CN106635283A - Thixotropic antirust oil composition - Google Patents

Thixotropic antirust oil composition Download PDF

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Publication number
CN106635283A
CN106635283A CN201610833620.2A CN201610833620A CN106635283A CN 106635283 A CN106635283 A CN 106635283A CN 201610833620 A CN201610833620 A CN 201610833620A CN 106635283 A CN106635283 A CN 106635283A
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Prior art keywords
oil
parts
thixotropic
antirust
agent
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Inventor
邓象贤
张志东
黄劲松
张明
李谨
王靖宇
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Priority to CN201610833620.2A priority Critical patent/CN106635283A/en
Publication of CN106635283A publication Critical patent/CN106635283A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • C10M2215/224Imidazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044Polyamides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to thixotropic antirust oil composition and mainly solves the problem that an antirust oil film flows easily after applied to a vertical face of a part in the prior art. The antirust oil composition is prepared from components in parts by weight as follows: a) 70-92 parts of base oil, b) 6-15 parts of an oil-soluble sulfonate antirust agent, c) 1-10 parts of a thixotropic agent and d) 1-5 parts of an auxiliary, wherein the base oil is selected from at least one of mineral oil or solvent oil; the oil-soluble sulfonate antirust agent is selected from at least one of petroleum sulfonate and synthetic sulfonate; the thixotropic agent is selected from at least one of modified calcium sulfonate, fumed silica, organobentonite, hydrogenated castor oil, modified polydiene, aluminium stearate and polyamide wax; the auxiliary is selected from at least one of pentaerythrityl oleate, Span 80, oleic acid, a triazole derivative, complex ester, alkenyl butanedioic acid, an imidazoline derivative and alkenyl succinate. The technical scheme better solves the problem and can be applied to industrial production of the thixotropic antirust oil composition.

Description

Thixotropic antirust oil composition
Technical field
The present invention relates to a kind of thixotropic antirust oil composition.
Background technology
Lubricating type rust preventing oil is to use a relatively broad class anti-rust oil in relevant industries such as China's iron and steel, lathes, Its advantage is easy to use, oil film thicker belts have certain lubricity, non-volatile, flash-point higher-security good, shortcoming Easily ground is dripped in trickling when being workpiece facade brushing, not only causes the waste of oil product, affects rustless property, and causes factory's ring The pollution in border.When increasing a certain amount of thixotropic agent in lubricating type rust preventing oil so as to after with certain thixotropy, substantially The shortcoming of lubricating type rust preventing oil easily trickling can be overcome, in facade stable oil film can be also formed, be reduced trickling and be lost in, can phase Rustless property is improved over the ground.
With the fast development of the industry seaborne trade such as iron and steel, lathe, especially band large-scale metal equipment or product are in high temperature During marine transportation under hyperpyrexia and salt mist environment, the common antirust oil for coating its surface is easily lost on pieces of equipment surface, Affect rust-proof effect.To guarantee that parts material installation surface coating antirust oil forms the stable oil film of optimum, facade stream is reduced Drop down, and as just there is realistic meaning with the thixotropic antirust oil for preventing from trickling, obtained wide during sea-freight Using.
Thixotropic antirust oil species is more in prior art.Document CN200810012720.4 discloses a kind of environmentally-friendly barium-free Thixotropic antirust oil, is made up of by weight following components:4~25 parts of antirust agent, 0.1~5 part of thixotropic agent, antioxidant 0.1~3 Part, 72~94 parts of mineral base oil.Document CN200910213280.3 discloses a kind of environment-friendly thixotropic antirust oil and its production Method, is made up of by weight following components:2~20 parts of barium-free antirust agent, 0.5~5 part of thixotropic agent, 0.1~5 part of antioxidant, 0.5~0.5 part of auxiliary agent, 73~96 parts of mineral base oil.Document CN201310362684.5 discloses a kind of environment-friendly thixotropic to be prevented Rust oil, is made up of by weight following components:5~6 parts of lanolin magnesium, 2~3 parts of rilanit special, sorbitan fatty acid Ester 2-4 parts, 4,4- dioctyl diphenylamine 1-2 parts, the β-positive octadecanol ester 0.2 of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid ~0.4 part, 2~3 parts of coalescents, 50~60 parts, No. 50 machinery oil 20-30 parts of 25# transformer oil.Document CN201410171126.5 discloses a kind of environment-friendly thixotropic antirust oil, is made up of by weight following components:Antirust agent 5~6 Part, 0.1~0.3 part of hydroxyethyl-pyrrolidone, 1~2 part of 1- ethoxy -2- oil-based imidazolines, 5~7 parts of dinonylnaphthalene sulfonic acid calcium, 1~2 part of organobentonite, NPE 0.7~1,3~4 parts of epoxidized soybean oil, 3~4 parts of decyl primary amine, 0.6~2 part of Span-80,81~90 parts of bobbin oil.Document CN201410544836.8 discloses a kind of environment-friendly type thixotropy to be prevented Rust oil and preparation method thereof, is made up of by weight following components:5~10 parts of barium-free antirust agent, 1~4 part of thixotropic agent, phenolic group resist 0.2~0.5 part of oxygen agent, 0.1~0.5 part of anilino- antioxidant, 0.2~1 part of olefin(e) acid antioxidant, 2~3 parts of coalescents, paraffin 57~65 parts of base base oil, 9~16 parts of naphthenic base oils, alkyl higher boiling base oil 6~11.In addition CN201410626896.4 discloses that have after a kind of dilution can thixotropic barium-free antirust grease and preparation method thereof; CN201410591534.6 discloses a kind of anti-oxidant thixotropic antirust oil.
But, thixotropic antirust oil film brushes easily trickling on parts facade in prior art.
The content of the invention
The technical problem to be solved is to provide a kind of new thixotropic antirust oil composition.Said composition has Good rust-preventing characteristic, sag resistance and it is cleaned performance.
To solve above-mentioned technical problem, the technical solution used in the present invention is as follows:A kind of thixotropic antirust oil composition, with Parts by weight meter, is made up of following component:
A) 70~92 parts of base oil;
B) 6~15 parts of oil-soluble sulfonic acid salt antirust agent;
C) 1~10 part of thixotropic agent;
D) 1~5 part of adjuvant;
At least one of the base oil in mineral oil or solvent naphtha;
At least one of the oil-soluble sulfonic acid salt antirust agent in petroleum sulfonate or synthesising sulfonate;
The thixotropic agent selected from modified sulfoacid calcium, aerosil, organobentonite, rilanit special, modified poly- two At least one in alkene, aluminum stearate or polyamide wax;
The adjuvant is selected from PETO, sorbester p17, oleic acid, benzotriazole derivative, complex ester, allyl butyrate two At least one in acid, imidazolidine derivatives or alkenyl succinic acid ester.
In above-mentioned technical proposal, it is preferable that in terms of parts by weight, the consumption of base oil is 75~85 parts, oil-soluble sulfonic acid The consumption of salt antirust agent is 8~12 parts, and the consumption of thixotropic agent is 2~7 parts, and the consumption of adjuvant is 1.5~4 parts.
In above-mentioned technical proposal, the mineral oil selected from HVI 60,70,75,100,125,150,250,350,400, 500th, 650, the 750, at least one in 90BS, 120BS, 150BS.
In above-mentioned technical proposal, the oil-soluble sulfonic acid salt antirust agent is selected from calcium mahogany sulfonate, petrolic magnesium sulfonate, oil sulphur Sour barium, middle calcium alkylbenzensulfonates, neutral dinonylnaphthalene sulfonic acid calcium, dinonylnaphthalene sulfonic acid calcium salt composition, dinonylnaphthalene sulfonic acid At least one in calcium carboxylate calcium complexes, neutral dinonyl naphthalene sulfonate barium or low alkali value synthesis barium sulfonate.
In above-mentioned technical proposal, the thixotropic agent is selected from modified sulfoacid calcium, aerosil, modified polydiene or polyamides At least one in amine wax.
In above-mentioned technical proposal, the adjuvant selected from PETO, oleic acid, benzotriazole derivative, complex ester, At least one in alkenyl succinic acid, imidazolidine derivatives or alkenyl succinic acid ester.
The preparation method of thixotropic antirust oil composition of the present invention, including:By 50~60 DEG C of heating stirrings of base oil, Oil-soluble sulfonic acid salt antirust agent, adjuvant and thixotropic agent are sequentially added, 40~50 DEG C of constant temperature are stirred 3~4 hours, through 10um Bag type filtering, obtains final product the thixotropic antirust oil composition.
Below by embodiment, the invention will be further elaborated.
Specific embodiment
【Embodiment 1~6】
By the parts by weight in table 1, blending kettle, 50~60 DEG C of heating stirrings is added to sequentially add oil soluble base oil Property sulfonate antirust agent, adjuvant and thixotropic agent, 40~50 DEG C of constant temperature stir 3~4 hours, through 10um bag type filterings, obtain final product The thixotropic antirust oil composition.
【Comparative example 1】
The method according to disclosed in document CN101724499A, in a kettle. add 73~96 parts of base oil, heating stirring, 2~20 parts of barium-free antirust agent, heating stirring are added to after 100~120 DEG C of dehydrations, when being cooled to less than 80 DEG C 0.5~5 is added Part thixotropic agent, 0.5~5 part of auxiliary agent, 0.1~5 part of antioxidant stirring fully dissolving, Jing 1um are filtered, and obtain final product this thixotropy antirust Oil.
Wherein, base oil is 87% neutral mineral oil.Antirust agent is 5% petroleum sodium sulfonate, 5% dinonyl naphthalene sulphur Sour calcium, thixotropic agent is 0.5% double stearic acid aluminium, and auxiliary agent is 2% APES, and antioxidant is the 2 of 0.5%, 6- BHTs.
As shown in Table 2, it is provided by the present invention【Embodiment 1~4】The combination property ratio such as rustless property and thixotropic property【It is right Ratio 1】Will get well.
Table 1
Table 2

Claims (6)

1. a kind of thixotropic antirust oil composition, in terms of parts by weight, is made up of following component:
A) 70~92 parts of base oil;
B) 6~15 parts of oil-soluble sulfonic acid salt antirust agent;
C) 1~10 part of thixotropic agent;
D) 1~5 part of adjuvant;
At least one of the base oil in mineral oil or solvent naphtha;
At least one of the oil-soluble sulfonic acid salt antirust agent in petroleum sulfonate or synthesising sulfonate;
The thixotropic agent is selected from modified sulfoacid calcium, aerosil, organobentonite, rilanit special, modified polydiene, hard At least one in resin acid aluminium or polyamide wax;
The adjuvant selected from PETO, sorbester p17, oleic acid, benzotriazole derivative, complex ester, alkenyl succinic acid, At least one in imidazolidine derivatives or alkenyl succinic acid ester.
2. thixotropic antirust oil composition according to claim 1, it is characterised in that in terms of parts by weight, the consumption of base oil For 75~85 parts, the consumption of oil-soluble sulfonic acid salt antirust agent is 8~12 parts, and the consumption of thixotropic agent is 2~7 parts, the use of adjuvant Measure as 1.5~4 parts.
3. thixotropic antirust oil composition according to claim 1, it is characterised in that the mineral oil selected from HVI 60,70, 75th, 100,125,150,250,350,400,500,650, the 750, at least one in 90BS, 120BS, 150BS.
4. thixotropic antirust oil composition according to claim 1, it is characterised in that the oil-soluble sulfonic acid salt antirust agent choosing From calcium mahogany sulfonate, petrolic magnesium sulfonate, barium mahogany sulfonate, middle calcium alkylbenzensulfonates, neutral dinonylnaphthalene sulfonic acid calcium, dinonyl Naphthalene sulfonic acids calcium salt composition, dinonylnaphthalene sulfonic acid calcium carboxylate calcium complexes, neutral dinonyl naphthalene sulfonate barium or low alkali value synthesis sulphur At least one in sour barium.
5. thixotropic antirust oil composition according to claim 1, it is characterised in that the thixotropic agent selected from modified sulfoacid calcium, At least one in aerosil, modified polydiene or polyamide wax.
6. thixotropic antirust oil composition according to claim 1, it is characterised in that the adjuvant is selected from pentaerythrite oil In acid esters, oleic acid, benzotriazole derivative, complex ester, alkenyl succinic acid, imidazolidine derivatives or alkenyl succinic acid ester at least one Kind.
CN201610833620.2A 2016-09-20 2016-09-20 Thixotropic antirust oil composition Pending CN106635283A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107338091A (en) * 2017-06-09 2017-11-10 中国石油化工股份有限公司 Environment-friendly type thixotropic antirust oil composition
CN110184113A (en) * 2019-05-31 2019-08-30 上海正玺新材料科技有限公司 A kind of antirust oil used for magnesium alloy and preparation method thereof
CN111989533A (en) * 2018-03-30 2020-11-24 大金工业株式会社 Refrigerant pipe, heat exchanger, and method for manufacturing refrigerant pipe
CN112980546A (en) * 2019-12-17 2021-06-18 深圳科创新源新材料股份有限公司 Antiseptic paste and preparation method and application thereof
CN113583741A (en) * 2021-07-20 2021-11-02 广东月福汽车用品有限公司 Brake anti-occlusion lubricant and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1961275A1 (en) * 1969-12-06 1971-06-16 Chemotherm Gmbh Thixotropic rust remover/preventative - compsn
CN101724499A (en) * 2009-10-23 2010-06-09 启东市合成化工厂有限公司 Environment-friendly thixotropic antirust oil and manufacturing method thereof
CN104312699A (en) * 2014-10-15 2015-01-28 上海中孚特种油品有限公司 Environment-friendly thixotropic antirust oil and preparation method thereof
CN104726177A (en) * 2013-12-21 2015-06-24 海安县盛泰冷拉型钢有限公司 Rust-preventive oil composition
CN105238520A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Dehydrated antirust oil composition and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1961275A1 (en) * 1969-12-06 1971-06-16 Chemotherm Gmbh Thixotropic rust remover/preventative - compsn
CN101724499A (en) * 2009-10-23 2010-06-09 启东市合成化工厂有限公司 Environment-friendly thixotropic antirust oil and manufacturing method thereof
CN104726177A (en) * 2013-12-21 2015-06-24 海安县盛泰冷拉型钢有限公司 Rust-preventive oil composition
CN104312699A (en) * 2014-10-15 2015-01-28 上海中孚特种油品有限公司 Environment-friendly thixotropic antirust oil and preparation method thereof
CN105238520A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Dehydrated antirust oil composition and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107338091A (en) * 2017-06-09 2017-11-10 中国石油化工股份有限公司 Environment-friendly type thixotropic antirust oil composition
CN111989533A (en) * 2018-03-30 2020-11-24 大金工业株式会社 Refrigerant pipe, heat exchanger, and method for manufacturing refrigerant pipe
CN110184113A (en) * 2019-05-31 2019-08-30 上海正玺新材料科技有限公司 A kind of antirust oil used for magnesium alloy and preparation method thereof
CN112980546A (en) * 2019-12-17 2021-06-18 深圳科创新源新材料股份有限公司 Antiseptic paste and preparation method and application thereof
CN112980546B (en) * 2019-12-17 2022-12-20 深圳科创新源新材料股份有限公司 Antiseptic paste and preparation method and application thereof
CN113583741A (en) * 2021-07-20 2021-11-02 广东月福汽车用品有限公司 Brake anti-occlusion lubricant and preparation method and application thereof

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Application publication date: 20170510