CN104818082A - Low viscosity long-acting dehydrated antirust oil - Google Patents
Low viscosity long-acting dehydrated antirust oil Download PDFInfo
- Publication number
- CN104818082A CN104818082A CN201510108369.9A CN201510108369A CN104818082A CN 104818082 A CN104818082 A CN 104818082A CN 201510108369 A CN201510108369 A CN 201510108369A CN 104818082 A CN104818082 A CN 104818082A
- Authority
- CN
- China
- Prior art keywords
- oil
- long
- acting
- low viscosity
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Belonging to the field of metal material surface treatment rust prevention, the invention specifically relates to a low viscosity long-acting dehydrated antirust oil and a preparation method thereof. The antirust oil is formed mainly by compounding of basic mineral oil, a film forming agent, a dehydration additive, an antirust additive and other additives. The long-acting antirust oil provided by the invention has the advantages of low viscosity, convenient use, good low temperature use effect, and long rust-proof life, and is generally suitable for long term antirust preservation of steel workpieces indoors. The outstanding characteristic of the antirust oil lies in that the oil membrane has good sunlight and rain erosion resistant effects, and is especially suitable for long-term antirust treatment of metal piece outdoor deposition, transportation process and engineering machinery export sea transportation.
Description
Technical field
The invention belongs to the antirust field of metal material surface process, be specifically related to a kind of low viscous long-acting dewatering rust preventive oil, and preparation method thereof.
Background technology
Along with the division of labor of production upstream is more and more professional, more and more refinement, logistics is day by day convenient in addition, and manufacturing components supplying chain is tending towards trans-regionalization, and even the whole world shares, and the sea-freight export volume of complete machine is also increasing.And due to the perishable characteristic of metallic substance itself, the problem of rustiness of machinework in manufacture, long storage periods, long-time transportation seriously hinders the cooperation relation in economic activity.In order to meet the requirement for anticorrosion of metal works under severe conditions, usual employing inert metal coating process (plating or electroless plating) coordinates the passivation antirust treatment in later stage to meet the requirement in industrial production again, this type of complex technical process, cost is high, also brings serious environmental pollution; Also having to place hope on directly adopts slushing oil process to reach the object of dealing with problems, but various slushing oil is unsatisfactory for the rust-proof effect of long storage periods, long-time transportation under severe condition on the market at present.
Therefore, exploitation one is really applicable to the indoor long-term rust prevention of metal products, outdoor storage, transportation long-term rust prevention, and the slushing oil product of construction machinery export sea-freight process long-term rust prevention has important engineering significance and economic worth.
Summary of the invention
Object of the present invention is mainly for the indoor long storage periods of current slushing oil product for metal products under severe condition, outdoor storage, transport be the medium-term and long-term antirust undesirable present situation of sea-freight process particularly, provides a kind of low viscous long-acting dewatering rust preventive oil and preparation method thereof.
For achieving the above object, technical scheme of the present invention comprises by being formed with volume fraction: membrane-forming agent 5% to 10%, basic mineral oil 73% to 84.5%, rust-inhibiting additive 8.5% to 12%, water-removal additive 1% to 3%, oxygenant 0.5% to 2%.
Wherein membrane-forming agent is a kind of mantle membrane-forming agent, by organo-siloxane, oil resin, modified rosin, acid modified alcoholic resin any two kinds or three kinds composite.
Wherein basic mineral oil by aviation kerosene, clean kerosene, tasteless kerosene, solar oil, spindle oil, machinery oil, hydraulic efficiency oil, industrial white oil, solvent oil any two kinds composite.
Wherein rust-inhibiting additive by barium mahogany sulfonate, petroleum sodium sulfonate, petrolic magnesium sulfonate, alkenyl succinic acid, zinc naphthenate, aluminum stearate, oxidized petrolatum, lanolin, sulfonation lanolin calcium salt any three kinds or four kinds composite.
Wherein water-removal additive by oleic acid, ethanol, Virahol, propyl carbinol, isopropylcarbinol, amylalcohol, trolamine, sherwood oil any two kinds composite.
Oxygenant is wherein made up of any two kinds in benzotriazole, department's benzene-80, Resorcinol.
Blending process of the present invention is:
(1) modification of each component of membrane-forming agent and composite: take each component of membrane-forming agent by mass fraction, constant temperature high speed shear blending dispersion 2 to 5 hours, cools for subsequent use at 70 DEG C to 80 DEG C temperature.
(2) rust-inhibiting additive is composite: take each component by mass fraction, with basic mineral oil for solvent, heats while stirring, until each components dissolved is complete, continues stirring 10 to 30 minutes, cools for subsequent use.
(3) join in container by basic mineral oil, under normal temperature condition, add composite membrane-forming agent, rust-inhibiting additive, water-removal additive and oxidant constituents respectively, limit edged stirs until each component disperses is complete, crosses and filters to remove impurity, collect finished product.
Beneficial effect of the present invention is: (1) has dehydrating function, and metal works immersion oil pre-treating technology is simple.(2) long-acting antirust performance is good; the soft film type protective membrane of dense hydrophobic and multiple composite rust-inhibiting additive acting in conjunction; in isolated air, oxygen directly contacts with bare metal face with water molecules, guarantees the object reaching long-term rust prevention, and neutral salt spray test test reaches more than 100 hours.(3) include antirust composition specially for the design of outdoor environment long-term rust prevention, the oil film of formation can stand sunshine and rain drop erosion for a long time and not be destroyed, and applicable metal products is sealed up for safekeeping antirust for a long time, and the antirust and outdoor placement long-term rust prevention of transportation uses.
Embodiment
Embodiment 1
Membrane-forming agent is formed with the alkyd resin of Modification design is voluntarily composite by organo-siloxane, solvent is made with clean kerosene and hydraulic efficiency oil, the mass ratio of organo-siloxane and alkyd resin is 1:4, be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is 80 DEG C, and the time is 5 hours.
Rust-inhibiting additive by barium mahogany sulfonate, zinc naphthenate, aluminum stearate, oxidized petrolatum is composite forms, mass ratio between them is 2:1:1:3 in order, be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is not less than 70 DEG C, and the time is 2 hours.
Water-removal additive is ethanol, sherwood oil, and mass ratio is 1:2.
Oxygenant is benzotriazole, Resorcinol, and mass ratio is 1:3.
Basis mineral oil is made up of with the volume ratio of 6:3 clean kerosene and machinery oil.
Mineral oil 78% based on the volume ratio of described each component, membrane-forming agent 10%, rust-inhibiting additive 10%, water-removal additive 1%, oxygenant 1%.
Basic mineral oil is joined in container, composite membrane-forming agent, rust-inhibiting additive, water-removal additive and oxidant constituents is added respectively under normal temperature condition, limit edged stirs until each component disperses is complete, crosses and filters to remove impurity, obtain low viscous long-acting dewatering rust preventive oil.
Embodiment 2
Membrane-forming agent by oil resin, acid modified alcoholic resin, organo-siloxane is composite forms, solvent is made with clean kerosene and hydraulic efficiency oil, the mass ratio of oil resin, acid modified alcoholic resin, organo-siloxane is 2:3:1, be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is 80 DEG C, and the time is 5 hours.
Rust-inhibiting additive by barium mahogany sulfonate, zinc naphthenate, aluminum stearate, oxidized petrolatum is composite forms, mass ratio between them is 2:1:1:3 in order, be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is not less than 70 DEG C, and the time is 2 hours.
Water-removal additive is trolamine, sherwood oil, and mass ratio is 1:2.
Oxygenant is benzotriazole, Resorcinol, and mass ratio is 1:3.
Basis mineral oil is made up of with the volume ratio of 6:3 clean kerosene and machinery oil.
Mineral oil 80% based on the volume ratio of described each component, membrane-forming agent 8%, rust-inhibiting additive 10%, water-removal additive 1%, oxygenant 1%.
Base oil is joined in container, composite membrane-forming agent, rust-inhibiting additive, water-removal additive and oxidant constituents is added respectively under normal temperature condition, limit edged stirs until each component disperses is complete, crosses and filters to remove impurity, obtain low viscous long-acting dewatering rust preventive oil.
Embodiment 3
Membrane-forming agent by oil resin, acid modified alcoholic resin, organo-siloxane is composite forms, solvent is made with clean kerosene and hydraulic efficiency oil, the mass ratio of oil resin, acid modified alcoholic resin, organo-siloxane is 2:3:1, be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is 80 DEG C, and the time is 5 hours.
Rust-inhibiting additive by petrolic magnesium sulfonate, zinc naphthenate, sulfonation lanolin calcium salt is composite forms, mass ratio between them is 3:1:2 in order, and be that the clean kerosene of 1:1 and hydraulic efficiency oil make solvent with mass ratio, quantity of solvent accounts for 80% of total amount, composite temperature is not less than 70 DEG C, and the time is 3 hours.
Water-removal additive is propyl carbinol, sherwood oil, and mass ratio is 1:1.
Oxygenant is benzotriazole, Resorcinol, and mass ratio is 1:3.
Basis mineral oil is made up of with the volume ratio of 6:3 clean kerosene and machinery oil
Mineral oil 78% based on the volume ratio of described each component, membrane-forming agent 8%, rust-inhibiting additive 12%, water-removal additive 1%, oxygenant 1%.
Base oil is joined in container, composite membrane-forming agent, rust-inhibiting additive, water-removal additive and oxidant constituents is added respectively under normal temperature condition, limit edged stirs until each component disperses is complete, crosses and filters to remove impurity, obtain low viscous long-acting dewatering rust preventive oil.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (7)
1. a low viscous long-acting dewatering rust preventive oil, is characterized in that, comprises by being formed with volume fraction: membrane-forming agent 5% to 10%, basic mineral oil 73% to 84.5%, rust-inhibiting additive 8.5% to 12%, water-removal additive 1% to 3%, oxygenant 0.5% to 2%.
2. the long-acting dewatering rust preventive oil of low viscosity according to claim 1, is characterized in that, wherein membrane-forming agent is a kind of mantle membrane-forming agent, by organo-siloxane, oil resin, modified rosin, acid modified alcoholic resin any two kinds or three kinds composite.
3. the long-acting dewatering rust preventive oil of low viscosity according to claim 1, it is characterized in that, wherein basic mineral oil by aviation kerosene, clean kerosene, tasteless kerosene, solar oil, spindle oil, machinery oil, hydraulic efficiency oil, industrial white oil, solvent oil any two kinds composite.
4. the long-acting dewatering rust preventive oil of low viscosity according to claim 1, it is characterized in that, wherein rust-inhibiting additive by barium mahogany sulfonate, petroleum sodium sulfonate, petrolic magnesium sulfonate, alkenyl succinic acid, zinc naphthenate, aluminum stearate, oxidized petrolatum, lanolin, sulfonation lanolin calcium salt any three kinds or four kinds composite.
5. the long-acting dewatering rust preventive oil of low viscosity according to claim 1, is characterized in that, wherein water-removal additive by oleic acid, ethanol, Virahol, propyl carbinol, isopropylcarbinol, amylalcohol, trolamine, sherwood oil any two kinds composite.
6. the long-acting dewatering rust preventive oil of low viscosity according to claim 1, is characterized in that, oxygenant is wherein made up of any two kinds in benzotriazole, department's benzene-80, Resorcinol.
7. low viscosity long-acting antirust oil according to claim 1, is characterized in that, its blending process is:
(1) modification of each component of membrane-forming agent and composite: take each component of membrane-forming agent by mass fraction, constant temperature high speed shear blending dispersion 2 to 5 hours, cools for subsequent use at 70 DEG C to 80 DEG C temperature;
(2) rust-inhibiting additive is composite: take each component by mass fraction, with basic mineral oil for solvent, heats while stirring, until each components dissolved is complete, continues stirring 10 to 30 minutes, cools for subsequent use;
(3) join in container by basic mineral oil, under normal temperature condition, add composite membrane-forming agent, rust-inhibiting additive, water-removal additive and oxidant constituents respectively, limit edged stirs until each component disperses is complete, crosses and filters to remove impurity, collect finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510108369.9A CN104818082A (en) | 2015-03-12 | 2015-03-12 | Low viscosity long-acting dehydrated antirust oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510108369.9A CN104818082A (en) | 2015-03-12 | 2015-03-12 | Low viscosity long-acting dehydrated antirust oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104818082A true CN104818082A (en) | 2015-08-05 |
Family
ID=53728566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510108369.9A Pending CN104818082A (en) | 2015-03-12 | 2015-03-12 | Low viscosity long-acting dehydrated antirust oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104818082A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190463A (en) * | 2016-07-06 | 2016-12-07 | 安徽红桥金属制造有限公司 | A kind of for process stamping parts thermostable rustproof oil and preparation method |
| CN106318575A (en) * | 2016-08-17 | 2017-01-11 | 吴江华威特种油有限公司 | Bearing anti-rust oil and preparation method thereof |
| CN106929128A (en) * | 2017-03-17 | 2017-07-07 | 希玛石油制品（镇江）有限公司 | A kind of clean type antirust oil and its preparation and application |
| CN108441299A (en) * | 2018-04-13 | 2018-08-24 | 华阳新兴科技（天津）集团有限公司 | A kind of water displaced type film rust proof oil and preparation method thereof |
| CN108822940A (en) * | 2018-07-26 | 2018-11-16 | 郑州市欧普士科技有限公司 | A kind of long-life viscosity oil film rust preventive oil and preparation method thereof |
| CN109135896A (en) * | 2018-10-10 | 2019-01-04 | 华阳-恩赛有限公司 | A kind of dehydration-type antirust agent, Preparation method and use |
| CN109294707A (en) * | 2018-11-05 | 2019-02-01 | 肇庆欧迪斯实业有限公司 | Slim rust preventive lubricating oil and its manufacture craft |
| CN109594092A (en) * | 2018-12-18 | 2019-04-09 | 北美防锈技术（上海）有限公司 | Dehydrating agent between a kind of process |
| CN111254000A (en) * | 2020-03-05 | 2020-06-09 | 许昌学院 | Environment-friendly barium-free thin-layer anti-rust oil and preparation method and application thereof |
| CN111635802A (en) * | 2020-07-07 | 2020-09-08 | 山东硕力新材料科技有限公司 | Preparation method of long-term dehydration rust-preventive oil |
| CN114164032A (en) * | 2021-12-09 | 2022-03-11 | 安美科技股份有限公司 | Dehydrating bearing antirust agent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353173A (en) * | 2001-11-21 | 2002-06-12 | 蔡毓英 | Dewatering antirust oil |
| CN1467271A (en) * | 2002-07-12 | 2004-01-14 | 杨晓波 | Novel antistatic soft film anti-rust oil |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
-
2015
- 2015-03-12 CN CN201510108369.9A patent/CN104818082A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353173A (en) * | 2001-11-21 | 2002-06-12 | 蔡毓英 | Dewatering antirust oil |
| CN1467271A (en) * | 2002-07-12 | 2004-01-14 | 杨晓波 | Novel antistatic soft film anti-rust oil |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张康夫等: "《防锈油脂与乳化切削油》", 31 May 1983, 国防工业出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190463A (en) * | 2016-07-06 | 2016-12-07 | 安徽红桥金属制造有限公司 | A kind of for process stamping parts thermostable rustproof oil and preparation method |
| CN106318575A (en) * | 2016-08-17 | 2017-01-11 | 吴江华威特种油有限公司 | Bearing anti-rust oil and preparation method thereof |
| CN106929128A (en) * | 2017-03-17 | 2017-07-07 | 希玛石油制品（镇江）有限公司 | A kind of clean type antirust oil and its preparation and application |
| CN108441299A (en) * | 2018-04-13 | 2018-08-24 | 华阳新兴科技（天津）集团有限公司 | A kind of water displaced type film rust proof oil and preparation method thereof |
| CN108822940A (en) * | 2018-07-26 | 2018-11-16 | 郑州市欧普士科技有限公司 | A kind of long-life viscosity oil film rust preventive oil and preparation method thereof |
| CN109135896A (en) * | 2018-10-10 | 2019-01-04 | 华阳-恩赛有限公司 | A kind of dehydration-type antirust agent, Preparation method and use |
| CN109294707A (en) * | 2018-11-05 | 2019-02-01 | 肇庆欧迪斯实业有限公司 | Slim rust preventive lubricating oil and its manufacture craft |
| CN109594092A (en) * | 2018-12-18 | 2019-04-09 | 北美防锈技术（上海）有限公司 | Dehydrating agent between a kind of process |
| CN111254000A (en) * | 2020-03-05 | 2020-06-09 | 许昌学院 | Environment-friendly barium-free thin-layer anti-rust oil and preparation method and application thereof |
| CN111635802A (en) * | 2020-07-07 | 2020-09-08 | 山东硕力新材料科技有限公司 | Preparation method of long-term dehydration rust-preventive oil |
| CN114164032A (en) * | 2021-12-09 | 2022-03-11 | 安美科技股份有限公司 | Dehydrating bearing antirust agent composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104818082A (en) | Low viscosity long-acting dehydrated antirust oil | |
| CN103254978B (en) | Anti-rust oil and preparation method thereof | |
| CN103525527B (en) | Film-cleaning anti-rust oil for automobile connecting rod, preparation method therefor and applications | |
| CN103726009A (en) | Multicomponent alloy co-permeation anticorrosive coating on surface of steel and co-permeation method thereof | |
| CN104046420A (en) | High-speed rail turnout rust-preventative oil | |
| CN104559523A (en) | Antirust coating composition for steel rails | |
| CN104341924A (en) | Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same | |
| CN103992858A (en) | Environment-friendly thixotropic anti-rust oil | |
| CN103992851A (en) | Low-temperature antirust oil for bearing seal | |
| CN103540393B (en) | Brown high-build quick-drying antirust oil applicable to diesel engines of ships and warships and preparation method thereof | |
| CN104178023A (en) | Tough self-repair metal anti-corrosion paint and preparation method thereof | |
| CN103540392B (en) | Black high-build quick-drying antirust oil applicable to diesel engines of ships and warships and preparation method thereof | |
| CN103980998A (en) | Gas-phase rust preventive oil | |
| CN103254979B (en) | Multi-base-oil anti-rust oil and preparation method thereof | |
| CN103602492A (en) | Multifunctional barium-free anti-rusting oil and preparation process thereof | |
| CN102757853A (en) | Metal cutting fluid with high extreme pressure resistance | |
| CN104004567A (en) | Antirust oil containing rare earth compound | |
| CN104099593A (en) | Surface treating agent for trace rare earth aluminum alloy | |
| CN103497805A (en) | Rust preventive oil and preparation method thereof | |
| CN102002700B (en) | Film-covering process method for preventing steel plate surface from being rusted in short term | |
| CN102924991A (en) | Application of rust-preventative oil in enhancing corrosion resistance of carbon steel material | |
| CN103740445A (en) | Hard film dry anti-rust oil with very strong water resistance | |
| CN103992857A (en) | Quick-drying stable antirust oil | |
| CN103254785A (en) | Long-acting anti-rust oil and preparation method thereof | |
| CN113667967A (en) | Post-treatment method for hot dip galvanizing of steel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150805 |
|
| RJ01 | Rejection of invention patent application after publication |