CN108865362A - Barium-free type electrostatic painting anticorrosive oil composition - Google Patents
Barium-free type electrostatic painting anticorrosive oil composition Download PDFInfo
- Publication number
- CN108865362A CN108865362A CN201810836286.5A CN201810836286A CN108865362A CN 108865362 A CN108865362 A CN 108865362A CN 201810836286 A CN201810836286 A CN 201810836286A CN 108865362 A CN108865362 A CN 108865362A
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- China
- Prior art keywords
- oil
- barium
- parts
- electrostatic painting
- sulfonic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/48—Slushing oils
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The present invention relates to a kind of barium-free type electrostatic painting anticorrosive oil compositions, and the heavy metal elements such as baric, do not belong to environmentally friendly product, mainly solve the occasion used restricted to barium salt antirust agent of electrostatic painting anticorrosive oil in the prior art.The present invention by using being made of the following components based on parts by weight:A) 65~90 parts of base oil;B) 5~20 parts of oil-soluble sulfonic acid salt antirust agent;C) 0.5~5 part of surfactant;D) technical solution of 0.5~10 part of adjuvant preferably solves the problems, such as this, and barium-free type electrostatic painting anticorrosive oil composition can be used in the electrostatic spraying industrial production of iron and steel metallurgical industry flat cold-rolled sheet.
Description
Technical field
The present invention relates to a kind of barium-free type electrostatic painting anticorrosive oil compositions.
Background technique
China's steel and iron industry is rapidly developed in recent years, and production continuous 3 years -2016 years 2014 crude steel years are super
800,000,000 tons are crossed, very vigorous situation is also presented always in cold-rolled thin sheet production requirement, with the matching used electrostatic of flat cold-rolled sheet
It is also considerable for applying the demand of antirust oil.
Sulfonic acid barium salt antirust agent has very excellent rustless property, and traditional common electrostatic spray anti-rust oil mostly uses
Sulfonic acid barium salt, but barium is heavy metal, has enrichment and difficult to degrade, has adverse effect to environment and the mankind.With society
Progressive and people's environmental consciousness enhancing, it is also higher and higher to the nonhazardous environmental protection cry of electrostatic painting anticorrosive oil, therefore develop one
Kind barium-free type electrostatic painting anticorrosive oil has realistic meaning.
Barium-free type electrostatic painting anticorrosive oil type is more in the prior art.104531291 A of patent CN discloses a kind of nothing
Barium electrostatic painting anticorrosive oil is made of by weight following components:T405 sulfurized olefin cotton oil 6~10%, 150sn base oil
70~80%, fatty alcohol polyoxyethylene ether 1~2%, 1- methyl anyl alcohol 0.4~1%, palm wax 2~3%, trimellitate 2~
3%, dimethylaminopropylamine 0.6~1%, ammonium metaborate 0.7~1%, chlorinated paraffin 3~4%, dimethyl succinate 1~2%,
2-mercaptobenzimidazole 0.6~2%, aluminum sulfate 1~2%, antistripping machinery oil 4~6%.CN 103911206 A
(CN103911206B) a kind of barium-free is disclosed without sulfonate electrostatic painting anticorrosive oil, is made of by weight following components:80
~90% No. 15 machinery oil, 2~10% zinc naphthenate, 1~6% KORANTIN SH octadecylamine, the 12 of 2~10%
Alkenyl succinic acid, 1~5% DBPC 2,6 ditertiary butyl p cresol.It is anti-that 104327913 A of CN discloses a kind of barium-free electrostatic spraying
Rust oil, is made of by weight following components:Rare earth antirust hydraulic oil 16~20%, No. 20 machinery oil 60~80%, chlorine phthalandiones
Dimethyl ester 1~3%, pitch 3~7%, N, bis- (2- cyanoethyl) formamides 1~2% of N-, polyoxyethylene stearic acid ester 2~3%,
Sorbitan fatty acid ester 1~2%, methyl benzotriazazole 1~3%, zinc naphthenate 0.5~1%, penta sodium pentachlorophenate 0.1~
3%, stannous sulfate 0.3~1%, allylthiourea 0.4~1%.CN104263475A discloses a kind of environmental protection type static spraying
Antirust oil and preparation method thereof is made of by weight following components:70~90% base oil, 5~25% antirust agent, 1
~5% surfactant, 0.5~5% antioxidant.104312699 A of CN discloses a kind of environment-friendly type thixotropic antirust oil
And preparation method thereof, it is made of by weight following components:Paraffin base oil 57~65%, naphthenic base oils 9~16%,
Alkyl high-boiling components base oil 6~11%, barium-free antirust agent 5~10%, thixotropic agent 1~4%, phenol-based anti-oxidants 0.2~
0.5%, anilino- antioxidant 0.1~0.5%, olefin(e) acid antioxidant 0.2~1%, coalescing agent 2~3%.Document " environmental protection
The development of type electrostatic painting anticorrosive oil,《2014 national inhibition antirust academic discussions and exchange of technology conference collected works》" be discussed in detail
The development process and performance characteristics of barium-free type electrostatic painting anticorrosive oil product.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of new barium-free type electrostatic painting anticorrosive oil compositions.The group
Object is closed to be free of heavy metal barium, there is good rust-preventing characteristic and cleaned performance.
In order to solve the above technical problems, the technical solution adopted by the present invention is as follows:A kind of barium-free type electrostatic painting anticorrosive oil
Composition is made of the following components based on parts by weight:
A) 65~90 parts of base oil;
B) 5~20 parts oil-soluble sulfonic acid salt (being free of barium salt) antirust agent;
C) 0.5~5 part of surfactant;
D) 0.5~10 part of adjuvant;
Wherein, the base oil is selected from least one of hydrogenated base oil or synthetic base oil;
Oil-soluble sulfonic acid salt (the being free of barium salt) antirust agent is selected from sulfoacid calcium or and its carboxylate, sulfonate sodium, sulfonic acid
At least one of magnesium salts etc.;
The surfactant is selected from polyoxyethylene stearyl alcohol, unsaturated polyol ester, methyl glycol fatty acid ester, lauroyl
Base glutamic acid, ethoxylated dodecyl alcohol, fatty glyceride, nonylphenol polyoxyethylene ether, glycerol stearate monoesters, alkyl are poly-
At least one of ether or Brij;
The adjuvant is selected from oleoyl sarcosine, benzotriazole derivative, phenolic antioxidant, alkenyl succinic acid, imidazoline and spreads out
At least one of biology or alkenyl succinic acid ester.
In above-mentioned technical proposal, it is preferable that the hydrogenated base oil is selected from least one of HVI II 2,4,6,8;It closes
At least one of alkylbenzene, polyethers are selected from base oil.
In above-mentioned technical proposal, it is preferable that the oil-soluble sulfonic acid salt (being free of barium salt) antirust agent be selected from calcium mahogany sulfonate,
Petrolic magnesium sulfonate, middle calcium alkylbenzensulfonates, neutral dinonylnaphthalene sulfonic acid calcium, dinonylnaphthalene sulfonic acid calcium salt composition, dinonyl
At least one of naphthalene sulfonic acids calcium carboxylate calcium complexes or sulfoacid calcium carboxylic acid calcium salt.
In above-mentioned technical proposal, it is preferable that the surfactant is selected from nonylphenol polyoxyethylene ether, polyoxyethylene stearyl
At least one of alcohol, fatty glyceride or Brij.
In above-mentioned technical proposal, it is preferable that the adjuvant is selected from benzotriazole derivative, phenolic antioxidant, oleoyl flesh ammonia
At least one of acid, imidazolidine derivatives or alkenyl succinic acid ester.
In above-mentioned technical proposal, it is preferable that based on parts by weight, the dosage of base oil is 75~90 parts, oil-soluble sulfonic acid
The dosage of salt antirust agent is 10~20 parts, and the dosage of surfactant is 0.5~2 part, and the dosage of adjuvant is 1~8 part.
The preparation method of barium-free type electrostatic painting anticorrosive oil composition of the present invention, including:By 70~80 DEG C of base oil
Heating stirring sequentially adds oil-soluble sulfonic acid salt antirust agent, adjuvant and surfactant, 50~60 DEG C of constant temperature stirrings 1~3
Hour, by 10um bag type filtering to get the barium-free type electrostatic painting anticorrosive oil composition.
The present invention will be further described below by way of examples.
Specific embodiment
【Examples 1 to 5】
By the parts by weight in table 1, blending kettle is added in base oil, it is molten to sequentially add oil for 70~80 DEG C of heating stirrings
Property sulfonate antirust agent, adjuvant and surfactant, 50~60 DEG C of constant temperature stir 1~3 hour, by 10um bag type filtering,
Up to the barium-free type electrostatic painting anticorrosive oil composition.
【Comparative example 1】
According to method disclosed in 103911206 A of patent CN, No. 15 machinery oil 80%, aphthenic acids are taken by mass percentage
Zinc 10%, KORANTIN SH octadecylamine 6%, dodecenylsuccinic acid 2%, 2,6-di-tert-butyl p-cresol 2%, by these originals
Material is uniformly mixed and made into electrostatic painting anticorrosive oil of the barium-free without sulfonate.
As shown in Table 2, provided by the present invention【Examples 1 to 5】The comprehensive performances ratio such as rustless property and degreasing performance【It is right
Ratio 1】Will get well.
Claims (7)
1. a kind of barium-free type electrostatic painting anticorrosive oil composition is made of the following components based on parts by weight:
A) 65~90 parts of base oil;
B) 5~20 parts of oil-soluble sulfonic acid salt antirust agent;
C) 0.5~5 part of surfactant;
D) 0.5~10 part of adjuvant;
Wherein, the base oil is selected from least one of hydrogenated base oil or synthetic base oil;
The oil-soluble sulfonic acid salt antirust agent selected from sulfoacid calcium or and its carboxylate, sulfonate sodium, sulfonic acid magnesium salts etc. at least
It is a kind of;
The surfactant is selected from polyoxyethylene stearyl alcohol, unsaturated polyol ester, methyl glycol fatty acid ester, lauroyl paddy
Propylhomoserin, ethoxylated dodecyl alcohol, fatty glyceride, nonylphenol polyoxyethylene ether, glycerol stearate monoesters, alkyl, polyether or
At least one of Brij;
The adjuvant is selected from oleoyl sarcosine, benzotriazole derivative, phenolic antioxidant, alkenyl succinic acid, imidazolidine derivatives
Or at least one of alkenyl succinic acid ester.
2. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that based on parts by weight, base
The dosage of plinth oil is 65~90 parts, and the dosage of oil-soluble sulfonic acid salt antirust agent is 5~20 parts, and the dosage of surfactant is 0.5
~5 parts, the dosage of adjuvant is 0.5~10 part.
3. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that the hydrogenated base oil choosing
From at least one of HVI II 2,4,6,8,10;Synthetic oil in alkylbenzene, polyethers, synthetic ester, poly alpha olefin etc. extremely
Few one kind.
4. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that the oil-soluble sulfonic acid salt
Antirust agent is selected from calcium mahogany sulfonate, petrolic magnesium sulfonate, petroleum sodium sulfonate, middle calcium alkylbenzensulfonates, neutral dinonylnaphthalene sulfonic acid
In calcium, dinonylnaphthalene sulfonic acid calcium salt composition, dinonylnaphthalene sulfonic acid calcium carboxylate calcium complexes or sulfoacid calcium carboxylic acid calcium salt at least
It is a kind of.
5. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that the surfactant choosing
From at least one of nonylphenol polyoxyethylene ether, polyoxyethylene stearyl alcohol, fatty glyceride or Brij.
6. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that the adjuvant is selected from benzene
At least one of triazole derivative, phenolic antioxidant, oleoyl sarcosine, imidazolidine derivatives or alkenyl succinic acid ester.
7. barium-free type electrostatic painting anticorrosive oil composition according to claim 1, which is characterized in that based on parts by weight, base
The dosage of plinth oil is 75~90 parts, and the dosage of oil-soluble sulfonic acid salt antirust agent is 10~20 parts, and the dosage of surfactant is 0.5
~2 parts, the dosage of adjuvant is 1~8 part.
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CN201810836286.5A CN108865362A (en) | 2018-07-26 | 2018-07-26 | Barium-free type electrostatic painting anticorrosive oil composition |
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CN201810836286.5A CN108865362A (en) | 2018-07-26 | 2018-07-26 | Barium-free type electrostatic painting anticorrosive oil composition |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109321338A (en) * | 2018-11-13 | 2019-02-12 | 上海帕卡兴产化工有限公司 | A kind of electrostatic painting anticorrosive oil and preparation method thereof |
CN110257189A (en) * | 2019-07-01 | 2019-09-20 | 张娟娟 | A kind of industrial greasy dirt detergent and preparation method thereof again |
CN110283641A (en) * | 2019-05-24 | 2019-09-27 | 清华大学天津高端装备研究院 | A kind of cold-rolled steel sheet is electrostatically sprayed antirust oil and its preparation and performance test methods |
CN110437917A (en) * | 2019-08-23 | 2019-11-12 | 广州市联诺化工科技有限公司 | A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof |
CN110923046A (en) * | 2019-12-17 | 2020-03-27 | 上海帕卡兴产化工有限公司 | Stamping lubricating anti-rust oil and preparation method thereof |
CN113621422A (en) * | 2021-07-21 | 2021-11-09 | 安美科技股份有限公司 | Antirust lubricating grease for automobile balancing pole |
CN114181762A (en) * | 2021-12-13 | 2022-03-15 | 安美科技股份有限公司 | Electrostatic spraying anti-rust oil composition |
CN116855297A (en) * | 2022-03-28 | 2023-10-10 | 中国石油化工股份有限公司 | Rust-proof oil for bearings and preparation method and application thereof |
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CN101016497A (en) * | 2007-03-05 | 2007-08-15 | 中国石油化工集团公司 | Electrostatic spraying antirust oil |
CN101486945A (en) * | 2008-12-15 | 2009-07-22 | 中国石油化工股份有限公司 | Electrostatic painting anticorrosive oil and production method thereof |
CN104263475A (en) * | 2014-09-12 | 2015-01-07 | 广州中机实业有限公司 | Environment-friendly electrostatic spraying antirust oil and preparation method thereof |
-
2018
- 2018-07-26 CN CN201810836286.5A patent/CN108865362A/en active Pending
Patent Citations (3)
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CN101016497A (en) * | 2007-03-05 | 2007-08-15 | 中国石油化工集团公司 | Electrostatic spraying antirust oil |
CN101486945A (en) * | 2008-12-15 | 2009-07-22 | 中国石油化工股份有限公司 | Electrostatic painting anticorrosive oil and production method thereof |
CN104263475A (en) * | 2014-09-12 | 2015-01-07 | 广州中机实业有限公司 | Environment-friendly electrostatic spraying antirust oil and preparation method thereof |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109321338A (en) * | 2018-11-13 | 2019-02-12 | 上海帕卡兴产化工有限公司 | A kind of electrostatic painting anticorrosive oil and preparation method thereof |
CN110283641A (en) * | 2019-05-24 | 2019-09-27 | 清华大学天津高端装备研究院 | A kind of cold-rolled steel sheet is electrostatically sprayed antirust oil and its preparation and performance test methods |
CN110283641B (en) * | 2019-05-24 | 2022-03-01 | 清华大学天津高端装备研究院 | Electrostatic spraying anti-rust oil for cold-rolled steel sheets and preparation and performance test methods thereof |
CN110257189A (en) * | 2019-07-01 | 2019-09-20 | 张娟娟 | A kind of industrial greasy dirt detergent and preparation method thereof again |
CN110437917A (en) * | 2019-08-23 | 2019-11-12 | 广州市联诺化工科技有限公司 | A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof |
CN110437917B (en) * | 2019-08-23 | 2021-09-24 | 广州市联诺化工科技有限公司 | Environment-friendly anti-rust oil for iron-based powder metallurgy parts and preparation method thereof |
CN110923046A (en) * | 2019-12-17 | 2020-03-27 | 上海帕卡兴产化工有限公司 | Stamping lubricating anti-rust oil and preparation method thereof |
CN113621422A (en) * | 2021-07-21 | 2021-11-09 | 安美科技股份有限公司 | Antirust lubricating grease for automobile balancing pole |
CN113621422B (en) * | 2021-07-21 | 2022-12-02 | 安美科技股份有限公司 | Antirust lubricating grease for automobile balancing pole |
CN114181762A (en) * | 2021-12-13 | 2022-03-15 | 安美科技股份有限公司 | Electrostatic spraying anti-rust oil composition |
CN116855297A (en) * | 2022-03-28 | 2023-10-10 | 中国石油化工股份有限公司 | Rust-proof oil for bearings and preparation method and application thereof |
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