CN105238520A - Dehydrated antirust oil composition and application thereof - Google Patents
Dehydrated antirust oil composition and application thereof Download PDFInfo
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- CN105238520A CN105238520A CN201510680532.9A CN201510680532A CN105238520A CN 105238520 A CN105238520 A CN 105238520A CN 201510680532 A CN201510680532 A CN 201510680532A CN 105238520 A CN105238520 A CN 105238520A
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Abstract
The invention relates to a dehydrated antirust oil composition and application thereof. The problem that in the prior art, sealing antirust performance and dehydrate performance can not be well achieved at the same time is mainly solved. The dehydrate antirust oil composition is prepared from, by weight, 75-95 parts of base oil, 5-15 parts of oil-soluble sulfonic acid calcium salt, 0.5-7 parts of additives and 0.1-3 parts of dehydrating agent. According to the technical scheme, the problems are well solved, and the dehydrated antirust oil composition can be used for industrial production.
Description
Technical field
The present invention relates to a kind of dewatering rust preventive oil composition and use thereof.
Background technology
In recent years, along with the develop rapidly of China's automobile component processing industry, metal products for various automobile fitting part carries out processing and after the process such as cleaning at the use water-bearing media such as cutting fluid, clean-out system, automobile fitting workpiece surface remains a small amount of moisture or water-bearing media, if coating does not have the slushing oil of dehydrating function, the water stain of surface can not effectively be removed, and is easy to the corrosion causing workpiece.And as the dewatering rust preventive oil using water-soluble metalworking liquid processing and aqueous cleaning agent aftertreatment technology to use, obtained applying more widely in the production process of automobile fitting industry.
In prior art, dewatering rust preventive oil kind is more.Document CN1353173A discloses a kind of dewatering antirust oil, is made up of by weight following component: rust-preventive agent 4 ~ 8 parts, water-removal additive 1 ~ 5 part, 0.5 ~ 2 part, oxidation inhibitor, auxiliary 0.1 ~ 0.5 part, mineral base oil 85 ~ 93 parts.Document " research and apply of dewatering rust preventive oil; " plating and environmental protection " the 26th volume the 2nd phase in 2006 ", " development of ZYS-T20 dewatering rust preventive oil and application; " bearing " the 6th phase in 2011 ", " research and apply of Normal Temperature Dehydrating Antirust Oil; " plating and finish " the 26th volume the 4th phase in 2004 " etc., all describe triturating and the performance characteristics of related products in detail.
In sum, the dewatering rust preventive oil of all design based on sulfonic acid barium salt (not meeting the requirement of the American-European concerned countries of outlet without barium) of the product development in Patents and open source literature, its dewatering and seal rustless property for a long time up for safekeeping and can not balance satisfied preferably, major part only can be done to dewater, rust prevention during manufacture uses, or dehydrating effect is undesirable, modern industry requirement fast dewatering can not be met and seal antirust requirement for a long time up for safekeeping.
Summary of the invention
One of technical problem to be solved by this invention is dewatering rust preventive oil rustless property of the prior art and the afoul problem of dewatering, provides a kind of new dewatering rust preventive oil composition.Said composition has good rust-preventing characteristic and dewatering.Two of technical problem to be solved by this invention is to provide a kind of purposes of the dewatering rust preventive oil composition corresponding with one of technical solution problem.
For one of solving the problems of the technologies described above, the technical solution used in the present invention is as follows: a kind of dewatering rust preventive oil composition, with weight parts, comprises following component:
A) base oil of 75 ~ 95 parts;
B) the oil-soluble sulfonic acid calcium salt rust-preventive agent of 5 ~ 15 parts;
C) auxiliary of 0.5 ~ 7 part;
D) dewatering agent of 0.1 ~ 3 part;
Wherein, described base oil is selected from least one in mineral oil or solvent oil;
Described oil-soluble antirust agent is selected from least one in calcium mahogany sulfonate or calcium alkylbenzenesulfonate;
Described auxiliary is selected from least one in pentaerythritol stearate, C12 ~ 14 aliphatic alcohol ester, oleic acid, sad dicyclohexyl amine, KORANTIN SH, alkenyl succinic acid, dibutyl phthalate or alkenyl succinic acid ester;
Described dewatering agent be selected from ethers, alcohols or alcohol ether mixed at least one.
In technique scheme, preferably, with weight parts, the consumption of base oil is 80 ~ 92 parts, and the consumption of oil-soluble sulfonic acid calcium salt rust-preventive agent is 8 ~ 12 parts, and the consumption of auxiliary is 1 ~ 5 part, and the consumption of dewatering agent is 0.5 ~ 2.5 part.
In technique scheme, preferably, barium salt is not contained in described composition.
In technique scheme, preferably, mahogany acid barium salt is not contained in described composition.
In technique scheme, preferably, described oil-soluble sulfonic acid salt rust-preventive agent is selected from T101 (low alkali value calcium mahogany sulfonate), T102 (middle base number calcium mahogany sulfonate), T103 (high base number calcium mahogany sulfonate), T104 (low alkali value calcium alkylbenzenesulfonate), T105 (middle calcium alkylbenzensulfonates), T106 (high base number calcium alkylbenzenesulfonate), NA-SUL729 (neutral dinonylnaphthalene sulfonic acid calcium), NA-SULCA/W1146 (dinonylnaphthalene sulfonic acid calcium salt composition), KX1177 (dinonylnaphthalene sulfonic acid calcium salt composition), KX1183 (dinonylnaphthalene sulfonic acid calcium), CA-HT3 (dinonylnaphthalene sulfonic acid calcium carboxylate calcium complexes), Lockguard6400 (high base number calcium alkylbenzenesulfonate), Lockguard6941 (natural neutral calcium sulfonate), Lockguard6942 (synthesis neutral calcium sulfonate), RN714 (neutral calcium sulfonate), CA25 (neutral calcium sulfonate), AdditinRC4220 (neutral dialkyl benzene sulfonic acids calcium), at least one in NA-SULCA-1089 (dinonylnaphthalene sulfonic acid calcium carboxylate calcium complexes) or AdditinRC4210 (calcium sulphonate calcium carboxylates mixture).More preferably, described oil-soluble sulfonic acid calcium rust-preventive agent is selected from least one in NA-SUL729, NA-SULCA-1089, T102, KX1183, RN714, CA25, AdditinRC4220, Lockguard6941 or Lockguard6942.
In technique scheme, preferably, described auxiliary is selected from least one in oleic acid, sad dicyclohexyl amine, KORANTIN SH, alkenyl succinic acid, dibutyl phthalate or alkenyl succinic acid ester.
In technique scheme, preferably, described dewatering agent is selected from least one in butanols, sherwood oil, fatty alcohol, C12 ~ 14 polyoxyethylenated alcohol, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, C8 ~ 22 polyoxyethylenated alcohol or fatty alcohol-ether.More preferably, described dewatering agent is selected from least one in alkylphenol polyoxyethylene, fatty alcohol, C12 ~ 14 polyoxyethylenated alcohol, fatty alcohol-polyoxyethylene ether, C8 ~ 22 polyoxyethylenated alcohol or fatty alcohol-ether.
In technique scheme, preferably, described mineral oil be selected from HVIIa75,100,125,150,250,350,400,500,650,750,90BS, 120BS, 150BS; Or HVIIb75,100,125,150,250,350,400,500,650,750,90BS, 120BS, 150BS; Or HVIIc75,100,125,150,250,350,400,500,650,750, at least one in 90BS, 120BS, 150BS.More preferably, mineral oil is selected from least one in HVIIc75,100,125,150,250,350,400,500,650,750.
In technique scheme, preferably, solvent oil is selected from least one in D60, D70, D80, D100, D110, D120 and D130.
The preparation method of dewatering rust preventive oil composition of the present invention, comprise: by base oil 40 ~ 50 DEG C of heated and stirred, add oil-soluble sulfonic acid calcium salt rust-preventive agent, auxiliary and dewatering agent more successively, 35 ~ 45 DEG C of constant temperature stir 1 ~ 2 hour, through 10um bag type filtering, obtain described dewatering rust preventive oil composition.
For solve the problems of the technologies described above two, the technical solution used in the present invention is as follows: described dewatering rust preventive oil composition be used for automobile fitting part product dehydration and seal up for safekeeping antirust.
The present composition is not containing heavy metal barium, and employing calcium sulphonate is rust-preventive agent, belongs to environmental protection friendly product.Make full use of the excellent permeability of Porous deproteinized bone harmonic motion viscosity solution base oil, the advantage of cleaning, complex calcium sulfonate base high-performance rust-preventive agent, then coordinate special water-removal additive, thus there is good rustless property, dewatering.The water-bearing media displacement that described anticorrosive oil composition can be used for automobile fitting product is removed and seals up for safekeeping antirust.Present composition rustless property and dewatering are taken into account, and under the prerequisite meeting product fast dewatering (normal circumstances can be dewatered complete in 1min) performance, what do not affect product seals rustless property up for safekeeping for a long time.Salt-fog test energy (45# steel) was more than 48 hours, and indoor antirust more than 1 year of the preservation and packaging after the process of automobile fitting product dehydrate, the product of band volatile rust prevention bag is antirust can reach more than 3 years, achieves good technique effect.
Below by embodiment, the invention will be further elaborated.
Embodiment
[embodiment 1 ~ 6]
By the parts by weight in table 1, base oil is added blending kettle, 40 ~ 50 DEG C of heated and stirred, add oil-soluble sulfonic acid calcium salt rust-preventive agent, auxiliary and dewatering agent more successively, 35 ~ 45 DEG C of constant temperature stir 1 ~ 2 hour, through 10um bag type filtering, obtain described dewatering rust preventive oil composition.
[comparative example 1]
Method disclosed in document CN1353173A, add base oil 85 ~ 93 parts in a kettle., be heated to 150 ~ 180 DEG C, add 4 ~ 8 parts of rust-preventive agent, 0.5 ~ 2 part of oxidation inhibitor again, stir and fully dissolve, wait to naturally cool to less than 60 DEG C, add 0.1 ~ 0.5 part of other additive, 1 ~ 5 part of dewatering agent, stirring and evenly mixing, naturally cools to room temperature and namely obtains this dewatering rust preventive oil.
Wherein, base oil is the transformer oil of 49.5% and the solar oil of 40%.Rust-preventive agent be the barium mahogany sulfonate of 4%, the stearic acid of 2% and 1% zinc naphthenate three kinds of material compounds.Oxidation inhibitor is the dialkyl group Resorcinol of 0.5%.Dewatering agent is the sherwood oil of 2%.Other additives are the phytic acid of 1%.
As shown in Table 2, [embodiment 1 ~ 6] over-all properties such as rustless property and dewatering provided by the present invention is all better than [comparative example 1].
Claims (10)
1. a dewatering rust preventive oil composition, with weight parts, comprises following component:
A) base oil of 75 ~ 95 parts;
B) the oil-soluble sulfonic acid calcium salt rust-preventive agent of 5 ~ 15 parts;
C) auxiliary of 0.5 ~ 7 part;
D) dewatering agent of 0.1 ~ 3 part;
Wherein, described base oil is selected from least one in mineral oil or solvent oil;
Described oil-soluble antirust agent is selected from least one in calcium mahogany sulfonate or calcium alkylbenzenesulfonate;
Described auxiliary is selected from least one in pentaerythritol stearate, C12 ~ 14 aliphatic alcohol ester, oleic acid, sad dicyclohexyl amine, KORANTIN SH, alkenyl succinic acid, dibutyl phthalate or alkenyl succinic acid ester;
Described dewatering agent be selected from ethers, alcohols or alcohol ether mixed at least one.
2. dewatering rust preventive oil composition according to claim 1, it is characterized in that with weight parts, the consumption of base oil is 80 ~ 92 parts, and the consumption of oil-soluble sulfonic acid calcium salt rust-preventive agent is 8 ~ 12 parts, the consumption of auxiliary is 1 ~ 5 part, and the consumption of dewatering agent is 0.5 ~ 2.5 part.
3. dewatering rust preventive oil composition according to claim 1, is characterized in that in described composition not containing barium salt.
4. dewatering rust preventive oil composition according to claim 1, is characterized in that in described composition not containing mahogany acid barium salt.
5. dewatering rust preventive oil composition according to claim 1, is characterized in that described oil-soluble sulfonic acid salt rust-preventive agent is selected from least one in T101, T102, T103, T104, T105, T106, NA-SUL729, NA-SULCA/W1146, KX1177, KX1183, CA-HT3, Lockguard6400, Lockguard6941, Lockguard6942, RN714, CA25, AdditinRC4220, NA-SULCA-1089 or AdditinRC4210.
6. dewatering rust preventive oil composition according to claim 5, is characterized in that described oil-soluble sulfonic acid calcium rust-preventive agent is selected from least one in NA-SUL729, NA-SULCA-1089, T102, KX1183, RN714, CA25, AdditinRC4220, Lockguard6941 or Lockguard6942.
7. dewatering rust preventive oil composition according to claim 1, is characterized in that described auxiliary is selected from least one in oleic acid, sad dicyclohexyl amine, KORANTIN SH, alkenyl succinic acid, dibutyl phthalate or alkenyl succinic acid ester.
8. dewatering rust preventive oil composition according to claim 1, is characterized in that described dewatering agent is selected from least one in butanols, sherwood oil, fatty alcohol, C12 ~ 14 polyoxyethylenated alcohol, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, C8 ~ 22 polyoxyethylenated alcohol or fatty alcohol-ether.
9. dewatering rust preventive oil composition according to claim 8, is characterized in that described dewatering agent is selected from least one in alkylphenol polyoxyethylene, fatty alcohol, C12 ~ 14 polyoxyethylenated alcohol, fatty alcohol-polyoxyethylene ether, C8 ~ 22 polyoxyethylenated alcohol or fatty alcohol-ether.
10. the arbitrary described dewatering rust preventive oil composition of claim 1 ~ 9 is used for the dehydration of automobile fitting part product and seals up for safekeeping antirust.
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| CN201510680532.9A CN105238520B (en) | 2015-10-19 | 2015-10-19 | Dewatering rust preventive oil composition and application thereof |
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| CN105238520B CN105238520B (en) | 2018-06-15 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118811A (en) * | 2016-06-22 | 2016-11-16 | 上海尤希路化学工业有限公司 | Thief zone, high oil-water separativeness environment-friendly type operation antirust oil |
| CN106635283A (en) * | 2016-09-20 | 2017-05-10 | 中国石油化工股份有限公司 | Thixotropic antirust oil composition |
| CN107286290A (en) * | 2017-05-26 | 2017-10-24 | 奎克化学（中国）有限公司 | A kind of Self-cleaning type antirust oil for metal base |
| CN108441299A (en) * | 2018-04-13 | 2018-08-24 | 华阳新兴科技（天津）集团有限公司 | A kind of water displaced type film rust proof oil and preparation method thereof |
| CN109022109A (en) * | 2018-07-31 | 2018-12-18 | 东莞市凯盟表面处理技术开发有限公司 | A kind of copper material antirust oil, preparation method and its application |
| CN109594092A (en) * | 2018-12-18 | 2019-04-09 | 北美防锈技术（上海）有限公司 | Dehydrating agent between a kind of process |
| CN109593593A (en) * | 2018-05-22 | 2019-04-09 | 中国石油天然气股份有限公司 | Antirust oil and preparation method thereof |
| CN109943400A (en) * | 2019-03-25 | 2019-06-28 | 广州科卢斯流体科技有限公司 | A kind of environment-protective water displacing type rust preventive oil |
| CN110157530A (en) * | 2019-05-28 | 2019-08-23 | 马鞍山华之杰金属表面处理剂有限公司 | A kind of environmental protection multiple-effect antirust agent and preparation method thereof |
| CN110257189A (en) * | 2019-07-01 | 2019-09-20 | 张娟娟 | A kind of industrial greasy dirt detergent and preparation method thereof again |
| CN110437917A (en) * | 2019-08-23 | 2019-11-12 | 广州市联诺化工科技有限公司 | A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof |
| CN111635805A (en) * | 2020-05-25 | 2020-09-08 | 广东欧派斯润滑科技有限公司 | Firearm protection oil and preparation method thereof |
| CN111868305A (en) * | 2018-03-28 | 2020-10-30 | 出光兴产株式会社 | Rust preventive oil composition and method for producing same |
| CN111925854A (en) * | 2020-08-13 | 2020-11-13 | 华阳-恩赛有限公司 | Lubricating oil type high-salt-spray dehydrated antirust oil, and preparation method and application thereof |
| CN114058429A (en) * | 2021-10-22 | 2022-02-18 | 华润宝润滑科技(宁波)有限公司 | Steel pipe antirust oil capable of improving drainage performance |
| CN114164032A (en) * | 2021-12-09 | 2022-03-11 | 安美科技股份有限公司 | Dehydrating bearing antirust agent composition |
| CN116855298A (en) * | 2022-03-28 | 2023-10-10 | 中国石油化工股份有限公司 | Rust-proof oil and preparation method and application thereof |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118811A (en) * | 2016-06-22 | 2016-11-16 | 上海尤希路化学工业有限公司 | Thief zone, high oil-water separativeness environment-friendly type operation antirust oil |
| CN106635283A (en) * | 2016-09-20 | 2017-05-10 | 中国石油化工股份有限公司 | Thixotropic antirust oil composition |
| CN107286290B (en) * | 2017-05-26 | 2020-08-04 | 奎克化学（中国）有限公司 | Self-cleaning type anti-rust oil for metal base material |
| CN107286290A (en) * | 2017-05-26 | 2017-10-24 | 奎克化学（中国）有限公司 | A kind of Self-cleaning type antirust oil for metal base |
| CN111868305A (en) * | 2018-03-28 | 2020-10-30 | 出光兴产株式会社 | Rust preventive oil composition and method for producing same |
| CN108441299A (en) * | 2018-04-13 | 2018-08-24 | 华阳新兴科技（天津）集团有限公司 | A kind of water displaced type film rust proof oil and preparation method thereof |
| CN109593593A (en) * | 2018-05-22 | 2019-04-09 | 中国石油天然气股份有限公司 | Antirust oil and preparation method thereof |
| CN109022109A (en) * | 2018-07-31 | 2018-12-18 | 东莞市凯盟表面处理技术开发有限公司 | A kind of copper material antirust oil, preparation method and its application |
| CN109022109B (en) * | 2018-07-31 | 2021-05-28 | 东莞市凯盟表面处理技术开发有限公司 | Copper material anti-rust oil, preparation method and application thereof |
| CN109594092A (en) * | 2018-12-18 | 2019-04-09 | 北美防锈技术（上海）有限公司 | Dehydrating agent between a kind of process |
| CN109943400A (en) * | 2019-03-25 | 2019-06-28 | 广州科卢斯流体科技有限公司 | A kind of environment-protective water displacing type rust preventive oil |
| CN110157530A (en) * | 2019-05-28 | 2019-08-23 | 马鞍山华之杰金属表面处理剂有限公司 | A kind of environmental protection multiple-effect antirust agent and preparation method thereof |
| CN110257189A (en) * | 2019-07-01 | 2019-09-20 | 张娟娟 | A kind of industrial greasy dirt detergent and preparation method thereof again |
| CN110437917A (en) * | 2019-08-23 | 2019-11-12 | 广州市联诺化工科技有限公司 | A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof |
| CN111635805A (en) * | 2020-05-25 | 2020-09-08 | 广东欧派斯润滑科技有限公司 | Firearm protection oil and preparation method thereof |
| CN111925854A (en) * | 2020-08-13 | 2020-11-13 | 华阳-恩赛有限公司 | Lubricating oil type high-salt-spray dehydrated antirust oil, and preparation method and application thereof |
| CN114058429A (en) * | 2021-10-22 | 2022-02-18 | 华润宝润滑科技(宁波)有限公司 | Steel pipe antirust oil capable of improving drainage performance |
| CN114164032A (en) * | 2021-12-09 | 2022-03-11 | 安美科技股份有限公司 | Dehydrating bearing antirust agent composition |
| CN116855298A (en) * | 2022-03-28 | 2023-10-10 | 中国石油化工股份有限公司 | Rust-proof oil and preparation method and application thereof |
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