CN105218863A - 一种硅基阻燃剂 - Google Patents
一种硅基阻燃剂 Download PDFInfo
- Publication number
- CN105218863A CN105218863A CN201510688570.9A CN201510688570A CN105218863A CN 105218863 A CN105218863 A CN 105218863A CN 201510688570 A CN201510688570 A CN 201510688570A CN 105218863 A CN105218863 A CN 105218863A
- Authority
- CN
- China
- Prior art keywords
- fire retardant
- silica
- water glass
- based fire
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 81
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 37
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 34
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 34
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 14
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 14
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 12
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 12
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 12
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 12
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 12
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 12
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 13
- QMMBZOSZCYBCDC-UHFFFAOYSA-N NCCNCCC[SiH](OC(OCC)(OCC)OCC)OC Chemical compound NCCNCCC[SiH](OC(OCC)(OCC)OCC)OC QMMBZOSZCYBCDC-UHFFFAOYSA-N 0.000 claims description 7
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 5
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 23
- 230000000694 effects Effects 0.000 abstract description 13
- 239000002131 composite material Substances 0.000 abstract description 8
- 235000019504 cigarettes Nutrition 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 22
- 239000000835 fiber Substances 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229920000297 Rayon Polymers 0.000 description 11
- 238000002485 combustion reaction Methods 0.000 description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 9
- 229910052698 phosphorus Inorganic materials 0.000 description 9
- 239000011574 phosphorus Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920006113 non-polar polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510688570.9A CN105218863B (zh) | 2015-10-21 | 2015-10-21 | 一种硅基阻燃剂 |
Applications Claiming Priority (1)
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CN201510688570.9A CN105218863B (zh) | 2015-10-21 | 2015-10-21 | 一种硅基阻燃剂 |
Publications (2)
Publication Number | Publication Date |
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CN105218863A true CN105218863A (zh) | 2016-01-06 |
CN105218863B CN105218863B (zh) | 2017-09-05 |
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CN201510688570.9A Active CN105218863B (zh) | 2015-10-21 | 2015-10-21 | 一种硅基阻燃剂 |
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CN (1) | CN105218863B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106521669A (zh) * | 2016-08-31 | 2017-03-22 | 浙江益南纤维科技有限公司 | 一种防火阻燃面料专用新型复合人棉纤维 |
CN109881287A (zh) * | 2019-01-28 | 2019-06-14 | 圣华盾防护科技股份有限公司 | 一种阻燃耐磨防护用品以及纤维 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1798799A (zh) * | 2003-04-30 | 2006-07-05 | 庆东塞拉泰克有限公司 | 具有优良不可燃性的泡沫塑料体 |
CN101248124A (zh) * | 2005-08-22 | 2008-08-20 | 巴斯夫欧洲公司 | 具有阻燃和疏油/疏水性能的开孔泡沫及其生产方法 |
CN102319499A (zh) * | 2011-07-19 | 2012-01-18 | 南京理工大学 | 复配协同型a、b类水系灭火剂 |
CN102409420A (zh) * | 2011-09-26 | 2012-04-11 | 宜宾丝丽雅股份有限公司 | 一种复合硅系阻燃粘胶纤维及其生产方法 |
KR20140081918A (ko) * | 2012-12-05 | 2014-07-02 | 주식회사 경동원 | 무기 팽창성 내화 조성물 |
CN104752658A (zh) * | 2013-12-27 | 2015-07-01 | 中国科学院青岛生物能源与过程研究所 | 一种静电纺丝制备的锂电池阻燃纤维素隔膜 |
KR20150091453A (ko) * | 2015-07-22 | 2015-08-11 | 한국신소재(유) | 난연성이 우수한 직물의 제조방법 |
-
2015
- 2015-10-21 CN CN201510688570.9A patent/CN105218863B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1798799A (zh) * | 2003-04-30 | 2006-07-05 | 庆东塞拉泰克有限公司 | 具有优良不可燃性的泡沫塑料体 |
CN101248124A (zh) * | 2005-08-22 | 2008-08-20 | 巴斯夫欧洲公司 | 具有阻燃和疏油/疏水性能的开孔泡沫及其生产方法 |
CN102319499A (zh) * | 2011-07-19 | 2012-01-18 | 南京理工大学 | 复配协同型a、b类水系灭火剂 |
CN102409420A (zh) * | 2011-09-26 | 2012-04-11 | 宜宾丝丽雅股份有限公司 | 一种复合硅系阻燃粘胶纤维及其生产方法 |
KR20140081918A (ko) * | 2012-12-05 | 2014-07-02 | 주식회사 경동원 | 무기 팽창성 내화 조성물 |
CN104752658A (zh) * | 2013-12-27 | 2015-07-01 | 中国科学院青岛生物能源与过程研究所 | 一种静电纺丝制备的锂电池阻燃纤维素隔膜 |
KR20150091453A (ko) * | 2015-07-22 | 2015-08-11 | 한국신소재(유) | 난연성이 우수한 직물의 제조방법 |
Non-Patent Citations (1)
Title |
---|
李群: "《纳米材料的制备与应用技术(2008年9月第1版)》", 30 September 2008, 化学工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106521669A (zh) * | 2016-08-31 | 2017-03-22 | 浙江益南纤维科技有限公司 | 一种防火阻燃面料专用新型复合人棉纤维 |
CN109881287A (zh) * | 2019-01-28 | 2019-06-14 | 圣华盾防护科技股份有限公司 | 一种阻燃耐磨防护用品以及纤维 |
CN109881287B (zh) * | 2019-01-28 | 2022-03-18 | 圣华盾防护科技股份有限公司 | 一种阻燃耐磨防护用品以及纤维 |
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CN105218863B (zh) | 2017-09-05 |
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Address after: 261300 Liu Tuan project area, Weifang, Shandong, Changyi Patentee after: Shandong Longgang Silicon Technology Co.,Ltd. Address before: 261300 Liu Tuan project area, Weifang, Shandong, Changyi Patentee before: CHANGYI CITY LONGGANG INORGANIC SILICON LTD. |
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Address after: 261300 Liutuan project area, Changyi City, Weifang City, Shandong Province Patentee after: Shandong Longgang Silicon Technology Co.,Ltd. Address before: 261300 Liutuan project area, Changyi City, Weifang City, Shandong Province Patentee before: Shandong Longgang Silicon Technology Co.,Ltd. |
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Effective date of registration: 20240416 Address after: 262100 East of the intersection of Yangchun Road and Wenshui South Road in Xin'an Street, Anqiu City, Weifang City, Shandong Province, 460 meters Patentee after: Shandong Taiming Investment Co.,Ltd. Country or region after: China Address before: 261300 Liutuan project area, Changyi City, Weifang City, Shandong Province Patentee before: Shandong Longgang Silicon Technology Co.,Ltd. Country or region before: China |