CN105176042A - 一种防雾性好的树脂镜片及其制备方法 - Google Patents
一种防雾性好的树脂镜片及其制备方法 Download PDFInfo
- Publication number
- CN105176042A CN105176042A CN201510662071.2A CN201510662071A CN105176042A CN 105176042 A CN105176042 A CN 105176042A CN 201510662071 A CN201510662071 A CN 201510662071A CN 105176042 A CN105176042 A CN 105176042A
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- Prior art keywords
- parts
- resin lens
- coupling agent
- preparation
- fog properties
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- 229920005989 resin Polymers 0.000 title claims abstract description 41
- 239000011347 resin Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 12
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 9
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 9
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 9
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 9
- 239000004417 polycarbonate Substances 0.000 claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 11
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical group CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 claims description 10
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical group CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 238000007711 solidification Methods 0.000 claims description 10
- 230000008023 solidification Effects 0.000 claims description 10
- 229950002083 octabenzone Drugs 0.000 claims description 9
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical group CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 claims description 9
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 8
- 239000012964 benzotriazole Substances 0.000 claims description 8
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 8
- 229940059574 pentaerithrityl Drugs 0.000 claims description 8
- 229920003987 resole Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 238000009966 trimming Methods 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 7
- 239000011521 glass Substances 0.000 abstract description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 abstract 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Eyeglasses (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201510662071.2A CN105176042B (zh) | 2015-10-11 | 2015-10-11 | 一种防雾性好的树脂镜片及其制备方法 |
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CN201510662071.2A CN105176042B (zh) | 2015-10-11 | 2015-10-11 | 一种防雾性好的树脂镜片及其制备方法 |
Publications (2)
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CN105176042A true CN105176042A (zh) | 2015-12-23 |
CN105176042B CN105176042B (zh) | 2017-03-29 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106273570A (zh) * | 2016-08-30 | 2017-01-04 | 东兴华鸿光学科技有限公司 | 树脂镜片的生产工艺 |
CN106842612A (zh) * | 2016-12-28 | 2017-06-13 | 江苏康耐特光学有限公司 | 一种双光树脂镜片及其制备方法 |
CN108148390A (zh) * | 2017-12-23 | 2018-06-12 | 洛阳名力科技开发有限公司 | 树脂眼镜片 |
CN108164670A (zh) * | 2017-12-05 | 2018-06-15 | 杏晖光学(厦门)有限公司 | 一种抗冲击镜片及其制备方法 |
CN108752536A (zh) * | 2018-04-12 | 2018-11-06 | 安徽皖东树脂科技有限公司 | 防雾树脂镜片及其制备方法 |
CN110105737A (zh) * | 2019-03-27 | 2019-08-09 | 宁波燕翔教育投资管理有限公司 | 一种高硬度防雾树脂镜片的制备方法 |
CN115926414A (zh) * | 2022-12-09 | 2023-04-07 | 视悦光学有限公司 | 一种抗老化防雾树脂镜片材料 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101516999A (zh) * | 2006-12-06 | 2009-08-26 | 帝人化成株式会社 | 眼镜镜片 |
CN102047171A (zh) * | 2008-05-28 | 2011-05-04 | 帝人化成株式会社 | 眼镜透镜 |
CN102405258A (zh) * | 2009-04-20 | 2012-04-04 | 三菱瓦斯化学株式会社 | 聚碳酸酯树脂组合物、使用其的成形品的制造方法及光学透镜 |
CN104497547A (zh) * | 2014-11-28 | 2015-04-08 | 李国金 | 一种高韧性耐冲击树脂镜片及其制备方法 |
-
2015
- 2015-10-11 CN CN201510662071.2A patent/CN105176042B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101516999A (zh) * | 2006-12-06 | 2009-08-26 | 帝人化成株式会社 | 眼镜镜片 |
CN102047171A (zh) * | 2008-05-28 | 2011-05-04 | 帝人化成株式会社 | 眼镜透镜 |
CN102405258A (zh) * | 2009-04-20 | 2012-04-04 | 三菱瓦斯化学株式会社 | 聚碳酸酯树脂组合物、使用其的成形品的制造方法及光学透镜 |
CN104497547A (zh) * | 2014-11-28 | 2015-04-08 | 李国金 | 一种高韧性耐冲击树脂镜片及其制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106273570A (zh) * | 2016-08-30 | 2017-01-04 | 东兴华鸿光学科技有限公司 | 树脂镜片的生产工艺 |
CN106842612A (zh) * | 2016-12-28 | 2017-06-13 | 江苏康耐特光学有限公司 | 一种双光树脂镜片及其制备方法 |
CN106842612B (zh) * | 2016-12-28 | 2019-03-05 | 江苏康耐特光学有限公司 | 一种双光树脂镜片及其制备方法 |
CN108164670A (zh) * | 2017-12-05 | 2018-06-15 | 杏晖光学(厦门)有限公司 | 一种抗冲击镜片及其制备方法 |
CN108148390A (zh) * | 2017-12-23 | 2018-06-12 | 洛阳名力科技开发有限公司 | 树脂眼镜片 |
CN108752536A (zh) * | 2018-04-12 | 2018-11-06 | 安徽皖东树脂科技有限公司 | 防雾树脂镜片及其制备方法 |
CN110105737A (zh) * | 2019-03-27 | 2019-08-09 | 宁波燕翔教育投资管理有限公司 | 一种高硬度防雾树脂镜片的制备方法 |
CN115926414A (zh) * | 2022-12-09 | 2023-04-07 | 视悦光学有限公司 | 一种抗老化防雾树脂镜片材料 |
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CN105176042B (zh) | 2017-03-29 |
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C06 | Publication | ||
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GR01 | Patent grant | ||
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Resin lens with good fog resistance and preparation method thereof Effective date of registration: 20191101 Granted publication date: 20170329 Pledgee: Zhejiang Ruian Rural Commercial Bank Co., Ltd. Jiangnan Branch of Science and Technology Pledgor: ZHEJIANG FANGSHI GLASSES MANUFACTURING CO., LTD. Registration number: Y2019990000450 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20201120 Granted publication date: 20170329 Pledgee: Zhejiang Ruian Rural Commercial Bank Co.,Ltd. Jiangnan Branch of Science and Technology Pledgor: ZHEJIANG FANGSHI GLASSES MANUFACTURING Co.,Ltd. Registration number: Y2019990000450 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A resin lens with good antifogging property and its preparation method Effective date of registration: 20201207 Granted publication date: 20170329 Pledgee: Zhejiang Ruian Rural Commercial Bank Co.,Ltd. Jiangnan Branch of Science and Technology Pledgor: ZHEJIANG FANGSHI GLASSES MANUFACTURING Co.,Ltd. Registration number: Y2020980008848 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211126 Granted publication date: 20170329 Pledgee: Zhejiang Ruian Rural Commercial Bank Co.,Ltd. Jiangnan Branch of Science and Technology Pledgor: ZHEJIANG FANGSHI GLASSES MANUFACTURING Co.,Ltd. Registration number: Y2020980008848 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a resin lens with good antifogging property and a preparation method thereof Effective date of registration: 20211126 Granted publication date: 20170329 Pledgee: Zhejiang Ruian Rural Commercial Bank Co., Ltd. Mayu sub branch Pledgor: ZHEJIANG FANGSHI GLASSES MANUFACTURING Co.,Ltd. Registration number: Y2021990001141 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |