CN105310893A - Condensate water mask and production method thereof - Google Patents
Condensate water mask and production method thereof Download PDFInfo
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- CN105310893A CN105310893A CN201510883013.2A CN201510883013A CN105310893A CN 105310893 A CN105310893 A CN 105310893A CN 201510883013 A CN201510883013 A CN 201510883013A CN 105310893 A CN105310893 A CN 105310893A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- Animal Behavior & Ethology (AREA)
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Abstract
The invention relates to a condensate water mask and a production method thereof. The condensate water mask comprises primary materials and auxiliary materials in parts by weight: 5-10 parts of a water-soluble polymer, 0.1-1 part of a pH modifier, 5-25 parts of polyhydric alcohol, 50-80 parts of water, 1-5 parts of a functional additive, 0.01-0.5 part of a freshener and 0.01-0.5 part of a flavoring agent. The production method of the mask comprises the following steps: adding the pH modifier and the functional additive to water, and stirring evenly to obtain a phase A; mixing and stirring the water-soluble polymer and the polyhydric alcohol evenly to obtain a phase B; mixing and stirring the flavoring agent and the freshener evenly to obtain a phase C; mixing and stirring the phase A, the phase B and the phase C evenly to obtain jelly; and evenly painting the jelly and standing at 40-60 DEG C under the condition that the humidity is 30%-60% for 1-2 hours, so as to obtain the mask. The condensate water mask has the beneficial effects that the skin can be smooth and elastic after the condensate water mask disclosed by the invention is used for a long period of time.
Description
Technical field
The invention belongs to cosmetic field, be specifically related to a kind of solidifying water surface film and production method thereof.
Background technology
Along with the development of science and technology and improving constantly of living standards of the people, cosmetics are in occupation of more and more consequence in people's life, and this has also driven the development of cosmetics.In recent years, the kind of cosmetics is on the increase, and it is functional also more and more stronger, and scientific and technological content is higher.Facial film, as one of the mainstream product of cosmetics, have also been obtained significant progress.
Commercially available facial film domestic at present mainly contains three classes: gel shape facial film, tearing type facial film and non-woven fabrics facial film.Wherein, gel shape facial film uses inconvenient, easily pollutes clothes etc.; Tearing type facial film applies after on the face, slowly become dry and finally become thin film, gently skin is moderately tightened up in this process, increase tension force, stimulate and improve skin, but because tearing type facial film absorbability is stronger, in the process peeled off, more easily cause horny layer excessively to be peeled off and injured skin; To exist with the form of wet cloth without anti-cloth facial film and use, inconvenient in use procedure, facial treatment essence liquid easily trickles the pollution caused clothes etc., simultaneously because facial treatment essence liquid is not well combined with nonwoven carrier, cause facial film facial treatment essence liquid to there is residual loss in packaging bag, greatly reduce the utilization to effective ingredient.
Summary of the invention
In order to solve the problems referred to above that prior art exists, the invention provides a kind of cohesiveness to skin appropriateness and skin of face compatible degree high, and skin is had to solidifying water surface film and the production method thereof of excellent effect and safety.
The technical solution adopted in the present invention is:
A kind of solidifying water surface film and production method thereof, comprise the major ingredient of following weight proportioning: water-soluble polymer 5-10 part, pH adjusting agent 0.1-1 part, polyhydric alcohol 5-25 part, water 50-80 part.
Further, a kind of solidifying water surface film and production method thereof, also comprise the adjuvant of following weight proportioning: functional additive 1-5 part, freshener 0.01-0.5 part, aromatic 0.01-0.5 part.
Further, described water-soluble polymer is one or more the mixture in polyacrylic acid, polyacrylate, gelatin, cellulose, polyvinyl alcohol, polyvinylpyrrolidone.Water-soluble polymer, also known as water-soluble resin or water soluble polymer, is a kind of hydrophilic high molecular material, can dissolve or swelling formation solution or dispersion liquid in water.Water solublity comes from the hydrophilic group contained in its molecule, modal hydrophilic group is carboxyl, hydroxyl, amide groups, amido etc., these groups not only make macromolecule have hydrophilic, and make it have the performance of many preciousnesses, as cohesive, film property, lubricity, anti-attrition, thickening property, moisture retention etc.The use amount of water-soluble polymer should control within suitable scope, when its consumption is too high, can affect cohesiveness and the formability of facial film, and when consumption is too low, the cohesiveness of facial film, shape-retaining ability and water absorbing capacity all can decline.
Further, described pH adjusting agent is one or more mixture of tartaric acid, citric acid, lactic acid, phosphoric acid, maleic acid, malic acid.
Further, described polyhydric alcohol is one or more the mixture in glycerol, propylene glycol, 1,3 butylene glycol.
Further, described functional additive is one or more the mixture in wetting agent, whitening agent, keratolytic, external skin wrinkling-preventing agent, skin renovation agent.Described wetting agent is one or more the mixture in chondroitin sulfate, allantoin, elastin, lactic acid, hyaluronic acid, sodium alginate, chitosan, chitin, casein, soybean protein, Aloe extract, wheat gluten protein, lactalbumin.
Described whitening agent is one or more the mixture in arbutin, kojic acid, Azelaic Acid, tretinoin, fruit acid, linolenic acid, linoleic acid, hydrolyzed pearl, fibroin, collagen protein, Radix Glycyrrhizae extract, greenweed extract, Fructus Hippophae extract, Rhizoma Atractylodis Macrocephalae extract, Flos Nelumbinis extract, vitamin C and vitamin E and derivant thereof.
Described keratolytic is one or more the mixture in Oleum Vitis viniferae, safflower oil, Radix Oenotherae erythrosepalae oil, lanoline, Jojoba oil, Oleum Helianthi, angle Trionyx sinensis Wiegmann alkane, keratinase.
Described external skin wrinkling-preventing agent is one or more the mixture in nicotinic acid, cigarette phthalein amine, D-VB5, vitamin E, collagen protein, Aesculus chinensis Bunge extract.
Described skin renovation agent is one or more mixture of hamamelis extract, Aloe extract, retinoic acid, collagen protein, ubiquinone, allantoin, salicylic acid, lactic acid, glycyrrhizic acid.
Further, described freshener is one or more the mixture in Oleum menthae, peppermint, Menthol, d-Camphora, d1-Camphora.
Further, described aromatic is one or more the mixture in Salvia farinacea oil, Flos Rosae Rugosae quintessence oil, jasmin quintessence oil, osmanthus essential oil, Herba Salviae Japonicae essential oil, Olibanum quintessence oil, chamomile essential oil, Herba Lysimachiae foenum-graeci quintessence oil, tea tree ethereal oil, Bergamot, Fructus Citri Limoniae quintessence oil, Semen pruni armeniacae oil, Peppermint essential oil.
Further, antiseptic, enhancer of cutaneous penetration and excipient is also included in described solidifying water surface film.
Further, the production method of described solidifying water surface film is:
(1) pH adjusting agent and functional additive are added to the water, stir to obtain A phase;
(2) water-soluble polymer and polyhydric alcohol mixing and stirring are obtained B phase;
(3) aromatic and freshener mixing and stirring are obtained C phase;
(4) ABC three-phase mixed and stir, obtaining jelly;
(5) jelly is smeared evenly, be 40-60 DEG C in temperature, under humidity is the condition of 30%-60%, places 1-2h, obtain facial film.
Further, be under the condition of 100-200r/min by ABC three-phase low whipping speed in step (4), stir 1-2h.
Further, the support of described solidifying water surface film to be staple fibre be breathability that raw material makes and the reasonable cloth of poisture-penetrability.
Beneficial effect of the present invention is: each composition of solidifying water surface film of the present invention merges, well can fit with skin, nutritional labeling is easy to skin and absorbs, because of good containing its moisturizing of water-soluble polymer lock water effectiveness comparison in facial film, life-time service skin can be made to become smooth and high resilience.In addition people can according to the needs of oneself, select the facial film of the present invention of difference in functionality, as whitening, horny layer softening, crease-resistant or repair skin, use more convenient, the scope of application is wider.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of solidifying water surface film and production method thereof, comprise major ingredient and the adjuvant of following weight proportioning:
Major ingredient: water-soluble polymer 5 parts, pH adjusting agent 0.1 part, polyhydric alcohol 5 parts, 50 parts, water;
Adjuvant: functional additive 1 part, freshener 0.01 part, aromatic 0.01 part.
Described water-soluble polymer is polyacrylic acid, and described pH adjusting agent is tartaric acid, and described polyhydric alcohol is glycerol.
Described functional additive is whitening agent, and described freshener is Oleum menthae, and described aromatic is Flos Rosae Rugosae quintessence oil.
Described whitening agent is the mixture of the quality such as arbutin, kojic acid, Azelaic Acid, tretinoin, fruit acid, linolenic acid, linoleic acid, hydrolyzed pearl, fibroin, collagen protein, Radix Glycyrrhizae extract, greenweed extract, Fructus Hippophae extract, Rhizoma Atractylodis Macrocephalae extract, Flos Nelumbinis extract, vitamin C and vitamin E.
The production method of solidifying water surface film described above comprises the following steps:
(1) pH adjusting agent and functional additive are added to the water, stir to obtain A phase;
(2) water-soluble polymer and polyhydric alcohol mixing and stirring are obtained B phase;
(3) aromatic and freshener mixing and stirring are obtained C phase;
(4) ABC three-phase being blended in mixing speed is stir 1h under the condition of 100r/min, obtains jelly;
(5) jelly is smeared evenly, be 40 DEG C in temperature, under humidity is the condition of 30%, places 1h, obtain facial film.
Embodiment 2
A kind of solidifying water surface film and production method thereof, comprise major ingredient and the adjuvant of following weight proportioning:
Major ingredient: water-soluble polymer 7 parts, pH adjusting agent 0.5 part, polyhydric alcohol 15 parts, 65 parts, water;
Adjuvant: functional additive 3 parts, freshener 0.25 part, aromatic 0.25 part.
Described water-soluble polymer is the mixture of the quality such as polyacrylic acid, polyacrylate and gelatin;
Described pH adjusting agent is the mixture of the quality such as tartaric acid, citric acid and lactic acid;
Described polyhydric alcohol is the mixture of the quality such as glycerol, propylene glycol and 1,3 butylene glycol;
Described functional additive is the mixture of the quality such as wetting agent, whitening agent and keratolytic;
Described freshener is the mixture of the quality such as Oleum menthae, peppermint and Menthol;
Described aromatic is the mixture of the quality such as Salvia farinacea oil, Flos Rosae Rugosae quintessence oil, jasmin quintessence oil and osmanthus essential oil.
Described wetting agent is the mixture of the quality such as chondroitin sulfate, allantoin and elastin.
Described whitening agent is the mixture of the quality such as arbutin, kojic acid, Azelaic Acid, tretinoin and fruit acid.
Described keratolytic is the mixture of the quality such as Oleum Vitis viniferae, safflower oil, Radix Oenotherae erythrosepalae oil and lanoline.
The production method processed of solidifying water surface film described above comprises the following steps:
(1) pH adjusting agent and functional additive are added to the water, stir to obtain A phase;
(2) water-soluble polymer and polyhydric alcohol mixing and stirring are obtained B phase;
(3) aromatic and freshener mixing and stirring are obtained C phase;
(4) ABC three-phase being blended in mixing speed is stir 1.5h under the condition of 150r/min, obtains jelly;
(5) jelly is smeared evenly, be 50 DEG C in temperature, under humidity is the condition of 45%, places 1.5h, obtain facial film.
Embodiment 3
A kind of solidifying water surface film and production method thereof, comprise major ingredient and the adjuvant of following weight proportioning:
Major ingredient: water-soluble polymer 10 parts, pH adjusting agent 1 part, polyhydric alcohol 25 parts, 80 parts, water;
Adjuvant: functional additive 5 parts, freshener 0.5 part, aromatic 0.5 part.
Described water-soluble polymer is the mixture of the quality such as polyacrylic acid, polyacrylate, gelatin, cellulose, polyvinyl alcohol and polyvinylpyrrolidone.
Described pH adjusting agent is the mixture of the quality such as tartaric acid, citric acid, lactic acid, phosphoric acid, maleic acid and malic acid.
Described polyhydric alcohol is the mixture of the quality such as glycerol, propylene glycol and 1,3 butylene glycol.
Described functional additive is the mixture of the quality such as wetting agent, whitening agent, keratolytic, external skin wrinkling-preventing agent and skin renovation agent.
Described freshener is the mixture of the quality such as Oleum menthae, peppermint, Menthol, d-Camphora and d1-Camphora.
Described aromatic is the mixture of Salvia farinacea oil, Flos Rosae Rugosae quintessence oil, jasmin quintessence oil, osmanthus essential oil, Herba Salviae Japonicae essential oil, Olibanum quintessence oil, chamomile essential oil, Herba Lysimachiae foenum-graeci quintessence oil, tea tree ethereal oil, Bergamot, Fructus Citri Limoniae quintessence oil, Semen pruni armeniacae oil and peppermint essence wet goods quality.
Described wetting agent is the mixture of the quality such as chondroitin sulfate, allantoin, elastin, lactic acid, hyaluronic acid, sodium alginate, chitosan, chitin, casein, soybean protein, Aloe extract, wheat gluten protein and lactalbumin.
Described whitening agent is the mixture of the quality such as arbutin, kojic acid, Azelaic Acid, tretinoin, fruit acid, linolenic acid, linoleic acid, hydrolyzed pearl, fibroin, collagen protein, Radix Glycyrrhizae extract, greenweed extract, Fructus Hippophae extract, Rhizoma Atractylodis Macrocephalae extract, Flos Nelumbinis extract, vitamin C and vitamin E.
Described keratolytic is the mixture of the quality such as Oleum Vitis viniferae, safflower oil, Radix Oenotherae erythrosepalae oil, lanoline, Jojoba oil, Oleum Helianthi, angle Trionyx sinensis Wiegmann alkane and keratinase.
Described external skin wrinkling-preventing agent is the mixture of the quality such as nicotinic acid, cigarette phthalein amine, D-VB5, vitamin E, collagen protein and Aesculus chinensis Bunge extract.
Described skin renovation agent is the mixture of the quality such as hamamelis extract, Aloe extract, retinoic acid, collagen protein, ubiquinone, allantoin, salicylic acid, lactic acid and glycyrrhizic acid.
The production method of solidifying water surface film described above comprises the following steps:
(1) pH adjusting agent and functional additive are added to the water, stir to obtain A phase;
(2) water-soluble polymer and polyhydric alcohol mixing and stirring are obtained B phase;
(3) aromatic and freshener mixing and stirring are obtained C phase;
(4) ABC three-phase being blended in mixing speed is stir 2h under the condition of 200r/min, obtains jelly;
(5) jelly is smeared evenly, be 60 DEG C in temperature, under humidity is the condition of 60%, puts 2h, obtain facial film.
The concrete case study on implementation of the solidifying water surface film described in embodiment 1:
Choose the crowd that 200 faces are dark yellow, dry, apply facial film of the present invention, 2-3 time weekly, the time of face mask film is each 15 minutes.During face mask film, the dietary life habits of 200 people and the cosmetics used all identical with before use facial film of the present invention.Experimental result is: excellent: 92%; Good: 8%.
Excellent: pale, the water profit that face becomes and glossy;
Good: the water profit that face becomes, but a little a little yellow;
Difference: facial dark yellow and dry phenomenon is all without significantly improving.
The concrete case study on implementation of embodiment 1:
Zhang, female, 18 years old, skin of face was dark yellow, and age of 18 years old look at picture more than 20 year old, upon somebody's introduction application solidifying water surface film of the present invention after one month skin become pale, continue application facial film of the present invention after three weeks, the water profit that skin becomes and glossy.
Huang, female, 25 years old, skin of face is dark yellow and more oily, after Huang uses the cosmetics of control oil, and the drying that skin of face becomes, after application the present invention two week of face, the salubrious non-greasy that Huang's skin of face becomes, continued application facial film of the present invention after one month, pale, the water profit that Huang's skin of face becomes and glossy.
Lee, man, 23 years old, skin of face was greasy, and Huang just no longer smears cosmetics after only using a facial cleaning cream for control oil to wash one's face at ordinary times, but skin of face or greasy, because skin of face is more greasy, sometimes can play acne, this brings puzzlement to the life of Lee.After application one week of facial film of the present invention, the greasy phenomenon of Lee's face is controlled substantially, continues to use the present invention's face after two weeks, and it is salubrious that Lee's face becomes.
Wang, female, 32 years old, face was dark yellow, often use sun screen to make the face of oneself look pale at ordinary times, but it was facial or dark yellow to wash sun screen off.Wang's application facial film of the present invention upon somebody's introduction, took facial film of the present invention after one month, and it is pale that the skin of Wang becomes.
Poplar, female, 43 years old, face was dark yellow and dry, because face has wrinkle, poplar often uses the cosmetics of anti-wrinkle, after often introducing, and poplar application the present invention face, after application five week of facial film of the present invention, the dark yellow of poplar face is taken off, and skin is a little somewhat pale.
Cloud, female, 52 years old, face was dark yellow, and application facial film of the present invention is after one month, and cloud dark yellow phenomenon on the face makes moderate progress.
The present invention is not limited to above-mentioned preferred forms; anyone can draw other various forms of products under enlightenment of the present invention; though but any change is done in its details, every have identical with the application or akin technical scheme, all drops within protection scope of the present invention.
Claims (10)
1. a solidifying water surface film, is characterized in that: the major ingredient comprising following weight parts: water-soluble polymer 5-10 part, pH adjusting agent 0.1-1 part, polyhydric alcohol 5-25 part, water 50-80 part.
2. solidifying water surface film according to claim 1, is characterized in that: the adjuvant also comprising following weight parts: functional additive 1-5 part, freshener 0.01-0.5 part, aromatic 0.01-0.5 part.
3. solidifying water surface film according to claim 2, is characterized in that: described water-soluble polymer is one or more the mixture in polyacrylic acid, polyacrylate, gelatin, cellulose, polyvinyl alcohol, polyvinylpyrrolidone.
4. solidifying water surface film according to claim 2, is characterized in that: described pH adjusting agent is one or more mixture of tartaric acid, citric acid, lactic acid, phosphoric acid, maleic acid, malic acid.
5. solidifying water surface film according to claim 2, is characterized in that: described polyhydric alcohol is one or more the mixture in glycerol, propylene glycol, 1,3 butylene glycol.
6. solidifying water surface film according to claim 2, is characterized in that: described functional additive is one or more the mixture in wetting agent, whitening agent, keratolytic, external skin wrinkling-preventing agent, skin renovation agent.
7. solidifying water surface film according to claim 2, is characterized in that: described freshener is one or more the mixture in Oleum menthae, peppermint, Menthol, d-Camphora, d1-Camphora.
8. solidifying water surface film according to claim 2, is characterized in that: described aromatic is one or more the mixture in Salvia farinacea oil, Flos Rosae Rugosae quintessence oil, jasmin quintessence oil, osmanthus essential oil, Herba Salviae Japonicae essential oil, Olibanum quintessence oil, chamomile essential oil, Herba Lysimachiae foenum-graeci quintessence oil, tea tree ethereal oil, Bergamot, Fructus Citri Limoniae quintessence oil, Semen pruni armeniacae oil, Peppermint essential oil.
9. the production method of the described solidifying water surface film of one of claim 2-8 is it is characterized in that: comprise the following steps:
(1) pH adjusting agent and functional additive are added to the water, stir to obtain A phase;
(2) water-soluble polymer and polyhydric alcohol mixing and stirring are obtained B phase;
(3) aromatic and freshener mixing and stirring are obtained C phase;
(4) ABC three-phase mixed and stir, obtaining jelly;
(5) jelly is smeared evenly, be 40-60 DEG C in temperature, under humidity is the condition of 30%-60%, places 1-2h, obtain facial film.
10. the production method of solidifying water surface film according to claim 9, is characterized in that: be stir 1-2h under the condition of 100-200r/min by ABC three-phase low whipping speed in step (4).
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| CN105997571A (en) * | 2016-04-14 | 2016-10-12 | 青岛科技大学 | Ultra-moisture modified chitosan water-washable facial mask and preparation method |
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| CN107190406A (en) * | 2017-05-09 | 2017-09-22 | 浙江梅盛实业股份有限公司 | Superfine fibre face mask substrate material and its manufacturing process with water suction and resilience function |
| CN108498355A (en) * | 2018-05-31 | 2018-09-07 | 邵延荣 | A kind of condensate film and preparation method thereof |
| CN110893161A (en) * | 2018-09-12 | 2020-03-20 | 广州赛度检测服务有限公司 | Seaweed moisturizing mask formula and processing technology thereof |
| CN116983229A (en) * | 2023-09-26 | 2023-11-03 | 广州创尔生物技术股份有限公司 | Preparation method and application of type I collagen composition |
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