CN109943400A - A kind of environment-protective water displacing type rust preventive oil - Google Patents

A kind of environment-protective water displacing type rust preventive oil Download PDF

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Publication number
CN109943400A
CN109943400A CN201910228249.0A CN201910228249A CN109943400A CN 109943400 A CN109943400 A CN 109943400A CN 201910228249 A CN201910228249 A CN 201910228249A CN 109943400 A CN109943400 A CN 109943400A
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China
Prior art keywords
environment
rust preventive
parts
preventive oil
protective water
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Withdrawn
Application number
CN201910228249.0A
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Chinese (zh)
Inventor
陈育祥
李朝圣
李稳新
孙明
叶飞
任清刚
李茂生
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Guangzhou Kelusi Fluid Technology Co Ltd
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Guangzhou Kelusi Fluid Technology Co Ltd
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Priority to CN201910228249.0A priority Critical patent/CN109943400A/en
Publication of CN109943400A publication Critical patent/CN109943400A/en
Withdrawn legal-status Critical Current

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  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The present invention relates to metal surface treatment technology domains, and in particular to a kind of environment-protective water displacing type rust preventive oil and its technology of preparing.A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction: 75-90 parts of base oil;5-15 parts of antirust agent;2-5 parts of dehydrating agent;1-5 parts of adjuvant.The present invention uses homemade antirust agent, has excellent water substituting and rust-preventing characteristic, can meet American-European environmental requirement, solves the problems, such as to export the antirust, anti-corrosive of American-European metal processing piece, while significantly reducing production cost for client.

Description

A kind of environment-protective water displacing type rust preventive oil
Technical field
The present invention relates to field of metal surface treatment technology, and in particular to a kind of environment-protective water displacing type rust preventive oil and its preparation Technology.
Background technique
In metal-working industry, due to laying in or in a short time can not carry out the processing of next process, It places it in warehouse and saves, in library procedure, metal can be because of the different environment of surrounding, and more or less is corroded. It will affect the characteristic of itself after corrosion and interfere its following process or use, the loss as caused by metal erosion every year is Huge, the meaning of protection is particularly important.Especially in the cutting process, cutting and water base clear is being carried out using aqueous cutting fluid It, can be certain water stain in workpiece surface residual after lotion is cleaned.If spraying the antirust oil of not dehydrating function, the water on surface Stain cannot be removed effectively, it is easy to cause the corrosion of workpiece.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of barium-free, environment-friendly type water displacing type rust preventive oils.
A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction:
75-90 parts of base oil;5-15 parts of antirust agent;2-5 parts of dehydrating agent;1-5 parts of adjuvant.
Further, the antirust agent is sulfanilic acid.
The sulfanilic acid synthesizes in accordance with the following methods:
Petroleum sodium sulfonate and alkylamine are pressed into content molar ratio for 1:1.5~1:2.0 addition reaction kettle, in extraction kettle It obtains air to air pressure and is less than or equal to 100Pa, being filled with nitrogen to air pressure is 3~3.5MPa;
Constant temperature stirs 120-140min after being heated to 110-120 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 130-140 DEG C, constant temperature stirs 60-80min, is evaporated under reduced pressure out excessive alkylamine;The sulfanilic acid that can be produced after cooling.
Further, the alkylamine is monoamine base.
Further, carbon atom is 14-20 in the alkylamine.
Further, the adjuvant is basic aluminium stearate.
Further, the dehydrating agent is at least one of oleic acid and fatty acid polyethylene ether.
Base oil of the invention can select the common white mineral oil of the art or solvent that the present invention can be achieved, excellent Select at least one of D60, D70, D80 and D100 in solvent naphtha.
Environment-protective water displacing type rust preventive oil of the invention can be prepared by the stirring accord method of this field routine:
Base oil investment blending kettle is heated to 35-50 DEG C and is stirred, antirust agent, adjuvant and dehydration are sequentially added Agent stirs 1-2 hours under the conditions of 35-45 DEG C of constant temperature to get the environment-protective water displacing type rust preventive oil.
The invention has the following beneficial effects:
The present invention has excellent rust-preventing characteristic and water substituting, can meet American-European environmental requirement without heavy metal, solve Export the antirust, anti-corrosive problem of American-European metal processing piece;Using homemade antirust agent, not only favorable rust preventing effect, but also can replace For similar high-end product, purchase cost is significantly reduced for client.
Specific embodiment
The present invention will now be described in detail with reference to examples, and the examples are only preferred embodiments of the present invention, It is not limitation of the invention.
Embodiment 1:
The sulfanilic acid of the present embodiment synthesizes in accordance with the following methods:
Reaction kettle is added by content molar ratio for 1:1.5 in petroleum sodium sulfonate and tetradecylamine, in extraction kettle Air to air pressure is less than or equal to 100Pa, and being filled with nitrogen to air pressure is 3MPa;
Constant temperature stirs 120min after being heated to 115 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 135 DEG C, constant temperature 70min is stirred, excessive tetradecylamine is evaporated under reduced pressure out;The sulfanilic acid that can be produced after cooling.
A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction: 84 parts of D100, sulfonic acid 8 parts of amine, 5 parts of oleic acid, 3 parts of basic aluminium stearate.
Embodiment 2:
The sulfanilic acid of the present embodiment synthesizes in accordance with the following methods:
Reaction kettle is added by content molar ratio for 1:1.7 in petroleum sodium sulfonate and hexadecylamine, in extraction kettle Air to air pressure is less than or equal to 100Pa, and being filled with nitrogen to air pressure is 3.2MPa;
Constant temperature stirs 140min after being heated to 110 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 140 DEG C, constant temperature 80min is stirred, excessive hexadecylamine is evaporated under reduced pressure out;The sulfanilic acid that can be produced after cooling.
A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction: 86 parts of D80, sulfanilic acid 8 parts, 2 parts of fatty acid polyethylene ether, 4 parts of basic aluminium stearate.
Embodiment 3:
The sulfanilic acid of the present embodiment synthesizes in accordance with the following methods:
Reaction kettle is added by content molar ratio for 1:2.0 in petroleum sodium sulfonate and heptadecyl amine, in extraction kettle Air to air pressure is less than or equal to 100Pa, and being filled with nitrogen to air pressure is 3.5MPa;
Constant temperature stirs 120min after being heated to 120 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 130 DEG C, constant temperature 60min is stirred, excessive heptadecyl amine is evaporated under reduced pressure out;The sulfanilic acid that can be produced after cooling.
A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction: 48 parts of D60, D70 37 Part, 10 parts of sulfanilic acid, 3 parts of oleic acid, 2 parts of basic aluminium stearate.
Embodiment 4:
The sulfanilic acid of the present embodiment synthesizes in accordance with the following methods:
Reaction kettle is added by content molar ratio for 1:2.0 in petroleum sodium sulfonate and octadecylamine, in extraction kettle Air to air pressure is less than or equal to 100Pa, and being filled with nitrogen to air pressure is 3.1MPa;
Constant temperature stirs 125min after being heated to 115 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 135 DEG C, constant temperature 65min is stirred, excessive octadecylamine is evaporated under reduced pressure out;The sulfanilic acid that can be produced after cooling.
A kind of environment-protective water displacing type rust preventive oil composition, is grouped as by the group of following mass fraction: 50 parts of D60, D70 34 Part, 12 parts of sulfanilic acid, 3 parts of fatty acid polyethylene ether, 2 parts of basic aluminium stearate.
Correlated performance test, test are carried out to the embodiment of the present invention according to the performance test methods of the art routine As a result as shown in the table:
Above is only a specific embodiment of the present invention, but structure feature of the invention is not limited to this, any ability Within the field of the present invention, made changes or modifications all cover in the scope of the patents of the invention the technical staff in domain.

Claims (7)

1. a kind of environment-protective water displacing type rust preventive oil composition, which is characterized in that be grouped as by the group of following mass fraction:
75-90 parts of base oil;5-15 parts of antirust agent;2-5 parts of dehydrating agent;1-5 parts of adjuvant.
2. a kind of environment-protective water displacing type rust preventive oil composition according to claim 1, which is characterized in that the antirust agent is Sulfanilic acid.
3. a kind of environment-protective water displacing type rust preventive oil composition according to claim 2, which is characterized in that the sulfanilic acid is pressed It is synthesized according to following methods:
Reaction kettle is added by content molar ratio for 1:1.5~1:2.0 in petroleum sodium sulfonate and alkylamine, is had leisure in extraction kettle Gas to air pressure is less than or equal to 100Pa, and being filled with nitrogen to air pressure is 3~3.5MPa;
Constant temperature stirs 120-140min after being heated to 110-120 DEG C, and extraction nitrogen to air pressure is less than 300Pa, is heated to 130-140 DEG C, constant temperature stirs 60-80min, is evaporated under reduced pressure out excessive alkylamine;The sulfanilic acid that can be produced after cooling.
4. a kind of environment-protective water displacing type rust preventive oil composition according to claim 3, which is characterized in that the alkylamine For monoamine base.
5. a kind of environment-protective water displacing type rust preventive oil composition according to claim 4, which is characterized in that the alkylamine Middle carbon atom is 14-20, and more conducively grease proofing oil film is formed and the performance of rust-proof effect.
6. a kind of environment-protective water displacing type rust preventive oil composition according to claim 1, which is characterized in that the adjuvant For basic aluminium stearate.
7. a kind of environment-protective water displacing type rust preventive oil composition according to claim 1, which is characterized in that the dehydrating agent For at least one of oleic acid and fatty acid polyethylene ether.
CN201910228249.0A 2019-03-25 2019-03-25 A kind of environment-protective water displacing type rust preventive oil Withdrawn CN109943400A (en)

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CN201910228249.0A CN109943400A (en) 2019-03-25 2019-03-25 A kind of environment-protective water displacing type rust preventive oil

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5322631A (en) * 1991-05-02 1994-06-21 Yushiro Chemical Industry Co., Ltd. Water-soluble lubricant composition
JP2004196830A (en) * 2002-10-24 2004-07-15 Neos Co Ltd Water-soluble metal working fluid composition
CN102459705A (en) * 2009-06-29 2012-05-16 吉坤日矿日石能源株式会社 Rust-preventive oil composition
CN103384730A (en) * 2009-09-09 2013-11-06 吉坤日矿日石能源株式会社 Anticorrosive oil composition
CN105238520A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Dehydrated antirust oil composition and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5322631A (en) * 1991-05-02 1994-06-21 Yushiro Chemical Industry Co., Ltd. Water-soluble lubricant composition
JP2004196830A (en) * 2002-10-24 2004-07-15 Neos Co Ltd Water-soluble metal working fluid composition
CN102459705A (en) * 2009-06-29 2012-05-16 吉坤日矿日石能源株式会社 Rust-preventive oil composition
CN103384730A (en) * 2009-09-09 2013-11-06 吉坤日矿日石能源株式会社 Anticorrosive oil composition
CN105238520A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Dehydrated antirust oil composition and application thereof

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
中国石油化工集团公司人事教育部: "《多种经营企业产品手册》", 30 September 1998, 中国石化出版社 *
王林山等: "《大学化学》", 31 August 2005, 冶金工业出版社 *
舍赫捷尔(苏): "《防锈油》", 28 February 1966, 中国工业出版社 *
范树清等: "《金属防锈及其试验方法》", 31 March 1989, 机械工业出版社 *
龚玉山: "油溶性防锈剂及其防蚀性能", 《材料保护》 *

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