoxy resin grouting material soon, this material is in laboratory environment Lower intensity is higher, development fast and the adhesion strength height of base material, good endurance, the features such as prepare simple, but be room temperature Can, the effect under low-temperature construction environment is unsatisfactory.
Since entering 21st century, China's steel industry fast development, create substantial amounts of discarded slag, cause to environment Huge pressure, and still increased with more than one hundred million every year tons of speed.How effectively to solve the comprehensive utilization of garbage, reduce ring Border pressure is so as to turning waste into wealth is recycling economy and sustainable development important topic.
In sum, it is developed for that epoxy grouting material under low-temperature construction environment is now particularly important, this material can fill Divide and absorb vibrational energy, improve the impact resistance of grout blanket;Meanwhile, can widely apply industrial residue again, for example steel-making slag powder and Granule, turns waste into wealth, and can be widely applied to the infrastructure grouting of the industries such as oil, chemical industry, papermaking, electronics and reinforcement adds Gu.
Content of the invention
In order to solve above-mentioned technical problem defect, it is an object of the invention to provide the large dosage slag ring for low-temperature construction Oxygen grouting material and its preparation method and application, this material uses under 0~5 DEG C of low temperature environment, easy construction, curing rate Hurry up, stable long-term strength, high with basic adhesion strength, steel slag content is big, and low toxic and environment-friendly is prepared simple.
For achieving the above object, the present invention adopts the following technical scheme that
According to an aspect of the present invention, there is provided a kind of large dosage slag epoxy grouting material for low-temperature construction, press Mass parts meter, its raw material includes:
2~4 parts of binding agent
1 part of curing component
15~20 parts of powder
Wherein, described binding agent is made up of epoxy resin, diluent, toughener and coupling agent, and forms as follows:
Described curing component is made up of firming agent and catalyst, and forms as follows:
20~40 parts of firming agent
1~3 part of catalyst
Described powder is made up of steel-making slag powder and slag aggregate, and forms as follows:
150~250 parts of steel-making slag powder
300~400 parts of slag aggregate.
In a preferred embodiment of the present invention, the large dosage epoxy grouting material for low-temperature construction of the present invention, its It is characterised by, in parts by mass, its raw material includes:
2~4 parts of binding agent
1 part of curing component
15~20 parts of powder
Wherein, described binding agent is made up of epoxy resin, diluent, toughener and coupling agent, and forms as follows:
Described curing component is made up of firming agent and catalyst, and forms as follows:
25~32 parts of firming agent
1.5~2.5 parts of catalyst
Described powder is made up of steel-making slag powder and slag aggregate, and forms as follows:
150~250 parts of steel-making slag powder
300~400 parts of slag aggregate.
The thermosetting of epoxy adhesive is higher, and the viscosity of itself is higher, is not easy to grouting construction, above-mentioned by adding Appropriate reactive diluent, can reduce the viscosity of epoxy resin, be easy to improve construction workability;After equipment investment runs, produce Raw vibration ratio is larger, thus also requires that Grouting Materials have higher impact flexibility, above-mentioned appropriate by adding Toughener, can improve the fatigue toughness of epoxy material further;The solidification rate of common epoxy resin is slower, by temperature shadow Sound is higher, and particularly under low temperature environment, solidification is slower, by adding above-mentioned appropriate catalyst, can accelerate epoxy resin Hardening, is easy to low-temperature construction.
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: when described epoxy resin is 25 DEG C Viscosity is less than 20000mpa s and Bisphenol-a Epoxy Resin between 0.32~0.55mol/100g for the epoxide number (for example E41, e44 and e51), Bisphenol-f epoxy resin (such as f51, f44) and bis-phenol ad type aliphatic glycidyl ether epoxy resin One or more of;
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described diluent is viscous when 25 DEG C The reactive diluent less than 25mpa s for the degree, and it is selected from butyl glycidyl ether, BDO bisglycidyl ether, second One or more of Hexanediol diglycidyl ether and polypropylene glycol diglycidyl ether;
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described toughener is non-epoxy type Thiorubber., carbamate one or more of polymers and modified polyether in advance, wherein, thiorubber. can be jly- 121st, one or more of jly-124, jlg-200, jly155 and jly215, modified polyether can be methylallyl alcohol polyoxy One or more of vinyl Ether, propylene polyoxyethylenated alcohol and methoxy polyoxyethylene ether.
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described coupling agent is silane coupled Agent, is selected from one or more of si133, si143, si151 and si171;
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described firming agent is amine number 300 One or more of the aliphatic amide of~600mg koh/g, the fatty amine containing aromatic rings and the amide containing aromatic rings, its In, aliphatic amide can be in polyenanthoamide, poly capryllactam, nylon 9, nylon 11 and nylon 12 One or more, the fatty amine containing aromatic rings can be for dodecyl polyaniline, to n-butyl aniline, 2- methyl -5 isopropyl aniline One or more of, the amide containing aromatic rings can for Benzoylamide, propenyl benzene amide, to methoxy benzamide, adjacent first One or more of yl acetamide, phydroxybenzeneactamide.
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described catalyst comprises alkali metal Hydroxide and selected from containing one or more of dicarboxyl quaternary ammonium salt and sulfonamide.
Large dosage slag Low-temperature epoxy grouting material as above it is characterised in that: described powder is slag metallic iron Content≤2%, the specific surface area >=200m of steel-making slag powder2/ kg, the slag that slag aggregate is 0.001~3mm continuous grading for particle diameter Granule;
According to a further aspect in the invention, present invention also offers the described large dosage slag epoxy for low-temperature construction fills The preparation method of pulp material it is characterised in that: (1) presses mass parts, take respectively 100 parts of epoxy resin, 5~15 parts of diluent, 10 ~20 parts of toughener and 1~2 part of coupling agent, each raw material is put in blender, continuous mix and blend 5~10 minutes, and mix is equal Even, obtain binding agent;
(2) press mass parts, take 20~40 parts of firming agent and 1~3 part of catalyst respectively, each raw material is put in blender, Continuous mix and blend 5~10 minutes, mix uniformly, obtains curing component;
(3) press mass parts, take 150~250 parts of steel-making slag powder and 300~400 parts of slag aggregates respectively, each raw material is put into and stirs Mix in machine, continuous mix and blend 5~10 minutes, mix uniformly, obtains powder.
In accordance with a further aspect of the present invention, present invention also offers being used for the large dosage slag of low-temperature construction as above The application of epoxy grouting material, applies the construction method of this material to include: during construction, by mass parts, by 2~4 parts of binding agent Put in forced stirrer with 1 part of curing component, stir, then 15~20 parts of powder is put into wherein, mix homogeneously; Uniformly the equipment Foundations grouting having vibration to require realized by mixed grouting material using deadweight method, especially under low temperature environment Equipment Foundations are in the milk.In construction, in mixed process, the concrete mass fraction of binding agent, curing component and powder is according to ring Working condition when border temperature and construction can suitably adjust, to meet construction requirement.
The invention has the beneficial effects as follows:
(1) present invention using low-temperature catalyzed technology so that the grouting material being configured to makes under 0~5 DEG C of low temperature environment With.
(2) present invention has good fluidity (initial flow degree >=270mm, 30min fluidity retention >=240mm), morning By force (when 5 DEG C, 10h comprcssive strength >=5mpa, when 20 DEG C, 10h comprcssive strength >=60mpa), high-strength (28d comprcssive strength >= 100mpa), good (thermal coefficient of expansion≤4 × 10 of heat stability-6Mm/mm/ DEG C), volume stability good (linear shrinkage ratio < 0.05%) Deng feature performance benefit.
(3) present invention be not required to vibrate just can reach grouting full closely knit.
(4) grouting material of the present invention adopts a large amount of trade waste slags, energy-conserving and environment-protective.
Specific embodiment
The present invention is expanded on further below in conjunction with specific embodiment, embodiments below be merely to illustrate the present invention rather than Limitation of the present invention.Performance test methods press existing national standards " cement-based grouting material application technology code " gb/ T50448-2008 executes.
Embodiment 1:
Proportioning raw materials are as follows:
3 parts of binding agent
1 part of curing component
18 parts of powder
Wherein:
Binding agent forms: epoxy resin e41(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 18000mpa s and epoxide number 0.41mol/100g) 100 parts, 10 parts of butyl glycidyl ether (when 25 DEG C, viscosity is 20mpa s), carbamate gathers in advance 10 parts of thing (Shanghai China biochemical plant), si133(Yueyang petrochemical industry) 1 part;
Curing component forms: 22 parts of 2- methyl -5 isopropyl aniline (amine number is 450mg koh/g, Shanghai plumage sail chemical industry), 0.5 part of sodium hydroxide, 0.5 part of alkyl dimethyl carboxyethyl quaternary ammonium salt (Shanxi Xin Tianyuan chemical industry, amine number is 400mg koh/g); Methanesulfomide (Shanghai to prosperous chemical industry, amine number is 310mg koh/g)
Powder forms: steel-making slag powder (iron content 1.4%, specific surface area 348m2/ kg) 150 parts, slag aggregate (iron content 1.5%, particle diameter 0.01~2.8mm continuous grading) 400 parts.
First by binding agent, curing component mix homogeneously, add powder mix homogeneously, the epoxy grouting material of the prepared present invention Material.Adjust the mixed proportion of binding agent, curing component and powder three according to ambient temperature and working condition, for equipment in good time Equipment Foundations grouting under foundation grouting, especially low temperature environment.
Embodiment 2:
Proportioning raw materials are as follows:
3.5 parts of binding agent
1 part of curing component
17 parts of powder
Wherein:
Binding agent forms: epoxy resin e51(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 15000mpa s and epoxide number 0.35mol/100g) 40 parts, epoxy resin f44(Yueyang petrochemical industry, when 25 DEG C, viscosity is 19500mpa s and epoxide number 0.44mol/100g) 60 parts, 12 parts of polypropylene glycol diglycidyl ether (when 25 DEG C, viscosity is 25mpa s), methylallyl alcohol gathers 14 parts of oxygen vinyl Ether, si143(Yueyang petrochemical industry) 1.3 parts;
Curing component forms: 25 parts of poly capryllactam (Yueyang petrochemical industry, amine number is 410mg koh/g), potassium hydroxide 0.5 Part, 1.5 parts of octadecyl sulfonamide (Shandong this specialization work of richness, amine number is 300mg koh/g);
Powder forms: steel-making slag powder (iron content 1.5%, specific surface area 390m2/ kg) 160 parts, slag aggregate (iron content 1.8%, particle diameter 0.01~2.5mm continuous grading) 330 parts.
Preparation is same as Example 1 with using method.
Embodiment 3:
Proportioning raw materials are as follows:
3.2 parts of binding agent
1 part of curing component
17 parts of powder
Wherein:
Binding agent forms: epoxy resin e51(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 12000mpa s and epoxide number 0.36mol/100g) 15 parts, epoxy resin e41(Yueyang petrochemical industry, when 25 DEG C, viscosity is 175000mpa s and epoxide number 0.55mol/100g) 25 parts, epoxy resin f44(Yueyang petrochemical industry, when 25 DEG C, viscosity is 20000mpa s and epoxide number 0.32mol/100g) 60 parts, 12 parts of BDO bisglycidyl ether (when 25 DEG C, viscosity is 15mpa s), methoxyl group polyoxy 10 parts of vinyl Ether, si1511.5 part;
Curing component forms: 33 parts of phydroxybenzeneactamide (Shanghai plumage sail chemical industry, amine number is 600mg koh/g), hydrogen-oxygen Change 0.8 part of lithium, 0.4 part of alkyl dimethyl carboxyethyl quaternary ammonium salt (Shanxi Xin Tianyuan chemical industry, amine number is 420mg koh/g), n- first Base Methanesulfomide (Shanxi Xin Tianyuan chemical industry, amine number is 300mg koh/g) 0.8;
Powder forms: steel-making slag powder (iron content 1.2%, specific surface area 410m2/ kg) 200 parts, slag aggregate (iron content 1.5%, particle diameter 0.01~3.0mm continuous grading) 300 parts.
Preparation is same as Example 1 with using method.
Embodiment 4:
Proportioning raw materials are as follows:
2.9 parts of binding agent
1 part of curing component
18 parts of powder
Wherein:
Binding agent forms: epoxy resin e41(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 11000mpa s and epoxide number 0.40mol/100g) 100 parts, 9 parts of butyl glycidyl ether (when 25 DEG C, viscosity is 10mpa s), jly-215(Yueyang petrochemical industry) 12 parts, si171(Yueyang petrochemical industry) 1.5 parts;
Curing component forms: to 30 parts of n-butyl aniline (Shanghai plumage sail chemical industry, amine number be 420mg koh/g), hydroxide 1.2 parts of sodium, 1.0 parts of octadecyl sulfonamide (Shanxi Xin Tianyuan chemical industry, amine number is 300mg koh/g);
Powder forms: steel-making slag powder (iron content 1.5%, specific surface area 326m2/ kg) 180 parts, slag aggregate (iron content 1.5%, particle diameter 0.01~3.0mm continuous grading) 330 parts.
Preparation is same as Example 1 with using method.
Embodiment 5:
Proportioning raw materials are as follows:
3.1 parts of binding agent
1 part of curing component
16 parts of powder
Wherein:
Binding agent forms: epoxy resin e41(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 15500mpa s and epoxide number 0.48mol/100g) 100 parts, 12 parts of BDO bisglycidyl ether (when 25 DEG C, viscosity is 16mpa s), jly-124 10 parts of (Yueyang petrochemical industry), si133(Yueyang petrochemical industry) 1 part;
Curing component forms: to 22 parts of methoxy benzamide (Shanghai plumage sail chemical industry, amine number be 580mg koh/g), hydrogen 0.8 part of sodium oxide, 0.7 part of alkyl dimethyl carboxyethyl quaternary ammonium salt (Shanxi Xin Tianyuan chemical industry, amine number is 480mg koh/g);
Powder forms: steel-making slag powder (iron content 1.4%, specific surface area 348m2/ kg) 190 parts, slag aggregate (iron content 1.5%, particle diameter 0.01~2.8mm continuous grading) 360 parts.
Preparation is same as Example 1 with using method.
Embodiment 6:
Proportioning raw materials are as follows:
3.5 parts of binding agent
1 part of curing component
17 parts of powder
Wherein:
Binding agent forms: epoxy resin e41(Yueyang petrochemical industry, and when 25 DEG C, viscosity is 12000mpa s and epoxide number 0.43mol/100g) 100 parts, 13 parts of butyl glycidyl ether (when 25 DEG C, viscosity is 14mpa s), jly-124(Yueyang petrochemical industry) 14 parts, si133(Yueyang petrochemical industry) 1.6 parts;
Curing component forms: 25 parts of dodecyl polyaniline (Shanghai plumage sail chemical industry, amine number is 510mg koh/g), hydroxide 0.5 part of sodium, 1.3 parts of octadecyl sulfonamide (Shanxi Xin Tianyuan chemical industry, amine number is 480mg koh/g);
Powder forms: steel-making slag powder (iron content 1.8%, specific surface area 450m2/ kg) 150 parts, slag aggregate (iron content 1.9%, particle diameter 0.01~2.5mm continuous grading) 350 parts.
Preparation is same as Example 1 with using method.
The performance parameter of table 1 embodiment 1~6
The epoxy grouting material that can be seen that the present invention from the experimental result of table 1 has relatively low thermal coefficient of expansion, higher Elastic modelling quantity and heat distortion temperature and suitable mobility.
As described above, being described in detail to embodiments of the invention, but as long as essentially without the disengaging present invention Inventive point and effect can have a lot of deformation, this will be readily apparent to persons skilled in the art.Therefore, so Variation be also contained within protection scope of the present invention.

Claims (9)

1. be used for the large dosage slag epoxy grouting material of low-temperature construction it is characterised in that: in parts by mass, by following group packet Become:
2~4 parts of binding agent
1 part of curing component
15~20 parts of powder
Wherein, described binding agent is made up of epoxy resin, diluent, toughener and coupling agent, and forms as follows:
Described curing component is made up of firming agent and catalyst, and forms as follows:
20~40 parts of firming agent
1~3 part of catalyst
Described powder is made up of steel-making slag powder and slag aggregate, and forms as follows:
150~250 parts of steel-making slag powder
300~400 parts of slag aggregate,
Described diluent be when 25 DEG C viscosity be less than 25mpa s reactive diluent, selected from butyl glycidyl ether, Isosorbide-5-Nitrae- One or more of butanediol bisglycidyl ether, Ethylene glycol diglycidyl ether and polypropylene glycol diglycidyl ether;
Described catalyst comprises alkali metal hydroxide and selected from containing one of dicarboxyl quaternary ammonium salt and sulfonamide or many Kind.
2. it is characterised in that in parts by mass, it is grouped into epoxy grouting material according to claim 1 by following group:
2~4 parts of binding agent
1 part of curing component
15~20 parts of powder
Wherein, described binding agent is made up of epoxy resin, diluent, toughener and coupling agent, and forms as follows:
Described curing component is made up of firming agent and catalyst, and forms as follows:
25~32 parts of firming agent
1.5~2.5 parts of catalyst
Described powder is made up of steel-making slag powder and slag aggregate, and forms as follows:
150~250 parts of steel-making slag powder
300~400 parts of slag aggregate.
3. epoxy grouting material according to claim 1 and 2 it is characterised in that:
Described epoxy resin is that when 25 DEG C, viscosity is less than 20000mpa s and epoxide number is between 0.32~0.55mol/100g Bisphenol-a Epoxy Resin and one or more of bis-phenol ad type aliphatic glycidyl ether epoxy resin;
Described toughener is one or more of thiorubber., carbamate prepolymer and modified polyether of non-epoxy type;
Described coupling agent is silane coupler.
4. epoxy grouting material according to claim 1 and 2 it is characterised in that:
Described firming agent is the aliphatic amide in 300~600mg koh/g for the amine number, the fatty amine containing aromatic rings and contains aromatic rings One or more of amide.
5. epoxy grouting material according to claim 1 and 2 it is characterised in that:
Metal Ferrum content≤2% in described slag, the specific surface area >=200m of steel-making slag powder2/ kg, slag aggregate is 0.001 for particle diameter The steel slag particle of~3mm continuous grading.
6. epoxy grouting material according to claim 3 it is characterised in that:
Described epoxy resin is selected from epoxy resin e41, epoxy resin e44, epoxy resin e51, epoxy resin f5 and asphalt mixtures modified by epoxy resin One or more of fat f44;
Described thiorubber. is selected from one or more of jly-121, jly-124, jlg-200, jly155 and jly215;
Described modified polyether is selected from metering system polyoxyethylenated alcohol, propylene polyoxyethylenated alcohol and methoxy polyoxyethylene ether One or more of;
Described silane coupler is selected from one or more of si133, si143, si151, si171.
7. epoxy grouting material according to claim 4 it is characterised in that:
Described aliphatic amide is selected from polyenanthoamide, poly capryllactam, nylon 9, nylon 11 and nylon 12 One or more of;
The described fatty amine containing aromatic rings is selected from dodecyl polyaniline, in n-butyl aniline, 2- methyl -5 isopropyl aniline One or more;
The described amide containing aromatic rings be selected from Benzoylamide, propenyl benzene amide, to methoxy benzamide, adjacent methyl vinyl One or more of amine, phydroxybenzeneactamide.
8. be used for preparing the method for epoxy grouting material described in claim 1 it is characterised in that: methods described includes following several Individual step:
(1) press mass parts, take 100 parts of epoxy resin, 5~15 parts of diluent, 10~20 parts of toughener and 1~2 part of coupling respectively Agent, each raw material is put in blender, continuous mix and blend 5~10 minutes, and mix uniformly, obtains binding agent;
(2) press mass parts, take 20~40 parts of firming agent and 1~3 part of catalyst respectively, each raw material is put in blender, continuously Mix and blend 5~10 minutes, mix uniformly, obtains curing component;
(3) press mass parts, take 150~250 parts of steel-making slag powder and 300~400 parts of slag aggregates respectively, each raw material is put into blender In, continuous mix and blend 5~10 minutes, mix uniformly, obtains powder.
9. usage right require 1 described in epoxy grouting material construction method it is characterised in that: methods described includes following several Individual step:
(1) press mass parts, the curing component of 2~4 parts of binding agent and 1 part is put in forced stirrer, stirs, then will 15~20 parts of powder puts into wherein, mix homogeneously;
(2) uniformly the equipment Foundations grouting having vibration to require realized by mixed grouting material using deadweight method.
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CN107759131A (en) * 2017-08-21 2018-03-06 福建省正丰数控科技有限公司 It is a kind of to utilize the bed piece for making steel tailings casting
CN109536102A (en) * 2018-12-06 2019-03-29 中国建材检验认证集团厦门宏业有限公司 A kind of high density underwater epoxy repair sheets and its preparation method and application
CN112210231A (en) * 2020-10-30 2021-01-12 中冶宝钢技术服务有限公司 Modified steel slag pigment filler, epoxy paint formed by same, preparation method and application thereof

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