CN105255241A - Formaldehyde purifying antibacterial seaweed mud paint and production process thereof - Google Patents

Formaldehyde purifying antibacterial seaweed mud paint and production process thereof Download PDF

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Publication number
CN105255241A
CN105255241A CN201510725994.8A CN201510725994A CN105255241A CN 105255241 A CN105255241 A CN 105255241A CN 201510725994 A CN201510725994 A CN 201510725994A CN 105255241 A CN105255241 A CN 105255241A
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CN
China
Prior art keywords
parts
antibacterial
paint
algae clay
agent
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Pending
Application number
CN201510725994.8A
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Chinese (zh)
Inventor
明邦锋
戴建国
吴斌华
明邦飞
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Jiangmen City Pengjiang District Woppon Paint Co Ltd
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Jiangmen City Pengjiang District Woppon Paint Co Ltd
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Application filed by Jiangmen City Pengjiang District Woppon Paint Co Ltd filed Critical Jiangmen City Pengjiang District Woppon Paint Co Ltd
Priority to CN201510725994.8A priority Critical patent/CN105255241A/en
Publication of CN105255241A publication Critical patent/CN105255241A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of a decoration material, and discloses formaldehyde purifying antibacterial seaweed mud paint. The formaldehyde purifying antibacterial seaweed mud paint consists of the following components in parts by weight: 18 to 22 parts of water, 0.5 to 0.8 parts of dispersing agent, 0.8 to 1.2 parts of anti-freezing agent, 0.8 to 1.5 parts of alcohol ester 12, 10 to 25 parts of titanium dioxide, 15 to 20 parts of calcium carbonate powder, 0.5 to 1 part of nano silver antibacterial agent, 2 to 6 parts of wollastonite powder, 0.5 to 1.5 parts of bentonite, 0.5 to 3 parts of thickening agent, 0.3 to 0.8 parts of anion additive, 15 to 30 parts of emulsion, 0.15 to 0.3 parts of mildew preventive agent, 0.2 to 0.3 parts of preservative, 0.3 to 0.5 parts of defoaming agent, 0.1 to 0.2 parts of water repellent agent and 10 to 12 parts of seaweed mud. The invention also discloses a preparation method of formaldehyde-free antibacterial seaweed mud. The prepared formaldehyde purifying antibacterial seaweed mud paint can release negative oxygen ions in a long time to purify the air, so that the air is maintained fresh; the indoor humidity is automatically adjusted, so that the indoor humidity is adjusted to the most comfortable degree for the human body.

Description

A kind of clean antibacterial algae clay paint of aldehyde and manufacture craft thereof
Technical field
The invention belongs to indoor decorating field of material technology, in particular to the antibacterial algae clay paint of the clean aldehyde of one and manufacture craft thereof.
Background technology
The all one's life of people about has the time of 80% to spend in indoor, and therefore, the quality of indoor environmental quality directly has influence on HUMAN HEALTH.From reality, IAQ (indoor air quality) is far inferior to outside atmosphere environment, and room air pollution degree usually more serious than outdoor air pollution 2 ~ 3 times, in some cases, even can reach more than 10 times.Can detect about 300 multiple pollutants in indoor, a lot of human body diseases is all relevant with room air pollution.Along with social development progress, the room air pollution that indoor decorating causes is more and more serious, causes the formaldehyde in the mainly finishing material of room air pollution, benzene-like compounds and ammoniac compounds etc., also has microorganism and nicotine material.
The appearance of algae clay coating well solves air pollution problem inside rooms, but lacks the algae clay product of flat painting type on the market at present, coarse in the algae clay product paint film feel of selling, and antibacterial and anti-mold effect still has deficiency, and can only adsorb but can not decomposing formaldehyde.
Summary of the invention
Object of the present invention provides the manufacture craft of the antibacterial algae clay paint of a kind of clean aldehyde.
For achieving the above object, the present invention by the following technical solutions:
A kind of clean antibacterial algae clay paint of aldehyde, according to parts by weight, consist of the following composition: the water of 18 ~ 22 parts, the dispersion agent of 0.5 ~ 0.8 part, the frostproofer of 0.8 ~ 1.2 part, the alcohol ester 12 of 0.8 ~ 1.5 part, the titanium dioxide of 10 ~ 25 parts, the Paris white of 15 ~ 20 parts, the nano silver antimicrobials of 0.5 ~ 1 part, the wollastonite powder of 2 ~ 6 parts, the wilkinite of 0.5 ~ 1.5 part, the thickening material of 0.5 ~ 3 part, the anionic additive of 0.3 ~ 0.8 part, the emulsion of 15 ~ 30 parts, the mould inhibitor of 0.15 ~ 0.3 part, the sanitas of 0.2 ~ 0.3 part, the defoamer of 0.3 ~ 0.5 part, the hydrophobizing agent of 0.1 ~ 0.2 part, the marine alga mud of 10 ~ 12 parts.
Further, dispersion agent is ammonium salt dispersion agent; Described frostproofer is propylene glycol.
Further, alcohol ester 12 is Texanol ester alcohol.
Further, titanium dioxide is Rutile type Titanium Dioxide.
Further, calcium carbonate is 800 ~ 1000 order calcium carbonate.
Further, thickening material is that west is across imperial 250HBR thickening material or Polyurethane thickening material.
Further, anionic additive is feel well TZY01-3 in sky.
Further, emulsion is Tao Shi DC-420V or U.S. Celanese VAE1608.
Further, mould inhibitor is ROCIMA343.
Further, sanitas is KATHONLXE sanitas or BLOBAN-TOBC40LE.
The preparation technology of the antibacterial algae clay paint of foregoing clean aldehyde, comprises the following steps:
(1) pre-mixing: add water in paint cylinder, then add the dispersion agent of half parts by weight, frostproofer, defoamer successively, low speed dispersion 3 ~ 5min, rotating speed controls at 300 ~ 600r/min;
(2) disperse: add again titanium dioxide, Paris white, wollastonite powder, 10% wilkinite slurry, higher speed dispersion 10 ~ 60min, rotating speed controls at 1000 ~ 1200r/min;
(3) auxiliary agent is added: the rotating speed of adjustment machine, to 1200-1500r/min, then adds mould inhibitor, anionic additive, nano silver antimicrobials, sanitas successively, dispersion 10 ~ 15min;
(4) defoamer is added: drop into the defoamer that the marine alga mud got ready in advance also adds emulsion and remaining half weight successively, pour polyurethane thickener into and slowly add in pan feeding with remaining water, dispersion 5 ~ 10min, obtains product.
The present invention has following beneficial effect:
1, the mud paint water suction oil suction that the clean aldehyde antibacterial algae clay paint water suction oil suction that the present invention obtains manufactures than general technology is few, makes it cause occurring quality problems depositing in process the oil suction that is not easy to absorb water;
2, the paint film of clean aldehyde antibacterial algae clay paint that the present invention obtains saves whole character of marine alga and has the function of stronger adsorption-decomposition function;
3, the antibacterial algae clay paint of clean aldehyde that the present invention obtains enhances algae clay paint and decomposes the ability of formaldehyde adsorption, more powerful more obtained than general technology of effect.Effectively can protect the over-all properties of algae clay;
4, the antibacterial algae clay paint of clean aldehyde that the present invention obtains can purify air by lasting releasing negative oxygen ion, keeps with fresh air; Humidity in automatic surge chamber, makes indoor moisture control to the degree of human body the most comfortable; Both solved common interiro wall latex paint at adsorption-decomposition function formaldehyde, eliminate deficiency in peculiar smell etc., also solve diatom ooze coating and only to adsorb and can not decomposing formaldehyde and the problem such as feel is coarse.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further:
Embodiment 1
The antibacterial algae clay paint of clean aldehyde of the present embodiment, according to parts by weight, comprise 21 parts of water, 0.6 part of dispersion agent, 1.0 parts of frostproofers, 1.5 parts of alcohol esters, 12,16 parts of titanium dioxides, 18 parts of Paris whites, 0.8 part of nano silver antimicrobials, 6 parts of silica ashes, 1.3 parts of wilkinites, 1.3 parts of thickening materials, 0.4 part of anionic additive, 21 parts of emulsions, 0.2 part of mould inhibitor, 0.25 portion of sanitass and 0.4 part of defoamers, 0.1 part of hydrophobizing agent, 10 parts of marine alga mud.
Prepare in accordance with the following methods:
(1) pre-mixing: add water in paint cylinder, then add the dispersion agent of half parts by weight, frostproofer, defoamer successively, low speed dispersion 3 ~ 5min, rotating speed controls at 300 ~ 600r/min;
(2) disperse: add again titanium dioxide, Paris white, wollastonite powder, 10% wilkinite slurry, higher speed dispersion 10 ~ 60min, rotating speed controls at 1000 ~ 1200r/min;
(3) auxiliary agent is added: the rotating speed of adjustment machine, to 1200-1500r/min, then adds mould inhibitor, anionic additive, nano silver antimicrobials, sanitas successively, dispersion 10 ~ 15min;
(4) defoamer is added: drop into the defoamer that the marine alga mud got ready in advance also adds emulsion and remaining half weight successively, pour polyurethane thickener into and slowly add in pan feeding with remaining water, dispersion 5 ~ 10min, obtains product.
Embodiment 2
The antibacterial algae clay paint of clean aldehyde of the present embodiment, according to parts by weight, comprise 22 parts of water, 0.8 part of dispersion agent, 1.0 parts of frostproofers, 1.5 parts of alcohol esters, 12,20 parts of titanium dioxides, 18 parts of Paris whites, 0.8 part of nano silver antimicrobials, 6 parts of silica ashes, 1.3 parts of wilkinites, 1.3 parts of thickening materials, 0.4 part of anionic additive, 23 parts of emulsions, 0.2 part of mould inhibitor, 0.25 portion of sanitass and 0.4 part of defoamers, 0.1 part of hydrophobizing agent, 10 parts of marine alga mud.
Prepare in accordance with the following methods:
(1) pre-mixing: add water in paint cylinder, then add the dispersion agent of half parts by weight, frostproofer, defoamer successively, low speed dispersion 3 ~ 5min, rotating speed controls at 300 ~ 600r/min;
(2) disperse: add again titanium dioxide, Paris white, wollastonite powder, 10% wilkinite slurry, higher speed dispersion 10 ~ 60min, rotating speed controls at 1000 ~ 1200r/min;
(3) auxiliary agent is added: the rotating speed of adjustment machine, to 1200-1500r/min, then adds mould inhibitor, anionic additive, nano silver antimicrobials, sanitas successively, dispersion 10 ~ 15min;
(4) defoamer is added: drop into the defoamer that the marine alga mud got ready in advance also adds emulsion and remaining half weight successively, pour polyurethane thickener into and slowly add in pan feeding with remaining water, dispersion 5 ~ 10min, obtains product.
The standard of antibacterial for clean aldehyde obtained by above-described embodiment algae clay paint by JC/T1074-2008 " function of purifying indoor air coating material purifying property " is detected, wherein the detected value of purifying formaldehyde efficiency is all more than 150, much larger than standard value 75, meet the requirement of " 1 class material " in this standard.
After testing, the clean aldehyde antibacterial algae clay paint of above embodiment still effectively can suppress the growth of various mould, bacterium, such as flavus, aspergillus niger, terreus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, Chaetomium globosum, intestinal bacteria, Bacillus subtilus, streptococcus aureus within half a year.
After testing, the clean aldehyde antibacterial algae clay paint VOC of above embodiment lower than 20g/L, far below the 120g/L of standard-required; Benzene, toluene, ethylbenzene, dimethylbenzene summation far below 4mg/kg, far below the 300mg/kg of standard-required; Soluble lead content lower than 3, far below standard value 90; Soluble cadmium content lower than 0.8, far below standard value 75; Soluble chromium content lower than 0.4, far below standard value 60; Soluble mercury content is lower than 0.5; Far below standard value 60; Free formaldehyde content lower than 30mg/kg, far below the 100mg/kg of standard-required.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, anyly belongs to those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.

Claims (9)

1. the antibacterial algae clay paint of clean aldehyde, it is characterized in that, according to parts by weight, consist of the following composition: the water of 18 ~ 22 parts, the dispersion agent of 0.5 ~ 0.8 part, the frostproofer of 0.8 ~ 1.2 part, the alcohol ester 12 of 0.8 ~ 1.5 part, the titanium dioxide of 10 ~ 25 parts, the Paris white of 15 ~ 20 parts, the nano silver antimicrobials of 0.5 ~ 1 part, the wollastonite powder of 2 ~ 6 parts, the wilkinite of 0.5 ~ 1.5 part, the thickening material of 0.5 ~ 3 part, the anionic additive of 0.3 ~ 0.8 part, the emulsion of 15 ~ 30 parts, the mould inhibitor of 0.15 ~ 0.3 part, the sanitas of 0.2 ~ 0.3 part, the defoamer of 0.3 ~ 0.5 part, the hydrophobizing agent of 0.1 ~ 0.2 part, the marine alga mud of 10 ~ 12 parts.
2. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described dispersion agent is ammonium salt dispersion agent; Described frostproofer is propylene glycol.
3. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described alcohol ester 12 is Texanol ester alcohol.
4. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described titanium dioxide is Rutile type Titanium Dioxide; Described calcium carbonate is 800 ~ 1000 order calcium carbonate.
5. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described thickening material is sub-to imperial 250HBR thickening material or Polyurethane thickening material.
6. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described anionic additive is feel well TZY01-3 in sky.
7. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described emulsion is Tao Shi DC-420V or U.S. Celanese VAE1608.
8. the antibacterial algae clay paint of clean aldehyde according to claim 1, is characterized in that, described mould inhibitor is ROCIMA343; Described sanitas is KATHONLXE sanitas or BLOBAN-TOBC40LE.
9. the preparation technology of the antibacterial algae clay paint of the clean aldehyde described in above-mentioned any one claim, it is characterized in that, comprise the following steps: (1) pre-mixing: in paint cylinder, add water, then dispersion agent, frostproofer, the defoamer of half parts by weight is added successively, low speed dispersion 3 ~ 5min, rotating speed controls at 300 ~ 600r/min;
(2) disperse: add again titanium dioxide, Paris white, wollastonite powder, 10% wilkinite slurry, higher speed dispersion 10 ~ 60min, rotating speed controls at 1000 ~ 1200r/min;
(3) auxiliary agent is added: the rotating speed of adjustment machine, to 1200-1500r/min, then adds mould inhibitor, anionic additive, nano silver antimicrobials, sanitas successively, dispersion 10 ~ 15min;
(4) defoamer is added: drop into the defoamer that the marine alga mud got ready in advance also adds emulsion and remaining half weight successively, pour polyurethane thickener into and slowly add in pan feeding with remaining water, dispersion 5 ~ 10min, obtains product.
(5) preparation of marine alga mud:
Water: 50-70
Efficient surfactant: 0.3-0.5
Mierocrystalline cellulose: 0.1-0.3
Dispersion agent: 0.2-0.5
Algae clay powder: 30-40
Multifunctional assistant: 0.1-0.3
The efficient surfactant of upper art is the G399 of Shanghai grid, and Mierocrystalline cellulose is sub-to imperial 250HBR, and dispersion agent is ammonium salt dispersion agent, and algae clay powder algae clay is 300 ~ 500 order algae clay through activation treatment, and multifunctional assistant is the AMP-95 of DOW Chemical.
CN201510725994.8A 2015-10-29 2015-10-29 Formaldehyde purifying antibacterial seaweed mud paint and production process thereof Pending CN105255241A (en)

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Application Number Priority Date Filing Date Title
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CN105255241A true CN105255241A (en) 2016-01-20

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517898A (en) * 2016-04-05 2017-03-22 中山市博瑞建材有限公司 Silver-loaded nano titanium dioxide bactericidal anti-mildew diatom mud and preparation method thereof
CN107115550A (en) * 2016-10-27 2017-09-01 三台县祺又环保科技有限公司 Air purifying preparation

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CN102277043A (en) * 2011-06-22 2011-12-14 嘉宝莉化工集团股份有限公司 Algae-clay air purification coating and preparation method thereof
CN102337064A (en) * 2011-07-16 2012-02-01 江苏冠军涂料科技集团有限公司 Algae clay mineral environmentally-friendly inner wall coating
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CN102277043A (en) * 2011-06-22 2011-12-14 嘉宝莉化工集团股份有限公司 Algae-clay air purification coating and preparation method thereof
CN102337064A (en) * 2011-07-16 2012-02-01 江苏冠军涂料科技集团有限公司 Algae clay mineral environmentally-friendly inner wall coating
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517898A (en) * 2016-04-05 2017-03-22 中山市博瑞建材有限公司 Silver-loaded nano titanium dioxide bactericidal anti-mildew diatom mud and preparation method thereof
CN106517898B (en) * 2016-04-05 2018-11-23 中山市博瑞建材有限公司 A kind of Ag-carried nanometer titanium dioxide fungus and mildew resistance diatom ooze and preparation method thereof
CN107115550A (en) * 2016-10-27 2017-09-01 三台县祺又环保科技有限公司 Air purifying preparation
CN107115550B (en) * 2016-10-27 2018-06-12 三台县祺又环保科技有限公司 Air purifying preparation

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Application publication date: 20160120