CN202809429U - Water-seepage brick containing hydrophilic epoxy resin binder - Google Patents
Water-seepage brick containing hydrophilic epoxy resin binder Download PDFInfo
- Publication number
- CN202809429U CN202809429U CN 201220336782 CN201220336782U CN202809429U CN 202809429 U CN202809429 U CN 202809429U CN 201220336782 CN201220336782 CN 201220336782 CN 201220336782 U CN201220336782 U CN 201220336782U CN 202809429 U CN202809429 U CN 202809429U
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- water
- seepage brick
- epoxy resin
- seepage
- surface layer
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Abstract
The utility model discloses a water-seepage brick containing a hydrophilic epoxy resin binder. The water-seepage brick is characterized by comprising a water-seepage brick surface layer and a water-seepage brick main body, wherein the water-seepage brick main body is fixedly provided with the water-seepage brick surface layer, and the water-seepage brick surface layer is provided with a mesh groove; and the water-seepage brick main body is a cuboid made by pressing a mixture including the hydrophilic epoxy resin binder and cement mortar. The water-seepage brick surface layer and the water-seepage brick body are molded through vibration pressing. A color sand layer is 2-10mm in thickness. The water-seepage brick body is 2-8cm in thickness. The hydrophilic epoxy resin binder is composed of bisphenol A-type epoxy resin, a curing agent, a surfactant Span and Tween, wherein the curing agent is one or more of an aliphatic polyamine curing agent, a cycloaliphatic polyamine curing agent or an aromatic-ring polyamine curing agent. The water-seepage brick disclosed by the utility model has the advantages of low price, simple synthesis process, environment friendliness, strong polarity and hydrophilicity, is applied to a water-permeable pavement, and is good in water-permeable effect and high in wet compressive strength.
Description
Technical field
The utility model belongs to building material field, relates in particular to a kind of seepage brick that contains the hydrophily epoxy adhesive.
Background technology
At present, because the needs of urban ecological environment development, urban ground is covered by materials impervious to water such as cement, pitch gradually and changes into the covering of water-permeable pavement material.Conventional method adopts bulky grain skeleton and epoxy resin to form.But epoxy resin in use, because its lipophile, the surface has hydrophobicity, therefore will make epoxy resin have hydrophily, must manage to introduce in its strand molecule segment or the complete water-soluble epoxy resin of preparation that hydrophilic interaction is arranged.But the water emulsification type epoxy resin that exists on the market now and can exist resin demand large by fully water-soluble hydantoin epoxy, the lower shortcoming of permeable goods wet compressive strength.
The utility model content
Technical problem to be solved in the utility model provides a kind of seepage brick that contains the hydrophily epoxy adhesive, and cheap, synthesis technique is simple, environmental protection, polarity are strong, can be hydrophilic; Be used for cement mortar, can form the mesh skeleton structure, improve cement products intensity; Be used for the permeable pavement road surface, permeable effective, wet compressive strength is high.
Technical problem to be solved in the utility model is achieved through the following technical solutions:
A kind of seepage brick that contains the hydrophily epoxy adhesive is characterized in that: comprise seepage brick surface layer and seepage brick main body; Fixing seepage brick surface layer on the described seepage brick main body, described seepage brick surface layer is provided with latticed groove; The cuboid that described seepage brick main body forms for the mixture compacting by hydrophily epoxy adhesive and cement mortar.
Described seepage brick surface layer and seepage brick main body adopt the vibration extrusion forming.
Described color burial depth is the 2-10 millimeter.
Described seepage brick body thickness is 2-8 centimetre.
Described hydrophily epoxy adhesive is comprised of bisphenol A type epoxy resin, curing compound, surfactant span and tween; Curing compound is one or more in aliphatic polyamine class curing compound, alicyclic polyamine class curing compound or the aromatic ring family polyamines class curing compound.
The utility model has following beneficial effect:
The utility model contains the hydrophily epoxy adhesive, and resin has active group, and has hydrophily, can be added in the inorganic material, improves inorganic material toughness, reduces fragility; Compare with the resin type water-permeable brick, cheap; Environment-friendly type cementing agent: nontoxic, tasteless, pollution-free; Good water permeability: by epoxy resin modification, make it to have certain hydrophily, permeable effective; Application is extensive: (a) can be directly and quartz sand, stone etc. are natural and manufactured aggregate prepares seepage brick, and be layed in the road surfaces such as sidewalk, square and park and form pervious layer; Also can be used for the permeable product of rainwater-collecting, water filtration, carry out dmp filter, reduce groundwater pollution; (b) be used for mortar, improve the mortar mechanical property.
Description of drawings
Fig. 1 is the utility model overall structure schematic diagram
Among the figure, 1. seepage brick surface layer, 2. seepage brick main body, 3. latticed groove
The specific embodiment
As shown in Figure 1, a kind of seepage brick that contains the hydrophily epoxy adhesive is characterized in that: comprise seepage brick surface layer and seepage brick main body; On the described seepage brick main body fixedly the described seepage brick surface layer of seepage brick surface layer be provided with latticed groove; The cuboid that described seepage brick main body forms for the mixture compacting by hydrophily epoxy adhesive and cement mortar.
Described seepage brick surface layer and seepage brick main body adopt the vibration extrusion forming.
Described color burial depth is the 2-10 millimeter.
Described seepage brick body thickness is 2-8 centimetre.
Described hydrophily epoxy adhesive is comprised of bisphenol A type epoxy resin, curing compound, surfactant span and tween; Curing compound is one or more in aliphatic polyamine class curing compound, alicyclic polyamine class curing compound or the aromatic ring family polyamines class curing compound.
Described hydrophily epoxy adhesive is bisphenol A type epoxy resin E-44, E-42, E-35, E-31, E-20, E-14, E-12, E-06, one of E-03 or its any combination.
In the process of synthesis hydrophilic epoxy adhesive, for improving the activity of cementing agent, add this dish of surfactant in the synthesizing formula, can be S-20, S-40, S-60, S-80, one of S-85 or its any combination.
In the process of synthesis hydrophilic epoxy adhesive, for improving the activity of cementing agent, add the surfactant tween in the synthesizing formula, can be T-20, T-40, T-60, T-80, one of T-85 or its any combination.
Described hydrophily epoxy adhesive is under catalyst action, introduces the hydrophily functional groups such as hydroxyl, ehter bond by chemical reaction in the bisphenol A type epoxy resin strand.Namely under the effect of catalyzer, utilize the epoxy radicals of bisphenol A type epoxy resin with hydroxyl reaction in the surfactant, make epoxy resin one end contain hydrophilic radical, thereby have certain hydrophilicity.
Described catalyzer is etamon chloride, butyl triphenyl phosphonium bromide, benzyl triethyl ammonium bromide, a kind of or its any combination of benzyltriethylammoinium chloride and glyoxal ethyline.
Need add one or more in aliphatic polyamine, alicyclic polyamine class curing compound or the aromatic ring family polyamines class curing compound in the described epoxy adhesive.
In the described epoxy curing agent be phenolic aldehyde amine, diethylenetriamine, IPD, N-cyanoethyl diethylenetriamines, 593 curing compound, 4,4 '-a kind of or its any combination of MDA.
The hydrophily epoxy adhesive of the present invention's preparation, the action principle in the modified cement process is:
At first, because the hydrophily epoxide resin polymer has hydrophily, and have polarity strong characteristics, minimizing along with moisture in the cement, hydrophily epoxy resin forms the film with higher adhesion stress, because the filling effect of film has improved the capillary structure of hardened cement paste, thereby stop up the hole in the mortar; Secondly, hydrated cementitious and polymer film forming carry out simultaneously, form at last be interweaved together inierpeneirating network structure of cement paste and polymer film, thereby have improved mechanical property and the durability of slurry.
Principle is in the water permeable paving material product:
At first, owing to the hydrophily of hydrophilic compounds and with active group, behind the resin solidification, formation is take the hydrophilic compounds decentralized photo as " island ", connecting phase epoxy resin is " island structure " in " sea ", reaches toughness reinforcing purpose, shows as water-permeable brick compressive strength and increases substantially; Secondly, because the microphase-separated of resin after solidifying, hydrophilic radical tends to be distributed in the external surface of resin molding, and ehter bond or the hydroxyl of this epoxy resin molecular side chain outwards stretch, so that the external surface of resin coating water-permeable brick has water-wet behavior.Because in the permeable products solidifying forming process, the aggregate such as stone, quartz sand presses together, but because aggregate has particle diameter, and exists certain sphericity, form the tiny tubular conduit that mutually connects between the aggregate, when water contacts with this passage, because the water-wet behavior of this resin, water infiltrates rapidly tube wall, and liquid level is spill in the pipe, the additonal pressure that the curved liquid surface that forms produces is pointed to tubule, promotes passing through of water.
The synthetic method of described hydrophily epoxy adhesive is characterized in that comprising the steps: 1) in there-necked flask, add bisphenol A type epoxy resin, stir; 2) according to the epoxy base unit weight of bisphenol A type epoxy resin, add the surfactant of metering coupling, stir 15～30min; 3) add the trace catalyzer, stir 15～30min; 4) control there-necked flask interior reaction temperature carries out synthetic reaction within the specific limits; 5) sampling detects, according to the epoxide number amount control extent of reaction; 6) reaction finishes, and stops to heat up and stirring discharging.
Below will describe the specific embodiment of the present utility model in detail:
Embodiment 1
Get quartz sand 80g, ordinary Portland cement 20g adds hydrophily epoxy modified resin 2g, phenolic aldehyde amine 0.6g, and water 4g by mould molding, is prepared into pavior brick after mixing.
Comparative Examples 1
Get quartz sand 80g, ordinary Portland cement 20g, water 4g by mould molding, is prepared into pavior brick after mixing.
Compare with the Comparative Examples brick, the compressive strength of embodiment brick significantly improves.Following table is results of property:
Example 2
Get the quartz sand 100g of 0.4～0.2mm, add hydrophily epoxy adhesive 3.9g, pnenolic aldehyde amine hardener 1.1g by mould molding, is prepared into water-permeable brick after mixing.
Comparative Examples 2
Get the quartz sand 100g of 0.4～0.2mm, the permeable epoxy adhesive 3.9g in market, pnenolic aldehyde amine hardener 1.1g by mould molding, is prepared into water-permeable brick after mixing.Following table is performance comparison:
According to above embodiment as can be known:
1. in the preparation versatility pavior brick of the present utility model, pavior brick compressive strength significantly improves;
2. by the application of water permeability epoxy adhesive of the present utility model, compare with similar resin type product, significantly improved actual effect and the water permeability of permeable product, and cheap.
Claims (4)
1. a seepage brick that contains the hydrophily epoxy adhesive is characterized in that: comprise seepage brick surface layer and seepage brick main body; Fixing seepage brick surface layer on the described seepage brick main body, described seepage brick surface layer is provided with latticed groove; Described seepage brick main body is cuboid.
2. the seepage brick that contains the hydrophily epoxy adhesive as claimed in claim 1 is characterized in that: described seepage brick surface layer and seepage brick main body employing vibration extrusion forming.
3. the seepage brick that contains the hydrophily epoxy adhesive as claimed in claim 1, it is characterized in that: described color burial depth is the 2-10 millimeter.
4. the seepage brick that contains the hydrophily epoxy adhesive as claimed in claim 1, it is characterized in that: described seepage brick body thickness is 2-8 centimetre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220336782 CN202809429U (en) | 2012-07-11 | 2012-07-11 | Water-seepage brick containing hydrophilic epoxy resin binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220336782 CN202809429U (en) | 2012-07-11 | 2012-07-11 | Water-seepage brick containing hydrophilic epoxy resin binder |
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| Publication Number | Publication Date |
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| CN202809429U true CN202809429U (en) | 2013-03-20 |
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| CN 201220336782 Expired - Lifetime CN202809429U (en) | 2012-07-11 | 2012-07-11 | Water-seepage brick containing hydrophilic epoxy resin binder |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103628386A (en) * | 2013-11-29 | 2014-03-12 | 拉法基技术服务（北京）有限公司 | Road pavement layer |
| CN105002804A (en) * | 2015-06-04 | 2015-10-28 | 保定维特瑞交通设施工程有限责任公司 | Construction process of surface layer blind sidewalk of cement concrete sidewalk |
| CN105316988A (en) * | 2014-08-05 | 2016-02-10 | 福建百花化学股份有限公司 | Permeable terrace brick manufacturing method |
| CN107083729A (en) * | 2017-04-17 | 2017-08-22 | 同济大学 | One kind stores permeable module and preparation method thereof |
| CN107739169A (en) * | 2017-10-30 | 2018-02-27 | 重庆亲禾建科建材有限公司 | A kind of preparation method of epoxy water-permeable brick |
| CN113717674A (en) * | 2021-09-22 | 2021-11-30 | 昆山赛阳电子材料有限公司 | Double-hardness composite polyurethane frictioning and preparation method thereof |
-
2012
- 2012-07-11 CN CN 201220336782 patent/CN202809429U/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103628386A (en) * | 2013-11-29 | 2014-03-12 | 拉法基技术服务（北京）有限公司 | Road pavement layer |
| CN103628386B (en) * | 2013-11-29 | 2015-12-09 | 拉法基技术服务（北京）有限公司 | A kind of road pavement layer |
| CN105316988A (en) * | 2014-08-05 | 2016-02-10 | 福建百花化学股份有限公司 | Permeable terrace brick manufacturing method |
| CN105002804A (en) * | 2015-06-04 | 2015-10-28 | 保定维特瑞交通设施工程有限责任公司 | Construction process of surface layer blind sidewalk of cement concrete sidewalk |
| CN107083729A (en) * | 2017-04-17 | 2017-08-22 | 同济大学 | One kind stores permeable module and preparation method thereof |
| CN107739169A (en) * | 2017-10-30 | 2018-02-27 | 重庆亲禾建科建材有限公司 | A kind of preparation method of epoxy water-permeable brick |
| CN113717674A (en) * | 2021-09-22 | 2021-11-30 | 昆山赛阳电子材料有限公司 | Double-hardness composite polyurethane frictioning and preparation method thereof |
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Legal Events
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180917 Address after: 017400 the west side of Yili Road, located in the Tara town of Hang Jin banner, Ordos City, the Inner Mongolia Autonomous Region. Patentee after: Hang Jin Qi Yi Jia Environmental Management Co.,Ltd. Address before: 017400 Yili sand material, clean energy park, Du GUI Tara Town, Hang Jin banner, Ordos City, the Inner Mongolia Autonomous Region Patentee before: YILISHA MATERIAL TECHNOLOGY CO.,LTD. |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20130320 |